CH182592A - Process for the preparation of an amine oxide. - Google Patents

Process for the preparation of an amine oxide.

Info

Publication number
CH182592A
CH182592A CH182592DA CH182592A CH 182592 A CH182592 A CH 182592A CH 182592D A CH182592D A CH 182592DA CH 182592 A CH182592 A CH 182592A
Authority
CH
Switzerland
Prior art keywords
dodecyl
ethyl
cyclohexylamine
oxide
amine oxide
Prior art date
Application number
Other languages
German (de)
Inventor
Gesellschaft Fuer Chemis Basel
Original Assignee
Chem Ind Basel
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chem Ind Basel filed Critical Chem Ind Basel
Publication of CH182592A publication Critical patent/CH182592A/en

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Description

  

  Verfahren zur Herstellung eines     Aminoxydes.       Es     wurde    gefunden, dass man ein neues       Aminoxyd    - das     Dodecyl-äthyl-cyclohexyl-          aminoxyd    - erhält, wenn man das     Dodecyl-          äthyl-cyclohexylamin    mit solchen Oxyda  tionsmittel behandelt, die     superoxydisch    ge  bundenen Sauerstoff enthalten.  



  Das     Dodecyl-äthyl-cyclohexylaminoxyd     bildet eine halbfeste Masse, die in Wasser,  verdünnten Alkalien und verdünnten Säuren  löslich ist. Die verdünnten wässerigen Lö  sungen des     Dodecyl-äthyl-cyclohexylamin-          oxyds    besitzen hervorragende     kapillaraktive     Eigenschaften, so dass dieses Produkt ein  wertvolles Hilfsmittel für die Textilindustrie  darstellt.  



  <I>Beispiel:</I>       3$    Teile     Dodecyl-äthyl-cyclohexylamin     werden in 140     Volumteilen    Aceton gelöst,  mit 23 Teilen einer Wasserstoffsuperoxyd  lösung von 30     Volumprozent    versetzt und  während 40 bis 50 Stunden auf 50 bis 55    erhitzt. Nach dem     Abdestillieren    des Ace  tons und des Wassers im Vakuum bei 60  erhält man das Oxyd des Dodecyl-äthyl-cy-         clohexylamins    als hellgefärbtes, allmählich  erstarrendes dickflüssiges Öl. Es ist     in    Was  ser,     verdünnten    Säuren und     Alkalien    klar  löslich.

   Die stark schäumenden Lösungen  besitzen hervorragende     kapillaraktive    Eigen  schaften.



  Process for the preparation of an amine oxide. It has been found that a new amine oxide - the dodecyl-ethyl-cyclohexyl-amine oxide - is obtained if the dodecyl-ethyl-cyclohexylamine is treated with such oxidizing agents which contain superoxide bound oxygen.



  The dodecyl-ethyl-cyclohexylamine oxide forms a semi-solid mass which is soluble in water, dilute alkalis and dilute acids. The dilute aqueous solutions of dodecyl-ethyl-cyclohexylamine-oxide have excellent capillary-active properties, so that this product is a valuable aid for the textile industry.



  <I> Example: </I> 3 parts of dodecyl-ethyl-cyclohexylamine are dissolved in 140 parts by volume of acetone, 23 parts of a hydrogen peroxide solution of 30 percent by volume are added and the mixture is heated to 50 to 55 hours for 40 to 50 hours. After the acetone and the water have been distilled off in vacuo at 60, the oxide of dodecyl-ethyl-cyclohexylamine is obtained as a light-colored, gradually solidifying, viscous oil. It is clearly soluble in water, dilute acids and alkalis.

   The highly foaming solutions have excellent capillary-active properties.

Claims (1)

PATENTANSPRUCH: Verfahren zur Herstellung eines Amin oxyds - des Dodecyl-äthyl-cyclohexylamin- oxyds - dadurch gekennzeichnet, dass man das Dodecyl-äthyl-cyclohexylamin mit sol chen Oxydationsmitteln behandelt, die super- oxydisch gebundenen Sauerstoff enthalten. Das Dodecyl-äthyl-cyclohexylaminoxyd bildet eine halbfeste Masse, die in Wasser, verdünnten Alkalien und verdünnten Säuren löslich ist. PATENT CLAIM: Process for the production of an amine oxide - the dodecyl-ethyl-cyclohexylamine oxide - characterized in that the dodecyl-ethyl-cyclohexylamine is treated with such oxidizing agents which contain superoxide bound oxygen. The dodecyl-ethyl-cyclohexylamine oxide forms a semi-solid mass which is soluble in water, dilute alkalis and dilute acids. Die verdünnten wässerigen Lö sungen des Dodecyl-äthyl-cyclohexylamin- oxyds besitzen hervorragende kapillaraktive Eigenschaften, so dass dieses Produkt ein wertvolles Hilfsmittel für die Textilindustrie darstellt. The dilute aqueous solutions of dodecyl-ethyl-cyclohexylamine-oxide have excellent capillary-active properties, so that this product is a valuable aid for the textile industry.
CH182592D 1935-06-19 1935-06-19 Process for the preparation of an amine oxide. CH182592A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH182592T 1935-06-19
CH175351T 1935-07-04

Publications (1)

Publication Number Publication Date
CH182592A true CH182592A (en) 1936-02-15

Family

ID=25719670

Family Applications (1)

Application Number Title Priority Date Filing Date
CH182592D CH182592A (en) 1935-06-19 1935-06-19 Process for the preparation of an amine oxide.

Country Status (1)

Country Link
CH (1) CH182592A (en)

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