CA3014685C - Process for preparing high-reactivity isobutene homo- or copolymers - Google Patents
Process for preparing high-reactivity isobutene homo- or copolymers Download PDFInfo
- Publication number
- CA3014685C CA3014685C CA3014685A CA3014685A CA3014685C CA 3014685 C CA3014685 C CA 3014685C CA 3014685 A CA3014685 A CA 3014685A CA 3014685 A CA3014685 A CA 3014685A CA 3014685 C CA3014685 C CA 3014685C
- Authority
- CA
- Canada
- Prior art keywords
- ether
- isobutene
- process according
- donor
- aluminum
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/08—Butenes
- C08F10/10—Isobutene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/08—Butenes
- C08F110/10—Isobutene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/08—Butenes
- C08F210/10—Isobutene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
- C08F4/12—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of boron, aluminium, gallium, indium, thallium or rare earths
- C08F4/14—Boron halides or aluminium halides; Complexes thereof with organic compounds containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/54—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/03—Narrow molecular weight distribution, i.e. Mw/Mn < 3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/04—Broad molecular weight distribution, i.e. Mw/Mn > 6
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/29—Terminal unsaturations, e.g. vinyl or vinylidene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerization Catalysts (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP16155930.7 | 2016-02-16 | ||
| EP16155930 | 2016-02-16 | ||
| PCT/EP2017/053098 WO2017140603A1 (en) | 2016-02-16 | 2017-02-13 | Process for preparing high-reactivity isobutene homo- or copolymers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA3014685A1 CA3014685A1 (en) | 2017-08-24 |
| CA3014685C true CA3014685C (en) | 2024-05-28 |
Family
ID=55398212
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA3014685A Active CA3014685C (en) | 2016-02-16 | 2017-02-13 | Process for preparing high-reactivity isobutene homo- or copolymers |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US10968294B2 (de) |
| EP (1) | EP3416992B1 (de) |
| JP (1) | JP6903069B2 (de) |
| KR (2) | KR20250049464A (de) |
| CN (2) | CN108602914B (de) |
| BR (1) | BR112018016567B1 (de) |
| CA (1) | CA3014685C (de) |
| MY (1) | MY189238A (de) |
| SG (1) | SG11201806870WA (de) |
| WO (1) | WO2017140603A1 (de) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR112018016567B1 (pt) * | 2016-02-16 | 2022-07-05 | Basf Se | Processo para preparar homo- ou copolímeros de isobuteno de alta reatividade |
| EP3444283B1 (de) | 2017-08-17 | 2020-02-26 | Basf Se | Verfahren zur herstellung von hochreaktiven isobuten-homo- oder -copolymeren |
| US10174138B1 (en) * | 2018-01-25 | 2019-01-08 | University Of Massachusetts | Method for forming highly reactive olefin functional polymers |
| US12221458B2 (en) | 2019-08-19 | 2025-02-11 | Lg Chem, Ltd. | Organic borate-based catalyst, method for preparing isobutene oligomer using the same and isobutene oligomer prepared thereby |
| EP3943518A1 (de) * | 2020-07-22 | 2022-01-26 | Indian Oil Corporation Limited | Polymerisationskatalysatorsystem und verfahren zur herstellung von hochreaktivem polyisobutylen |
| WO2022258417A1 (en) | 2021-06-07 | 2022-12-15 | Basf Se | Polyisobutene with high content of certain double bond isomers |
| CA3251435A1 (en) | 2022-02-11 | 2023-08-17 | Basf Se | Medium molecular polyisobutene with a certain distribution of double-bonded isomers |
| WO2023152033A1 (en) | 2022-02-11 | 2023-08-17 | Basf Se | Medium molecular polyisobutene with a certain distribution of double bond isomers |
| CA3256362A1 (en) | 2022-04-14 | 2023-10-19 | Basf Se | PROCESS FOR THE MANUFACTURE OF POLYISOBUTENE SUCCINIC ANHYDRIDES |
| CA3256275A1 (en) | 2022-04-14 | 2023-10-19 | Basf Se | PROCESS FOR THE MANUFACTURE OF POLYISOBUTENE SUCCINIC ANHYDRIDES |
| WO2025082909A1 (en) | 2023-10-18 | 2025-04-24 | Basf Se | Process for improving the stability of polyisobutenes |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2702604C2 (de) | 1977-01-22 | 1984-08-30 | Basf Ag, 6700 Ludwigshafen | Polyisobutene |
| GB8329082D0 (en) | 1983-11-01 | 1983-12-07 | Bp Chem Int Ltd | Low molecular weight polymers of 1-olefins |
| BE1006694A5 (fr) | 1991-06-22 | 1994-11-22 | Basf Ag | Procede de preparation de polyisobutenes extremement reactifs. |
| US5340881A (en) | 1992-11-16 | 1994-08-23 | The University Of Akron | Aldehyde-telechelic polyisobutylenes, catalytic method for preparing the same with high conversion and selectivity, and block copolymers made thereform |
| DE19825334A1 (de) | 1998-06-05 | 1999-12-09 | Basf Ag | Verfahren zur Herstellung hochreaktiver Polyisobutene |
| MY127714A (en) * | 1999-07-16 | 2006-12-29 | Basf Ag | Method for producing highly reactive polyisobutenes |
| US7893176B2 (en) * | 2007-03-23 | 2011-02-22 | Exxonmobil Chemical Patents Inc. | Polydispersity-controlled isoolefin polymerization with polymorphogenates |
| SG182759A1 (en) * | 2010-02-17 | 2012-09-27 | Basf Se | Method for producing highly reactive isobutene homo or copolymers |
| US8349977B2 (en) * | 2010-02-17 | 2013-01-08 | Basf Se | Process for preparing high-reactivity isobutene homo- or copolymers |
| US8697820B2 (en) * | 2011-08-11 | 2014-04-15 | Basf Se | Process for preparing high-reactivity isobutene homo- or copolymers |
| EP2742073A1 (de) * | 2011-08-11 | 2014-06-18 | Basf Se | Verfahren zur herstellung von hochreaktiven isobutenhomo- oder -copolymeren |
| CA2866897C (en) * | 2012-06-18 | 2016-03-29 | Petrochemical Supply, Inc. | Polyisobutylene composition having internal vinylidene and process for preparing the polyisobutylene polymer composition |
| US9631038B2 (en) * | 2013-10-11 | 2017-04-25 | University Of Massachusetts | Polymerization initiating system and method to produce highly reactive olefin functional polymers |
| BR112018016567B1 (pt) * | 2016-02-16 | 2022-07-05 | Basf Se | Processo para preparar homo- ou copolímeros de isobuteno de alta reatividade |
| BR112018015440B1 (pt) | 2016-02-16 | 2022-07-05 | Basf Se | Processo para preparar homo- ou copolímeros de isobuteno de alta reatividade |
-
2017
- 2017-02-13 BR BR112018016567-0A patent/BR112018016567B1/pt active IP Right Grant
- 2017-02-13 CA CA3014685A patent/CA3014685C/en active Active
- 2017-02-13 US US16/073,586 patent/US10968294B2/en active Active
- 2017-02-13 EP EP17703773.6A patent/EP3416992B1/de active Active
- 2017-02-13 CN CN201780010148.5A patent/CN108602914B/zh active Active
- 2017-02-13 MY MYPI2018001346A patent/MY189238A/en unknown
- 2017-02-13 KR KR1020257011171A patent/KR20250049464A/ko active Pending
- 2017-02-13 KR KR1020187023630A patent/KR102795843B1/ko active Active
- 2017-02-13 CN CN202110971580.9A patent/CN113698514B/zh active Active
- 2017-02-13 SG SG11201806870WA patent/SG11201806870WA/en unknown
- 2017-02-13 JP JP2018543189A patent/JP6903069B2/ja active Active
- 2017-02-13 WO PCT/EP2017/053098 patent/WO2017140603A1/en not_active Ceased
-
2021
- 2021-03-26 US US17/213,703 patent/US11629206B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| US11629206B2 (en) | 2023-04-18 |
| US10968294B2 (en) | 2021-04-06 |
| KR102795843B1 (ko) | 2025-04-14 |
| US20210253752A1 (en) | 2021-08-19 |
| JP2019505643A (ja) | 2019-02-28 |
| CN113698514A (zh) | 2021-11-26 |
| CN108602914B (zh) | 2021-09-24 |
| JP6903069B2 (ja) | 2021-07-14 |
| EP3416992A1 (de) | 2018-12-26 |
| MY189238A (en) | 2022-01-31 |
| CN108602914A (zh) | 2018-09-28 |
| KR20250049464A (ko) | 2025-04-11 |
| SG11201806870WA (en) | 2018-09-27 |
| WO2017140603A1 (en) | 2017-08-24 |
| KR20180109939A (ko) | 2018-10-08 |
| EP3416992B1 (de) | 2020-04-15 |
| CA3014685A1 (en) | 2017-08-24 |
| US20190062472A1 (en) | 2019-02-28 |
| CN113698514B (zh) | 2023-11-10 |
| BR112018016567B1 (pt) | 2022-07-05 |
| BR112018016567A2 (pt) | 2019-01-02 |
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| EEER | Examination request |
Effective date: 20220211 |
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| MPN | Maintenance fee for patent paid |
Free format text: FEE DESCRIPTION TEXT: MF (PATENT, 8TH ANNIV.) - STANDARD Year of fee payment: 8 |
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| U00 | Fee paid |
Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U00-U101 (AS PROVIDED BY THE NATIONAL OFFICE); EVENT TEXT: MAINTENANCE REQUEST RECEIVED Effective date: 20250123 |
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| U11 | Full renewal or maintenance fee paid |
Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U11-U102 (AS PROVIDED BY THE NATIONAL OFFICE); EVENT TEXT: MAINTENANCE FEE PAYMENT DETERMINED COMPLIANT Effective date: 20250123 |