CH492752A - Wärmestabilisierte Polyamidmasse - Google Patents
Wärmestabilisierte PolyamidmasseInfo
- Publication number
- CH492752A CH492752A CH92267A CH92267A CH492752A CH 492752 A CH492752 A CH 492752A CH 92267 A CH92267 A CH 92267A CH 92267 A CH92267 A CH 92267A CH 492752 A CH492752 A CH 492752A
- Authority
- CH
- Switzerland
- Prior art keywords
- polyamide
- copper
- polyamides
- compound
- halogen
- Prior art date
Links
- 239000004952 Polyamide Substances 0.000 title claims abstract description 32
- 229920002647 polyamide Polymers 0.000 title claims abstract description 32
- 239000005749 Copper compound Substances 0.000 title claims description 9
- 150000001880 copper compounds Chemical class 0.000 title claims description 9
- 150000001875 compounds Chemical class 0.000 claims abstract description 14
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 8
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000460 chlorine Substances 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 12
- 229910052736 halogen Inorganic materials 0.000 claims description 9
- 150000002367 halogens Chemical class 0.000 claims description 9
- -1 Copper (I) compound Chemical class 0.000 claims description 8
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 4
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 4
- 229910052794 bromium Inorganic materials 0.000 claims description 4
- 229910052801 chlorine Inorganic materials 0.000 claims description 4
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 4
- 239000011630 iodine Chemical group 0.000 claims description 4
- 229910052740 iodine Inorganic materials 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 3
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 3
- 239000012760 heat stabilizer Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 2
- XZXYQEHISUMZAT-UHFFFAOYSA-N 2-[(2-hydroxy-5-methylphenyl)methyl]-4-methylphenol Chemical class CC1=CC=C(O)C(CC=2C(=CC=C(C)C=2)O)=C1 XZXYQEHISUMZAT-UHFFFAOYSA-N 0.000 claims 2
- 150000001340 alkali metals Chemical class 0.000 claims 2
- 229940107816 ammonium iodide Drugs 0.000 claims 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 1
- 229910052783 alkali metal Inorganic materials 0.000 claims 1
- 229910001516 alkali metal iodide Inorganic materials 0.000 claims 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims 1
- 229910001619 alkaline earth metal iodide Inorganic materials 0.000 claims 1
- 150000001342 alkaline earth metals Chemical class 0.000 claims 1
- 125000001246 bromo group Chemical group Br* 0.000 claims 1
- 230000005540 biological transmission Effects 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 230000003019 stabilising effect Effects 0.000 abstract 1
- 239000010949 copper Substances 0.000 description 18
- 239000003381 stabilizer Substances 0.000 description 12
- 150000001879 copper Chemical class 0.000 description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 5
- 238000007792 addition Methods 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 4
- 238000002845 discoloration Methods 0.000 description 4
- 150000002989 phenols Chemical class 0.000 description 4
- UGXAIVCNTXGYSA-UHFFFAOYSA-N 2,2,2-trichloroethyl dihydrogen phosphite Chemical compound OP(O)OCC(Cl)(Cl)Cl UGXAIVCNTXGYSA-UHFFFAOYSA-N 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 150000007522 mineralic acids Chemical class 0.000 description 3
- 150000007524 organic acids Chemical class 0.000 description 3
- 235000005985 organic acids Nutrition 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 150000003018 phosphorus compounds Chemical class 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 229910021589 Copper(I) bromide Inorganic materials 0.000 description 2
- 229910021591 Copper(I) chloride Inorganic materials 0.000 description 2
- 229910021595 Copper(I) iodide Inorganic materials 0.000 description 2
- 229920002292 Nylon 6 Polymers 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 150000004982 aromatic amines Chemical class 0.000 description 2
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 description 2
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 2
- OPQARKPSCNTWTJ-UHFFFAOYSA-L copper(ii) acetate Chemical compound [Cu+2].CC([O-])=O.CC([O-])=O OPQARKPSCNTWTJ-UHFFFAOYSA-L 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 description 2
- 150000003951 lactams Chemical class 0.000 description 2
- RLSSMJSEOOYNOY-UHFFFAOYSA-N m-cresol Chemical compound CC1=CC=CC(O)=C1 RLSSMJSEOOYNOY-UHFFFAOYSA-N 0.000 description 2
- 150000002696 manganese Chemical class 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- ZSOMTXWIPDPHLT-UHFFFAOYSA-N 2,2,2-tribromoethyl dihydrogen phosphite Chemical compound OP(O)OCC(Br)(Br)Br ZSOMTXWIPDPHLT-UHFFFAOYSA-N 0.000 description 1
- WUPHOULIZUERAE-UHFFFAOYSA-N 3-(oxolan-2-yl)propanoic acid Chemical compound OC(=O)CCC1CCCO1 WUPHOULIZUERAE-UHFFFAOYSA-N 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical class NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
- 229910021592 Copper(II) chloride Inorganic materials 0.000 description 1
- VMQMZMRVKUZKQL-UHFFFAOYSA-N Cu+ Chemical compound [Cu+] VMQMZMRVKUZKQL-UHFFFAOYSA-N 0.000 description 1
- 241000530268 Lycaena heteronea Species 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910001508 alkali metal halide Inorganic materials 0.000 description 1
- 150000008045 alkali metal halides Chemical class 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- UKFWSNCTAHXBQN-UHFFFAOYSA-N ammonium iodide Chemical class [NH4+].[I-] UKFWSNCTAHXBQN-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052980 cadmium sulfide Inorganic materials 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- NKNDPYCGAZPOFS-UHFFFAOYSA-M copper(i) bromide Chemical compound Br[Cu] NKNDPYCGAZPOFS-UHFFFAOYSA-M 0.000 description 1
- DOBRDRYODQBAMW-UHFFFAOYSA-N copper(i) cyanide Chemical compound [Cu+].N#[C-] DOBRDRYODQBAMW-UHFFFAOYSA-N 0.000 description 1
- LSXDOTMGLUJQCM-UHFFFAOYSA-M copper(i) iodide Chemical compound I[Cu] LSXDOTMGLUJQCM-UHFFFAOYSA-M 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- PYFRLDVYGBCYLI-UHFFFAOYSA-N decyl dihydrogen phosphite Chemical compound CCCCCCCCCCOP(O)O PYFRLDVYGBCYLI-UHFFFAOYSA-N 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- JZPCVNQVJCFHOZ-UHFFFAOYSA-N dichloro ethyl phosphite Chemical compound CCOP(OCl)OCl JZPCVNQVJCFHOZ-UHFFFAOYSA-N 0.000 description 1
- XMQYIPNJVLNWOE-UHFFFAOYSA-N dioctyl hydrogen phosphite Chemical compound CCCCCCCCOP(O)OCCCCCCCC XMQYIPNJVLNWOE-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 150000004694 iodide salts Chemical class 0.000 description 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
- 150000002497 iodine compounds Chemical class 0.000 description 1
- 150000004715 keto acids Chemical class 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000004792 oxidative damage Effects 0.000 description 1
- 150000003003 phosphines Chemical class 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
- QQBLOZGVRHAYGT-UHFFFAOYSA-N tris-decyl phosphite Chemical compound CCCCCCCCCCOP(OCCCCCCCCCC)OCCCCCCCCCC QQBLOZGVRHAYGT-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/524—Esters of phosphorous acids, e.g. of H3PO3
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEF48630A DE1259094B (de) | 1966-03-10 | 1966-03-10 | Stabilisierung von Polyamiden |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH492752A true CH492752A (de) | 1970-06-30 |
Family
ID=7102372
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH92267A CH492752A (de) | 1966-03-10 | 1967-01-23 | Wärmestabilisierte Polyamidmasse |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US3507833A (en:Method) |
| BE (1) | BE695196A (en:Method) |
| CH (1) | CH492752A (en:Method) |
| DE (1) | DE1259094B (en:Method) |
| DK (1) | DK116245B (en:Method) |
| FR (1) | FR1516468A (en:Method) |
| GB (1) | GB1141423A (en:Method) |
| NL (1) | NL6703580A (en:Method) |
| SE (1) | SE326833B (en:Method) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2220992C2 (ru) * | 1998-10-15 | 2004-01-10 | Л.Брюггеманн Кг | Полиамидная композиция, стабилизированная с помощью комплексов меди и органических галоидных соединений, стабилизатор и способ получения композиции |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2837027A1 (de) * | 1978-08-24 | 1980-03-06 | Bayer Ag | Neue phosphorigsaeureester und ihre verwendung zur stabilisierung von polyamiden |
| JPH02212533A (ja) * | 1989-02-10 | 1990-08-23 | Tonen Sekiyukagaku Kk | ポリマー組成物 |
| US5216054A (en) * | 1989-02-10 | 1993-06-01 | Tonen Sekiyukagaku Kabushiki Kaisha | Polymer composition |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR906893A (fr) * | 1943-01-09 | 1946-02-22 | Ig Farbenindustrie Ag | Procédé pour empêcher des polymères linéaires contenant des groupes amides dans leur chaîne de devenir cassants |
| US2705227A (en) * | 1954-03-15 | 1955-03-29 | Du Pont | Heat stabilization of polyamides |
| US2996466A (en) * | 1956-01-07 | 1961-08-15 | Onderzoekings Inst Res | Process for preparing extruded high molecular weight substances and the resulting products |
| FR84140A (en:Method) * | 1958-07-18 | |||
| US3248597A (en) * | 1962-02-16 | 1966-04-26 | Gen Electric | Multiple-beam klystron apparatus with periodic alternate capacitance loaded waveguide |
-
1966
- 1966-03-10 DE DEF48630A patent/DE1259094B/de active Pending
-
1967
- 1967-01-23 CH CH92267A patent/CH492752A/de not_active IP Right Cessation
- 1967-02-06 GB GB5564/67A patent/GB1141423A/en not_active Expired
- 1967-03-03 US US620249A patent/US3507833A/en not_active Expired - Lifetime
- 1967-03-07 NL NL6703580A patent/NL6703580A/xx unknown
- 1967-03-08 BE BE695196D patent/BE695196A/xx unknown
- 1967-03-08 FR FR97899A patent/FR1516468A/fr not_active Expired
- 1967-03-09 SE SE03293/67A patent/SE326833B/xx unknown
- 1967-03-09 DK DK124267AA patent/DK116245B/da unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2220992C2 (ru) * | 1998-10-15 | 2004-01-10 | Л.Брюггеманн Кг | Полиамидная композиция, стабилизированная с помощью комплексов меди и органических галоидных соединений, стабилизатор и способ получения композиции |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1259094B (de) | 1968-01-18 |
| BE695196A (en:Method) | 1967-08-14 |
| SE326833B (en:Method) | 1970-08-03 |
| FR1516468A (fr) | 1968-03-08 |
| US3507833A (en) | 1970-04-21 |
| NL6703580A (en:Method) | 1967-09-11 |
| GB1141423A (en) | 1969-01-29 |
| DK116245B (da) | 1969-12-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PL | Patent ceased |