CH203858A - Process for the production of a valuable highly capillary-active substance. - Google Patents
Process for the production of a valuable highly capillary-active substance.Info
- Publication number
- CH203858A CH203858A CH203858DA CH203858A CH 203858 A CH203858 A CH 203858A CH 203858D A CH203858D A CH 203858DA CH 203858 A CH203858 A CH 203858A
- Authority
- CH
- Switzerland
- Prior art keywords
- propane
- sodium
- acid
- reaction
- chloro
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 9
- 239000013543 active substance Substances 0.000 title claims description 5
- 238000004519 manufacturing process Methods 0.000 title claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 10
- 229910052708 sodium Inorganic materials 0.000 claims description 10
- 239000011734 sodium Substances 0.000 claims description 10
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical class [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 5
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 4
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 4
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 4
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 4
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 4
- 239000005642 Oleic acid Substances 0.000 claims description 4
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 4
- 239000003513 alkali Substances 0.000 claims description 4
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 4
- 239000004571 lime Substances 0.000 claims description 4
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 4
- 150000007513 acids Chemical class 0.000 claims description 3
- 150000001447 alkali salts Chemical class 0.000 claims description 3
- 239000007795 chemical reaction product Substances 0.000 claims description 3
- 238000004140 cleaning Methods 0.000 claims description 3
- 230000001804 emulsifying effect Effects 0.000 claims description 3
- 235000019341 magnesium sulphate Nutrition 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- 238000009736 wetting Methods 0.000 claims description 3
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- DCXXMTOCNZCJGO-UHFFFAOYSA-N Glycerol trioctadecanoate Natural products CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 claims description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 2
- 238000009835 boiling Methods 0.000 claims description 2
- 239000003610 charcoal Substances 0.000 claims description 2
- 238000004042 decolorization Methods 0.000 claims description 2
- 238000004090 dissolution Methods 0.000 claims description 2
- 230000000694 effects Effects 0.000 claims description 2
- 238000005187 foaming Methods 0.000 claims description 2
- 239000000463 material Substances 0.000 claims description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 2
- 150000002889 oleic acids Chemical class 0.000 claims description 2
- 229940114930 potassium stearate Drugs 0.000 claims description 2
- ANBFRLKBEIFNQU-UHFFFAOYSA-M potassium;octadecanoate Chemical compound [K+].CCCCCCCCCCCCCCCCCC([O-])=O ANBFRLKBEIFNQU-UHFFFAOYSA-M 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- 239000000047 product Substances 0.000 claims description 2
- -1 sodium 3-chloro-oxy-propane-1-sulphonic acid Chemical compound 0.000 claims description 2
- 235000002639 sodium chloride Nutrition 0.000 claims description 2
- 239000011780 sodium chloride Substances 0.000 claims description 2
- 229940114926 stearate Drugs 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims description 2
- 239000004753 textile Substances 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/02—Alkyl sulfonates or sulfuric acid ester salts derived from monohydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Detergent Compositions (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
Verfahren zur Herstellung eines wertvollen hochkapillaraktiven Stoffes.
Zur Herstellung eines wertvollen hochkapillaraktiven Stoffes kann nach dem Hauptpatent durch Umsetzung von 3-chlor2-oxy-propan-1-sulfonsaurem Natrium mit Kaliumstearat intermediÏr gebildetes 2,3oxido-propan-1-sulfonsaures Natrium mit dem bei dieserUnisetzunggleichzeitigfrei- gewordenen Stearin zu einem bei der Verar beitung von Textilien n tzlichen Endstoff umgesetzt werden. Gemäss dem vorliegenden Verfaihren wird an Stelle des ga. liumstearats ein Alkalisalz der technischen ÍlsÏure verwendet. Das Produkt zeichnet sich durch ein hervorra, gend, es Netz-, Waseh-, Reinigungs-, Emulgier-und Dispergiervermogen und durch eine ebensolche SÏure-, Bittersalz- und Kalkbeständigkeit a. us.
Nach einem Ausführungsbeispiel des Verfahrens werden in 27 Teile erwÏrmte technische OLsäure unter Rühren 5, 3 Teile kalzinierte Soda. oder ein anderes, die Neu- tra. lisa. tion bewirkendes Alkali in entspre- chender Menge allmählich eingebtraoht und mach Aufhören der Gasentwieklung bei 140 bis M5 C 20 Teile wasserfreies 3-Chlor-2- oxy-propan-1-sulfonsaures Natrium zugef gt.
Nach gutem Durchmischen wird die Masse so lange auf'dieserTempera-targelia,lten, bis eine titrierte Probe da, s Ende der Reaktion anzeigt. Bei der Reaktion des 3-Chlor-2-oxypropan-1-sulfonsauren Natriums mit dem Alkal. isalz der ÍlsÏure wird 2,3-oxido-propan-1-sulfonsaures Natrium intermediÏr gebild, und gleichzeitig mit der freiwerdenden ÍlsÏ ure zum Endstoff Timgesetzt. Dieser kann durch kochenden Alkohol vom Kochsalz. getrennt und aus der Spritl¯sung, gegebenenfalls nach EntfÏrben mit Kohle, als farbloses Pulver erhalten werden. Dieses gibt mit Wasser stark schäumende, kalk-und säureunempfindliehe, klare Losungen.
PATENTANSPRUCH :
Verfahren zur Eerstellungeines,wertvol- len hochkapillaraktiven Stoffes, dadurch gekennzeichnet, da¯ durch Umsetzung von 3
**WARNUNG** Ende DESC Feld konnte Anfang CLMS uberlappen**.
Process for the production of a valuable highly capillary-active substance.
According to the main patent, by reacting sodium 3-chloro-oxy-propane-1-sulphonic acid with potassium stearate, sodium 2,3oxido-propane-1-sulphonic acid formed as an intermediate with the stearin released at the same time during this dissolution can be used to produce a valuable substance with high capillary activity Processing of textiles useful end material can be implemented. According to the present procedure, instead of the ga. lium stearate is an alkali salt of technical Ísure used. The product is characterized by excellent wetting, washing, cleaning, emulsifying and dispersing properties and by its resistance to acids, Epsom salts and lime a. us.
According to one exemplary embodiment of the process, 5.3 parts of calcined soda are added to 27 parts of heated technical grade acid with stirring. or another, the neutra. Lisa. Gradually add the appropriate amount of alkali causing the reaction and add 20 parts of anhydrous sodium 3-chloro-2-oxy-propane-1-sulphonic acid to stop the evolution of gas at 140 to M5 C.
After thorough mixing, the mass is kept on this tempera-targelia, until a titrated sample indicates the end of the reaction. In the reaction of 3-chloro-2-oxypropane-1-sulfonic acid sodium with the alkali. The oleic acid salt is formed as an intermediate 2,3-oxido-propane-1-sulfonic acid sodium, and at the same time, with the released oleic acid, it is converted into the end product Tim. This can be achieved by boiling alcohol from the table salt. separated and obtained from the Spritl¯sung, optionally after decolorization with charcoal, as a colorless powder. This gives strongly foaming, lime and acid-insensitive, clear solutions with water.
PATENT CLAIM:
Process for the production of a valuable highly capillary-active substance, characterized in that by converting 3
** WARNING ** End of DESC field could overlap beginning of CLMS **.
Claims (1)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE203858X | 1935-11-05 | ||
| CH195069T | 1936-10-02 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH203858A true CH203858A (en) | 1939-03-31 |
Family
ID=25722718
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH203858D CH203858A (en) | 1935-11-05 | 1936-10-02 | Process for the production of a valuable highly capillary-active substance. |
Country Status (1)
| Country | Link |
|---|---|
| CH (1) | CH203858A (en) |
-
1936
- 1936-10-02 CH CH203858D patent/CH203858A/en unknown
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