CH265759A - Process for the preparation of a new mercury compound. - Google Patents

Process for the preparation of a new mercury compound.

Info

Publication number
CH265759A
CH265759A CH265759DA CH265759A CH 265759 A CH265759 A CH 265759A CH 265759D A CH265759D A CH 265759DA CH 265759 A CH265759 A CH 265759A
Authority
CH
Switzerland
Prior art keywords
mercury compound
preparation
new mercury
parts
volume
Prior art date
Application number
Other languages
German (de)
Inventor
Aktiengesellschaft Ciba
Original Assignee
Ciba Geigy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Geigy filed Critical Ciba Geigy
Publication of CH265759A publication Critical patent/CH265759A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic System
    • C07F3/10—Mercury compounds

Description

  

  Verfahren zur Herstellung einer neuen Quecksilberverbindung.    Gegenstand des vorliegenden Patentes ist  ein Verfahren zur Herstellung einer neuen  Quecksilberverbindung, das dadurch gekenn  zeichnet ist, dass man     n-Propylmercurithio-          :ithyl-dimethylamin    mit     Dimethylsulfat    um  setzt.  



  Das so erhaltene n -     Propylmercurithio-          äthyl-trimethylammonium-methosulfat    ist .ein  gelbliches, in Wasser lösliches Öl und soll als  Desinfektionsmittel Verwendung finden.  



       Beispiel:     3,25 Teile eines Gemisches von     n-Propyl-          quecksilberchlorid    werden in 30     Vol.-Teilen     Alkohol suspendiert und nach Zusatz von  1     Vol.-Teil        10n-Natronlauge    20 Minuten lang  gekocht.

   Es wird kalt filtriert und das     Filtrat     zu einer Lösung von     Dimethylaminoäthyl-          mercaptan    gegeben, die durch Umsatz von 1,5  Teilen     Dimethylaminoäthylmercaptan-hy        dro-          ehlorid    in 15     Vol.-Teilen    Alkohol unter Zu  satz von 1     Vol.-Teil        10n-Natronlauge    und Fil  trieren in der Kälte bereitet wird. Diese Lö  sung kocht man eine Stunde lang am Rück-         fluss,    destilliert den Alkohol ab und nimmt  den Rückstand in Äther auf.

   Nach dem Ab  destillieren des Äthers     hinterbleiben    2,4 Teile  des     n-Propylmercurithioäthyl-dimethylamins.     



  2,4 Teile dieser Quecksilberverbindung  wurden in 8     Vol.-Teilen        abs.    Alkohol aufge  nommen, mit 0,7     Vol.-Teilen        Dimethylsulfat     versetzt und der Alkohol nach der erfolgten  Reaktion auf dem Wasserbade     abdestilliert.     Der Rückstand wird mit Äther behandelt. Es       hinterbleibt    das in Wasser lösliche     n-Propyl-          mercurithioäthyl    -     trimethy        lammonium-metho-          sulfat    als gelbliches öl.



  Process for the preparation of a new mercury compound. The subject of the present patent is a process for the production of a new mercury compound, which is characterized in that n-propylmercurithio-: ithyl-dimethylamine is implemented with dimethyl sulfate.



  The n-propylmercurithioethyl trimethylammonium methosulfate obtained in this way is a yellowish oil which is soluble in water and is intended to be used as a disinfectant.



       Example: 3.25 parts of a mixture of n-propyl mercury chloride are suspended in 30 parts by volume of alcohol and, after addition of 1 part by volume of 10N sodium hydroxide solution, boiled for 20 minutes.

   It is filtered cold and the filtrate is added to a solution of dimethylaminoethyl mercaptan, which is obtained by reacting 1.5 parts of dimethylaminoethyl mercaptan hydrochloride in 15 parts by volume of alcohol with the addition of 1 part by volume of 10N sodium hydroxide solution and Fil trieres in the cold is prepared. This solution is refluxed for one hour, the alcohol is distilled off and the residue is taken up in ether.

   After distilling off the ether, 2.4 parts of n-propylmercurithioethyl-dimethylamine remain.



  2.4 parts of this mercury compound were abs in 8 parts by volume. Alcohol taken up, treated with 0.7 parts by volume of dimethyl sulfate and the alcohol was distilled off after the reaction on the water bath. The residue is treated with ether. The water-soluble n-propyl mercurithioethyl trimethylammonium methosulfate remains as a yellowish oil.

Claims (1)

PATENTANSPRUCH: Verfahren zur Herstellung einer neuen Quecksilberverbindung, dadurch gekennzeich net, da.ss man n-Propylmercurithioäthyl-dime- thylamin mit Dimethylsul.fat umsetzt. Das so erhaltene n-Propy lm.ercurithioäthyl- trimethylammonium-methosulfat ist ein gelb liches, in Wasser lösliches Öl und soll als Des infektionsmittel Verwendung finden. PATENT CLAIM: Process for the production of a new mercury compound, characterized in that n-propylmercurithioethyl-dimethylamine is reacted with dimethylsul.fat. The n-Propy lm.ercurithioäthyltrimethylammonium methosulphate obtained is a yellowish, water-soluble oil and should be used as a disinfectant.
CH265759D 1944-08-04 1944-08-04 Process for the preparation of a new mercury compound. CH265759A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH257579T 1944-08-04
CH265759T 1944-08-04

Publications (1)

Publication Number Publication Date
CH265759A true CH265759A (en) 1949-12-15

Family

ID=25730084

Family Applications (1)

Application Number Title Priority Date Filing Date
CH265759D CH265759A (en) 1944-08-04 1944-08-04 Process for the preparation of a new mercury compound.

Country Status (1)

Country Link
CH (1) CH265759A (en)

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