CA2904373C - Water-soluble film for delayed release - Google Patents
Water-soluble film for delayed release Download PDFInfo
- Publication number
- CA2904373C CA2904373C CA2904373A CA2904373A CA2904373C CA 2904373 C CA2904373 C CA 2904373C CA 2904373 A CA2904373 A CA 2904373A CA 2904373 A CA2904373 A CA 2904373A CA 2904373 C CA2904373 C CA 2904373C
- Authority
- CA
- Canada
- Prior art keywords
- water
- soluble
- film
- packet
- pvoh
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
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- 230000003111 delayed effect Effects 0.000 title claims description 36
- 239000000203 mixture Substances 0.000 claims abstract description 139
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 120
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 117
- 239000007844 bleaching agent Substances 0.000 claims abstract description 110
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 106
- 238000000034 method Methods 0.000 claims abstract description 77
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims abstract description 66
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 11
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 64
- 239000007788 liquid Substances 0.000 claims description 58
- 239000003795 chemical substances by application Substances 0.000 claims description 47
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 43
- 238000000576 coating method Methods 0.000 claims description 40
- 239000011248 coating agent Substances 0.000 claims description 37
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 35
- 229920001577 copolymer Polymers 0.000 claims description 34
- -1 fatty acid esters Chemical class 0.000 claims description 33
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 32
- 238000004090 dissolution Methods 0.000 claims description 30
- 229940045872 sodium percarbonate Drugs 0.000 claims description 30
- 239000000463 material Substances 0.000 claims description 29
- 239000004094 surface-active agent Substances 0.000 claims description 29
- 239000000843 powder Substances 0.000 claims description 26
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 claims description 25
- 229920001223 polyethylene glycol Polymers 0.000 claims description 24
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 20
- 239000000194 fatty acid Substances 0.000 claims description 20
- 229930195729 fatty acid Natural products 0.000 claims description 20
- 239000004014 plasticizer Substances 0.000 claims description 20
- 239000002202 Polyethylene glycol Substances 0.000 claims description 19
- 235000011187 glycerol Nutrition 0.000 claims description 16
- 239000000654 additive Substances 0.000 claims description 15
- 150000004665 fatty acids Chemical class 0.000 claims description 13
- 229960004063 propylene glycol Drugs 0.000 claims description 13
- 235000013772 propylene glycol Nutrition 0.000 claims description 13
- 150000003839 salts Chemical class 0.000 claims description 13
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 12
- 125000000217 alkyl group Chemical group 0.000 claims description 12
- 238000009495 sugar coating Methods 0.000 claims description 11
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims description 10
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims description 10
- 235000005822 corn Nutrition 0.000 claims description 10
- 239000011734 sodium Substances 0.000 claims description 10
- 229910052708 sodium Inorganic materials 0.000 claims description 10
- 239000006188 syrup Substances 0.000 claims description 10
- 235000020357 syrup Nutrition 0.000 claims description 10
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 9
- 235000021552 granulated sugar Nutrition 0.000 claims description 9
- 238000000638 solvent extraction Methods 0.000 claims description 9
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 claims description 8
- 229920006026 co-polymeric resin Polymers 0.000 claims description 7
- 150000002148 esters Chemical class 0.000 claims description 7
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims description 6
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 6
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 6
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 6
- 230000000996 additive effect Effects 0.000 claims description 6
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 6
- 239000000600 sorbitol Substances 0.000 claims description 6
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- 150000002170 ethers Chemical class 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- QWGRWMMWNDWRQN-UHFFFAOYSA-N 2-methylpropane-1,3-diol Chemical compound OCC(C)CO QWGRWMMWNDWRQN-UHFFFAOYSA-N 0.000 claims description 4
- 125000005210 alkyl ammonium group Chemical group 0.000 claims description 4
- 239000001087 glyceryl triacetate Substances 0.000 claims description 4
- 235000013773 glyceryl triacetate Nutrition 0.000 claims description 4
- 229960002622 triacetin Drugs 0.000 claims description 4
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 claims description 3
- KMZHZAAOEWVPSE-UHFFFAOYSA-N 2,3-dihydroxypropyl acetate Chemical compound CC(=O)OCC(O)CO KMZHZAAOEWVPSE-UHFFFAOYSA-N 0.000 claims description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 3
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 3
- 229920001213 Polysorbate 20 Polymers 0.000 claims description 3
- 229920001214 Polysorbate 60 Polymers 0.000 claims description 3
- 229920002642 Polysorbate 65 Polymers 0.000 claims description 3
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 3
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 claims description 3
- UWHCKJMYHZGTIT-UHFFFAOYSA-N Tetraethylene glycol, Natural products OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 claims description 3
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 claims description 3
- DOOTYTYQINUNNV-UHFFFAOYSA-N Triethyl citrate Chemical compound CCOC(=O)CC(O)(C(=O)OCC)CC(=O)OCC DOOTYTYQINUNNV-UHFFFAOYSA-N 0.000 claims description 3
- 235000019270 ammonium chloride Nutrition 0.000 claims description 3
- 235000019437 butane-1,3-diol Nutrition 0.000 claims description 3
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 claims description 3
- 239000004310 lactic acid Substances 0.000 claims description 3
- 235000014655 lactic acid Nutrition 0.000 claims description 3
- 235000010445 lecithin Nutrition 0.000 claims description 3
- 239000000787 lecithin Substances 0.000 claims description 3
- 229940067606 lecithin Drugs 0.000 claims description 3
- ONHFWHCMZAJCFB-UHFFFAOYSA-N myristamine oxide Chemical compound CCCCCCCCCCCCCC[N+](C)(C)[O-] ONHFWHCMZAJCFB-UHFFFAOYSA-N 0.000 claims description 3
- 229920000570 polyether Polymers 0.000 claims description 3
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 claims description 3
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 claims description 3
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 3
- 239000000244 polyoxyethylene sorbitan monooleate Substances 0.000 claims description 3
- 235000010989 polyoxyethylene sorbitan monostearate Nutrition 0.000 claims description 3
- 239000001818 polyoxyethylene sorbitan monostearate Substances 0.000 claims description 3
- 235000010988 polyoxyethylene sorbitan tristearate Nutrition 0.000 claims description 3
- 239000001816 polyoxyethylene sorbitan tristearate Substances 0.000 claims description 3
- 229940068977 polysorbate 20 Drugs 0.000 claims description 3
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- 229920000053 polysorbate 80 Polymers 0.000 claims description 3
- 150000003856 quaternary ammonium compounds Chemical class 0.000 claims description 3
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 3
- 239000001069 triethyl citrate Substances 0.000 claims description 3
- 235000013769 triethyl citrate Nutrition 0.000 claims description 3
- VMYFZRTXGLUXMZ-UHFFFAOYSA-N triethyl citrate Natural products CCOC(=O)C(O)(C(=O)OCC)C(=O)OCC VMYFZRTXGLUXMZ-UHFFFAOYSA-N 0.000 claims description 3
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims description 3
- 241000209149 Zea Species 0.000 claims 2
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- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 11
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- 102000004190 Enzymes Human genes 0.000 description 11
- 229940088598 enzyme Drugs 0.000 description 11
- 235000019441 ethanol Nutrition 0.000 description 11
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- 125000004432 carbon atom Chemical group C* 0.000 description 10
- 238000009472 formulation Methods 0.000 description 10
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- 230000007423 decrease Effects 0.000 description 8
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- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
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- 229910052700 potassium Inorganic materials 0.000 description 7
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- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
- C11D17/045—Multi-compartment
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Wrappers (AREA)
- Detergent Compositions (AREA)
- Packages (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201361801807P | 2013-03-15 | 2013-03-15 | |
| US61/801,807 | 2013-03-15 | ||
| PCT/US2014/026305 WO2014151718A2 (en) | 2013-03-15 | 2014-03-13 | Water-soluble film for delayed release |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2904373A1 CA2904373A1 (en) | 2014-09-25 |
| CA2904373C true CA2904373C (en) | 2017-01-17 |
Family
ID=50631022
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2904373A Active CA2904373C (en) | 2013-03-15 | 2014-03-13 | Water-soluble film for delayed release |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP2970839B1 (ja) |
| JP (2) | JP6246891B2 (ja) |
| KR (1) | KR101711455B1 (ja) |
| CN (1) | CN105143425B (ja) |
| AU (1) | AU2014236931B2 (ja) |
| BR (1) | BR112015023216B1 (ja) |
| CA (1) | CA2904373C (ja) |
| MX (1) | MX346270B (ja) |
| WO (1) | WO2014151718A2 (ja) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI697517B (zh) * | 2014-10-03 | 2020-07-01 | 美商摩諾索公司 | 可降解材料及由彼所製造之包裝 |
| US10815346B2 (en) * | 2015-03-27 | 2020-10-27 | Monosol, Llc | Water soluble film, packets employing the film, and methods of making and using same |
| DE102015217759A1 (de) * | 2015-09-16 | 2017-03-16 | Henkel Ag & Co. Kgaa | Wasserlöslicher Behälter mit einer Beschichtung |
| JP7161277B2 (ja) | 2015-11-19 | 2022-10-26 | 三菱ケミカル株式会社 | 水溶性フィルム及び薬剤包装体 |
| WO2017132540A1 (en) * | 2016-01-29 | 2017-08-03 | Monosol, Llc | Water soluble film for thermoforming deep-drawn profiles and thermoformed articles comprising same |
| CA3019343C (en) * | 2016-04-13 | 2021-11-09 | The Procter & Gamble Company | Pouches having water-soluble films made from polyvinyl alcohol polymer blends |
| CA2964137C (en) * | 2016-04-13 | 2019-08-20 | The Procter & Gamble Company | Container systems with water-soluble pouches |
| PL3443030T3 (pl) | 2016-04-13 | 2022-10-10 | Monosol, Llc | Folia rozpuszczalna w wodzie, opakowania z folią oraz sposoby jej wytwarzania i stosowania |
| JP2019513871A (ja) * | 2016-04-13 | 2019-05-30 | モノソル リミテッド ライアビリティ カンパニー | 水溶性フィルム、パウチ、及び容器システム |
| US10443024B2 (en) | 2016-06-13 | 2019-10-15 | Monosol, Llc | Water-soluble unit dose articles made from a combination of different films |
| JP7059205B2 (ja) | 2016-06-13 | 2022-04-25 | モノソル リミテッド ライアビリティ カンパニー | 水溶性の密封強度を改善するための第１のフィルムおよび第２のフィルムの使用 |
| CA2970575A1 (en) * | 2016-06-13 | 2017-08-31 | The Procter & Gamble Company | Water-soluble unit dose articles made from a combination of different films and containing household care compositions |
| US10377980B2 (en) * | 2016-06-13 | 2019-08-13 | The Procter & Gamble Company | Process of washing fabrics |
| WO2017218448A1 (en) * | 2016-06-13 | 2017-12-21 | The Procter & Gamble Company | Use of a first film and a second film to improve seal strength of a water-soluble unit dose article |
| US10745655B2 (en) | 2016-06-13 | 2020-08-18 | The Procter & Gamble Company | Water-soluble unit dose articles made from a combination of different films and containing household care compositions |
| US10899518B2 (en) | 2016-06-13 | 2021-01-26 | Monosol, Llc | Water-soluble packets |
| CA3023508A1 (en) * | 2016-06-13 | 2017-12-21 | The Procter & Gamble Company | Water-soluble unit dose articles made from a combination of different films and containing household care compositions |
| JP6749424B2 (ja) * | 2016-06-13 | 2020-09-02 | ザ プロクター アンド ギャンブル カンパニーＴｈｅ Ｐｒｏｃｔｅｒ ＆ Ｇａｍｂｌｅ Ｃｏｍｐａｎｙ | 消費者の洗剤投与体験を向上させる、水溶性単位用量物品の使用 |
| CA3029969A1 (en) | 2016-08-01 | 2018-02-08 | Monosol, Llc | Plasticizer blend for chlorine stability of water-soluble films |
| JP7162010B2 (ja) * | 2017-05-19 | 2022-10-27 | ダウ グローバル テクノロジーズ エルエルシー | 水溶性膜用シーリング組成物およびその組成物または膜の使用方法 |
| DE102018221674A1 (de) * | 2018-12-13 | 2020-06-18 | Henkel Ag & Co. Kgaa | Vorrichtung und Verfahren zur Herstellung einer wasserlöslichen Hülle sowie diese wasserlösliche Hülle enthaltene Wasch- oder Reinigungsmittelportionen |
| DE102018221671A1 (de) * | 2018-12-13 | 2020-06-18 | Henkel Ag & Co. Kgaa | Vorrichtung und Verfahren zur Herstellung einer wasserlöslichen Hülle sowie diese wasserlösliche Hülle enthaltene Wasch- oder Reinigungsmittelportionen mit viskoelastischer, festförmiger Füllsubstanz |
| EP3962831A1 (en) * | 2019-04-30 | 2022-03-09 | L'oreal | Dissolvable packages of pre-measured powdered hair bleach |
| KR102168668B1 (ko) * | 2020-02-14 | 2020-10-21 | 김종남 | 시트 비누 및 그 제조방법 |
| EP4015567A1 (en) * | 2020-12-15 | 2022-06-22 | Monosol, LLC | Water-soluble films, water-soluble unit dose articles, and methods of making and using the same |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AT397345B (de) * | 1990-04-04 | 1994-03-25 | Chemiefaser Lenzing Ag | Pharmazeutisches präparat mit verzögerter wirkstofffreisetzung auf basis von hemicellulosen |
| FR2666348B1 (fr) * | 1990-08-28 | 1994-06-03 | Nln Sa | Detergent en sachet-dose pour le nettoyage du linge. |
| FR2666349B1 (fr) * | 1990-08-28 | 1994-06-03 | Nln Sa | Detergent en sachet-dose pour le nettoyage de la vaisselle. |
| US5547948A (en) * | 1995-01-17 | 1996-08-20 | American Home Products Corporation | Controlled release of steroids from sugar coatings |
| JPH11116467A (ja) * | 1997-10-08 | 1999-04-27 | Taisho Pharmaceut Co Ltd | 糖衣錠 |
| GB2361687A (en) * | 2000-04-28 | 2001-10-31 | Procter & Gamble | Layered water soluble pouch for detergents |
| GB2361688A (en) * | 2000-04-28 | 2001-10-31 | Procter & Gamble | Multi-compartment water soluble pouch for detergents |
| US6831051B2 (en) * | 2000-04-28 | 2004-12-14 | The Procter & Gamble Company | Pouched compositions |
| EP1305396B1 (de) * | 2000-07-14 | 2005-11-02 | Henkel Kommanditgesellschaft auf Aktien | Kompartiment-hohlkörper enthaltend wasch-, reinigungs- oder spülmittelportion |
| JP5504312B2 (ja) * | 2000-10-06 | 2014-05-28 | 武田薬品工業株式会社 | 薄層糖衣錠およびその製造方法 |
| US8728449B2 (en) | 2005-01-22 | 2014-05-20 | Monosol Llc | Water-soluble film article having salt layer, and method of making the same |
| ATE481444T1 (de) * | 2005-05-13 | 2010-10-15 | Procter & Gamble | Funktionalisierte folien |
| US7745517B2 (en) * | 2006-05-02 | 2010-06-29 | Sekisui Specialty Chemicals America, Llc | Polyvinyl alcohol films with improved resistance to oxidizing chemicals |
| EP2014756B1 (en) * | 2007-07-02 | 2011-03-30 | The Procter & Gamble Company | Laundry multi-compartment pouch composition |
| JP2011511123A (ja) * | 2008-01-31 | 2011-04-07 | ザ プロクター アンド ギャンブル カンパニー | キトサンのアセチル化 |
| US20100125046A1 (en) * | 2008-11-20 | 2010-05-20 | Denome Frank William | Cleaning products |
| RU2546651C2 (ru) * | 2010-01-29 | 2015-04-10 | МОНОСОЛ, ЭлЭлСи | Водорастворимая пленка с улучшенной растворимостью и улучшенными механическими свойствами, а также пакеты, изготовленные из нее |
| WO2012087821A1 (en) * | 2010-12-22 | 2012-06-28 | Sekisui Specialty Chemicals America, Llc | Cold water soluble polyvinyl alcohol/alkyl acrylate copolymers and films thereof |
| US8802612B2 (en) * | 2012-02-09 | 2014-08-12 | Aicello Corporation | Detergent packet |
-
2014
- 2014-03-13 KR KR1020157029037A patent/KR101711455B1/ko active IP Right Grant
- 2014-03-13 JP JP2016502099A patent/JP6246891B2/ja active Active
- 2014-03-13 CN CN201480015973.0A patent/CN105143425B/zh active Active
- 2014-03-13 CA CA2904373A patent/CA2904373C/en active Active
- 2014-03-13 MX MX2015012296A patent/MX346270B/es active IP Right Grant
- 2014-03-13 BR BR112015023216-7A patent/BR112015023216B1/pt active IP Right Grant
- 2014-03-13 EP EP14721078.5A patent/EP2970839B1/en active Active
- 2014-03-13 WO PCT/US2014/026305 patent/WO2014151718A2/en active Application Filing
- 2014-03-13 AU AU2014236931A patent/AU2014236931B2/en not_active Ceased
-
2017
- 2017-11-15 JP JP2017220111A patent/JP2018030649A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| BR112015023216A2 (pt) | 2017-07-18 |
| EP2970839B1 (en) | 2017-02-22 |
| KR101711455B1 (ko) | 2017-03-02 |
| WO2014151718A3 (en) | 2015-01-08 |
| KR20150126411A (ko) | 2015-11-11 |
| JP2018030649A (ja) | 2018-03-01 |
| CN105143425B (zh) | 2019-04-09 |
| AU2014236931B2 (en) | 2016-09-29 |
| CA2904373A1 (en) | 2014-09-25 |
| MX346270B (es) | 2017-03-13 |
| EP2970839A2 (en) | 2016-01-20 |
| BR112015023216B1 (pt) | 2022-05-31 |
| CN105143425A (zh) | 2015-12-09 |
| MX2015012296A (es) | 2016-05-16 |
| WO2014151718A2 (en) | 2014-09-25 |
| JP6246891B2 (ja) | 2017-12-13 |
| JP2016520668A (ja) | 2016-07-14 |
| AU2014236931A1 (en) | 2015-10-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request |
Effective date: 20150904 |