CA2880244C - Composition of quinone methide derivatives and amines for control and inhibition of polymerization of monomers, and method of preparation and use thereof - Google Patents

Composition of quinone methide derivatives and amines for control and inhibition of polymerization of monomers, and method of preparation and use thereof Download PDF

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Publication number
CA2880244C
CA2880244C CA2880244A CA2880244A CA2880244C CA 2880244 C CA2880244 C CA 2880244C CA 2880244 A CA2880244 A CA 2880244A CA 2880244 A CA2880244 A CA 2880244A CA 2880244 C CA2880244 C CA 2880244C
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CA
Canada
Prior art keywords
quinone methide
polymerization
ppm
composition
additive composition
Prior art date
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Active
Application number
CA2880244A
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English (en)
French (fr)
Other versions
CA2880244A1 (en
Inventor
Mahesh Subramaniyam
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dorf Ketal Chemicals India Pvt Ltd
Original Assignee
Dorf Ketal Chemicals India Pvt Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dorf Ketal Chemicals India Pvt Ltd filed Critical Dorf Ketal Chemicals India Pvt Ltd
Publication of CA2880244A1 publication Critical patent/CA2880244A1/en
Application granted granted Critical
Publication of CA2880244C publication Critical patent/CA2880244C/en
Active legal-status Critical Current
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F112/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F112/02—Monomers containing only one unsaturated aliphatic radical
    • C08F112/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F112/06—Hydrocarbons
    • C08F112/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C08F2/42—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation using short-stopping agents
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/20—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/06—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C08F2/40—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation using retarding agents
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
    • C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
    • C09K15/16—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing nitrogen
    • C09K15/18—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing nitrogen containing an amine or imine moiety
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
    • C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
    • C09K15/20—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing nitrogen and oxygen
    • C09K15/24—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing nitrogen and oxygen containing a phenol or quinone moiety

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Analytical Chemistry (AREA)
  • Polymerisation Methods In General (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CA2880244A 2012-08-24 2013-08-21 Composition of quinone methide derivatives and amines for control and inhibition of polymerization of monomers, and method of preparation and use thereof Active CA2880244C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
IN2465/MUM/2012 2012-08-24
IN2465MU2012 2012-08-24
PCT/IB2013/056787 WO2014030131A1 (en) 2012-08-24 2013-08-21 Composition of quinone methide derivatives and amines for control and inhibition of polymerization of monomers, and method of preparation and use thereof

Publications (2)

Publication Number Publication Date
CA2880244A1 CA2880244A1 (en) 2014-02-27
CA2880244C true CA2880244C (en) 2017-05-16

Family

ID=54187096

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2880244A Active CA2880244C (en) 2012-08-24 2013-08-21 Composition of quinone methide derivatives and amines for control and inhibition of polymerization of monomers, and method of preparation and use thereof

Country Status (16)

Country Link
US (1) US9234057B2 (enExample)
EP (1) EP2888212B1 (enExample)
JP (1) JP6255405B2 (enExample)
KR (1) KR101803750B1 (enExample)
CN (1) CN104718181B (enExample)
AU (1) AU2013307242B2 (enExample)
BR (1) BR112015003564B1 (enExample)
CA (1) CA2880244C (enExample)
ES (1) ES2686127T3 (enExample)
MX (1) MX360426B (enExample)
MY (1) MY182112A (enExample)
PL (1) PL2888212T3 (enExample)
RU (1) RU2632879C2 (enExample)
SG (1) SG11201500774WA (enExample)
TW (1) TWI610915B (enExample)
WO (1) WO2014030131A1 (enExample)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2632879C2 (ru) * 2012-08-24 2017-10-11 Дорф Кетал Кемикалс (Индия) Прайвит Лимитэд Композиция производных хинон-метида и аминов для контроля и ингибирования полимеризации мономеров, а также способ их получения и применение
IN2013MU01165A (enExample) * 2013-03-26 2015-04-24 Dorf Ketal Chemicals India Private Ltd
RU2680811C1 (ru) * 2016-02-13 2019-02-27 Дорф Кетал Кемикалс (Индия) Прайвит Лимитэд Композиции для контроля и ингибирования полимеризации винилароматических мономеров и способы их применения
TW202005938A (zh) 2018-07-13 2020-02-01 美商藝康美國公司 具有胺穩定劑之聚合抑制劑及阻滯劑組合物
KR102763208B1 (ko) * 2018-07-13 2025-02-04 에코랍 유에스에이 인코퍼레이티드 비닐계 단량체에 대한 항파울런트로서의 산소화 아민 및 퀴논 메티드의 조성물
TWI880966B (zh) * 2019-10-11 2025-04-21 美商藝康美國公司 醌甲基化物及銨鹽抗聚合劑組合物及方法
CN116553996A (zh) * 2023-07-07 2023-08-08 吉林金海化工新材料有限公司 一种阻聚剂及其应用

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2039757C1 (ru) * 1992-05-15 1995-07-20 Нижнекамское производственное объединение "Нижнекамскнефтехим" Способ ингибирования полимеризации винилароматических мономеров
US5583247A (en) * 1995-04-14 1996-12-10 Ciba-Geigy Corporation 7-substituted quinone methides as inhibitors for unsaturated monomers
US6024894A (en) 1998-03-25 2000-02-15 Betzdearborn Inc. Compositions and methods for inhibiting vinyl aromatic monomer polymerization
US7045647B2 (en) * 2000-10-16 2006-05-16 Uniroyal Chemical Company, Inc. Blends of quinone alkide and nitroxyl compounds and polymerization inhibitors
US20040034247A1 (en) * 2002-08-16 2004-02-19 Sherif Eldin Compositions and methods for inhibiting vinyl aromatic monomer polymerization
CN101102984A (zh) * 2004-12-03 2008-01-09 科聚亚公司 作为聚合抑制剂的与含氮氧自由基的化合物或c-亚硝基苯胺结合的芳族磺酸、胺和硝基酚
US7651635B1 (en) * 2009-02-05 2010-01-26 Nalco Company Polymer inhibition of vinyl aromatic monomers using a quinone methide/alkyl hydroxylamine combination
US8298440B2 (en) 2010-06-03 2012-10-30 General Electric Company Methods and compositions for inhibiting vinyl aromatic monomer polymerization
BR112014004284B1 (pt) * 2011-08-26 2020-05-05 Dorf Ketal Chemicals (I) Private Limited processo de preparação de uma composição aromática contendo vanilina e etilvanilina
PL2797864T3 (pl) * 2011-12-26 2015-11-30 Dorf Ketal Chemicals India Private Ltd Ulepszona kompozycja dodatków na bazie amin do kontroli i hamowania polimeryzacji aromatycznych monomerów winylowych oraz sposób jej stosowania
RU2632879C2 (ru) 2012-08-24 2017-10-11 Дорф Кетал Кемикалс (Индия) Прайвит Лимитэд Композиция производных хинон-метида и аминов для контроля и ингибирования полимеризации мономеров, а также способ их получения и применение

Also Published As

Publication number Publication date
WO2014030131A1 (en) 2014-02-27
JP2015526562A (ja) 2015-09-10
MY182112A (en) 2021-01-18
EP2888212B1 (en) 2018-06-13
SG11201500774WA (en) 2015-02-27
BR112015003564B1 (pt) 2021-01-05
EP2888212A1 (en) 2015-07-01
ES2686127T3 (es) 2018-10-16
US9234057B2 (en) 2016-01-12
TW201412706A (zh) 2014-04-01
CN104718181B (zh) 2018-01-30
AU2013307242A1 (en) 2015-03-12
CN104718181A (zh) 2015-06-17
US20150225495A1 (en) 2015-08-13
AU2013307242B2 (en) 2016-09-29
KR20150048797A (ko) 2015-05-07
MX2015002382A (es) 2015-06-03
MX360426B (es) 2018-11-01
PL2888212T3 (pl) 2018-11-30
JP6255405B2 (ja) 2017-12-27
BR112015003564A2 (pt) 2017-08-22
RU2015109877A (ru) 2016-10-20
TWI610915B (zh) 2018-01-11
RU2632879C2 (ru) 2017-10-11
KR101803750B1 (ko) 2017-12-01
CA2880244A1 (en) 2014-02-27

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