KR102675365B1 - 이산화탄소 포집을 위한 사이클릭 디아민이 첨가된 금속-유기 프레임워크 - Google Patents
이산화탄소 포집을 위한 사이클릭 디아민이 첨가된 금속-유기 프레임워크 Download PDFInfo
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- KR102675365B1 KR102675365B1 KR1020207006095A KR20207006095A KR102675365B1 KR 102675365 B1 KR102675365 B1 KR 102675365B1 KR 1020207006095 A KR1020207006095 A KR 1020207006095A KR 20207006095 A KR20207006095 A KR 20207006095A KR 102675365 B1 KR102675365 B1 KR 102675365B1
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- 239000012621 metal-organic framework Substances 0.000 title claims abstract description 13
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title claims description 43
- 229910002092 carbon dioxide Inorganic materials 0.000 title claims description 21
- 239000001569 carbon dioxide Substances 0.000 title claims description 8
- 125000004122 cyclic group Chemical group 0.000 title abstract description 7
- 238000001179 sorption measurement Methods 0.000 claims abstract description 103
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- 238000003795 desorption Methods 0.000 claims abstract description 19
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- 238000000034 method Methods 0.000 claims description 23
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- MICQYKLVZMNNIO-UHFFFAOYSA-N 4-(4-carboxyphenyl)-2,3-dihydroxybenzoic acid Chemical compound OC(=O)c1ccc(cc1)-c1ccc(C(O)=O)c(O)c1O MICQYKLVZMNNIO-UHFFFAOYSA-N 0.000 claims description 5
- DBLXGWZXBPJXAK-UHFFFAOYSA-N 5-[4-(3-carboxy-4-hydroxyphenyl)phenyl]-2-hydroxybenzoic acid Chemical compound OC1=C(C=C(C=C1)C1=CC=C(C=C1)C1=CC(=C(C=C1)O)C(=O)O)C(=O)O DBLXGWZXBPJXAK-UHFFFAOYSA-N 0.000 claims description 5
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- RHPBLLCTOLJFPH-UHFFFAOYSA-N piperidin-2-ylmethanamine Chemical compound NCC1CCCCN1 RHPBLLCTOLJFPH-UHFFFAOYSA-N 0.000 abstract description 3
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- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
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- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
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- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
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- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
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- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
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- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/223—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material containing metals, e.g. organo-metallic compounds, coordination complexes
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
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- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Treating Waste Gases (AREA)
- Separation Of Gases By Adsorption (AREA)
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| PCT/US2018/045259 WO2019028421A1 (en) | 2017-08-04 | 2018-08-03 | ORGANOMETALLIC STRUCTURES ADDED TO CYCLIC DIAMINES FOR CAPTURING CARBON DIOXIDE |
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| EP3856748B1 (en) * | 2018-09-28 | 2024-03-06 | The Regents of The University of California | Metal-organic framework phase and crystallite shape control |
| EP3959008A1 (en) * | 2019-04-26 | 2022-03-02 | ExxonMobil Research and Engineering Company | Mixed-metal mixed-organic framework systems for selective co capture |
| KR102902679B1 (ko) * | 2019-07-15 | 2025-12-22 | 엑손모빌 테크놀로지 앤드 엔지니어링 컴퍼니 | 기체 분리를 위한 국부적 결함을 갖는 금속-유기 골격구조 |
| US12403446B2 (en) * | 2020-01-30 | 2025-09-02 | Korea University Research And Business Foundation | Alkanolamine/amine-grafted metal-organic framework-based carbon dioxide adsorbent |
| US11872537B2 (en) | 2020-08-06 | 2024-01-16 | ExxonMobil Technology and Engineering Company | Metal-organic frameworks for carbon dioxide capture |
| JP7707282B2 (ja) * | 2020-08-13 | 2025-07-14 | エクソンモービル テクノロジー アンド エンジニアリング カンパニー | 金属有機構造体の合成方法およびリサイクル方法 |
| EP4340976A4 (en) * | 2021-05-21 | 2025-10-22 | Exxonmobil Technology & Engineering Company | POLYMERIC SORBENT FIBROUS COMPOSITIONS INCORPORATING ORGANOMETALLIC STRUCTURES |
| CN113663649A (zh) * | 2021-08-05 | 2021-11-19 | 华东师范大学 | 一种mof成型材料应用于低温二氧化碳捕获 |
| CN116693866B (zh) * | 2022-02-25 | 2026-04-17 | 中国科学院福建物质结构研究所 | 一种钛基金属有机框架材料及其制备方法和应用 |
| CN114644888B (zh) * | 2022-04-01 | 2022-10-21 | 飞思仪表（深圳）有限公司 | 一种改性湿敏材料及其制备方法及应用、湿度传感器 |
| GB202206101D0 (en) * | 2022-04-27 | 2022-06-08 | Mof Tech Limited | Method and apparatus for carbon dioxide separation |
| WO2024202759A1 (ja) * | 2023-03-29 | 2024-10-03 | ウシオ電機株式会社 | 二酸化炭素の回収方法 |
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| WO2017059130A2 (en) | 2015-09-30 | 2017-04-06 | The Regents Of The University Of California | Gas purification with diamine-appended metal-organic frameworks |
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| ATE495813T1 (de) * | 2005-08-09 | 2011-02-15 | Exxonmobil Res & Eng Co | Gehinderte cyclische polyamine und ihre salze für ein säuregaswäscheverfahren |
| JP5698229B2 (ja) | 2009-06-19 | 2015-04-08 | ザ リージェンツ オブ ザ ユニバーシティ オブ カリフォルニアＴｈｅ Ｒｅｇｅｎｔｓ Ｏｆ Ｔｈｅ Ｕｎｉｖｅｒｓｉｔｙ Ｏｆ Ｃａｌｉｆｏｒｎｉａ | 錯体混合リガンド開骨格材料 |
| CN101816924A (zh) * | 2010-04-13 | 2010-09-01 | 东南大学 | 用于co2吸附与分离的金属有机骨架材料及其制备方法 |
| KR20120029586A (ko) * | 2010-09-17 | 2012-03-27 | 한국전력공사 | 혼합가스 중 산성가스 분리용 흡수제 및 이를 이용한 분리방법 |
| WO2015164543A1 (en) | 2014-04-22 | 2015-10-29 | The Regents Of The University Of California | Cooperative chemical adsorption of acid gases in functionalized metal-organic frameworks |
| EP2768608A4 (en) | 2011-10-18 | 2015-06-03 | Univ California | ALKYLAMINE-FUNCTIONALIZED METAL-ORGANIC FRAMING MATERIALS FOR COMPOSITE GAS SEPARATION |
| CN102962036B (zh) * | 2012-10-30 | 2016-06-29 | 中国科学院大连化学物理研究所 | 基于过渡金属钴的多孔金属有机骨架材料及其制备方法 |
| US9421517B2 (en) * | 2015-01-20 | 2016-08-23 | Chung Yuan Christian University | Metal-organic framework polymer for solid-phase microextraction |
| US11458431B2 (en) * | 2017-02-17 | 2022-10-04 | The Regents Of The University Of California | Amine-appended metal-organic frameworks exhibiting a new adsorption mechanism for carbon dioxide separations |
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- 2018-08-03 CA CA3071434A patent/CA3071434A1/en active Pending
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| WO2017059130A2 (en) | 2015-09-30 | 2017-04-06 | The Regents Of The University Of California | Gas purification with diamine-appended metal-organic frameworks |
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| KR20200038273A (ko) | 2020-04-10 |
| US20190039015A1 (en) | 2019-02-07 |
| JP7246367B2 (ja) | 2023-03-27 |
| JP2020531249A (ja) | 2020-11-05 |
| AU2018309168B2 (en) | 2022-09-29 |
| CN111093824B (zh) | 2023-05-26 |
| WO2019028421A1 (en) | 2019-02-07 |
| US10780388B2 (en) | 2020-09-22 |
| AU2018309168A1 (en) | 2020-02-27 |
| SG11202000934TA (en) | 2020-02-27 |
| EP3661644A1 (en) | 2020-06-10 |
| CA3071434A1 (en) | 2019-02-07 |
| CN111093824A (zh) | 2020-05-01 |
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