CA3071434A1 - Metal-organic frameworks appended with cyclic diamines for carbon dioxide capture - Google Patents

Metal-organic frameworks appended with cyclic diamines for carbon dioxide capture Download PDF

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Publication number
CA3071434A1
CA3071434A1 CA3071434A CA3071434A CA3071434A1 CA 3071434 A1 CA3071434 A1 CA 3071434A1 CA 3071434 A CA3071434 A CA 3071434A CA 3071434 A CA3071434 A CA 3071434A CA 3071434 A1 CA3071434 A1 CA 3071434A1
Authority
CA
Canada
Prior art keywords
adsorption
adsorption material
emm
desorption
halogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CA3071434A
Other languages
English (en)
French (fr)
Inventor
Jeffrey R. Long
Simon Christopher Weston
Phillip J. Milner
Rebecca L. Siegelman
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
University of California San Diego UCSD
ExxonMobil Technology and Engineering Co
Original Assignee
ExxonMobil Research and Engineering Co
University of California San Diego UCSD
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ExxonMobil Research and Engineering Co, University of California San Diego UCSD filed Critical ExxonMobil Research and Engineering Co
Publication of CA3071434A1 publication Critical patent/CA3071434A1/en
Pending legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456—Removing acid components
    • B01D53/1475—Removing carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/0462—Temperature swing adsorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/047—Pressure swing adsorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/223—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material containing metals, e.g. organo-metallic compounds, coordination complexes
    • B01J20/226—Coordination polymers, e.g. metal-organic frameworks [MOF], zeolitic imidazolate frameworks [ZIF]
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
    • C07F3/02—Magnesium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20436—Cyclic amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/20—Organic adsorbents
    • B01D2253/204—Metal organic frameworks (MOF's)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30—Physical properties of adsorbents
    • B01D2253/302—Dimensions
    • B01D2253/306—Surface area, e.g. BET-specific surface
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/504—Carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/02—Other waste gases
    • B01D2258/0283—Flue gases
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2

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  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Treating Waste Gases (AREA)
  • Separation Of Gases By Adsorption (AREA)
CA3071434A 2017-08-04 2018-08-03 Metal-organic frameworks appended with cyclic diamines for carbon dioxide capture Pending CA3071434A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201762541616P 2017-08-04 2017-08-04
US62/541,616 2017-08-04
PCT/US2018/045259 WO2019028421A1 (en) 2017-08-04 2018-08-03 ORGANOMETALLIC STRUCTURES ADDED TO CYCLIC DIAMINES FOR CAPTURING CARBON DIOXIDE

Publications (1)

Publication Number Publication Date
CA3071434A1 true CA3071434A1 (en) 2019-02-07

Family

ID=63371776

Family Applications (1)

Application Number Title Priority Date Filing Date
CA3071434A Pending CA3071434A1 (en) 2017-08-04 2018-08-03 Metal-organic frameworks appended with cyclic diamines for carbon dioxide capture

Country Status (9)

Country Link
US (1) US10780388B2 (https=)
EP (1) EP3661644A1 (https=)
JP (1) JP7246367B2 (https=)
KR (1) KR102675365B1 (https=)
CN (1) CN111093824B (https=)
AU (1) AU2018309168B2 (https=)
CA (1) CA3071434A1 (https=)
SG (1) SG11202000934TA (https=)
WO (1) WO2019028421A1 (https=)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116472112A (zh) * 2020-08-13 2023-07-21 埃克森美孚技术与工程公司 合成和再循环金属有机骨架体系的方法

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019108847A1 (en) 2017-11-29 2019-06-06 The Regents Of The University Of California A vanadium metal-organic framework for selective adsorption
EP3856748B1 (en) * 2018-09-28 2024-03-06 The Regents of The University of California Metal-organic framework phase and crystallite shape control
EP3959008A1 (en) * 2019-04-26 2022-03-02 ExxonMobil Research and Engineering Company Mixed-metal mixed-organic framework systems for selective co capture
KR102902679B1 (ko) * 2019-07-15 2025-12-22 엑손모빌 테크놀로지 앤드 엔지니어링 컴퍼니 기체 분리를 위한 국부적 결함을 갖는 금속-유기 골격구조
US12403446B2 (en) * 2020-01-30 2025-09-02 Korea University Research And Business Foundation Alkanolamine/amine-grafted metal-organic framework-based carbon dioxide adsorbent
US11872537B2 (en) 2020-08-06 2024-01-16 ExxonMobil Technology and Engineering Company Metal-organic frameworks for carbon dioxide capture
EP4340976A4 (en) * 2021-05-21 2025-10-22 Exxonmobil Technology & Engineering Company POLYMERIC SORBENT FIBROUS COMPOSITIONS INCORPORATING ORGANOMETALLIC STRUCTURES
CN113663649A (zh) * 2021-08-05 2021-11-19 华东师范大学 一种mof成型材料应用于低温二氧化碳捕获
CN116693866B (zh) * 2022-02-25 2026-04-17 中国科学院福建物质结构研究所 一种钛基金属有机框架材料及其制备方法和应用
CN114644888B (zh) * 2022-04-01 2022-10-21 飞思仪表（深圳）有限公司 一种改性湿敏材料及其制备方法及应用、湿度传感器
GB202206101D0 (en) * 2022-04-27 2022-06-08 Mof Tech Limited Method and apparatus for carbon dioxide separation
WO2024202759A1 (ja) * 2023-03-29 2024-10-03 ウシオ電機株式会社 二酸化炭素の回収方法

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ATE495813T1 (de) * 2005-08-09 2011-02-15 Exxonmobil Res & Eng Co Gehinderte cyclische polyamine und ihre salze für ein säuregaswäscheverfahren
JP5698229B2 (ja) 2009-06-19 2015-04-08 ザ リージェンツ オブ ザ ユニバーシティ オブ カリフォルニアＴｈｅ Ｒｅｇｅｎｔｓ Ｏｆ Ｔｈｅ Ｕｎｉｖｅｒｓｉｔｙ Ｏｆ Ｃａｌｉｆｏｒｎｉａ 錯体混合リガンド開骨格材料
CN101816924A (zh) * 2010-04-13 2010-09-01 东南大学 用于co2吸附与分离的金属有机骨架材料及其制备方法
KR20120029586A (ko) * 2010-09-17 2012-03-27 한국전력공사 혼합가스 중 산성가스 분리용 흡수제 및 이를 이용한 분리방법
WO2015164543A1 (en) 2014-04-22 2015-10-29 The Regents Of The University Of California Cooperative chemical adsorption of acid gases in functionalized metal-organic frameworks
EP2768608A4 (en) 2011-10-18 2015-06-03 Univ California ALKYLAMINE-FUNCTIONALIZED METAL-ORGANIC FRAMING MATERIALS FOR COMPOSITE GAS SEPARATION
CN102962036B (zh) * 2012-10-30 2016-06-29 中国科学院大连化学物理研究所 基于过渡金属钴的多孔金属有机骨架材料及其制备方法
US9421517B2 (en) * 2015-01-20 2016-08-23 Chung Yuan Christian University Metal-organic framework polymer for solid-phase microextraction
US20180272314A1 (en) 2015-09-30 2018-09-27 The Regents Of The University Of California Gas purification with diamine-appended metal-organic frameworks
US11458431B2 (en) * 2017-02-17 2022-10-04 The Regents Of The University Of California Amine-appended metal-organic frameworks exhibiting a new adsorption mechanism for carbon dioxide separations

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116472112A (zh) * 2020-08-13 2023-07-21 埃克森美孚技术与工程公司 合成和再循环金属有机骨架体系的方法

Also Published As

Publication number Publication date
KR20200038273A (ko) 2020-04-10
US20190039015A1 (en) 2019-02-07
JP7246367B2 (ja) 2023-03-27
KR102675365B1 (ko) 2024-06-13
JP2020531249A (ja) 2020-11-05
AU2018309168B2 (en) 2022-09-29
CN111093824B (zh) 2023-05-26
WO2019028421A1 (en) 2019-02-07
US10780388B2 (en) 2020-09-22
AU2018309168A1 (en) 2020-02-27
SG11202000934TA (en) 2020-02-27
EP3661644A1 (en) 2020-06-10
CN111093824A (zh) 2020-05-01

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