CH201848A - Process for the preparation of a disazo dye. - Google Patents
Process for the preparation of a disazo dye.Info
- Publication number
- CH201848A CH201848A CH201848DA CH201848A CH 201848 A CH201848 A CH 201848A CH 201848D A CH201848D A CH 201848DA CH 201848 A CH201848 A CH 201848A
- Authority
- CH
- Switzerland
- Prior art keywords
- preparation
- disazo dye
- dye
- parts
- disazo
- Prior art date
Links
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 title claims description 5
- RDMFEHLCCOQUMH-UHFFFAOYSA-N 2,4'-Diphenyldiamine Chemical group C1=CC(N)=CC=C1C1=CC=CC=C1N RDMFEHLCCOQUMH-UHFFFAOYSA-N 0.000 claims description 3
- 239000003960 organic solvent Substances 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- QPQKUYVSJWQSDY-CCEZHUSRSA-N 4-(phenylazo)aniline Chemical compound C1=CC(N)=CC=C1\N=N\C1=CC=CC=C1 QPQKUYVSJWQSDY-CCEZHUSRSA-N 0.000 description 1
- 150000008049 diazo compounds Chemical class 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- XONPDZSGENTBNJ-UHFFFAOYSA-N molecular hydrogen;sodium Chemical compound [Na].[H][H] XONPDZSGENTBNJ-UHFFFAOYSA-N 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B35/00—Disazo and polyazo dyes of the type A<-D->B prepared by diazotising and coupling
- C09B35/02—Disazo dyes
- C09B35/021—Disazo dyes characterised by two coupling components of the same type
- C09B35/023—Disazo dyes characterised by two coupling components of the same type in which the coupling component is a hydroxy or polyhydroxy compound
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B35/00—Disazo and polyazo dyes of the type A<-D->B prepared by diazotising and coupling
- C09B35/02—Disazo dyes
- C09B35/039—Disazo dyes characterised by the tetrazo component
- C09B35/08—Disazo dyes characterised by the tetrazo component the tetrazo component being a derivative of biphenyl
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Description
<B>Zusatzpatent</B> zum Hauptpatent Nr. 198710. Verfahren zur Herstellung eines BisazofarbstofTes. Nach dem im Hauptpatent beschriebenen Verfahren erhält man einen Disazofarbstoff, der sich in organischen Lösungsmitteln mit bräunlich gelber Farbe löst, wenn man p- Aminoazobenzol diazotiert und die Diazover- bindung mit p-Isohegylphenol kuppelt.
Wie nun weiter gefupden wurde, erhält man einen Disazofarbstofl von ähnlichen Ei genschaften, wenn man 2.4'-Diamino-diphenyl tetrazotiert und die Tetrazoverbindung mit p-Isohegylpheriol kuppelt.
<I>Beispiel:</I> Klan tetrazotiert 18,4 Teile 2.4'-Diamino- diphenyl unter Zugabe von 100 Teilen Salz säure, 12 Bd, mit 13,8 Teilen Natriumnitrit und lässt die filtrierte Lösung bei 0 zu einer Lösung von 35,6 Teilen p-Isohegylphenol, 16 Teilen Natriumhydrogyd und 6 Teilen eines Emulgiermittels einlaufen. Der Farb stoff wird in üblicher Weise aufgearbeitet. Er färbt organische Lösungsmittel gelb.
<B> Additional patent </B> to main patent no. 198710. Process for the production of a bisazo dye. The process described in the main patent gives a disazo dye which dissolves in organic solvents with a brownish yellow color when p-aminoazobenzene is diazotized and the diazo compound is coupled with p-isohegylphenol.
As has now been found, a disazo dye of similar properties is obtained if 2,4'-diamino-diphenyl is tetrazotized and the tetrazo compound is coupled with p-isohegylpheriol.
<I> Example: </I> Klan tetrazotizes 18.4 parts of 2,4'-diaminodiphenyl with the addition of 100 parts of hydrochloric acid, 12 Bd, with 13.8 parts of sodium nitrite and leaves the filtered solution at 0 to a solution of 35 , 6 parts of p-isohegylphenol, 16 parts of sodium hydrogen and 6 parts of an emulsifier. The dye is worked up in the usual way. It turns organic solvents yellow.
Claims (1)
Applications Claiming Priority (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE201849X | 1936-03-31 | ||
| DE201848X | 1936-03-31 | ||
| DE201847X | 1936-03-31 | ||
| DE201844X | 1936-03-31 | ||
| DE201845X | 1936-03-31 | ||
| DE201846X | 1936-03-31 | ||
| CH198710T | 1937-01-22 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH201848A true CH201848A (en) | 1938-12-15 |
Family
ID=27561165
Family Applications (6)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH201846D CH201846A (en) | 1936-03-31 | 1937-01-22 | Process for the preparation of a disazo dye. |
| CH201845D CH201845A (en) | 1936-03-31 | 1937-01-22 | Process for the preparation of a disazo dye. |
| CH201844D CH201844A (en) | 1936-03-31 | 1937-01-22 | Process for the preparation of a disazo dye. |
| CH201847D CH201847A (en) | 1936-03-31 | 1937-01-22 | Process for the preparation of a disazo dye. |
| CH201848D CH201848A (en) | 1936-03-31 | 1937-01-22 | Process for the preparation of a disazo dye. |
| CH201849D CH201849A (en) | 1936-03-31 | 1937-01-22 | Process for the preparation of a disazo dye. |
Family Applications Before (4)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH201846D CH201846A (en) | 1936-03-31 | 1937-01-22 | Process for the preparation of a disazo dye. |
| CH201845D CH201845A (en) | 1936-03-31 | 1937-01-22 | Process for the preparation of a disazo dye. |
| CH201844D CH201844A (en) | 1936-03-31 | 1937-01-22 | Process for the preparation of a disazo dye. |
| CH201847D CH201847A (en) | 1936-03-31 | 1937-01-22 | Process for the preparation of a disazo dye. |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH201849D CH201849A (en) | 1936-03-31 | 1937-01-22 | Process for the preparation of a disazo dye. |
Country Status (1)
| Country | Link |
|---|---|
| CH (6) | CH201846A (en) |
-
1937
- 1937-01-22 CH CH201846D patent/CH201846A/en unknown
- 1937-01-22 CH CH201845D patent/CH201845A/en unknown
- 1937-01-22 CH CH201844D patent/CH201844A/en unknown
- 1937-01-22 CH CH201847D patent/CH201847A/en unknown
- 1937-01-22 CH CH201848D patent/CH201848A/en unknown
- 1937-01-22 CH CH201849D patent/CH201849A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CH201845A (en) | 1938-12-15 |
| CH201847A (en) | 1938-12-15 |
| CH201846A (en) | 1938-12-15 |
| CH201844A (en) | 1938-12-15 |
| CH201849A (en) | 1938-12-15 |
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