CA2989329A1 - Water solvated glass/amorphous solid ionic conductors - Google Patents
Water solvated glass/amorphous solid ionic conductors Download PDFInfo
- Publication number
- CA2989329A1 CA2989329A1 CA2989329A CA2989329A CA2989329A1 CA 2989329 A1 CA2989329 A1 CA 2989329A1 CA 2989329 A CA2989329 A CA 2989329A CA 2989329 A CA2989329 A CA 2989329A CA 2989329 A1 CA2989329 A1 CA 2989329A1
- Authority
- CA
- Canada
- Prior art keywords
- water
- glass
- amorphous solid
- solvated
- electrolyte
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000011521 glass Substances 0.000 title claims abstract description 125
- 239000007787 solid Substances 0.000 title claims abstract description 114
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims description 47
- 239000010416 ion conductor Substances 0.000 title description 9
- 238000000034 method Methods 0.000 claims abstract description 49
- 239000012212 insulator Substances 0.000 claims abstract description 36
- 239000003990 capacitor Substances 0.000 claims abstract description 22
- 239000000446 fuel Substances 0.000 claims abstract description 20
- 239000000463 material Substances 0.000 claims abstract description 18
- 238000005868 electrolysis reaction Methods 0.000 claims abstract description 8
- 239000003792 electrolyte Substances 0.000 claims description 68
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 30
- 239000007788 liquid Substances 0.000 claims description 28
- 229920000447 polyanionic polymer Polymers 0.000 claims description 28
- 150000002500 ions Chemical class 0.000 claims description 27
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims description 23
- 150000001768 cations Chemical group 0.000 claims description 23
- 239000002243 precursor Substances 0.000 claims description 20
- 239000007784 solid electrolyte Substances 0.000 claims description 20
- 239000000470 constituent Substances 0.000 claims description 19
- 229910001416 lithium ion Inorganic materials 0.000 claims description 18
- 239000002002 slurry Substances 0.000 claims description 18
- 239000000654 additive Substances 0.000 claims description 17
- 230000000996 additive effect Effects 0.000 claims description 17
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 claims description 15
- 229910052783 alkali metal Inorganic materials 0.000 claims description 15
- 150000001340 alkali metals Chemical class 0.000 claims description 15
- 229910001415 sodium ion Inorganic materials 0.000 claims description 15
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Inorganic materials [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 claims description 14
- 230000002378 acidificating effect Effects 0.000 claims description 13
- 150000001450 anions Chemical class 0.000 claims description 12
- 150000004820 halides Chemical class 0.000 claims description 12
- 229920000642 polymer Polymers 0.000 claims description 12
- 239000007789 gas Substances 0.000 claims description 11
- 238000007496 glass forming Methods 0.000 claims description 11
- 239000000395 magnesium oxide Substances 0.000 claims description 10
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 10
- 229910052751 metal Inorganic materials 0.000 claims description 10
- 239000002184 metal Substances 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- 238000007614 solvation Methods 0.000 claims description 10
- RQPZNWPYLFFXCP-UHFFFAOYSA-L barium dihydroxide Chemical compound [OH-].[OH-].[Ba+2] RQPZNWPYLFFXCP-UHFFFAOYSA-L 0.000 claims description 9
- 239000002608 ionic liquid Substances 0.000 claims description 9
- 239000002245 particle Substances 0.000 claims description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 8
- 239000000460 chlorine Substances 0.000 claims description 8
- -1 Al Chemical compound 0.000 claims description 7
- 229910019142 PO4 Inorganic materials 0.000 claims description 7
- 239000003513 alkali Substances 0.000 claims description 7
- 229910001422 barium ion Inorganic materials 0.000 claims description 7
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 7
- 239000011244 liquid electrolyte Substances 0.000 claims description 7
- 230000002441 reversible effect Effects 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 7
- 229910011255 B2O3 Inorganic materials 0.000 claims description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 6
- 239000000292 calcium oxide Substances 0.000 claims description 6
- 229910052681 coesite Inorganic materials 0.000 claims description 6
- 229910052906 cristobalite Inorganic materials 0.000 claims description 6
- 239000002178 crystalline material Substances 0.000 claims description 6
- 239000005518 polymer electrolyte Substances 0.000 claims description 6
- 229910052682 stishovite Inorganic materials 0.000 claims description 6
- 238000003860 storage Methods 0.000 claims description 6
- UUCCCPNEFXQJEL-UHFFFAOYSA-L strontium dihydroxide Chemical compound [OH-].[OH-].[Sr+2] UUCCCPNEFXQJEL-UHFFFAOYSA-L 0.000 claims description 6
- 229910001866 strontium hydroxide Inorganic materials 0.000 claims description 6
- IATRAKWUXMZMIY-UHFFFAOYSA-N strontium oxide Inorganic materials [O-2].[Sr+2] IATRAKWUXMZMIY-UHFFFAOYSA-N 0.000 claims description 6
- 230000001131 transforming effect Effects 0.000 claims description 6
- 229910052905 tridymite Inorganic materials 0.000 claims description 6
- 229910001216 Li2S Inorganic materials 0.000 claims description 5
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 5
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 5
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 5
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 5
- 239000000920 calcium hydroxide Substances 0.000 claims description 5
- 235000011116 calcium hydroxide Nutrition 0.000 claims description 5
- 229910001679 gibbsite Inorganic materials 0.000 claims description 5
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 5
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 5
- 239000000347 magnesium hydroxide Substances 0.000 claims description 5
- 235000012254 magnesium hydroxide Nutrition 0.000 claims description 5
- 229910052701 rubidium Inorganic materials 0.000 claims description 5
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 claims description 5
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- XDFCIPNJCBUZJN-UHFFFAOYSA-N barium(2+) Chemical compound [Ba+2] XDFCIPNJCBUZJN-UHFFFAOYSA-N 0.000 claims description 4
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 4
- 229910052794 bromium Inorganic materials 0.000 claims description 4
- 229910052792 caesium Inorganic materials 0.000 claims description 4
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims description 4
- 229910052801 chlorine Inorganic materials 0.000 claims description 4
- 230000000694 effects Effects 0.000 claims description 4
- 230000009477 glass transition Effects 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- 229910052740 iodine Inorganic materials 0.000 claims description 4
- 239000011630 iodine Substances 0.000 claims description 4
- 229910001092 metal group alloy Inorganic materials 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 3
- 229910000039 hydrogen halide Inorganic materials 0.000 claims description 3
- 239000012433 hydrogen halide Substances 0.000 claims description 3
- 229910052909 inorganic silicate Inorganic materials 0.000 claims description 3
- 238000007639 printing Methods 0.000 claims description 3
- NCCSSGKUIKYAJD-UHFFFAOYSA-N rubidium(1+) Chemical compound [Rb+] NCCSSGKUIKYAJD-UHFFFAOYSA-N 0.000 claims description 3
- 238000010345 tape casting Methods 0.000 claims description 3
- 238000007740 vapor deposition Methods 0.000 claims description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
- 229910052788 barium Inorganic materials 0.000 claims description 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 2
- 150000002739 metals Chemical class 0.000 claims description 2
- 238000010422 painting Methods 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
- 239000010452 phosphate Substances 0.000 claims description 2
- 229910052700 potassium Inorganic materials 0.000 claims description 2
- 239000011591 potassium Substances 0.000 claims description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 2
- 229910052593 corundum Inorganic materials 0.000 claims 2
- 239000000377 silicon dioxide Substances 0.000 claims 2
- 235000012239 silicon dioxide Nutrition 0.000 claims 2
- 229910001845 yogo sapphire Inorganic materials 0.000 claims 2
- 230000008569 process Effects 0.000 abstract description 6
- 210000004027 cell Anatomy 0.000 description 42
- 239000011734 sodium Substances 0.000 description 17
- 239000004020 conductor Substances 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 8
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 8
- 229910052708 sodium Inorganic materials 0.000 description 8
- 229910052744 lithium Inorganic materials 0.000 description 7
- 230000032258 transport Effects 0.000 description 7
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 6
- 238000007747 plating Methods 0.000 description 6
- 238000000926 separation method Methods 0.000 description 6
- NJXPYZHXZZCTNI-UHFFFAOYSA-N 3-aminobenzonitrile Chemical compound NC1=CC=CC(C#N)=C1 NJXPYZHXZZCTNI-UHFFFAOYSA-N 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 238000001704 evaporation Methods 0.000 description 5
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 5
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 4
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 4
- 230000001351 cycling effect Effects 0.000 description 4
- 230000005684 electric field Effects 0.000 description 4
- 230000008020 evaporation Effects 0.000 description 4
- 238000004768 lowest unoccupied molecular orbital Methods 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 210000001787 dendrite Anatomy 0.000 description 3
- 239000003989 dielectric material Substances 0.000 description 3
- 238000004770 highest occupied molecular orbital Methods 0.000 description 3
- 239000012528 membrane Substances 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- 230000003068 static effect Effects 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 230000009466 transformation Effects 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- 229910013470 LiC1 Inorganic materials 0.000 description 2
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical class [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 2
- 229920000557 Nafion® Polymers 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 229910001863 barium hydroxide Inorganic materials 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000002001 electrolyte material Substances 0.000 description 2
- 230000006870 function Effects 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000000543 intermediate Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 229910001414 potassium ion Inorganic materials 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000000565 sealant Substances 0.000 description 2
- 230000004580 weight loss Effects 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 239000007836 KH2PO4 Substances 0.000 description 1
- 229910001290 LiPF6 Inorganic materials 0.000 description 1
- NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 description 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 230000022131 cell cycle Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 230000016507 interphase Effects 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910000402 monopotassium phosphate Inorganic materials 0.000 description 1
- 235000019796 monopotassium phosphate Nutrition 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- GNSKLFRGEWLPPA-UHFFFAOYSA-M potassium dihydrogen phosphate Chemical compound [K+].OP(O)([O-])=O GNSKLFRGEWLPPA-UHFFFAOYSA-M 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/006—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels to produce glass through wet route
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B11/00—Oxides or oxyacids of halogens; Salts thereof
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/26—Phosphates
- C01B25/30—Alkali metal phosphates
- C01B25/305—Preparation from phosphorus-containing compounds by alkaline treatment
- C01B25/306—Preparation from phosphorus-containing compounds by alkaline treatment from phosphates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/26—Phosphates
- C01B25/32—Phosphates of magnesium, calcium, strontium, or barium
- C01B25/322—Preparation by neutralisation of orthophosphoric acid
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/24—Alkaline-earth metal silicates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/32—Alkali metal silicates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D5/00—Sulfates or sulfites of sodium, potassium or alkali metals in general
- C01D5/02—Preparation of sulfates from alkali metal salts and sulfuric acid or bisulfates; Preparation of bisulfates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F11/00—Compounds of calcium, strontium, or barium
- C01F11/46—Sulfates
- C01F11/462—Sulfates of Sr or Ba
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/18—Compositions for glass with special properties for ion-sensitive glass
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B13/00—Diaphragms; Spacing elements
- C25B13/04—Diaphragms; Spacing elements characterised by the material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/54—Electrolytes
- H01G11/56—Solid electrolytes, e.g. gels; Additives therein
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/54—Electrolytes
- H01G11/58—Liquid electrolytes
- H01G11/62—Liquid electrolytes characterised by the solute, e.g. salts, anions or cations therein
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/84—Processes for the manufacture of hybrid or EDL capacitors, or components thereof
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
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- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M8/124—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the process of manufacturing or by the material of the electrolyte
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- H01M2300/0068—Solid electrolytes inorganic
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- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
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| US62/189,865 | 2015-07-08 | ||
| PCT/US2016/036661 WO2016205064A1 (en) | 2015-06-18 | 2016-06-09 | Water solvated glass/amorphous solid ionic conductors |
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| CA2989329A1 true CA2989329A1 (en) | 2016-12-22 |
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| US10411293B2 (en) | 2014-02-26 | 2019-09-10 | Universidade Do Porto | Solid electrolyte glass for lithium or sodium ions conduction |
| CN107750406B (zh) * | 2015-06-18 | 2021-02-12 | 德克萨斯大学系统董事会 | 水溶剂化玻璃/非晶态固体离子导体 |
| US11289700B2 (en) | 2016-06-28 | 2022-03-29 | The Research Foundation For The State University Of New York | KVOPO4 cathode for sodium ion batteries |
| WO2018013471A1 (en) | 2016-07-11 | 2018-01-18 | Board Of Regents, The University Of Texas System | Metal plating-based electrical energy storage cell |
| CA3030559A1 (en) | 2016-07-11 | 2018-01-18 | Board Of Regents, The University Of Texas System | Self-charging and/or self-cycling electrochemical cells |
| US11024876B2 (en) | 2016-11-01 | 2021-06-01 | Giner, Inc. | Composite membrane comprising solid electrolyte, method of making said composite membrane, and electrochemical cell comprising said composite membrane |
| EP3348671B1 (de) * | 2017-01-13 | 2021-04-21 | Airbus Defence and Space GmbH | Raumflugkörper mit einer antriebsstofferzeugungsvorrichtung |
| EP3940850A1 (en) | 2017-04-03 | 2022-01-19 | Hydro-Québec | Electrochemical cells with a high voltage cathode |
| CN107275672A (zh) * | 2017-08-03 | 2017-10-20 | 上海铷戈科技发展有限公司 | 一种含铷和/或铯阳离子的钠离子电池电解液添加剂及其应用 |
| US10490360B2 (en) | 2017-10-12 | 2019-11-26 | Board Of Regents, The University Of Texas System | Heat energy-powered electrochemical cells |
| CZ309338B6 (cs) | 2017-12-29 | 2022-09-07 | ŠKODA AUTO a.s. | Sekundární bateriový článek pro elektromobily, obsahující pevné amorfní skelné materiály a nano/mikro materiály |
| WO2019191054A1 (en) * | 2018-03-27 | 2019-10-03 | Board Of Regents, The University Of Texas System | Electrochemical cell with insulator relay layer |
| US12173416B2 (en) | 2018-10-01 | 2024-12-24 | Giner, Inc. | High-temperature alkaline water electrolysis using a composite electrolyte support membrane |
| WO2020090340A1 (ja) | 2018-10-31 | 2020-05-07 | Ａｇｃ株式会社 | ガラスフリット、結晶化ガラス、結晶化ガラスの製造方法、固体電解質およびリチウムイオン二次電池 |
| WO2021188797A1 (en) * | 2020-03-19 | 2021-09-23 | Board Of Regents, The University Of Texas System | A class of artificial sei layers for stabilizing lithium deposition in lithium batteries and related methods |
| US11817550B2 (en) | 2021-04-24 | 2023-11-14 | Ali Sadeghi | Method of synthesizing a solid-state electrolyte for use in a lithium-ion battery |
| US11817570B2 (en) | 2021-08-05 | 2023-11-14 | Ali Sadeghi | Method of manufacturing a solid-state lithium battery and a battery manufactured by the method |
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| US4307163A (en) | 1980-10-24 | 1981-12-22 | Ray-O-Vac Corporation | Lithium oxide halide solid state electrolyte |
| CN100595964C (zh) * | 2001-07-27 | 2010-03-24 | 麻省理工学院 | 电池结构、自组织结构及相关方法 |
| JP3889605B2 (ja) * | 2001-10-31 | 2007-03-07 | ニッポン高度紙工業株式会社 | 高イオン伝導性固体電解質及び該固体電解質を使用した電気化学システム |
| US6858337B2 (en) * | 2002-12-27 | 2005-02-22 | Utc Fuel Cells, Llc | Reversible fuel cell power plant |
| DE102004010892B3 (de) | 2004-03-06 | 2005-11-24 | Christian-Albrechts-Universität Zu Kiel | Chemisch stabiler fester Lithiumionenleiter |
| US7960057B2 (en) | 2004-05-17 | 2011-06-14 | Toyota Motor Engineering & Manufacturing North America, Inc. | Battery with molten salt electrolyte and phosphorus-containing cathode |
| JP4759256B2 (ja) * | 2004-11-29 | 2011-08-31 | 公立大学法人大阪府立大学 | 新規高イオン伝導性イオンガラス組成物およびその製造方法 |
| JP2007157413A (ja) * | 2005-12-02 | 2007-06-21 | Forestry & Forest Products Research Institute | 良好な高誘電性、焦電性、圧電性を有する電子部品材料 |
| JP5110850B2 (ja) * | 2006-10-31 | 2012-12-26 | 株式会社オハラ | リチウムイオン伝導性固体電解質およびその製造方法 |
| DE102007030604A1 (de) * | 2007-07-02 | 2009-01-08 | Weppner, Werner, Prof. Dr. | Ionenleiter mit Granatstruktur |
| US9246188B2 (en) * | 2011-02-14 | 2016-01-26 | Los Alamos National Security, Llc | Anti-perovskite solid electrolyte compositions |
| WO2012112229A2 (en) * | 2011-02-14 | 2012-08-23 | Los Alamos National Security, Llc | Anti-perovskite solid electrolyte compositions |
| JPWO2012161055A1 (ja) * | 2011-05-23 | 2014-07-31 | 国立大学法人 名古屋工業大学 | エネルギーデバイス及び蓄電デバイスの内の少なくともいずれか一方に用いられる材料の製造方法 |
| EP2783418B1 (en) | 2011-11-22 | 2016-07-13 | Robert Bosch GmbH | Lithium battery with charging redox couple |
| WO2013140607A1 (ja) * | 2012-03-23 | 2013-09-26 | 株式会社 東芝 | 固体電解質、固体電解質の製造方法、電池及び電池パック |
| US10008736B2 (en) * | 2012-10-23 | 2018-06-26 | Quantumscape Corporation | Method for forming and processing antiperovskite material doped with aluminum material |
| TWI623130B (zh) | 2012-11-21 | 2018-05-01 | 國立臺灣大學 | 鋰離子電池、具有摻雜之鋰離子電池電極結構及其製造方法 |
| WO2014159545A1 (en) * | 2013-03-13 | 2014-10-02 | Quantumscape Corporation | Iron, fluorine, sulfur compounds for cathodes |
| US10411293B2 (en) | 2014-02-26 | 2019-09-10 | Universidade Do Porto | Solid electrolyte glass for lithium or sodium ions conduction |
| US10044061B2 (en) | 2014-06-11 | 2018-08-07 | Los Alamos National Security, Llc | Methods for growth of lithium-rich antiperovskite electrolyte films and use thereof |
| CN106797052B (zh) | 2014-08-22 | 2019-04-02 | 内华达高等教育系统董事会代表拉斯维加斯内华达大学 | 钠反钙钛矿固体电解质组合物 |
| CN104536613B (zh) * | 2015-01-08 | 2017-11-24 | 厦门大学 | 聚偏氟乙烯压电纳米纤维触摸屏敏感元件的制备方法 |
| WO2016142927A1 (en) | 2015-03-12 | 2016-09-15 | Sousa Soares De Oliveira Braga Maria Helena | An electrochemical solid carbon-sulfur li-ion based device and uses thereof |
| WO2016157083A1 (en) | 2015-03-27 | 2016-10-06 | Sousa Soares De Oliveira Braga Maria Helena | An electrochemical solid carbon-sulfur na-ion based device and uses thereof |
| CN107750406B (zh) * | 2015-06-18 | 2021-02-12 | 德克萨斯大学系统董事会 | 水溶剂化玻璃/非晶态固体离子导体 |
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| JP2018530100A (ja) | 2018-10-11 |
| US20160368777A1 (en) | 2016-12-22 |
| US20180305216A1 (en) | 2018-10-25 |
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| US20180127280A1 (en) | 2018-05-10 |
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| KR20180095442A (ko) | 2018-08-27 |
| CN107750406A (zh) | 2018-03-02 |
| WO2016205064A1 (en) | 2016-12-22 |
| US9890048B2 (en) | 2018-02-13 |
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