CA2882746C - Vapor phase preparation of fluorided solid oxides - Google Patents
Vapor phase preparation of fluorided solid oxides Download PDFInfo
- Publication number
- CA2882746C CA2882746C CA2882746A CA2882746A CA2882746C CA 2882746 C CA2882746 C CA 2882746C CA 2882746 A CA2882746 A CA 2882746A CA 2882746 A CA2882746 A CA 2882746A CA 2882746 C CA2882746 C CA 2882746C
- Authority
- CA
- Canada
- Prior art keywords
- solid oxide
- fluorided
- peak
- temperature
- silica
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/617—500-1000 m2/g
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/12—Silica and alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/638—Pore volume more than 1.0 ml/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/22—Halogenating
- B01J37/26—Fluorinating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Crystallography & Structural Chemistry (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/594,906 US8916494B2 (en) | 2012-08-27 | 2012-08-27 | Vapor phase preparation of fluorided solid oxides |
| US13/594,906 | 2012-08-27 | ||
| PCT/US2013/056606 WO2014035875A1 (en) | 2012-08-27 | 2013-08-26 | Vapor phase preparation of fluorided solid oxides |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2882746A1 CA2882746A1 (en) | 2014-03-06 |
| CA2882746C true CA2882746C (en) | 2017-08-15 |
Family
ID=49165837
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2882746A Active CA2882746C (en) | 2012-08-27 | 2013-08-26 | Vapor phase preparation of fluorided solid oxides |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US8916494B2 (enExample) |
| EP (1) | EP2888045B1 (enExample) |
| KR (1) | KR102071742B1 (enExample) |
| CN (1) | CN103626130B (enExample) |
| BR (1) | BR112015004032B1 (enExample) |
| CA (1) | CA2882746C (enExample) |
| ES (1) | ES2718646T3 (enExample) |
| IN (1) | IN2015DN01588A (enExample) |
| MX (1) | MX381789B (enExample) |
| SA (1) | SA515360072B1 (enExample) |
| SG (1) | SG11201501350UA (enExample) |
| WO (1) | WO2014035875A1 (enExample) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2501081B (en) | 2012-04-11 | 2017-08-30 | Sca Ipla Holdings Inc | Telecommunications apparatus and methods |
| WO2016028277A1 (en) * | 2014-08-19 | 2016-02-25 | Univation Technologies, Llc | Fluorinated catalyst supports and catalyst systems |
| SG11201701265UA (en) * | 2014-08-19 | 2017-03-30 | Univation Tech Llc | Fluorinated catalyst supports and catalyst systems |
| US10208139B2 (en) | 2014-08-19 | 2019-02-19 | Univation Technologies, Llc | Fluorinated catalyst supports and catalyst systems |
| EP3320004B2 (en) | 2015-07-08 | 2023-12-06 | Chevron Phillips Chemical Company LP | Ziegler-natta-metallocene dual catalyst systems with activator-supports |
| CN105111040B (zh) * | 2015-08-18 | 2017-07-25 | 巨化集团技术中心 | 一种偏氟乙烯为原料合成四氟丙烯HFO1234yf的方法 |
| US9650459B2 (en) | 2015-09-09 | 2017-05-16 | Chevron Phillips Chemical Company Lp | Methods for controlling die swell in dual catalyst olefin polymerization systems |
| US9758599B2 (en) | 2015-09-24 | 2017-09-12 | Chevron Phillips Chemical Company Lp | Heterogeneous Ziegler-Natta catalysts with fluorided silica-coated alumina |
| US9845367B2 (en) | 2015-09-24 | 2017-12-19 | Chevron Phillips Chemical Company Lp | Heterogeneous Ziegler-Natta catalysts with fluorided silica-coated alumina |
| US9540457B1 (en) | 2015-09-24 | 2017-01-10 | Chevron Phillips Chemical Company Lp | Ziegler-natta—metallocene dual catalyst systems with activator-supports |
| US9505856B1 (en) * | 2016-01-13 | 2016-11-29 | Chevron Phillips Chemical Company Lp | Methods for making fluorided chromium (VI) catalysts, and polymerization processes using the same |
| KR101856202B1 (ko) * | 2016-07-12 | 2018-05-10 | 대림산업 주식회사 | 개질된 담체를 포함하는 폴리올레핀 중합 촉매 및 이를 이용한 폴리올레핀의 제조 방법 |
| CA3112425A1 (en) | 2018-09-24 | 2020-04-02 | Chevron Phillips Chemical Company Lp | Methods for making supported chromium catalysts with increased polymerization activity |
| US11420196B2 (en) | 2018-09-27 | 2022-08-23 | Chevron Phillips Chemical Company Lp | Processes for producing fluorided solid oxides and uses thereof in metallocene-based catalyst systems |
| WO2023235799A1 (en) * | 2022-06-02 | 2023-12-07 | Chevron Phillips Chemical Company Lp | High porosity fluorided silica-coated alumina activator-supports and uses thereof in metallocene-based catalyst systems for olefin polymerization |
| CN115010113B (zh) * | 2022-06-24 | 2024-02-13 | 山东重山光电材料股份有限公司 | 一种氟化碳材料及其应用和锂电池 |
| US11920089B1 (en) | 2023-05-11 | 2024-03-05 | Chevron Phillips Chemical Company Lp | Solid oxide and chemically-treated solid oxide catalysts for the pyrolysis of polyethylene |
| WO2024233733A2 (en) | 2023-05-11 | 2024-11-14 | Chevron Phillips Chemical Company Lp | Solid oxide and chemically-treated solid oxide catalysts for the pyrolysis of polyethylene |
Family Cites Families (103)
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|---|---|---|---|---|
| DE1051004B (de) | 1953-01-27 | 1959-02-19 | Phillips Petroleum Company, Bartlesville, OkIa. (V. St. A.) | Verfahren zur Herstellung von hochmolekularen Olefinpolymeren oder Olefinmischpolymeren |
| US3226205A (en) | 1960-10-03 | 1965-12-28 | Phillips Petroleum Co | Reactor impeller with feed inlet along shaft |
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| US3119569A (en) | 1962-03-28 | 1964-01-28 | Baricordi Antonio | Grinding apparatus |
| US3225023A (en) | 1962-11-30 | 1965-12-21 | Phillips Petroleum Co | Process for controlling melt index |
| US3242099A (en) | 1964-03-27 | 1966-03-22 | Union Carbide Corp | Olefin polymerization catalysts |
| US3622521A (en) | 1967-08-21 | 1971-11-23 | Phillips Petroleum Co | Olefin polymerization with chromium and titanium-containing compounds |
| US3625864A (en) | 1969-04-23 | 1971-12-07 | Phillips Petroleum Co | Polymerization catalyst system additives |
| US3843747A (en) | 1970-06-25 | 1974-10-22 | Texaco Inc | Isomerization of c10-c14 hydrocarbons with fluorided metal-alumina catalyst |
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| US7312283B2 (en) | 2005-08-22 | 2007-12-25 | Chevron Phillips Chemical Company Lp | Polymerization catalysts and process for producing bimodal polymers in a single reactor |
| US7226886B2 (en) | 2005-09-15 | 2007-06-05 | Chevron Phillips Chemical Company, L.P. | Polymerization catalysts and process for producing bimodal polymers in a single reactor |
| US7619047B2 (en) | 2006-02-22 | 2009-11-17 | Chevron Phillips Chemical Company, Lp | Dual metallocene catalysts for polymerization of bimodal polymers |
| US7884163B2 (en) | 2008-03-20 | 2011-02-08 | Chevron Phillips Chemical Company Lp | Silica-coated alumina activator-supports for metallocene catalyst compositions |
| US8114946B2 (en) | 2008-12-18 | 2012-02-14 | Chevron Phillips Chemical Company Lp | Process for producing broader molecular weight distribution polymers with a reverse comonomer distribution and low levels of long chain branches |
| US8309485B2 (en) | 2009-03-09 | 2012-11-13 | Chevron Phillips Chemical Company Lp | Methods for producing metal-containing sulfated activator-supports |
| US9289739B2 (en) | 2009-06-23 | 2016-03-22 | Chevron Philips Chemical Company Lp | Continuous preparation of calcined chemically-treated solid oxides |
-
2012
- 2012-08-27 US US13/594,906 patent/US8916494B2/en active Active
-
2013
- 2013-08-15 CN CN201310356587.5A patent/CN103626130B/zh active Active
- 2013-08-26 BR BR112015004032-2A patent/BR112015004032B1/pt active IP Right Grant
- 2013-08-26 IN IN1588DEN2015 patent/IN2015DN01588A/en unknown
- 2013-08-26 CA CA2882746A patent/CA2882746C/en active Active
- 2013-08-26 SG SG11201501350UA patent/SG11201501350UA/en unknown
- 2013-08-26 MX MX2015002472A patent/MX381789B/es unknown
- 2013-08-26 KR KR1020157004587A patent/KR102071742B1/ko active Active
- 2013-08-26 EP EP13762317.9A patent/EP2888045B1/en active Active
- 2013-08-26 ES ES13762317T patent/ES2718646T3/es active Active
- 2013-08-26 WO PCT/US2013/056606 patent/WO2014035875A1/en not_active Ceased
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Also Published As
| Publication number | Publication date |
|---|---|
| SG11201501350UA (en) | 2015-03-30 |
| CN103626130A (zh) | 2014-03-12 |
| SA515360072B1 (ar) | 2015-09-28 |
| CA2882746A1 (en) | 2014-03-06 |
| KR102071742B1 (ko) | 2020-01-30 |
| IN2015DN01588A (enExample) | 2015-07-03 |
| ES2718646T3 (es) | 2019-07-03 |
| US20140058054A1 (en) | 2014-02-27 |
| BR112015004032B1 (pt) | 2021-01-05 |
| BR112015004032A2 (pt) | 2017-08-08 |
| MX381789B (es) | 2025-03-13 |
| EP2888045B1 (en) | 2019-01-09 |
| EP2888045A1 (en) | 2015-07-01 |
| CN103626130B (zh) | 2018-04-03 |
| WO2014035875A1 (en) | 2014-03-06 |
| US8916494B2 (en) | 2014-12-23 |
| MX2015002472A (es) | 2015-06-05 |
| KR20150058168A (ko) | 2015-05-28 |
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