CH196872A - Process for the preparation of a quaternary aminoacetic acid amide derivative. - Google Patents

Process for the preparation of a quaternary aminoacetic acid amide derivative.

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Publication number
CH196872A
CH196872A CH196872DA CH196872A CH 196872 A CH196872 A CH 196872A CH 196872D A CH196872D A CH 196872DA CH 196872 A CH196872 A CH 196872A
Authority
CH
Switzerland
Prior art keywords
quaternary
preparation
acid amide
amide derivative
aminoacetic acid
Prior art date
Application number
Other languages
German (de)
Inventor
A-G J R Geigy
Original Assignee
Geigy Ag J R
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Geigy Ag J R filed Critical Geigy Ag J R
Publication of CH196872A publication Critical patent/CH196872A/en

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Description

  

  Verfahren zur Darstellung eines     quaternären        Aminoessigsäureamidderivates.       Es wurde gefunden, dass man durch Um  setzung von     Chloracetyl-N-spermacetanilid,     wie es aus     N-Spermacetanilirr,    hergestellt unter  Verwendung der Mischung der gesättigten  und ungesättigten     Spermacetalkohole,    die  durch     Verseifung    von     Spermacetöl    erhalten  werden, und     Chloracetylchlorid    erhältlich ist,

    mit     Trimethylamin    zum     quaternären        Dimethyl-          aminoessigsäu        re    -N-     spermacetanilid-        Chlorme-          thylat    gelangen kann. Die neue Verbindung,  in festem Zustand eine salben- bis wachs  artige Masse von brauner Farbe, löst sich  sehr leicht in Wasser und weist stark aus  geprägte,     kapillaraktive    Eigenschaften auf.

    Sie soll Verwendung finden als     Weich-          machungsmittel,    Abziehmittel für     Naphthol-          AS-    und     güpenfärbungen    und als Mittel zum  Verbessern der Wasserechtheit von direkt  gefärbter, nativer und umgefällter Zellulose.

    <I>Beispiel:</I>  37 g     Chloracefyl-N-spermacetanilid    werden  mit 37 g     Trimethylamin,    verwendet als 33  /o-         ige,    alkoholische Lösung, mit 200 g     Äthyl-          alkohol    b Stunden im     Autoklav    auf 130 bis  140' erhitzt; dann werden Alkohol und über  schüssiges     Trimethylamin        abdestilliert    und  der Rückstand kurze Zeit im Vakuum ge  trocknet. Man erhält eine braune, wachs  ähnliche, in Wasser klar lösliche Masse, die  stark ausgeprägte,     kapillaraktiveEigenschaften     aufweist.

   Die neue Verbindung soll Verwen  dung finden als     Weichmachungsmittel,    Abzieh  mittel für     Naphthol-AS-    und     güpenfärbungen     und als Mittel zum Verbessern der Wasser  echtheit von direkt gefärbter, nativer und um  gefällter Zellulose.



  Process for the preparation of a quaternary aminoacetic acid amide derivative. It has been found that by converting chloroacetyl-N-spermacetanilide, as it is produced from N-spermacetanilirr, using the mixture of the saturated and unsaturated spermacetal alcohols obtained by saponification of spermacetol and chloroacetyl chloride,

    with trimethylamine, the quaternary dimethylaminoacetic acid -N- spermacetanilide chloromethylate can be obtained. The new compound, in the solid state an ointment-like to waxy mass of brown color, dissolves very easily in water and has strong, capillary-active properties.

    It is said to be used as a plasticizer, a stripping agent for naphthol, AS and güpen dyeings and as an agent for improving the waterfastness of directly dyed, native and reprecipitated cellulose.

    <I> Example: </I> 37 g of chloracefyl-N-spermacetanilide are heated with 37 g of trimethylamine, used as a 33% alcoholic solution, with 200 g of ethyl alcohol for b hours in the autoclave to 130 to 140 °; then alcohol and excess trimethylamine are distilled off and the residue is dried in vacuo for a short time. A brown, wax-like mass is obtained which is clearly soluble in water and which has very pronounced, capillary-active properties.

   The new compound is said to be used as a plasticizer, a stripping agent for naphthol AS and güpenfyeing and as a means to improve the water fastness of directly dyed, native and reprecipitated cellulose.

Claims (1)

PATENTANSPRUCH: Verfahren zur Darstellung eines quater- nären Aminoessigsäureamidderivates, dadurch gekennzeichnet, dass man Chloracetyl-N- apermacetanilid, wie *es aus Chloracetylchlorid und N-Spermacetanilin, hergestellt unter Ver wendung der Mischung der gesättigten und ungesättigten Spermacetalkohole, die durch Verseifung von Spermacetöl erhalten werden, erhältlich ist, PATENT CLAIM: Process for the preparation of a quaternary Aminoessigsäureamidderivates, characterized in that chloroacetyl-N-apermacetanilide, such as * it from chloroacetyl chloride and N-spermacetaniline, produced using the mixture of saturated and unsaturated spermacetal alcohols obtained by saponification is available, mit Trimethylamin zum qua- ternären Dimethylaminoessigsäure-N-sperm- acetanilid-chlormethylat umsetzt. Die neue Verbindung, in festem Zustand eine salben- bis wachsartige 1VIasse von brauner Farbe, löst sich sehr leicht in Wasser und weist stark ausgeprägte, kapillaraktive Eigen schaften auf. with trimethylamine to form the quaternary dimethylaminoacetic acid-N-sperm-acetanilide-chloromethylate. The new compound, in the solid state an ointment-like to waxy brown color, dissolves very easily in water and has very pronounced, capillary-active properties. Sie soll Verwendung finden als Weichmachungsmittel,Abziehmittel für Napb- thol-AS- und Küpenfärbungen und als Mittel zum Verbessern der Wasserechtheit von direkt gefärbter, nativer und umgefällter Zellulose. It is said to be used as a plasticizer, a stripping agent for napthol-AS and vat dyeings and as an agent for improving the water fastness of directly dyed, native and reprecipitated cellulose.
CH196872D 1935-12-23 1936-11-12 Process for the preparation of a quaternary aminoacetic acid amide derivative. CH196872A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE196872X 1935-12-23
DE198052X 1935-12-23

Publications (1)

Publication Number Publication Date
CH196872A true CH196872A (en) 1938-03-31

Family

ID=25758378

Family Applications (1)

Application Number Title Priority Date Filing Date
CH196872D CH196872A (en) 1935-12-23 1936-11-12 Process for the preparation of a quaternary aminoacetic acid amide derivative.

Country Status (1)

Country Link
CH (1) CH196872A (en)

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