SG11201501350UA - Vapor phase preparation of fluorided solid oxides - Google Patents

Vapor phase preparation of fluorided solid oxides

Info

Publication number
SG11201501350UA
SG11201501350UA SG11201501350UA SG11201501350UA SG11201501350UA SG 11201501350U A SG11201501350U A SG 11201501350UA SG 11201501350U A SG11201501350U A SG 11201501350UA SG 11201501350U A SG11201501350U A SG 11201501350UA SG 11201501350U A SG11201501350U A SG 11201501350UA
Authority
SG
Singapore
Prior art keywords
vapor phase
phase preparation
solid oxides
fluorided solid
fluorided
Prior art date
Application number
SG11201501350UA
Inventor
Max P Mcdaniel
Kathy S Collins
Qing Yang
Tony R Crain
Original Assignee
Chevron Phillips Chemical Co
Max P Mcdaniel
Kathy S Collins
Qing Yang
Tony R Crain
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chevron Phillips Chemical Co, Max P Mcdaniel, Kathy S Collins, Qing Yang, Tony R Crain filed Critical Chevron Phillips Chemical Co
Publication of SG11201501350UA publication Critical patent/SG11201501350UA/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61Surface area
    • B01J35/617500-1000 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12Silica and alumina
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61Surface area
    • B01J35/615100-500 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63Pore volume
    • B01J35/638Pore volume more than 1.0 ml/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/22Halogenating
    • B01J37/26Fluorinating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Compositions Of Oxide Ceramics (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
SG11201501350UA 2012-08-27 2013-08-26 Vapor phase preparation of fluorided solid oxides SG11201501350UA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US13/594,906 US8916494B2 (en) 2012-08-27 2012-08-27 Vapor phase preparation of fluorided solid oxides
PCT/US2013/056606 WO2014035875A1 (en) 2012-08-27 2013-08-26 Vapor phase preparation of fluorided solid oxides

Publications (1)

Publication Number Publication Date
SG11201501350UA true SG11201501350UA (en) 2015-03-30

Family

ID=49165837

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11201501350UA SG11201501350UA (en) 2012-08-27 2013-08-26 Vapor phase preparation of fluorided solid oxides

Country Status (12)

Country Link
US (1) US8916494B2 (en)
EP (1) EP2888045B1 (en)
KR (1) KR102071742B1 (en)
CN (1) CN103626130B (en)
BR (1) BR112015004032B1 (en)
CA (1) CA2882746C (en)
ES (1) ES2718646T3 (en)
IN (1) IN2015DN01588A (en)
MX (1) MX2015002472A (en)
SA (1) SA515360072B1 (en)
SG (1) SG11201501350UA (en)
WO (1) WO2014035875A1 (en)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2501081B (en) 2012-04-11 2017-08-30 Sca Ipla Holdings Inc Telecommunications apparatus and methods
CA2958435C (en) * 2014-08-19 2023-06-13 Univation Technologies, Llc Fluorinated catalyst supports and catalyst systems
CN107148316B (en) * 2014-08-19 2020-10-09 尤尼威蒂恩技术有限责任公司 Fluorination catalyst support and catalyst system
WO2016028278A1 (en) * 2014-08-19 2016-02-25 Univation Technologies, Llc Fluorinated catalyst supports and catalyst systems
EP3320004B2 (en) 2015-07-08 2023-12-06 Chevron Phillips Chemical Company LP Ziegler-natta-metallocene dual catalyst systems with activator-supports
CN105111040B (en) * 2015-08-18 2017-07-25 巨化集团技术中心 A kind of vinylidene is Material synthesis tetrafluoropropene HFO1234yf method
US9650459B2 (en) 2015-09-09 2017-05-16 Chevron Phillips Chemical Company Lp Methods for controlling die swell in dual catalyst olefin polymerization systems
US9845367B2 (en) 2015-09-24 2017-12-19 Chevron Phillips Chemical Company Lp Heterogeneous Ziegler-Natta catalysts with fluorided silica-coated alumina
US9758599B2 (en) 2015-09-24 2017-09-12 Chevron Phillips Chemical Company Lp Heterogeneous Ziegler-Natta catalysts with fluorided silica-coated alumina
US9540457B1 (en) * 2015-09-24 2017-01-10 Chevron Phillips Chemical Company Lp Ziegler-natta—metallocene dual catalyst systems with activator-supports
US9505856B1 (en) * 2016-01-13 2016-11-29 Chevron Phillips Chemical Company Lp Methods for making fluorided chromium (VI) catalysts, and polymerization processes using the same
KR101856202B1 (en) * 2016-07-12 2018-05-10 대림산업 주식회사 Polyolefin polymerization catalyst including modified carrier and method of producing polyolefin using the same
CN117964819A (en) 2018-09-24 2024-05-03 切弗朗菲利浦化学公司 Method for preparing supported chromium catalysts with enhanced polymerization activity
CN112672821B (en) 2018-09-27 2023-11-07 切弗朗菲利浦化学公司 Method for producing fluorinated solid oxides and use thereof in metallocene-based catalyst systems
US11912809B2 (en) 2022-06-02 2024-02-27 Chevron Phillips Chemical Company Lp High porosity fluorided silica-coated alumina activator-supports and uses thereof in metallocene-based catalyst systems for olefin polymerization
CN115010113B (en) * 2022-06-24 2024-02-13 山东重山光电材料股份有限公司 Fluorocarbon material and application thereof, and lithium battery
US11920089B1 (en) 2023-05-11 2024-03-05 Chevron Phillips Chemical Company Lp Solid oxide and chemically-treated solid oxide catalysts for the pyrolysis of polyethylene

Family Cites Families (103)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
LU34020A1 (en) 1953-01-27 1956-02-06
US3226205A (en) 1960-10-03 1965-12-28 Phillips Petroleum Co Reactor impeller with feed inlet along shaft
US3248179A (en) 1962-02-26 1966-04-26 Phillips Petroleum Co Method and apparatus for the production of solid polymers of olefins
US3119569A (en) 1962-03-28 1964-01-28 Baricordi Antonio Grinding apparatus
US3225023A (en) 1962-11-30 1965-12-21 Phillips Petroleum Co Process for controlling melt index
US3242099A (en) 1964-03-27 1966-03-22 Union Carbide Corp Olefin polymerization catalysts
US3622521A (en) 1967-08-21 1971-11-23 Phillips Petroleum Co Olefin polymerization with chromium and titanium-containing compounds
US3625864A (en) 1969-04-23 1971-12-07 Phillips Petroleum Co Polymerization catalyst system additives
US3843747A (en) 1970-06-25 1974-10-22 Texaco Inc Isomerization of c10-c14 hydrocarbons with fluorided metal-alumina catalyst
US3900457A (en) 1970-10-08 1975-08-19 Phillips Petroleum Co Olefin polymerization catalyst
US3887494A (en) 1970-11-12 1975-06-03 Phillips Petroleum Co Olefin polymerization catalyst
US4130505A (en) 1974-09-26 1978-12-19 Phillips Petroleum Company Two stage activation of fluorided chromium-containing catalyst
US3976632A (en) 1974-12-04 1976-08-24 Phillips Petroleum Company Reactivation of organochromium olefin polymerization catalyst in presence of oxygen
US4053436A (en) 1975-08-26 1977-10-11 Phillips Petroleum Company Spray dried titanium-containing catalyst for stress crack resistant polymer
US4081407A (en) 1976-03-18 1978-03-28 Phillips Petroleum Company Catalyst support prepared by alcohol treatment of hydrogels
US4151122A (en) 1977-12-05 1979-04-24 Phillips Petroleum Company Reduction and reoxidation of cogel or self-reduced catalyst
US4248735A (en) 1979-06-01 1981-02-03 Phillips Petroleum Company Treatment of silica
US4182815A (en) 1977-12-05 1980-01-08 Phillips Petroleum Company Reduction and reoxidation of cogel or self-reduced catalyst
US4247421A (en) 1979-05-03 1981-01-27 Phillips Petroleum Company Activation of supported chromium oxide catalysts
US4297460A (en) 1979-06-01 1981-10-27 Phillips Petroleum Co. Treatment of silica
US4397766A (en) 1979-12-14 1983-08-09 Phillips Petroleum Company Solubilized chromium salt in particulate support
US4296001A (en) 1980-02-06 1981-10-20 Phillips Petroleum Company Titanium impregnated silica-chromium catalysts
US4339559A (en) 1980-05-21 1982-07-13 Phillips Petroleum Company Polymerization using silica from single phase controlled hydrolysis of silicate ester
US4301034A (en) 1980-05-21 1981-11-17 Phillips Petroleum Company Silica from single phase controlled hydrolysis of silicate ester
US4364854A (en) 1980-12-31 1982-12-21 Phillips Petroleum Company Acid gelling aluminum phosphate from concentrated mass and catalyst containing same
US4444965A (en) 1980-12-31 1984-04-24 Phillips Petroleum Company Olefin polymerization using chromium on an aluminum phosphate produced from a concentrated mass
US4364842A (en) 1980-12-31 1982-12-21 Phillips Petroleum Company Phosphate supported chromium catalyst
US4444964A (en) 1980-12-31 1984-04-24 Phillips Petroleum Company Polymerization process using phosphate supported chromium catalyst
US4444962A (en) 1980-12-31 1984-04-24 Phillips Petroleum Company Polymerization process using catalysts with acid gelled aluminum phosphate base
US4504638A (en) 1980-12-31 1985-03-12 Phillips Petroleum Company Ethylene polymers made from phosphate supported chromium catalyst
US4364855A (en) 1980-12-31 1982-12-21 Phillips Petroleum Company Production of aluminum phosphate from concentrated mass
US4460756A (en) 1981-04-02 1984-07-17 Phillips Petroleum Company Olefin polymerization method
US4501885A (en) 1981-10-14 1985-02-26 Phillips Petroleum Company Diluent and inert gas recovery from a polymerization process
US4405501A (en) 1982-01-20 1983-09-20 Phillips Petroleum Company Aging of chromium-containing gel at high pH
US4392990A (en) 1982-01-20 1983-07-12 Phillips Petroleum Company Heating silica gel in inert atmosphere before activation
US4588790A (en) 1982-03-24 1986-05-13 Union Carbide Corporation Method for fluidized bed polymerization
US4806513A (en) 1984-05-29 1989-02-21 Phillips Petroleum Company Silicon and fluorine-treated alumina containing a chromium catalyst and method of producing same
US4547557A (en) 1984-07-09 1985-10-15 Phillips Petroleum Company Silica-titania cogel from two-step hydrolysis
US4808561A (en) 1985-06-21 1989-02-28 Exxon Chemical Patents Inc. Supported polymerization catalyst
US4735931A (en) 1986-06-16 1988-04-05 Phillips Petroleum Company In situ comonomer generation in olefin polymerization
US4820785A (en) 1986-06-16 1989-04-11 Phillips Petroleum Company In situ comonomer generation in olefin polymerization
US4794096A (en) 1987-04-03 1988-12-27 Fina Technology, Inc. Hafnium metallocene catalyst for the polymerization of olefins
US4939217A (en) 1987-04-03 1990-07-03 Phillips Petroleum Company Process for producing polyolefins and polyolefin catalysts
US4855271A (en) 1987-06-22 1989-08-08 Phillips Petroleum Company Catalyst and polymerization of olefins
US4981831A (en) 1988-07-25 1991-01-01 Phillips Petroleum Company Twice-aged porous inorganic oxides, catalysts, and polymerization processes
US5705478A (en) 1989-02-21 1998-01-06 Washington University Covalently linked β subunits of the glycoprotein hormones as antagonists
US4988657A (en) 1989-10-06 1991-01-29 Phillips Petroleum Company Process for olefin polymerization
US5565175A (en) 1990-10-01 1996-10-15 Phillips Petroleum Company Apparatus and method for producing ethylene polymer
CA2043904C (en) 1990-10-09 1997-10-07 Kent E. Mitchell Olefin polymerization
US5237025A (en) 1990-10-09 1993-08-17 Phillips Petroleum Company Process for making bimodal polyolefins using two independent particulate catalysts
US5221654A (en) 1991-01-02 1993-06-22 Phillips Petroleum Company Fluorided aluminas, catalysts, and polymerization processes
US5219817A (en) 1991-01-02 1993-06-15 Phillips Petroleum Company Fluorided aluminas, catalysts, and polymerization processes
US5575979A (en) 1991-03-04 1996-11-19 Phillips Petroleum Company Process and apparatus for separating diluents from solid polymers utilizing a two-stage flash and a cyclone separator
US5451649A (en) 1991-05-09 1995-09-19 Phillips Petroleum Company Organometallic fluorenyl compounds, preparation, and use
US5347026A (en) 1993-06-11 1994-09-13 Phillips Petroleum Company Fluorene compounds and methods for making
US5210352A (en) 1991-05-09 1993-05-11 Phillips Petroleum Company Fluorene compounds
US5436305A (en) 1991-05-09 1995-07-25 Phillips Petroleum Company Organometallic fluorenyl compounds, preparation, and use
US5466766A (en) 1991-05-09 1995-11-14 Phillips Petroleum Company Metallocenes and processes therefor and therewith
US5631335A (en) 1991-05-09 1997-05-20 Phillips Petroleum Company Process of polymerizing olefins using diphenylsilyl or dimethyl tin bridged 1-methyl fluorenyl metallocenes
US5571880A (en) 1991-05-09 1996-11-05 Phillips Petroleum Company Organometallic fluorenyl compounds and use thereof in an alpha-olefin polymerization process
US5401817A (en) 1991-05-09 1995-03-28 Phillips Petroleum Company Olefin polymerization using silyl-bridged metallocenes
US5627247A (en) 1991-05-09 1997-05-06 Phillips Petroleum Company Organometallic fluorenyl compounds and use thereof in olefin polymerization
US5191132A (en) 1991-05-09 1993-03-02 Phillips Petroleum Company Cyclopentadiene type compounds and method for making
US5399636A (en) 1993-06-11 1995-03-21 Phillips Petroleum Company Metallocenes and processes therefor and therewith
US5594078A (en) 1991-07-23 1997-01-14 Phillips Petroleum Company Process for producing broad molecular weight polyolefin
US5668230A (en) 1991-07-23 1997-09-16 Phillips Petroleum Company Olefin polymerization
US5610247A (en) 1991-07-23 1997-03-11 Phillips Petroleum Company Unbridged metallocenes of 9-substituted fluorenyl compounds and use thereof
US5244990A (en) 1992-01-07 1993-09-14 Phillips Petroleum Company Prepolymerized catalyst and use thereof
US5352749A (en) 1992-03-19 1994-10-04 Exxon Chemical Patents, Inc. Process for polymerizing monomers in fluidized beds
US5436304A (en) 1992-03-19 1995-07-25 Exxon Chemical Patents Inc. Process for polymerizing monomers in fluidized beds
US5179178A (en) 1992-05-15 1993-01-12 Phillips Petroleum Company Olefin polymerization
US5354721A (en) 1993-06-22 1994-10-11 Phillips Petroleum Company Organo-aluminoxy product and use
US5576259A (en) 1993-10-14 1996-11-19 Tosoh Corporation Process for producing α-olefin polymer
US5496781A (en) 1994-05-16 1996-03-05 Phillips Petroleum Company Metallocene catalyst systems, preparation, and use
US5498581A (en) 1994-06-01 1996-03-12 Phillips Petroleum Company Method for making and using a supported metallocene catalyst system
US5541272A (en) 1994-06-03 1996-07-30 Phillips Petroleum Company High activity ethylene selective metallocenes
US5420320A (en) 1994-06-08 1995-05-30 Phillips Petroleum Company Method for preparing cyclopentadienyl-type ligands and metallocene compounds
US5455314A (en) 1994-07-27 1995-10-03 Phillips Petroleum Company Method for controlling removal of polymerization reaction effluent
US5563284A (en) 1994-09-09 1996-10-08 Phillips Petroleum Company Cyclopentadienyl-type ligands, metallocenes, catalyst systems, preparation, and use
EP0727443B1 (en) 1995-02-20 2001-01-17 Tosoh Corporation Catalyst for olefin polymerization and process for producing olefin polymers
US5631203A (en) 1995-05-04 1997-05-20 Phillips Petroleum Company Metallocene compounds and preparation thereof containing terminal alkynes
US5654454A (en) 1995-05-30 1997-08-05 Phillips Petroleum Company Metallocene preparation and use
BR9708232A (en) 1996-03-27 1999-08-03 Dow Chemical Co Catalyst activator catalyst system for polymerization of alpha-olefins and polymerization process
US5705579A (en) 1996-07-17 1998-01-06 Phillips Petroleum Company Olefin polymerization
US6239235B1 (en) 1997-07-15 2001-05-29 Phillips Petroleum Company High solids slurry polymerization
KR100531628B1 (en) 1998-03-20 2005-11-29 엑손모빌 케미칼 패턴츠 인코포레이티드 Continuous slurry polymerization volatile removal
US6300271B1 (en) 1998-05-18 2001-10-09 Phillips Petroleum Company Compositions that can produce polymers
ES2572756T3 (en) 1998-05-18 2016-06-02 Chevron Phillips Chemical Company Lp Process for the polymerization of a monomer with a catalyst composition containing an organometallic compound, an organoaluminum compound and a treated solid oxide compound
US6262191B1 (en) 1999-03-09 2001-07-17 Phillips Petroleum Company Diluent slip stream to give catalyst wetting agent
US6355594B1 (en) 1999-09-27 2002-03-12 Phillips Petroleum Company Organometal catalyst compositions
US6395666B1 (en) 1999-09-29 2002-05-28 Phillips Petroleum Company Organometal catalyst compositions
US6613712B1 (en) 1999-11-24 2003-09-02 Phillips Petroleum Company Organometal catalyst compositions with solid oxide supports treated with fluorine and boron
US6548442B1 (en) 1999-12-03 2003-04-15 Phillips Petroleum Company Organometal compound catalyst
CA2395292C (en) 1999-12-16 2009-05-26 Phillips Petroleum Company Organometal compound catalyst
WO2005037431A1 (en) 2003-10-14 2005-04-28 E.I. Dupont De Nemours And Company Chromium oxide compositions containing zinc, their preparation, and their use as catalysts and catalyst precursors
US7294599B2 (en) 2004-06-25 2007-11-13 Chevron Phillips Chemical Co. Acidic activator-supports and catalysts for olefin polymerization
US7226886B2 (en) 2005-09-15 2007-06-05 Chevron Phillips Chemical Company, L.P. Polymerization catalysts and process for producing bimodal polymers in a single reactor
US7312283B2 (en) 2005-08-22 2007-12-25 Chevron Phillips Chemical Company Lp Polymerization catalysts and process for producing bimodal polymers in a single reactor
US7619047B2 (en) 2006-02-22 2009-11-17 Chevron Phillips Chemical Company, Lp Dual metallocene catalysts for polymerization of bimodal polymers
US7884163B2 (en) 2008-03-20 2011-02-08 Chevron Phillips Chemical Company Lp Silica-coated alumina activator-supports for metallocene catalyst compositions
US8114946B2 (en) 2008-12-18 2012-02-14 Chevron Phillips Chemical Company Lp Process for producing broader molecular weight distribution polymers with a reverse comonomer distribution and low levels of long chain branches
US8309485B2 (en) 2009-03-09 2012-11-13 Chevron Phillips Chemical Company Lp Methods for producing metal-containing sulfated activator-supports
US9289739B2 (en) 2009-06-23 2016-03-22 Chevron Philips Chemical Company Lp Continuous preparation of calcined chemically-treated solid oxides

Also Published As

Publication number Publication date
US20140058054A1 (en) 2014-02-27
SA515360072B1 (en) 2015-09-28
MX2015002472A (en) 2015-06-05
CA2882746A1 (en) 2014-03-06
EP2888045A1 (en) 2015-07-01
WO2014035875A1 (en) 2014-03-06
ES2718646T3 (en) 2019-07-03
CN103626130A (en) 2014-03-12
KR20150058168A (en) 2015-05-28
US8916494B2 (en) 2014-12-23
EP2888045B1 (en) 2019-01-09
CN103626130B (en) 2018-04-03
BR112015004032B1 (en) 2021-01-05
IN2015DN01588A (en) 2015-07-03
BR112015004032A2 (en) 2017-08-08
CA2882746C (en) 2017-08-15
KR102071742B1 (en) 2020-01-30

Similar Documents

Publication Publication Date Title
SG11201501350UA (en) Vapor phase preparation of fluorided solid oxides
IL237275A0 (en) Compounds for the treatment of paramoxyvirus viral infectiones
EP2665733A4 (en) Preparation of metal-triazolate frameworks
EP2670761A4 (en) Preparation of metal-catecholate frameworks
EP2834247A4 (en) Preparation of ticagrelor
EP2871239A4 (en) Cell capable of producing adeno-associated virus vector
ZA201406082B (en) Use of ccr3-inhibitors
EP2876439A4 (en) Stationary phase
EP2807551A4 (en) Roaming of note-taking application features
IL236312A0 (en) Preparation of 18f-fluciclovine
SG11201504134SA (en) External preparation
EP2881113A4 (en) New application of pogostone
IL236450A (en) Process for the preparation of 5-fluoro-1h-pyrazoles
PL399419A1 (en) Process for the preparation of 4-methoxydihydrochalcone
PL399418A1 (en) Process for the preparation of 4-methoxydihydrochalcone
HUE059883T2 (en) Envelope calculation by means of phase shifting
IL249668A0 (en) Improved processes for the preparation of 1-aryl-5-alkyl pyrazole compounds
HK1214601A1 (en) New bis-iridium-complexes for manufacturing of ecl-labels ecl---
EP2926804A4 (en) Cosmetic preparation
EP2892529A4 (en) Uses of (-)-perhexiline
EP2684869A4 (en) Preparation of 3-mercaptopropionates
ZA201405824B (en) Process for the preparation of substituted phenylpropanones
EP2837632A4 (en) Compound jk12a and preparation thereof
EP2857020A4 (en) Mirtazapine-containing transdermally-absorbable skin-adhesive preparation
GB201215184D0 (en) Therapeutic virus