CA2891748C - Tiger stripe modifier - Google Patents
Tiger stripe modifier Download PDFInfo
- Publication number
- CA2891748C CA2891748C CA2891748A CA2891748A CA2891748C CA 2891748 C CA2891748 C CA 2891748C CA 2891748 A CA2891748 A CA 2891748A CA 2891748 A CA2891748 A CA 2891748A CA 2891748 C CA2891748 C CA 2891748C
- Authority
- CA
- Canada
- Prior art keywords
- polypropylene composition
- heterophasic polypropylene
- heco1
- fraction
- heterophasic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 241000282376 Panthera tigris Species 0.000 title abstract description 3
- 239000003607 modifier Substances 0.000 title abstract description 3
- -1 polypropylene Polymers 0.000 claims abstract description 183
- 239000000203 mixture Substances 0.000 claims abstract description 166
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims abstract description 165
- 239000004743 Polypropylene Substances 0.000 claims abstract description 162
- 229920001155 polypropylene Polymers 0.000 claims abstract description 159
- 229920001577 copolymer Polymers 0.000 claims abstract description 132
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims abstract description 74
- 239000008096 xylene Substances 0.000 claims abstract description 74
- 229920001384 propylene homopolymer Polymers 0.000 claims abstract description 42
- 101100023124 Schizosaccharomyces pombe (strain 972 / ATCC 24843) mfr2 gene Proteins 0.000 claims abstract description 39
- 239000000155 melt Substances 0.000 claims abstract description 29
- 229920000098 polyolefin Polymers 0.000 claims description 57
- 239000005977 Ethylene Substances 0.000 claims description 32
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 31
- 239000007924 injection Substances 0.000 claims description 30
- 238000002347 injection Methods 0.000 claims description 30
- 239000011256 inorganic filler Substances 0.000 claims description 18
- 229910003475 inorganic filler Inorganic materials 0.000 claims description 18
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 claims description 16
- 238000009826 distribution Methods 0.000 claims description 14
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 claims description 8
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- 229910010066 TiC14 Inorganic materials 0.000 description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
- KOFGHHIZTRGVAF-UHFFFAOYSA-N n-ethyl-n-triethoxysilylethanamine Chemical compound CCO[Si](OCC)(OCC)N(CC)CC KOFGHHIZTRGVAF-UHFFFAOYSA-N 0.000 description 5
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- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 3
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 3
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- JWCYDYZLEAQGJJ-UHFFFAOYSA-N dicyclopentyl(dimethoxy)silane Chemical compound C1CCCC1[Si](OC)(OC)C1CCCC1 JWCYDYZLEAQGJJ-UHFFFAOYSA-N 0.000 description 3
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- 125000004122 cyclic group Chemical group 0.000 description 1
- 125000000392 cycloalkenyl group Chemical group 0.000 description 1
- UVJHQYIOXKWHFD-UHFFFAOYSA-N cyclohexa-1,4-diene Chemical compound C1C=CCC=C1 UVJHQYIOXKWHFD-UHFFFAOYSA-N 0.000 description 1
- HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- VHPUZTHRFWIGAW-UHFFFAOYSA-N dimethoxy-di(propan-2-yl)silane Chemical compound CO[Si](OC)(C(C)C)C(C)C VHPUZTHRFWIGAW-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical compound C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- 238000010191 image analysis Methods 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229910052622 kaolinite Inorganic materials 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- SJYNFBVQFBRSIB-UHFFFAOYSA-N norbornadiene Chemical compound C1=CC2C=CC1C2 SJYNFBVQFBRSIB-UHFFFAOYSA-N 0.000 description 1
- 150000002848 norbornenes Chemical class 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 229910052615 phyllosilicate Inorganic materials 0.000 description 1
- 239000004597 plastic additive Substances 0.000 description 1
- 238000013001 point bending Methods 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920005653 propylene-ethylene copolymer Polymers 0.000 description 1
- 238000011002 quantification Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 239000012488 sample solution Substances 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000012748 slip agent Substances 0.000 description 1
- 229910021647 smectite Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Ethene-propene or ethene-propene-diene copolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/02—Heterophasic composition
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP12194766.7 | 2012-11-29 | ||
| EP12194766.7A EP2738215B1 (en) | 2012-11-29 | 2012-11-29 | Tiger stripe modifier |
| PCT/EP2013/075014 WO2014083129A1 (en) | 2012-11-29 | 2013-11-28 | Tiger stripe modifier |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2891748A1 CA2891748A1 (en) | 2014-06-05 |
| CA2891748C true CA2891748C (en) | 2016-06-07 |
Family
ID=47226061
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2891748A Expired - Fee Related CA2891748C (en) | 2012-11-29 | 2013-11-28 | Tiger stripe modifier |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US9388304B2 (OSRAM) |
| EP (1) | EP2738215B1 (OSRAM) |
| JP (1) | JP5998290B2 (OSRAM) |
| KR (1) | KR101594284B1 (OSRAM) |
| CN (1) | CN104884525B (OSRAM) |
| BR (1) | BR112015011546B1 (OSRAM) |
| CA (1) | CA2891748C (OSRAM) |
| EA (1) | EA029895B1 (OSRAM) |
| ES (1) | ES2543642T3 (OSRAM) |
| IN (1) | IN2015DN03906A (OSRAM) |
| MX (1) | MX2015006225A (OSRAM) |
| WO (1) | WO2014083129A1 (OSRAM) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2542435T3 (es) * | 2012-11-29 | 2015-08-05 | Borealis Ag | Modificador del defecto de rayas de tigre |
| JP6490303B2 (ja) | 2015-10-06 | 2019-03-27 | ボレアリス エージー | 自動車適用のためのポリプロピレン組成物 |
| EP3159377B1 (en) * | 2015-10-23 | 2021-07-14 | Borealis AG | Heterophasic composition |
| EP3494175B1 (en) * | 2016-08-03 | 2020-06-10 | Borealis AG | Fiber reinforced polypropylene composite |
| ES2897714T3 (es) | 2016-12-01 | 2022-03-02 | Borealis Ag | Composición de polipropileno expandido |
| JP7004499B2 (ja) | 2016-12-20 | 2022-01-21 | サンアロマー株式会社 | マスターバッチ組成物 |
| EP3882309A1 (en) * | 2017-02-03 | 2021-09-22 | Borealis AG | Use of a polymer composition for the production of articles with improved paintability and surface appearance |
| JP7088165B2 (ja) * | 2017-03-14 | 2022-06-21 | 住友化学株式会社 | ヘテロファジックプロピレン重合材料及びプロピレン系樹脂組成物 |
| ES2959196T3 (es) * | 2017-06-29 | 2024-02-21 | Borealis Ag | Composición de polipropileno con excelente rendimiento al impacto |
| UA123615C2 (uk) * | 2017-06-30 | 2021-04-28 | Бореаліс Аґ | Поліпропіленова композиція з відмінним зовнішнім виглядом |
| EP3421538B1 (en) * | 2017-06-30 | 2021-03-17 | Borealis AG | Polyolefin composition with improved surface appearance |
| US10907036B2 (en) * | 2017-10-13 | 2021-02-02 | Borealis Ag | Multimodal random heterophasic polypropylene composition |
| EP3728461B8 (en) * | 2017-12-20 | 2022-03-30 | Borealis AG | Heterophasic polypropylene composition |
| KR102530392B1 (ko) * | 2018-10-04 | 2023-05-10 | 보레알리스 아게 | 업그레이드된 재활용되는 상대적으로 폴리에틸렌-풍부 폴리올레핀 물질 |
| CN112714781A (zh) * | 2018-10-04 | 2021-04-27 | 博里利斯股份公司 | 改质的循环的富聚丙烯的聚烯烃材料 |
| WO2021080803A1 (en) | 2019-10-22 | 2021-04-29 | Exxonmobil Chemical Patents Inc. | Impact copolymer compositions |
| CN113004617B (zh) * | 2021-03-09 | 2022-07-12 | 万华化学（宁波）有限公司 | 一种抗虎皮纹的免喷涂底护板用聚丙烯复合材料及其制备方法 |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FI80055C (fi) | 1986-06-09 | 1990-04-10 | Neste Oy | Foerfarande foer framstaellning av katalytkomponenter foer polymerisation av olefiner. |
| IT1243188B (it) * | 1990-08-01 | 1994-05-24 | Himont Inc | Composizioni poliolefiniche elastoplastiche |
| FI86866C (fi) | 1990-12-19 | 1992-10-26 | Neste Oy | Foerfarande foer modifiering av katalysatorer avsedda foer polymerisation av olefiner |
| FI86867C (fi) | 1990-12-28 | 1992-10-26 | Neste Oy | Flerstegsprocess foer framstaellning av polyeten |
| FI88048C (fi) | 1991-05-09 | 1993-03-25 | Neste Oy | Grovkornig polyolefin, dess framstaellningsmetod och en i metoden anvaend katalysator |
| FI88047C (fi) | 1991-05-09 | 1993-03-25 | Neste Oy | Pao tvenne elektrondonorer baserad katalysator foer polymerisation av olefiner |
| FI111848B (fi) | 1997-06-24 | 2003-09-30 | Borealis Tech Oy | Menetelmä ja laitteisto propeenin homo- ja kopolymeerien valmistamiseksi |
| FI980342A0 (fi) | 1997-11-07 | 1998-02-13 | Borealis As | Polymerroer och -roerkopplingar |
| FI974175A7 (fi) | 1997-11-07 | 1999-05-08 | Borealis As | Menetelmä polypropeenin valmistamiseksi |
| FI991057A0 (fi) | 1999-05-07 | 1999-05-07 | Borealis As | Korkean jäykkyyden propeenipolymeerit ja menetelmä niiden valmistamiseksi |
| US6586531B2 (en) * | 2000-10-04 | 2003-07-01 | Basell Poliolefine Italia S.P.A. | Polyolefin masterbatch and composition suitable for injection molding |
| DE60239297D1 (de) | 2002-06-25 | 2011-04-07 | Borealis Tech Oy | Polyolefin mit verbesserter kratzfestigkeit und verfahren zu seiner herstelung |
| KR101030711B1 (ko) * | 2002-08-19 | 2011-04-26 | 우베 고산 가부시키가이샤 | α-올레핀의 중합 또는 공중합에 사용되는 α-올레핀의중합 또는 공중합용 촉매, 그 촉매 성분 및 그 촉매를사용한 α-올레핀의 중합방법 |
| EP1484343A1 (en) | 2003-06-06 | 2004-12-08 | Universiteit Twente | Process for the catalytic polymerization of olefins, a reactor system and its use in the same process |
| JP2007217633A (ja) * | 2006-02-20 | 2007-08-30 | Prime Polymer:Kk | 成形体及びその製造方法 |
| KR101693062B1 (ko) * | 2009-03-23 | 2017-01-04 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 사출 성형에 적합한 폴리올레핀 마스터배치 및 조성물 |
| ES2365797T3 (es) | 2009-06-22 | 2011-10-11 | Borealis Ag | Composición copolímera de polipropileno heterofásico. |
| EP2397517B1 (en) * | 2010-06-16 | 2012-12-26 | Borealis AG | Propylene polymer compositions having superior hexane extractables/impact balance |
-
2012
- 2012-11-29 EP EP12194766.7A patent/EP2738215B1/en active Active
- 2012-11-29 ES ES12194766.7T patent/ES2543642T3/es active Active
-
2013
- 2013-11-28 KR KR1020157015621A patent/KR101594284B1/ko active Active
- 2013-11-28 EA EA201500541A patent/EA029895B1/ru not_active IP Right Cessation
- 2013-11-28 US US14/443,797 patent/US9388304B2/en active Active
- 2013-11-28 CN CN201380060969.1A patent/CN104884525B/zh active Active
- 2013-11-28 BR BR112015011546-2A patent/BR112015011546B1/pt active IP Right Grant
- 2013-11-28 WO PCT/EP2013/075014 patent/WO2014083129A1/en active Application Filing
- 2013-11-28 MX MX2015006225A patent/MX2015006225A/es unknown
- 2013-11-28 JP JP2015544463A patent/JP5998290B2/ja active Active
- 2013-11-28 IN IN3906DEN2015 patent/IN2015DN03906A/en unknown
- 2013-11-28 CA CA2891748A patent/CA2891748C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN104884525B (zh) | 2016-08-31 |
| JP5998290B2 (ja) | 2016-09-28 |
| KR101594284B1 (ko) | 2016-02-15 |
| ES2543642T3 (es) | 2015-08-20 |
| CN104884525A (zh) | 2015-09-02 |
| BR112015011546A2 (pt) | 2017-07-11 |
| US20150299443A1 (en) | 2015-10-22 |
| WO2014083129A1 (en) | 2014-06-05 |
| JP2015535549A (ja) | 2015-12-14 |
| US9388304B2 (en) | 2016-07-12 |
| MX2015006225A (es) | 2015-08-14 |
| EA201500541A1 (ru) | 2015-11-30 |
| EP2738215A1 (en) | 2014-06-04 |
| IN2015DN03906A (OSRAM) | 2015-10-02 |
| EA029895B1 (ru) | 2018-05-31 |
| BR112015011546B1 (pt) | 2021-08-24 |
| KR20150074211A (ko) | 2015-07-01 |
| EP2738215B1 (en) | 2015-05-27 |
| CA2891748A1 (en) | 2014-06-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request |
Effective date: 20150515 |
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| MKLA | Lapsed |
Effective date: 20201130 |