CH224877A - Process for the preparation of a new, water-soluble dye of the anthraquinone series. - Google Patents

Process for the preparation of a new, water-soluble dye of the anthraquinone series.

Info

Publication number
CH224877A
CH224877A CH224877DA CH224877A CH 224877 A CH224877 A CH 224877A CH 224877D A CH224877D A CH 224877DA CH 224877 A CH224877 A CH 224877A
Authority
CH
Switzerland
Prior art keywords
water
new
preparation
soluble dye
anthraquinone series
Prior art date
Application number
Other languages
German (de)
Inventor
Sandoz A G
Original Assignee
Sandoz Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sandoz Ag filed Critical Sandoz Ag
Publication of CH224877A publication Critical patent/CH224877A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B1/00—Dyes with anthracene nucleus not condensed with any other ring
    • C09B1/16—Amino-anthraquinones
    • C09B1/20—Preparation from starting materials already containing the anthracene nucleus
    • C09B1/26—Dyes with amino groups substituted by hydrocarbon radicals
    • C09B1/32—Dyes with amino groups substituted by hydrocarbon radicals substituted by aryl groups
    • C09B1/34—Dyes with amino groups substituted by hydrocarbon radicals substituted by aryl groups sulfonated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Coloring (AREA)

Description

  

  Verfahren zur Darstellung eines neuen, wasserlöslichen Farbstoffes  der     Anthr        achinonr        eihe.       Das vorliegende Patent betrifft ein Ver  fahren zur Darstellung eines neuen, wasserlös  lichen     Anthrachinonfarbstoffes    und ist dadurch  gekennzeichnet, dass man 1     Mol        1-Amino-          4-phenylaminoanthrachinon,    1     Mol    Phenol und  1     Mol    Formaldehyd aufeinander einwirken  lässt und das erhaltene Produkt sulfoniert.  



  Der neue     Farbstoff    enthält eine     Sulfogruppe     und löst sich in konzentrierter Schwefelsäure  mit schwach grünblauer, in Wasser mit grün  stichig blauer Farbe. Er soll zum Färben  von     Acetatseide,        acetylierter    Baumwolle und  von     Acetylzellulosefolien    verwendet werden.  Das Färbegut wird in der wässerigen Lösung       rotstichig    blau gefärbt.  



  <I>Beispiel:</I>  20 kg     1-Amino-4-phenylaminoanthrachinon     und 100 kg Phenol werden bis zur Lösung  erwärmt und auf 401 C abgekühlt. 10 kg       Formaldehydlösung    von 40     Vol.-1/o    werden  langsam eingerührt und nach weiteren zwei  Stunden die Schmelze in     alkalisches    Salz-         wasser    gedrückt. Das ausgefallene Konden  sationsprodukt wird     abfiltriert,    in Wasser auf  genommen und mit Schwefelsäure neutral ge  stellt. Man filtriert, wäscht und     trocknet.     



  Durch     Sulfonieren    bei 200 C in Schwefel  säuremonohydrat erhält man einen Farbstoff,  der sich in     konzentrierter    Schwefelsäure mit  schwach grünblauer, in Wasser mit grün  stichig blauer Farbe löst. Er soll zum Fär  ben von     Acetatseide,        acetylierter    Baumwolle  und von     Acetylzellulosefolien    verwendet wer  den. Das. Färbegut     wird    in der wässerigen  Lösung     rotstichig    blau gefärbt.



  Process for the preparation of a new, water-soluble dye of the anthracinone series. The present patent relates to a process for the preparation of a new, water-soluble anthraquinone dye and is characterized in that 1 mole of 1-amino-4-phenylaminoanthraquinone, 1 mole of phenol and 1 mole of formaldehyde are allowed to interact and the product obtained is sulfonated.



  The new dye contains a sulfo group and dissolves in concentrated sulfuric acid with a pale green-blue color, and in water with a green-tinged blue color. It is said to be used for dyeing acetate silk, acetylated cotton and acetyl cellulose films. The material to be dyed is colored a reddish blue in the aqueous solution.



  <I> Example: </I> 20 kg of 1-amino-4-phenylaminoanthraquinone and 100 kg of phenol are heated until they dissolve and then cooled to 401 ° C. 10 kg of formaldehyde solution of 40 vol. 1 / o are slowly stirred in and, after a further two hours, the melt is pressed into alkaline salt water. The precipitated condensation product is filtered off, taken up in water and neutralized with sulfuric acid. It is filtered, washed and dried.



  By sulfonating at 200 ° C. in sulfuric acid monohydrate, a dye is obtained which dissolves in concentrated sulfuric acid with a pale green-blue color, in water with a green-tinged blue color. It is said to be used for dyeing acetate silk, acetylated cotton and acetyl cellulose sheets. The. The material to be dyed is colored a reddish blue in the aqueous solution.

Claims (1)

PATENTANSPRUCH: Verfahren zur Darstellung eines neuen, wasserlöslichen Farbstoffes der Anthrachinon- reihe, dadurch gekennzeichnet, dass man 1 Dlol 1-Amino-4-phenylaminoanthrachinon, PATENT CLAIM: Process for the preparation of a new, water-soluble dye of the anthraquinone series, characterized in that 1 Dlol of 1-amino-4-phenylaminoanthraquinone, 1 Mol Phenol und 1 Mol Formaldehyd aufeinander einwirken lässt und das erhaltene Produkt sulfoniert. Der neue Farbstoff enthält eine Sulfo- gruppe und löst sich in konzentrierter Schwe felsäure mit schwach grünblauer, in Wasser mit grünetichig blauer Farbe. Er soll zum Färben von Acetatseide, Lets 1 mol of phenol and 1 mol of formaldehyde act on one another and sulfonated the product obtained. The new dye contains a sulfo group and dissolves in concentrated sulfuric acid with a pale green-blue color, in water with a greenish-blue color. It is said to be used for dyeing acetate silk, aeetylierter Baum- wolle und von ,Aeetylzellulosefolien verwen det werden. Das Färbegut wird in der wäs serigen Lösung rotstiohig blau gefärbt. acetylated cotton and acetyl cellulose films can be used. The material to be dyed is colored red in the aqueous solution in blue.
CH224877D 1938-12-19 1939-04-22 Process for the preparation of a new, water-soluble dye of the anthraquinone series. CH224877A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH536303X 1938-12-19
CH224877T 1939-04-22

Publications (1)

Publication Number Publication Date
CH224877A true CH224877A (en) 1942-12-15

Family

ID=25726802

Family Applications (1)

Application Number Title Priority Date Filing Date
CH224877D CH224877A (en) 1938-12-19 1939-04-22 Process for the preparation of a new, water-soluble dye of the anthraquinone series.

Country Status (1)

Country Link
CH (1) CH224877A (en)

Similar Documents

Publication Publication Date Title
CH224877A (en) Process for the preparation of a new, water-soluble dye of the anthraquinone series.
CH224878A (en) Process for the preparation of a new, water-soluble dye of the anthraquinone series.
CH224874A (en) Process for the preparation of a new, water-soluble dye of the anthraquinone series.
CH224876A (en) Process for the preparation of a new, water-soluble dye of the anthraquinone series.
CH224879A (en) Process for the preparation of a new, water-soluble dye of the anthraquinone series.
CH224875A (en) Process for the preparation of a new, water-soluble dye of the anthraquinone series.
AT156582B (en) Process for the preparation of o-oxyazo dyes.
DE673024C (en) Process for the production of azo dyes
CH222155A (en) Process for the preparation of a new dye of the anthraquinone series.
CH224548A (en) Process for the preparation of a new dye of the anthraquinone series.
CH184016A (en) Process for the production of a new anthraquinone dye.
CH191160A (en) Process for the preparation of a new monoazo dye.
CH265737A (en) Process for the preparation of a water-soluble dye of the naphthoquinone series.
CH164430A (en) Process for the production of a new azo dye.
CH224550A (en) Process for the preparation of a new dye of the anthraquinone series.
CH184193A (en) Process for the production of an asymmetrical vat dye of the thioindigo series.
CH207452A (en) Process for the preparation of a condensation product.
CH205072A (en) Process for the preparation of a polymethine dye.
CH265738A (en) Process for the preparation of a water-soluble dye of the naphthoquinone series.
CH222151A (en) Process for the preparation of a new dye of the anthraquinone series.
CH224551A (en) Process for the preparation of a new dye of the anthraquinone series.
CH186744A (en) Process for the production of a new anthraquinone dye.
CH138878A (en) Process for the preparation of a new, nitrogenous vat dye.
CH270743A (en) Process for the preparation of a vivid acid dye of the anthraquinone series.
CH118627A (en) Process for the preparation of a basic dye of the malachite green series.