CA2880244C - Composition of quinone methide derivatives and amines for control and inhibition of polymerization of monomers, and method of preparation and use thereof - Google Patents

Composition of quinone methide derivatives and amines for control and inhibition of polymerization of monomers, and method of preparation and use thereof Download PDF

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Publication number
CA2880244C
CA2880244C CA2880244A CA2880244A CA2880244C CA 2880244 C CA2880244 C CA 2880244C CA 2880244 A CA2880244 A CA 2880244A CA 2880244 A CA2880244 A CA 2880244A CA 2880244 C CA2880244 C CA 2880244C
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Prior art keywords
quinone methide
polymerization
ppm
composition
additive composition
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CA2880244A
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English (en)
French (fr)
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CA2880244A1 (en
Inventor
Mahesh Subramaniyam
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dorf Ketal Chemicals India Pvt Ltd
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Dorf Ketal Chemicals India Pvt Ltd
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Publication of CA2880244A1 publication Critical patent/CA2880244A1/en
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Publication of CA2880244C publication Critical patent/CA2880244C/en
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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F112/00Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F112/02Monomers containing only one unsaturated aliphatic radical
    • C08F112/04Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F112/06Hydrocarbons
    • C08F112/08Styrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C08F2/42Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation using short-stopping agents
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00Purification; Separation; Use of additives
    • C07C7/20Use of additives, e.g. for stabilisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02Monomers containing only one unsaturated aliphatic radical
    • C08F12/04Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/06Hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C08F2/40Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation using retarding agents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K15/00Anti-oxidant compositions; Compositions inhibiting chemical change
    • C09K15/04Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
    • C09K15/16Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing nitrogen
    • C09K15/18Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing nitrogen containing an amine or imine moiety
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K15/00Anti-oxidant compositions; Compositions inhibiting chemical change
    • C09K15/04Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
    • C09K15/20Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing nitrogen and oxygen
    • C09K15/24Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing nitrogen and oxygen containing a phenol or quinone moiety

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Analytical Chemistry (AREA)
  • Polymerisation Methods In General (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CA2880244A 2012-08-24 2013-08-21 Composition of quinone methide derivatives and amines for control and inhibition of polymerization of monomers, and method of preparation and use thereof Active CA2880244C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
IN2465MU2012 2012-08-24
IN2465/MUM/2012 2012-08-24
PCT/IB2013/056787 WO2014030131A1 (en) 2012-08-24 2013-08-21 Composition of quinone methide derivatives and amines for control and inhibition of polymerization of monomers, and method of preparation and use thereof

Publications (2)

Publication Number Publication Date
CA2880244A1 CA2880244A1 (en) 2014-02-27
CA2880244C true CA2880244C (en) 2017-05-16

Family

ID=54187096

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2880244A Active CA2880244C (en) 2012-08-24 2013-08-21 Composition of quinone methide derivatives and amines for control and inhibition of polymerization of monomers, and method of preparation and use thereof

Country Status (16)

Country Link
US (1) US9234057B2 (enExample)
EP (1) EP2888212B1 (enExample)
JP (1) JP6255405B2 (enExample)
KR (1) KR101803750B1 (enExample)
CN (1) CN104718181B (enExample)
AU (1) AU2013307242B2 (enExample)
BR (1) BR112015003564B1 (enExample)
CA (1) CA2880244C (enExample)
ES (1) ES2686127T3 (enExample)
MX (1) MX360426B (enExample)
MY (1) MY182112A (enExample)
PL (1) PL2888212T3 (enExample)
RU (1) RU2632879C2 (enExample)
SG (1) SG11201500774WA (enExample)
TW (1) TWI610915B (enExample)
WO (1) WO2014030131A1 (enExample)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2686127T3 (es) * 2012-08-24 2018-10-16 Dorf Ketal Chemicals (India) Private Limited Composición de derivados de métido de quinona y aminas para el control y la inhibición de la polimerización de monómeros, y procedimiento de preparación y uso de la misma
IN2013MU01165A (enExample) * 2013-03-26 2015-04-24 Dorf Ketal Chemicals India Private Ltd
KR102091718B1 (ko) * 2016-02-13 2020-03-20 도르프 케탈 케미칼즈 (인디아) 프라이비트 리미티드 비닐 방향족 모노머의 중합의 조절 및 억제를 위한 조성물, 및 이의 사용 방법
TWI826485B (zh) * 2018-07-13 2023-12-21 美商藝康美國公司 作為乙烯系單體之防垢劑之含氧胺及醌甲基化物之組合物
TW202005938A (zh) 2018-07-13 2020-02-01 美商藝康美國公司 具有胺穩定劑之聚合抑制劑及阻滯劑組合物
TWI880966B (zh) * 2019-10-11 2025-04-21 美商藝康美國公司 醌甲基化物及銨鹽抗聚合劑組合物及方法
CN116553996A (zh) * 2023-07-07 2023-08-08 吉林金海化工新材料有限公司 一种阻聚剂及其应用

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2039757C1 (ru) * 1992-05-15 1995-07-20 Нижнекамское производственное объединение "Нижнекамскнефтехим" Способ ингибирования полимеризации винилароматических мономеров
US5583247A (en) * 1995-04-14 1996-12-10 Ciba-Geigy Corporation 7-substituted quinone methides as inhibitors for unsaturated monomers
US6024894A (en) 1998-03-25 2000-02-15 Betzdearborn Inc. Compositions and methods for inhibiting vinyl aromatic monomer polymerization
JP4248875B2 (ja) * 2000-10-16 2009-04-02 ケムチュア コーポレイション 重合抑制剤としての、キノンアルカイドとニトロキシル化合物の混合物
US20040034247A1 (en) 2002-08-16 2004-02-19 Sherif Eldin Compositions and methods for inhibiting vinyl aromatic monomer polymerization
CN101102984A (zh) * 2004-12-03 2008-01-09 科聚亚公司 作为聚合抑制剂的与含氮氧自由基的化合物或c-亚硝基苯胺结合的芳族磺酸、胺和硝基酚
US7651635B1 (en) * 2009-02-05 2010-01-26 Nalco Company Polymer inhibition of vinyl aromatic monomers using a quinone methide/alkyl hydroxylamine combination
US8298440B2 (en) 2010-06-03 2012-10-30 General Electric Company Methods and compositions for inhibiting vinyl aromatic monomer polymerization
BR112014004284B1 (pt) * 2011-08-26 2020-05-05 Dorf Ketal Chemicals (I) Private Limited processo de preparação de uma composição aromática contendo vanilina e etilvanilina
MX339599B (es) * 2011-12-26 2016-05-31 Dorf Ketal Chemicals (India) Private Ltd Composicion de aditivo a base de amina mejorada para el control y la inhibicion de la polimerizacion de monomeros de vinilo aromaticos, y metodo de uso de la misma.
ES2686127T3 (es) 2012-08-24 2018-10-16 Dorf Ketal Chemicals (India) Private Limited Composición de derivados de métido de quinona y aminas para el control y la inhibición de la polimerización de monómeros, y procedimiento de preparación y uso de la misma

Also Published As

Publication number Publication date
KR101803750B1 (ko) 2017-12-01
CN104718181B (zh) 2018-01-30
US20150225495A1 (en) 2015-08-13
WO2014030131A1 (en) 2014-02-27
ES2686127T3 (es) 2018-10-16
EP2888212A1 (en) 2015-07-01
BR112015003564A2 (pt) 2017-08-22
AU2013307242A1 (en) 2015-03-12
TWI610915B (zh) 2018-01-11
RU2015109877A (ru) 2016-10-20
MX2015002382A (es) 2015-06-03
MY182112A (en) 2021-01-18
TW201412706A (zh) 2014-04-01
KR20150048797A (ko) 2015-05-07
JP6255405B2 (ja) 2017-12-27
CN104718181A (zh) 2015-06-17
JP2015526562A (ja) 2015-09-10
CA2880244A1 (en) 2014-02-27
SG11201500774WA (en) 2015-02-27
RU2632879C2 (ru) 2017-10-11
PL2888212T3 (pl) 2018-11-30
EP2888212B1 (en) 2018-06-13
BR112015003564B1 (pt) 2021-01-05
AU2013307242B2 (en) 2016-09-29
MX360426B (es) 2018-11-01
US9234057B2 (en) 2016-01-12

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