CH143287A - Process for the preparation of a cyclammonium compound. - Google Patents

Process for the preparation of a cyclammonium compound.

Info

Publication number
CH143287A
CH143287A CH143287DA CH143287A CH 143287 A CH143287 A CH 143287A CH 143287D A CH143287D A CH 143287DA CH 143287 A CH143287 A CH 143287A
Authority
CH
Switzerland
Prior art keywords
cyclammonium
compound
formula
preparation
product
Prior art date
Application number
Other languages
German (de)
Inventor
Gesellschaft Fuer Chemis Basel
Original Assignee
Chem Ind Basel
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chem Ind Basel filed Critical Chem Ind Basel
Publication of CH143287A publication Critical patent/CH143287A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
    • C07D209/04—Indoles; Hydrogenated indoles
    • C07D209/08—Indoles; Hydrogenated indoles with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to carbon atoms of the hetero ring
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B23/00—Methine or polymethine dyes, e.g. cyanine dyes
    • C09B23/02—Methine or polymethine dyes, e.g. cyanine dyes the polymethine chain containing an odd number of >CH- or >C[alkyl]- groups
    • C09B23/06—Methine or polymethine dyes, e.g. cyanine dyes the polymethine chain containing an odd number of >CH- or >C[alkyl]- groups three >CH- groups, e.g. carbocyanines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Description

  

      Zimsatzpatent    zum Hauptpatent Nr.     141551.       Es wurde befunden, dass man eine       Cyclammoniumverbindung    erhalten kann.  wenn man das Produkt der Formel  
EMI0001.0004     
    in nicht alkalischem Medium mit     Chinonen     oxydiert und auf das gebildete Additions  produkt mit dem ebenfalls entstandenen       Hydrochinon    Alkalien einwirken lässt.  



  Die hierbei ausgeschiedene     Cyclammo-          'niumverbindung    stellt ein in Wasser schwer  lösliches, gelbbraunes     Pulver    dar. Dieses  bildet durch     Behandlung    mit Säuren Salze  der Formel  
EMI0001.0011     
    die tannierte Baumwolle in rotvioletten Tö  nen färben.  



       Beispiel:     427 Teile des Produktes der Formel  
EMI0001.0013     
    werden in 2200 Teilen Benzol gelöst; und       portionenweise    innert einer Stunde mit 75  Teilen Eisessig und 1390 Teilen     Chinon-          lösung        (10,7%        Vol.        Chi.non    in Benzol) ver  setzt. Zur Vervollständigung der Reaktion  wird 15 bis 20 Stunden bei gewöhnlicher  Temperatur gerührt und hierauf von den ab  geschiedenen metallglänzenden Kristallen ab  filtriert.

   Die Untersuchung des erhaltenen  Produktes lässt vermuten, dass ein Addi  tionsprodukt von     Hy        drochinon    an das  1 . 3 . 3 . 1'. 3' .     3'-Hexa.metliyl-5    . 5'-dichlor-      9.     \?'-sirepl < @nionoviny        1 < >nindoeyaniance.tal:    vor  liegt. Der Körper löst sich leicht in heissem  Wasser. Beim     Versetzen    der wässerigen  Lösung mit verdünnter Natronlauge fällt die       Cvclammoniumverbindung    aus.



      Cinnamon patent for main patent No. 141551. It has been found that a cyclammonium compound can be obtained. when you get the product of the formula
EMI0001.0004
    oxidized with quinones in a non-alkaline medium and allowed to act on the addition product formed with the hydroquinone alkalis that were also formed.



  The cyclammonium compound precipitated in the process is a yellow-brown powder that is sparingly soluble in water. This forms salts of the formula on treatment with acids
EMI0001.0011
    dye the tannic cotton in red-violet tones.



       Example: 427 parts of the product of the formula
EMI0001.0013
    are dissolved in 2200 parts of benzene; and add 75 parts of glacial acetic acid and 1390 parts of quinone solution (10.7% vol. Chi.non in benzene) in portions within one hour. To complete the reaction, the mixture is stirred for 15 to 20 hours at ordinary temperature and then filtered off from the separated shiny metal crystals.

   Examination of the product obtained suggests that an addition product of hydroquinone to the 1st 3. 3. 1'. 3 '. 3'-hexa.metliyl-5. 5'-dichloro- 9. \? '- sirepl <@nionoviny 1 <> nindoeyaniance.tal: is available. The body dissolves easily in hot water. When the aqueous solution is mixed with dilute sodium hydroxide solution, the ammonium compound precipitates.

Claims (1)

PATENTANSPRUCH: Verfahren zur Herstellung einer Cyclam- moniumverbindung. dadurch gekennzeichnet. dass man das Produkt der Formel EMI0002.0007 in nicht alkalischem Medium mit Chinonen oxydiert und auf das gebildete Additions- produkt mit dent ebenfalls entstandenen Hydrochinon Alkalien einwirken lässt. PATENT CLAIM: Process for the production of a cyclammonium compound. characterized. that you get the product of the formula EMI0002.0007 oxidized with quinones in a non-alkaline medium and allowed to act on the addition product formed with the hydroquinone alkalis which have also formed. Die hierbei ausgeschiedene Cy clammo- niumverbindung stellt ein in Wasser schwer lösliches, gelbbraiilles Pulver dar. Dieses bildet durch Behandlung mit Säuren Salze der Formel EMI0002.0020 die tannierte Baumwolle in rotvioletten Tönen färben. The cyclammonium compound separated out is a yellow-brown powder which is sparingly soluble in water. This forms salts of the formula on treatment with acids EMI0002.0020 dye the tannic cotton in red-violet tones.
CH143287D 1928-06-21 1928-06-21 Process for the preparation of a cyclammonium compound. CH143287A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH143287T 1928-06-21
CH141551T 1928-06-21

Publications (1)

Publication Number Publication Date
CH143287A true CH143287A (en) 1930-10-31

Family

ID=25713892

Family Applications (1)

Application Number Title Priority Date Filing Date
CH143287D CH143287A (en) 1928-06-21 1928-06-21 Process for the preparation of a cyclammonium compound.

Country Status (1)

Country Link
CH (1) CH143287A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11572475B2 (en) 2011-07-18 2023-02-07 Georgia State University Research Foundation, Inc. Carbocyanines for G-quadruplex DNA stabilization and telomerase inhibition

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11572475B2 (en) 2011-07-18 2023-02-07 Georgia State University Research Foundation, Inc. Carbocyanines for G-quadruplex DNA stabilization and telomerase inhibition

Similar Documents

Publication Publication Date Title
CH143287A (en) Process for the preparation of a cyclammonium compound.
CH143288A (en) Process for the preparation of a cyclammonium compound.
CH143286A (en) Process for the preparation of a cyclammonium compound.
CH143289A (en) Process for the preparation of a cyclammonium compound.
CH143291A (en) Process for the preparation of a cyclammonium compound.
CH143290A (en) Process for the preparation of a cyclammonium compound.
CH143292A (en) Process for the preparation of a cyclammonium compound.
DE557246C (en) Process for the preparation of sulfoanthracene carboxylic acids
DE1111144B (en) Post-treatment agent for direct dyeing
DE565177C (en) Process for the production of acidic wool dyes of the anthraquinone series
AT88646B (en) Process for the production of tanning substances.
CH141551A (en) Process for the preparation of a cyclammonium compound.
CH170453A (en) Process for the production of a new wool dye of the anthraquinone series.
AT107857B (en) Process for the preparation of quinine salts of oxyphenylarsinic acids.
AT112126B (en) Process for the preparation of derivatives of cyclic aminometal mercapto compounds.
AT216004B (en) Process for the preparation of the new N- (4-sulfonamidophenyl) -butanesultam
DE723790C (en) Process for the production of water-soluble compounds of 4-aminobenzene sulfonamides
CH265758A (en) Process for the preparation of a new mercury compound.
CH265759A (en) Process for the preparation of a new mercury compound.
CH174910A (en) Process for the preparation of the salt of 2,3-dimethoxy-6-nitro-9- (ydiäthylamino-B-oxy-propylamino) -acridine with 2-methyl-4-glycolylaminobenzene-1-arsic acid.
CH140407A (en) Process for the preparation of oxythionaphtenes from cyanaryl-o-thioglycolic acids.
CH117894A (en) Process for the preparation of the symmetrical urea of p-oxy-m-aminophenylarsinic acid.
CH125395A (en) Process for the preparation of diphenetylisatin.
DE1108703B (en) Process for the preparation of mercapto fatty acid hydrazides
CH293018A (en) Process for the preparation of a thiosemicarbazone of a heterocyclic aldehyde.