CH137936A - Process for the production of a new intermediate product in the tar color industry. - Google Patents

Process for the production of a new intermediate product in the tar color industry.

Info

Publication number
CH137936A
CH137936A CH137936DA CH137936A CH 137936 A CH137936 A CH 137936A CH 137936D A CH137936D A CH 137936DA CH 137936 A CH137936 A CH 137936A
Authority
CH
Switzerland
Prior art keywords
mole
production
new intermediate
intermediate product
sulfonic acid
Prior art date
Application number
Other languages
German (de)
Inventor
Gesellschaft Fuer Chemis Basel
Original Assignee
Chem Ind Basel
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chem Ind Basel filed Critical Chem Ind Basel
Publication of CH137936A publication Critical patent/CH137936A/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
    • C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
    • C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D251/26—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hetero atoms directly attached to ring carbon atoms
    • C07D251/40—Nitrogen atoms
    • C07D251/54—Three nitrogen atoms
    • C07D251/70—Other substituted melamines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Description

  

  Verfahren zur Herstellung eines neuen Zwischenproduktes der Teerfarbenindustrie.    Es wurde gefunden, dass man ein neues  Zwischenprodukt erhält, wenn man 1     Mol          Cyanurchlorid,    1     1M1        1,4-Phenylendiamin-3-          sulfosäure,    1     Mol    Anilin und 1     Mol        Dehydro-          thiotoluidinsulfosäu:-e    aufeinander einwirken  lässt.  



  Das     ternäre    Kondensationsprodukt aus  1     Mol        Cyanurchlorid,    1     Mol        1,4-Phenylendi-          amin-3-sulfosäure,    1     Mol    Anilin und 1     Mol          Dehydrothiotoluidinsulfosäure    bildet ein gel  bes Pulver, das sich in     Sodalösung    fast farb  los löst. Es besitzt ausgesprochene Affinität  zur Baumwollfaser und kann auf dieser, zum  Beispiel durch     Diazotieren    und entwickeln  mit     Kupplungskomponenten,    in Farbstoffe  übergeführt werden.

           Beispiel:     Eine feine Suspension von 18,5 Gewichts  teilen     Cyanurchlorid    in Eiswasser wird mit  einer neutralen Lösung von 3179 Gewichts-    teilen     1,4-Phenylendiamin-3-sulfosäure    verei  nigt und damit während     1-11/s    Stunden  bei 0   gerührt. Während dieser Zeit lässt  man langsam eine Lösung von 5,3 Gewichts  teilen Soda zufliessen. Hierauf fügt man eine  neutrale Lösung von 32 Gewichtsteilen     1)e-          hydrothiotoluidinsulfosäure    zu, steigert die  Temperatur auf 400 und lässt während     11z     Stunden wieder eine Lösung von 5,3 Ge  wichtsteilen Soda zufliessen.  



  Man fügt nun 9,3     Gewichtsteile    Anilin  zu und erwärmt     11s    Stunden auf 80  . Es  bildet sich das     ternäre    Kondensationsprodukt  aus 1     Mol        Cyanurchlorid,    1     Mol        1,4-Phe-          nylendiamin-3-sulfosäure,    1     Mol        Dehydro-          thiotoluidinsulfosäure    und 1     Mol    Anilin, das  durch     Aussalzen    gefällt und isoliert werden  kann.  



  Zum gleichen Produkt gelangt man, wenn  man die drei Komponenten in einer andern       Reihenfolge    auf     C7anurchlorid    einwirken lässt.



  Process for the production of a new intermediate product in the tar color industry. It has been found that a new intermediate is obtained if 1 mol of cyanuric chloride, 1 1M1 of 1,4-phenylenediamine-3-sulfonic acid, 1 mol of aniline and 1 mol of dehydrothiotoluidinsulfonic acid are allowed to act on one another.



  The ternary condensation product of 1 mole of cyanuric chloride, 1 mole of 1,4-phenylenediamine-3-sulfonic acid, 1 mole of aniline and 1 mole of dehydrothiotoluidinsulfonic acid forms a yellow powder which dissolves almost colorlessly in soda solution. It has a pronounced affinity for cotton fibers and can be converted into dyes on this, for example by diazotizing and developing with coupling components.

           Example: A fine suspension of 18.5 parts by weight of cyanuric chloride in ice water is combined with a neutral solution of 3179 parts by weight of 1,4-phenylenediamine-3-sulfonic acid and stirred at 0 for 1-11 / s hours. During this time, a solution of 5.3 parts by weight of soda is allowed to flow in slowly. A neutral solution of 32 parts by weight of 1) e-hydrothiotoluidinsulfonic acid is then added, the temperature is increased to 400 and a solution of 5.3 parts by weight of soda is allowed to flow in again over 11z hours.



  9.3 parts by weight of aniline are then added and the mixture is heated to 80 for 11 seconds. The ternary condensation product is formed from 1 mole of cyanuric chloride, 1 mole of 1,4-phenylenediamine-3-sulfonic acid, 1 mole of dehydrothiotoluidinsulfonic acid and 1 mole of aniline, which can be precipitated and isolated by salting out.



  The same product is obtained if the three components are allowed to act on C7anuric chloride in a different order.

Claims (1)

PATENTANSPRUCH: Verfahren zur Herstellung eines neuen Zwischenproduktes der Teerfarbenindustrie, dadurch gekennzeichnet, dass man 1 Mol Cyanurchlorid, 1 Mol 1,4-Phenylendiamin- 3-sulfosäure, 1 Mol Anilin und 1 Mol De- hydrothiotoluidinsulfosäure aufeinander ein wirken lässt. PATENT CLAIM: Process for the production of a new intermediate product in the tar color industry, characterized in that 1 mole of cyanuric chloride, 1 mole of 1,4-phenylenediamine-3-sulfonic acid, 1 mole of aniline and 1 mole of dehydrothiotoluidine sulfonic acid are allowed to act on one another. Das ternäre Kondensationsprodukt aus 1 Mol Cyanurchlorid, 1 Mol 1,4-Phenylendi- amin-3-sulfosäure, 1 Mol Anilin und 1 Mol Dehydrothiotoluidinsulfosäure bildet ein gel bes Pulver, das sich in Sodalösung fast farb los löst. Es besitzt ausgesprochene Affinität zur Baumwollfaser und kann auf dieser in Farbstoffe übergeführt werden. The ternary condensation product of 1 mole of cyanuric chloride, 1 mole of 1,4-phenylenediamine-3-sulfonic acid, 1 mole of aniline and 1 mole of dehydrothiotoluidinsulfonic acid forms a yellow powder which dissolves almost colorlessly in soda solution. It has a pronounced affinity for cotton fibers and can be converted into dyes on this.
CH137936D 1922-09-07 1927-10-22 Process for the production of a new intermediate product in the tar color industry. CH137936A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH103430T 1922-09-07
CH137936T 1927-10-22

Publications (1)

Publication Number Publication Date
CH137936A true CH137936A (en) 1930-01-31

Family

ID=25706448

Family Applications (1)

Application Number Title Priority Date Filing Date
CH137936D CH137936A (en) 1922-09-07 1927-10-22 Process for the production of a new intermediate product in the tar color industry.

Country Status (1)

Country Link
CH (1) CH137936A (en)

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