CN111093824B - 用于二氧化碳捕集的附接有环二胺的金属-有机框架 - Google Patents

用于二氧化碳捕集的附接有环二胺的金属-有机框架 Download PDF

Info

Publication number
CN111093824B
CN111093824B CN201880060695.9A CN201880060695A CN111093824B CN 111093824 B CN111093824 B CN 111093824B CN 201880060695 A CN201880060695 A CN 201880060695A CN 111093824 B CN111093824 B CN 111093824B
Authority
CN
China
Prior art keywords
adsorption
adsorbent material
dobpdc
emm
desorption
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201880060695.9A
Other languages
English (en)
Chinese (zh)
Other versions
CN111093824A (zh
Inventor
J·R·龙
S·C·威斯顿
P·J·米尔纳
R·L·西格曼
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
University of California San Diego UCSD
ExxonMobil Technology and Engineering Co
Original Assignee
University of California San Diego UCSD
ExxonMobil Technology and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by University of California San Diego UCSD, ExxonMobil Technology and Engineering Co filed Critical University of California San Diego UCSD
Publication of CN111093824A publication Critical patent/CN111093824A/zh
Application granted granted Critical
Publication of CN111093824B publication Critical patent/CN111093824B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/223—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material containing metals, e.g. organo-metallic compounds, coordination complexes
    • B01J20/226—Coordination polymers, e.g. metal-organic frameworks [MOF], zeolitic imidazolate frameworks [ZIF]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/0462—Temperature swing adsorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/047—Pressure swing adsorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456—Removing acid components
    • B01D53/1475—Removing carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
    • C07F3/02—Magnesium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20436—Cyclic amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/20—Organic adsorbents
    • B01D2253/204—Metal organic frameworks (MOF's)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30—Physical properties of adsorbents
    • B01D2253/302—Dimensions
    • B01D2253/306—Surface area, e.g. BET-specific surface
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/504—Carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/02—Other waste gases
    • B01D2258/0283—Flue gases
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2

Landscapes

  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Treating Waste Gases (AREA)
  • Separation Of Gases By Adsorption (AREA)
CN201880060695.9A 2017-08-04 2018-08-03 用于二氧化碳捕集的附接有环二胺的金属-有机框架 Active CN111093824B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201762541616P 2017-08-04 2017-08-04
US62/541,616 2017-08-04
PCT/US2018/045259 WO2019028421A1 (en) 2017-08-04 2018-08-03 ORGANOMETALLIC STRUCTURES ADDED TO CYCLIC DIAMINES FOR CAPTURING CARBON DIOXIDE

Publications (2)

Publication Number Publication Date
CN111093824A CN111093824A (zh) 2020-05-01
CN111093824B true CN111093824B (zh) 2023-05-26

Family

ID=63371776

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201880060695.9A Active CN111093824B (zh) 2017-08-04 2018-08-03 用于二氧化碳捕集的附接有环二胺的金属-有机框架

Country Status (9)

Country Link
US (1) US10780388B2 (https=)
EP (1) EP3661644A1 (https=)
JP (1) JP7246367B2 (https=)
KR (1) KR102675365B1 (https=)
CN (1) CN111093824B (https=)
AU (1) AU2018309168B2 (https=)
CA (1) CA3071434A1 (https=)
SG (1) SG11202000934TA (https=)
WO (1) WO2019028421A1 (https=)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019108847A1 (en) 2017-11-29 2019-06-06 The Regents Of The University Of California A vanadium metal-organic framework for selective adsorption
EP3856748B1 (en) * 2018-09-28 2024-03-06 The Regents of The University of California Metal-organic framework phase and crystallite shape control
EP3959008A1 (en) * 2019-04-26 2022-03-02 ExxonMobil Research and Engineering Company Mixed-metal mixed-organic framework systems for selective co capture
KR102902679B1 (ko) * 2019-07-15 2025-12-22 엑손모빌 테크놀로지 앤드 엔지니어링 컴퍼니 기체 분리를 위한 국부적 결함을 갖는 금속-유기 골격구조
US12403446B2 (en) * 2020-01-30 2025-09-02 Korea University Research And Business Foundation Alkanolamine/amine-grafted metal-organic framework-based carbon dioxide adsorbent
US11872537B2 (en) 2020-08-06 2024-01-16 ExxonMobil Technology and Engineering Company Metal-organic frameworks for carbon dioxide capture
JP7707282B2 (ja) * 2020-08-13 2025-07-14 エクソンモービル テクノロジー アンド エンジニアリング カンパニー 金属有機構造体の合成方法およびリサイクル方法
EP4340976A4 (en) * 2021-05-21 2025-10-22 Exxonmobil Technology & Engineering Company POLYMERIC SORBENT FIBROUS COMPOSITIONS INCORPORATING ORGANOMETALLIC STRUCTURES
CN113663649A (zh) * 2021-08-05 2021-11-19 华东师范大学 一种mof成型材料应用于低温二氧化碳捕获
CN116693866B (zh) * 2022-02-25 2026-04-17 中国科学院福建物质结构研究所 一种钛基金属有机框架材料及其制备方法和应用
CN114644888B (zh) * 2022-04-01 2022-10-21 飞思仪表（深圳）有限公司 一种改性湿敏材料及其制备方法及应用、湿度传感器
GB202206101D0 (en) * 2022-04-27 2022-06-08 Mof Tech Limited Method and apparatus for carbon dioxide separation
WO2024202759A1 (ja) * 2023-03-29 2024-10-03 ウシオ電機株式会社 二酸化炭素の回収方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101816924A (zh) * 2010-04-13 2010-09-01 东南大学 用于co2吸附与分离的金属有机骨架材料及其制备方法
CN102962036A (zh) * 2012-10-30 2013-03-13 中国科学院大连化学物理研究所 基于过渡金属钴的多孔金属有机骨架材料及其制备方法
CN106457120A (zh) * 2014-04-22 2017-02-22 加利福尼亚大学董事会 酸性气体在功能化的金属‑有机骨架中的协同化学吸附
WO2017059130A2 (en) * 2015-09-30 2017-04-06 The Regents Of The University Of California Gas purification with diamine-appended metal-organic frameworks

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE495813T1 (de) * 2005-08-09 2011-02-15 Exxonmobil Res & Eng Co Gehinderte cyclische polyamine und ihre salze für ein säuregaswäscheverfahren
JP5698229B2 (ja) 2009-06-19 2015-04-08 ザ リージェンツ オブ ザ ユニバーシティ オブ カリフォルニアＴｈｅ Ｒｅｇｅｎｔｓ Ｏｆ Ｔｈｅ Ｕｎｉｖｅｒｓｉｔｙ Ｏｆ Ｃａｌｉｆｏｒｎｉａ 錯体混合リガンド開骨格材料
KR20120029586A (ko) * 2010-09-17 2012-03-27 한국전력공사 혼합가스 중 산성가스 분리용 흡수제 및 이를 이용한 분리방법
EP2768608A4 (en) 2011-10-18 2015-06-03 Univ California ALKYLAMINE-FUNCTIONALIZED METAL-ORGANIC FRAMING MATERIALS FOR COMPOSITE GAS SEPARATION
US9421517B2 (en) * 2015-01-20 2016-08-23 Chung Yuan Christian University Metal-organic framework polymer for solid-phase microextraction
US11458431B2 (en) * 2017-02-17 2022-10-04 The Regents Of The University Of California Amine-appended metal-organic frameworks exhibiting a new adsorption mechanism for carbon dioxide separations

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101816924A (zh) * 2010-04-13 2010-09-01 东南大学 用于co2吸附与分离的金属有机骨架材料及其制备方法
CN102962036A (zh) * 2012-10-30 2013-03-13 中国科学院大连化学物理研究所 基于过渡金属钴的多孔金属有机骨架材料及其制备方法
CN106457120A (zh) * 2014-04-22 2017-02-22 加利福尼亚大学董事会 酸性气体在功能化的金属‑有机骨架中的协同化学吸附
WO2017059130A2 (en) * 2015-09-30 2017-04-06 The Regents Of The University Of California Gas purification with diamine-appended metal-organic frameworks

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
"Controlling Cooperative CO2 Adsorption in Diamine-Appended Mg-2(dobpdc) Metal-Organic Frameworks";Rebecca L.Siegelman et al.;《Journal of the American Chemical Society》;AMER CHEMICAL SOC;20170702;第139卷(第30期);全文 *
"Enhancing CO2 adsorption of a Zn-phosphonocarboxylate framework by pore space partitions";Yun Ling et al.;《Chemical Communications》;ROYAL SOC CHEMISTRY;20121105;第49卷(第1期);全文 *

Also Published As

Publication number Publication date
KR20200038273A (ko) 2020-04-10
US20190039015A1 (en) 2019-02-07
JP7246367B2 (ja) 2023-03-27
KR102675365B1 (ko) 2024-06-13
JP2020531249A (ja) 2020-11-05
AU2018309168B2 (en) 2022-09-29
WO2019028421A1 (en) 2019-02-07
US10780388B2 (en) 2020-09-22
AU2018309168A1 (en) 2020-02-27
SG11202000934TA (en) 2020-02-27
EP3661644A1 (en) 2020-06-10
CA3071434A1 (en) 2019-02-07
CN111093824A (zh) 2020-05-01

Similar Documents

Publication Publication Date Title
CN111093824B (zh) 用于二氧化碳捕集的附接有环二胺的金属-有机框架
US11014067B2 (en) Polyamine-appended metal-organic frameworks for carbon dioxide separations
US12048892B2 (en) Amine-appended metal-organic frameworks exhibiting a new adsorption mechanism for carbon dioxide separations
KR102647619B1 (ko) 디아민-부가 금속-유기 프레임워크에서 2개 이산화탄소 흡착 단계의 극복
US11872537B2 (en) Metal-organic frameworks for carbon dioxide capture

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
CB02 Change of applicant information
CB02 Change of applicant information

Address after: California, USA

Applicant after: THE REGENTS OF THE University OF CALIFORNIA

Applicant after: ExxonMobil Technology Engineering

Address before: California, USA

Applicant before: THE REGENTS OF THE University OF CALIFORNIA

Applicant before: EXXONMOBIL RESEARCH AND ENGINEERING Co.

GR01 Patent grant
GR01 Patent grant