CH143290A - Process for the preparation of a cyclammonium compound. - Google Patents

Process for the preparation of a cyclammonium compound.

Info

Publication number
CH143290A
CH143290A CH143290DA CH143290A CH 143290 A CH143290 A CH 143290A CH 143290D A CH143290D A CH 143290DA CH 143290 A CH143290 A CH 143290A
Authority
CH
Switzerland
Prior art keywords
compound
formula
cyclammonium
preparation
product
Prior art date
Application number
Other languages
German (de)
Inventor
Gesellschaft Fuer Chemis Basel
Original Assignee
Chem Ind Basel
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chem Ind Basel filed Critical Chem Ind Basel
Publication of CH143290A publication Critical patent/CH143290A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
    • C07D209/04—Indoles; Hydrogenated indoles
    • C07D209/08—Indoles; Hydrogenated indoles with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to carbon atoms of the hetero ring
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B23/00—Methine or polymethine dyes, e.g. cyanine dyes
    • C09B23/02—Methine or polymethine dyes, e.g. cyanine dyes the polymethine chain containing an odd number of >CH- or >C[alkyl]- groups
    • C09B23/06—Methine or polymethine dyes, e.g. cyanine dyes the polymethine chain containing an odd number of >CH- or >C[alkyl]- groups three >CH- groups, e.g. carbocyanines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Description

  

      Yerfalireii    für     lierstellutig    einer     Cyclainnioniiunverbüidung.       Es wurde gefunden, dass man eine       Cyclammoniumverbindung    erhalten kann,  wenn man das Produkt der Formel  
EMI0001.0005     
    in nicht alkalischem Medium mit     Uhinonen          oxydiert    und auf das gebildete     Additions-          produkt    mit. dem ebenfalls entstandenen       I-Ivdroeliinon        Alkalien    einwirken     lässt.     



  . Die     hierbei < uisgeschiecleneCyclainmoniuni-          verbindung    stellt ein in Wasser schwer  lösliches, braunes     Pulver    dar. Dieses bildet       dni-cli    Behandlung mit Säuren Salze der       Formel     
EMI0001.0018     
    die tannierte Baumwolle in     blauvioletten     Tönen färben.  



  <I>Beispiel:</I>  448 Teile des Produktes der     Formel     
EMI0001.0021     
         werden    in 4000     'Geilen    Benzol gelöst     bezw.          suspendiert    und unter     Rühren   <B>66,6</B> Teile Eis  essig und 122 Teile     Chinon    innert ein bis  zwei Stunden bei 30 bis 85       zugefügt.     Hierauf wird 15 bis 20 Stunden bei ge  wöhnlicher     Tempera.tür    weiter gerührt     un < 1     hierauf von den     abgeschiedenen        metallglän-          z(-,

  iiden    Kristallen     abfiltriert.    Die     Unter-          suchung    des erhaltenen     Produktes        lässt    ver  muten,     class    ein Additionsprodukt von     Hydro-          chinon        in    das 1 . 3 . 3 .     L'    . 3' . 3' -     Hexa-          niethyl    - 5 . 5' -     dinitro    - 2 . 2' - streptomono-           vil'iylenindoey        aninacetat    vorliegt. Der Kör  per löst sich leicht in heissem Wasser.

   Beim  Versetzen der wässerigen Lösung mit ver  dünnter Natronlauge fällt die     Cyelammo-          niumverbindung    aus.



      Yerfalireii for one digit of a Cyclainnioniiunverbünung. It has been found that a cyclammonium compound can be obtained by using the product of the formula
EMI0001.0005
    oxidized in a non-alkaline medium with uhinones and on the addition product formed with. the also created I-Ivdroeliinon alkalis can act.



  . The cyclainmonium compound described here is a brown powder which is sparingly soluble in water. This forms salts of the formula when treated with acids
EMI0001.0018
    dye the tannic cotton in blue-violet tones.



  <I> Example: </I> 448 parts of the product of the formula
EMI0001.0021
         are dissolved in 4000 'Geile benzene respectively. suspended and with stirring <B> 66.6 </B> parts of glacial vinegar and 122 parts of quinone within one to two hours at 30 to 85 added. Stirring is then continued for 15 to 20 hours at the usual temperature, and the metallic luster (-,

  iiden crystals filtered off. Examination of the product obtained suggests that an addition product of hydroquinone in the 1. 3. 3. L '. 3 '. 3 '- hexaniethyl - 5. 5 '- dinitro - 2nd 2 '- streptomonovil'iylenindoey aninacetat is present. The body dissolves easily in hot water.

   When the aqueous solution is mixed with dilute sodium hydroxide solution, the cyelammonium compound precipitates.

Claims (1)

PATENTANSPRUCH: Verfahren zur Herstellung einer Cyclain- nioniumverbindung, dadurch gekennzeichnet. dass man das Produkt der Formel EMI0002.0008 in nicht alkalischem 141.ediuni mit Chinonen oxydiert und auf das gebildete Additions- Produkt mit dem ebenfalls entstandenen Hydroeliinon Alkalien einwirken lässt. Die hierbei ausgeschiedeneCyelammoniuin- verbindung stellt ein in Wasser schwer lösliches, braunes Pulver dar. PATENT CLAIM: Process for the production of a Cyclain- nioniumverbindungen, characterized. that you get the product of the formula EMI0002.0008 is oxidized in non-alkaline 141.ediuni with quinones and allowed to act on the addition product formed with the hydroeliinone also formed. The cyelammoniuin compound excreted in this way is a brown powder that is poorly soluble in water. Dieses bildet durch Behandlung mit Säuren Salze der Formel EMI0002.0015 die tannierte Baumwolle in blauvioletten Tönen färben. This forms salts of the formula when treated with acids EMI0002.0015 dye the tannic cotton in blue-violet tones.
CH143290D 1928-06-21 1928-06-21 Process for the preparation of a cyclammonium compound. CH143290A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH143290T 1928-06-21
CH141551T 1928-06-21

Publications (1)

Publication Number Publication Date
CH143290A true CH143290A (en) 1930-10-31

Family

ID=25713895

Family Applications (1)

Application Number Title Priority Date Filing Date
CH143290D CH143290A (en) 1928-06-21 1928-06-21 Process for the preparation of a cyclammonium compound.

Country Status (1)

Country Link
CH (1) CH143290A (en)

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