CA2880876C - Production of a spinel material - Google Patents

Production of a spinel material Download PDF

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Publication number
CA2880876C
CA2880876C CA2880876A CA2880876A CA2880876C CA 2880876 C CA2880876 C CA 2880876C CA 2880876 A CA2880876 A CA 2880876A CA 2880876 A CA2880876 A CA 2880876A CA 2880876 C CA2880876 C CA 2880876C
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Prior art keywords
powder
process according
lithium
compound
manganese
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CA2880876A
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English (en)
French (fr)
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CA2880876A1 (en
Inventor
Kenneth Ikechukwu Ozoemena
Charl Jeremy Jafta
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Council for Scientific and Industrial Research CSIR
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Council for Scientific and Industrial Research CSIR
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    • C—CHEMISTRY; METALLURGY
    • C30—CRYSTAL GROWTH
    • C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
    • C30B1/00—Single-crystal growth directly from the solid state
    • C30B1/02—Single-crystal growth directly from the solid state by thermal treatment, e.g. strain annealing
    • C30B1/04—Isothermal recrystallisation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Complex oxides containing nickel and at least one other metal element
    • C01G53/42—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • C01G53/44—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
    • C01G53/54—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (Mn2O4)-, e.g. Li(NixMn2-x)O4 or Li(MyNixMn2-x-y)O4
    • C—CHEMISTRY; METALLURGY
    • C30—CRYSTAL GROWTH
    • C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
    • C30B29/00—Single crystals or homogeneous polycrystalline material with defined structure characterised by the material or by their shape
    • C30B29/10—Inorganic compounds or compositions
    • C30B29/16—Oxides
    • C30B29/22—Complex oxides
    • C—CHEMISTRY; METALLURGY
    • C30—CRYSTAL GROWTH
    • C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
    • C30B30/00—Production of single crystals or homogeneous polycrystalline material with defined structure characterised by the action of electric or magnetic fields, wave energy or other specific physical conditions
    • C30B30/02—Production of single crystals or homogeneous polycrystalline material with defined structure characterised by the action of electric or magnetic fields, wave energy or other specific physical conditions using electric fields, e.g. electrolysis
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/30—Three-dimensional structures
    • C01P2002/32—Three-dimensional structures spinel-type (AB2O4)
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/50—Solid solutions
    • C01P2002/52—Solid solutions containing elements as dopants
    • C01P2002/54—Solid solutions containing elements as dopants one element only
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/74—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by peak-intensities or a ratio thereof only
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/77—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by unit-cell parameters, atom positions or structure diagrams
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
    • C01P2002/85—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by XPS, EDX or EDAX data
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/01—Particle morphology depicted by an image
    • C01P2004/03—Particle morphology depicted by an image obtained by SEM
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028—Positive electrodes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
CA2880876A 2012-08-10 2013-07-25 Production of a spinel material Active CA2880876C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
ZA201206016 2012-08-10
ZA2012/06016 2012-08-10
PCT/IB2013/056103 WO2014024075A1 (en) 2012-08-10 2013-07-25 Production of a spinel material

Publications (2)

Publication Number Publication Date
CA2880876A1 CA2880876A1 (en) 2014-02-13
CA2880876C true CA2880876C (en) 2020-07-07

Family

ID=49304034

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2880876A Active CA2880876C (en) 2012-08-10 2013-07-25 Production of a spinel material

Country Status (10)

Country Link
US (1) US9834854B2 (enExample)
EP (1) EP2882690B1 (enExample)
JP (1) JP6316812B2 (enExample)
KR (1) KR102085903B1 (enExample)
CN (1) CN104703920A (enExample)
AR (1) AR092069A1 (enExample)
BR (1) BR112015002884B1 (enExample)
CA (1) CA2880876C (enExample)
WO (1) WO2014024075A1 (enExample)
ZA (1) ZA201501121B (enExample)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR112017000017A2 (pt) 2014-07-03 2018-11-06 Csir produção de material óxido de lítio, manganês, níquel e cobalto, em camadas
US9979011B2 (en) * 2014-09-26 2018-05-22 The United States Of America As Represented By The Secretary Of The Army LixMn2O4-y(C1z) spinal cathode material, method of preparing the same, and rechargeable lithium and li-ion electrochemical systems containing the same
EP3212578A2 (en) * 2014-10-31 2017-09-06 Csir Production of a spinel material
US10505188B2 (en) * 2015-03-03 2019-12-10 The Government Of The United States As Represented By The Secretary Of The Army “B” and “O” site doped AB2O4 spinel cathode material, method of preparing the same, and rechargeable lithium and Li-ion electrochemical systems containing the same
WO2017109646A1 (en) * 2015-12-22 2017-06-29 Csir Spinel material
CN105576231A (zh) * 2016-02-25 2016-05-11 江南大学 一种具有尖晶石结构的高电压锂离子电池正极材料及其制备方法
EP3435157B1 (en) 2016-03-24 2021-01-06 FUJIFILM Corporation Active light sensitive or radiation sensitive composition, method for producing active light sensitive or radiation sensitive composition, pattern forming method, and electronic device producing method
EP3435159A4 (en) 2016-03-24 2019-04-10 Fujifilm Corporation ACTIVE RADIATION SENSITIVE OR RADIATION-SENSITIVE COMPOSITION, METHODS FOR CLEANING OF ACTIVE RADIATION SENSITIVE OR RADIATION-SENSITIVE COMPOSITION, PROCESS FOR PRODUCING THE ACTIVE RADIATION SENSITIVE OR RADIATION-SENSITIVE COMPOSITION, PATTERN FORMATION METHOD AND METHOD FOR PRODUCING AN ELECTRONIC DEVICE
JP6796635B2 (ja) 2016-03-24 2020-12-09 富士フイルム株式会社 感活性光線性又は感放射線性組成物、感活性光線性又は感放射線性組成物の精製方法、パターン形成方法、及び電子デバイスの製造方法
US10516156B2 (en) * 2016-05-25 2019-12-24 The Government Of The United States As Represented By The Secretary Of The Army Chlorinated lithium manganese oxide spinel cathode material with charge transfer catalyst coating, method of preparing the same, and Li electrochemical cell containing the same
KR101963251B1 (ko) * 2017-10-17 2019-03-29 한국과학기술연구원 양극 활물질 제조방법 및 이를 이용한 이차전지
CN114369863B (zh) * 2021-12-08 2023-02-14 中国科学院地球化学研究所 一种高温高压下制备锰铝榴石单晶的方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2221213B (en) * 1988-07-12 1991-09-04 Csir Synthesizing lithium manganese oxide
CN1042377C (zh) * 1996-05-10 1999-03-03 中国科学院物理研究所 一种合成锂离子电池中正极材料的方法
JP2973299B2 (ja) * 1996-06-27 1999-11-08 本荘ケミカル株式会社 スピネル型構造を有するリチウム−マンガン複合酸化物の製造方法
US6348182B1 (en) * 1996-06-27 2002-02-19 The Honjo Chemical Corporation Process for producing lithium manganese oxide with spinel structure
JP3411488B2 (ja) * 1997-12-01 2003-06-03 本荘ケミカル株式会社 リチウムイオン二次電池用正極活物質の製造方法
JP2000281355A (ja) * 1999-03-29 2000-10-10 Nippon Chem Ind Co Ltd リチウム複合酸化物の製造方法
US8728666B2 (en) * 2005-04-28 2014-05-20 Nissan Motor Co., Ltd. Positive electrode material for lithium ion battery with nonaqueous electrolyte, and battery using the same
US8496855B2 (en) * 2009-07-27 2013-07-30 Samsung Electronics Co., Ltd. Cathode active material, cathode including cathode active material, and lithium battery including cathode
JP2011210463A (ja) * 2010-03-29 2011-10-20 Jx Nippon Mining & Metals Corp リチウムイオン電池用正極活物質の製造方法

Also Published As

Publication number Publication date
BR112015002884B1 (pt) 2021-06-08
JP2015525734A (ja) 2015-09-07
CA2880876A1 (en) 2014-02-13
JP6316812B2 (ja) 2018-04-25
ZA201501121B (en) 2016-01-27
US20150197872A1 (en) 2015-07-16
CN104703920A (zh) 2015-06-10
WO2014024075A1 (en) 2014-02-13
EP2882690A1 (en) 2015-06-17
EP2882690B1 (en) 2016-10-12
AR092069A1 (es) 2015-03-18
US9834854B2 (en) 2017-12-05
BR112015002884A2 (pt) 2019-10-08
KR20150056542A (ko) 2015-05-26
KR102085903B1 (ko) 2020-03-06

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