CA2873322A1 - Novel composition for preparing polysaccharide fibers - Google Patents
Novel composition for preparing polysaccharide fibers Download PDFInfo
- Publication number
- CA2873322A1 CA2873322A1 CA2873322A CA2873322A CA2873322A1 CA 2873322 A1 CA2873322 A1 CA 2873322A1 CA 2873322 A CA2873322 A CA 2873322A CA 2873322 A CA2873322 A CA 2873322A CA 2873322 A1 CA2873322 A1 CA 2873322A1
- Authority
- CA
- Canada
- Prior art keywords
- solution
- glucan
- poly
- fwdarw
- alpha
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 77
- 239000000203 mixture Substances 0.000 title description 20
- 150000004676 glycans Chemical class 0.000 title description 14
- 229920001282 polysaccharide Polymers 0.000 title description 12
- 239000005017 polysaccharide Substances 0.000 title description 12
- 229920001503 Glucan Polymers 0.000 claims abstract description 56
- 238000009987 spinning Methods 0.000 claims abstract description 42
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims abstract description 21
- 230000002378 acidificating effect Effects 0.000 claims abstract description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical group [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 57
- 238000000034 method Methods 0.000 claims description 37
- 230000008569 process Effects 0.000 claims description 25
- 239000007787 solid Substances 0.000 claims description 24
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 23
- 239000008103 glucose Substances 0.000 claims description 23
- 239000007788 liquid Substances 0.000 claims description 12
- 229930182470 glycoside Natural products 0.000 claims description 11
- 150000002338 glycosides Chemical class 0.000 claims description 11
- 239000000701 coagulant Substances 0.000 claims description 8
- 125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 claims description 8
- 230000015271 coagulation Effects 0.000 abstract description 25
- 238000005345 coagulation Methods 0.000 abstract description 25
- 230000000704 physical effect Effects 0.000 abstract description 9
- 238000000855 fermentation Methods 0.000 abstract description 3
- 230000004151 fermentation Effects 0.000 abstract description 3
- 239000000243 solution Substances 0.000 description 85
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 69
- 229920000642 polymer Polymers 0.000 description 44
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 32
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 30
- 235000011149 sulphuric acid Nutrition 0.000 description 26
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 23
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 21
- 229910001868 water Inorganic materials 0.000 description 19
- 239000010935 stainless steel Substances 0.000 description 17
- 229910001220 stainless steel Inorganic materials 0.000 description 17
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 12
- 238000003756 stirring Methods 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- -1 MgSO4 heptahydrate Chemical class 0.000 description 11
- ZOOODBUHSVUZEM-UHFFFAOYSA-N ethoxymethanedithioic acid Chemical compound CCOC(S)=S ZOOODBUHSVUZEM-UHFFFAOYSA-N 0.000 description 11
- 239000002609 medium Substances 0.000 description 11
- 239000012991 xanthate Substances 0.000 description 11
- 108090000790 Enzymes Proteins 0.000 description 10
- 102000004190 Enzymes Human genes 0.000 description 10
- 229960000583 acetic acid Drugs 0.000 description 9
- 239000001913 cellulose Substances 0.000 description 9
- 229920002678 cellulose Polymers 0.000 description 9
- 238000002360 preparation method Methods 0.000 description 9
- 238000007792 addition Methods 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 8
- 238000002156 mixing Methods 0.000 description 8
- 229930006000 Sucrose Natural products 0.000 description 7
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 7
- 238000002474 experimental method Methods 0.000 description 7
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 239000005720 sucrose Substances 0.000 description 7
- 108010055629 Glucosyltransferases Proteins 0.000 description 6
- 102000000340 Glucosyltransferases Human genes 0.000 description 6
- 239000004743 Polypropylene Substances 0.000 description 6
- 239000012362 glacial acetic acid Substances 0.000 description 6
- 239000011521 glass Substances 0.000 description 6
- 229920001155 polypropylene Polymers 0.000 description 6
- 235000017557 sodium bicarbonate Nutrition 0.000 description 6
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 6
- 229920002307 Dextran Polymers 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 5
- 230000015556 catabolic process Effects 0.000 description 5
- 238000006731 degradation reaction Methods 0.000 description 5
- 239000000284 extract Substances 0.000 description 5
- 230000037361 pathway Effects 0.000 description 5
- 229920000742 Cotton Polymers 0.000 description 4
- 238000005481 NMR spectroscopy Methods 0.000 description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
- 229920002472 Starch Polymers 0.000 description 4
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 4
- 239000004327 boric acid Substances 0.000 description 4
- CSNNHWWHGAXBCP-UHFFFAOYSA-L magnesium sulphate Substances [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 4
- 239000000523 sample Substances 0.000 description 4
- 229910052938 sodium sulfate Inorganic materials 0.000 description 4
- 235000011152 sodium sulphate Nutrition 0.000 description 4
- 239000008107 starch Substances 0.000 description 4
- 235000019698 starch Nutrition 0.000 description 4
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 4
- 229910000368 zinc sulfate Inorganic materials 0.000 description 4
- 241000660147 Escherichia coli str. K-12 substr. MG1655 Species 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 239000007832 Na2SO4 Substances 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 241000194024 Streptococcus salivarius Species 0.000 description 3
- 239000002518 antifoaming agent Substances 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 3
- 235000019341 magnesium sulphate Nutrition 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000000053 physical method Methods 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 108090000623 proteins and genes Proteins 0.000 description 3
- 238000011218 seed culture Methods 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- 239000011686 zinc sulphate Substances 0.000 description 3
- 235000009529 zinc sulphate Nutrition 0.000 description 3
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- 108020004414 DNA Proteins 0.000 description 2
- 241000588724 Escherichia coli Species 0.000 description 2
- 239000007836 KH2PO4 Substances 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- AVKUERGKIZMTKX-NJBDSQKTSA-N ampicillin Chemical compound C1([C@@H](N)C(=O)N[C@H]2[C@H]3SC([C@@H](N3C2=O)C(O)=O)(C)C)=CC=CC=C1 AVKUERGKIZMTKX-NJBDSQKTSA-N 0.000 description 2
- 229960000723 ampicillin Drugs 0.000 description 2
- AFYNADDZULBEJA-UHFFFAOYSA-N bicinchoninic acid Chemical compound C1=CC=CC2=NC(C=3C=C(C4=CC=CC=C4N=3)C(=O)O)=CC(C(O)=O)=C21 AFYNADDZULBEJA-UHFFFAOYSA-N 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 229940041514 candida albicans extract Drugs 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000005119 centrifugation Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 239000012065 filter cake Substances 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 150000004688 heptahydrates Chemical class 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 230000006698 induction Effects 0.000 description 2
- 238000010369 molecular cloning Methods 0.000 description 2
- 229910000402 monopotassium phosphate Inorganic materials 0.000 description 2
- 235000019796 monopotassium phosphate Nutrition 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000013612 plasmid Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 150000004804 polysaccharides Polymers 0.000 description 2
- GNSKLFRGEWLPPA-UHFFFAOYSA-M potassium dihydrogen phosphate Chemical compound [K+].OP(O)([O-])=O GNSKLFRGEWLPPA-UHFFFAOYSA-M 0.000 description 2
- 238000001542 size-exclusion chromatography Methods 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 2
- 229960000999 sodium citrate dihydrate Drugs 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 239000011550 stock solution Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000011573 trace mineral Substances 0.000 description 2
- 235000013619 trace mineral Nutrition 0.000 description 2
- 238000002166 wet spinning Methods 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- 239000012138 yeast extract Substances 0.000 description 2
- YTPMCWYIRHLEGM-BQYQJAHWSA-N 1-[(e)-2-propylsulfonylethenyl]sulfonylpropane Chemical compound CCCS(=O)(=O)\C=C\S(=O)(=O)CCC YTPMCWYIRHLEGM-BQYQJAHWSA-N 0.000 description 1
- GZCGUPFRVQAUEE-UHFFFAOYSA-N 2,3,4,5,6-pentahydroxyhexanal Chemical compound OCC(O)C(O)C(O)C(O)C=O GZCGUPFRVQAUEE-UHFFFAOYSA-N 0.000 description 1
- FWMNVWWHGCHHJJ-SKKKGAJSSA-N 4-amino-1-[(2r)-6-amino-2-[[(2r)-2-[[(2r)-2-[[(2r)-2-amino-3-phenylpropanoyl]amino]-3-phenylpropanoyl]amino]-4-methylpentanoyl]amino]hexanoyl]piperidine-4-carboxylic acid Chemical compound C([C@H](C(=O)N[C@H](CC(C)C)C(=O)N[C@H](CCCCN)C(=O)N1CCC(N)(CC1)C(O)=O)NC(=O)[C@H](N)CC=1C=CC=CC=1)C1=CC=CC=C1 FWMNVWWHGCHHJJ-SKKKGAJSSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 229920000856 Amylose Polymers 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- YASYEJJMZJALEJ-UHFFFAOYSA-N Citric acid monohydrate Chemical compound O.OC(=O)CC(O)(C(O)=O)CC(O)=O YASYEJJMZJALEJ-UHFFFAOYSA-N 0.000 description 1
- 108020004705 Codon Proteins 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 240000005265 Lupinus mutabilis Species 0.000 description 1
- 235000008755 Lupinus mutabilis Nutrition 0.000 description 1
- XDIYNQZUNSSENW-ZCEBMVQDSA-N OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)C=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O Chemical compound OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)C=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O XDIYNQZUNSSENW-ZCEBMVQDSA-N 0.000 description 1
- 108020004511 Recombinant DNA Proteins 0.000 description 1
- 235000019095 Sechium edule Nutrition 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000005273 aeration Methods 0.000 description 1
- 125000000704 aldohexosyl group Chemical group 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- FRHBOQMZUOWXQL-UHFFFAOYSA-L ammonium ferric citrate Chemical compound [NH4+].[Fe+3].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O FRHBOQMZUOWXQL-UHFFFAOYSA-L 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 235000011148 calcium chloride Nutrition 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229960002303 citric acid monohydrate Drugs 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 238000000502 dialysis Methods 0.000 description 1
- 238000002050 diffraction method Methods 0.000 description 1
- 150000004683 dihydrates Chemical class 0.000 description 1
- ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 description 1
- 235000019797 dipotassium phosphate Nutrition 0.000 description 1
- 229910000396 dipotassium phosphate Inorganic materials 0.000 description 1
- USAIOOFEIMNEDN-UHFFFAOYSA-L disodium;carbonotrithioate Chemical compound [Na+].[Na+].[S-]C([S-])=S USAIOOFEIMNEDN-UHFFFAOYSA-L 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 229960004642 ferric ammonium citrate Drugs 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000001963 growth medium Substances 0.000 description 1
- 150000002373 hemiacetals Chemical class 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000004313 iron ammonium citrate Substances 0.000 description 1
- 235000000011 iron ammonium citrate Nutrition 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 238000009629 microbiological culture Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 238000001208 nuclear magnetic resonance pulse sequence Methods 0.000 description 1
- 108020004707 nucleic acids Proteins 0.000 description 1
- 102000039446 nucleic acids Human genes 0.000 description 1
- 150000007523 nucleic acids Chemical class 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 150000004686 pentahydrates Chemical class 0.000 description 1
- 230000029553 photosynthesis Effects 0.000 description 1
- 238000010672 photosynthesis Methods 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 239000008057 potassium phosphate buffer Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000002731 protein assay Methods 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- RYVMUASDIZQXAA-UHFFFAOYSA-N pyranoside Natural products O1C2(OCC(C)C(OC3C(C(O)C(O)C(CO)O3)O)C2)C(C)C(C2(CCC3C4(C)CC5O)C)C1CC2C3CC=C4CC5OC(C(C1O)O)OC(CO)C1OC(C1OC2C(C(OC3C(C(O)C(O)C(CO)O3)O)C(O)C(CO)O2)O)OC(CO)C(O)C1OC1OCC(O)C(O)C1O RYVMUASDIZQXAA-UHFFFAOYSA-N 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000012064 sodium phosphate buffer Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/06—Wet spinning methods
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B37/00—Preparation of polysaccharides not provided for in groups C08B1/00 - C08B35/00; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B37/00—Preparation of polysaccharides not provided for in groups C08B1/00 - C08B35/00; Derivatives thereof
- C08B37/0006—Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid
- C08B37/0009—Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid alpha-D-Glucans, e.g. polydextrose, alternan, glycogen; (alpha-1,4)(alpha-1,6)-D-Glucans; (alpha-1,3)(alpha-1,4)-D-Glucans, e.g. isolichenan or nigeran; (alpha-1,4)-D-Glucans; (alpha-1,3)-D-Glucans, e.g. pseudonigeran; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B37/00—Preparation of polysaccharides not provided for in groups C08B1/00 - C08B35/00; Derivatives thereof
- C08B37/0006—Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid
- C08B37/0009—Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid alpha-D-Glucans, e.g. polydextrose, alternan, glycogen; (alpha-1,4)(alpha-1,6)-D-Glucans; (alpha-1,3)(alpha-1,4)-D-Glucans, e.g. isolichenan or nigeran; (alpha-1,4)-D-Glucans; (alpha-1,3)-D-Glucans, e.g. pseudonigeran; Derivatives thereof
- C08B37/0021—Dextran, i.e. (alpha-1,4)-D-glucan; Derivatives thereof, e.g. Sephadex, i.e. crosslinked dextran
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L5/00—Compositions of polysaccharides or of their derivatives not provided for in groups C08L1/00 or C08L3/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L5/00—Compositions of polysaccharides or of their derivatives not provided for in groups C08L1/00 or C08L3/00
- C08L5/02—Dextran; Derivatives thereof
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F11/00—Chemical after-treatment of artificial filaments or the like during manufacture
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S424/00—Drug, bio-affecting and body treating compositions
- Y10S424/13—Burn treatment
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Textile Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Molecular Biology (AREA)
- General Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Artificial Filaments (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/479,990 US9034092B2 (en) | 2012-05-24 | 2012-05-24 | Composition for preparing polysaccharide fibers |
| US13/479,990 | 2012-05-24 | ||
| PCT/US2013/042329 WO2013177348A1 (en) | 2012-05-24 | 2013-05-23 | Novel composition for preparing polysaccharide fibers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2873322A1 true CA2873322A1 (en) | 2013-11-28 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2873322A Abandoned CA2873322A1 (en) | 2012-05-24 | 2013-05-23 | Novel composition for preparing polysaccharide fibers |
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| Country | Link |
|---|---|
| US (2) | US9034092B2 (enExample) |
| EP (1) | EP2855536B1 (enExample) |
| JP (1) | JP6167172B2 (enExample) |
| KR (1) | KR102049792B1 (enExample) |
| CN (1) | CN104379607B (enExample) |
| AU (1) | AU2013266331B2 (enExample) |
| BR (1) | BR112014028870B1 (enExample) |
| CA (1) | CA2873322A1 (enExample) |
| IN (1) | IN2014DN08909A (enExample) |
| MY (1) | MY166348A (enExample) |
| NZ (1) | NZ701241A (enExample) |
| PH (1) | PH12014502607B1 (enExample) |
| SG (1) | SG11201407488SA (enExample) |
| WO (1) | WO2013177348A1 (enExample) |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
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| US9034092B2 (en) * | 2012-05-24 | 2015-05-19 | E I Du Pont De Nemours And Company | Composition for preparing polysaccharide fibers |
| JP6305509B2 (ja) * | 2013-03-15 | 2018-04-04 | シマノ アメリカン コーポレイションＳｈｉｍａｎｏ Ａｍｅｒｉｃａｎ Ｃｏｒｐｏｒａｔｉｏｎ | 加熱液体テーパ付ライン生産装置および方法 |
| AT514137A1 (de) * | 2013-04-05 | 2014-10-15 | Lenzing Akiengesellschaft | Polysaccharidfaser und Verfahren zu ihrer Herstellung |
| AT514136A1 (de) | 2013-04-05 | 2014-10-15 | Lenzing Akiengesellschaft | Polysaccharidfaser mit erhöhtem Fibrillationsvermögen und Verfahren zu ihrer Herstellung |
| AT514476A1 (de) * | 2013-06-17 | 2015-01-15 | Lenzing Akiengesellschaft | Polysaccharidfaser und Verfahren zu ihrer Herstellung |
| AT514475B1 (de) * | 2013-06-17 | 2016-11-15 | Chemiefaser Lenzing Ag | Polysaccharidfaser und Verfahren zu ihrer Herstellung |
| AT514468A1 (de) | 2013-06-17 | 2015-01-15 | Lenzing Akiengesellschaft | Hochsaugfähige Polysaccharidfaser und ihre Verwendung |
| AT514474B1 (de) * | 2013-06-18 | 2016-02-15 | Chemiefaser Lenzing Ag | Polysaccharidfaser und Verfahren zu ihrer Herstellung |
| US20150126730A1 (en) * | 2013-11-07 | 2015-05-07 | E I Du Pont De Nemours And Company | Novel composition for preparing polysaccharide fibers |
| CN106103551A (zh) | 2014-01-06 | 2016-11-09 | 纳幕尔杜邦公司 | 聚α‑1,3‑葡聚糖膜的制备 |
| WO2015109066A1 (en) | 2014-01-17 | 2015-07-23 | E. I. Du Pont De Nemours And Company | Production of poly alpha-1,3-glucan formate films |
| WO2015200593A1 (en) * | 2014-06-26 | 2015-12-30 | E.I. Du Pont De Nemours And Company | Production of poly alpha-1,3-glucan formate films |
| WO2015200612A1 (en) * | 2014-06-26 | 2015-12-30 | E. I. Du Pont De Nemours And Company | Production of poly alpha-1,3-glucan food casings |
| WO2015200589A1 (en) * | 2014-06-26 | 2015-12-30 | E. I. Du Pont De Nemours And Company | Production of poly alpha-1,3-glucan films |
| JP2017525791A (ja) * | 2014-06-26 | 2017-09-07 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーＥ．Ｉ．Ｄｕ Ｐｏｎｔ Ｄｅ Ｎｅｍｏｕｒｓ Ａｎｄ Ｃｏｍｐａｎｙ | ポリα−１，３−グルカンエステルフィルムの作製 |
| BR112017013368B1 (pt) * | 2014-12-22 | 2021-11-23 | Nutrition & Biosciences USA 4, Inc. | Composição de mistura polimérica |
| EP3253454B1 (en) | 2015-02-06 | 2020-04-22 | DuPont Industrial Biosciences USA, LLC | Colloidal dispersions of poly alpha-1,3-glucan based polymers |
| JP6956013B2 (ja) * | 2015-06-01 | 2021-10-27 | ニュートリション・アンド・バイオサイエンシーズ・ユーエスエー・フォー，インコーポレイテッド | ポリα−１，３−グルカンフィブリッド及びその使用、並びにポリα−１，３−グルカンフィブリッドを製造する方法 |
| WO2016196021A1 (en) | 2015-06-01 | 2016-12-08 | E I Du Pont De Nemours And Company | Structured liquid compositions comprising colloidal dispersions of poly alpha-1,3-glucan |
| EP3368717B1 (en) | 2015-10-26 | 2022-12-14 | Nutrition & Biosciences USA 4, Inc. | Polysaccharide coatings for paper |
| CN108350660B (zh) | 2015-10-26 | 2022-04-29 | 营养与生物科学美国4公司 | 水不溶性α-(1，3→葡聚糖)组合物 |
| JP6970678B2 (ja) * | 2015-11-10 | 2021-11-24 | ニュートリション・アンド・バイオサイエンシーズ・ユーエスエー・フォー，インコーポレイテッド | グルカン不織ウェブ |
| WO2017083228A1 (en) | 2015-11-13 | 2017-05-18 | E. I. Du Pont De Nemours And Company | Glucan fiber compositions for use in laundry care and fabric care |
| WO2017083229A1 (en) | 2015-11-13 | 2017-05-18 | E. I. Du Pont De Nemours And Company | Glucan fiber compositions for use in laundry care and fabric care |
| WO2017083226A1 (en) | 2015-11-13 | 2017-05-18 | E. I. Du Pont De Nemours And Company | Glucan fiber compositions for use in laundry care and fabric care |
| US10895028B2 (en) | 2015-12-14 | 2021-01-19 | Dupont Industrial Biosciences Usa, Llc | Nonwoven glucan webs |
| CN107366031A (zh) * | 2017-07-19 | 2017-11-21 | 宜宾运通塑料助剂有限公司 | 一种湿法纺丝机、氯化聚氯乙烯纤维及其制备方法 |
| CN114828992B (zh) * | 2019-12-23 | 2024-05-17 | 东丽株式会社 | 分离膜和其制造方法 |
| CN113136628B (zh) * | 2021-05-25 | 2023-04-28 | 清华大学 | 一种生物纤维及其制备方法和湿法纺丝装置 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6054322B2 (ja) | 1977-09-30 | 1985-11-29 | 株式会社林原生物化学研究所 | 成形物の製法 |
| US4501886A (en) | 1982-08-09 | 1985-02-26 | E. I. Du Pont De Nemours And Company | Cellulosic fibers from anisotropic solutions |
| JPS6040102A (ja) * | 1983-08-15 | 1985-03-02 | Asahi Chem Ind Co Ltd | ビスコ−スの製造法 |
| JPH0621184B2 (ja) * | 1985-05-01 | 1994-03-23 | 旭化成工業株式会社 | セルロ−ス系のド−プ |
| JPS61239018A (ja) * | 1986-04-14 | 1986-10-24 | Shogo Sataku | 繊維の連続製造法 |
| KR20010101647A (ko) * | 1999-01-25 | 2001-11-14 | 메리 이. 보울러 | 폴리사카라이드 섬유 |
| US8013148B2 (en) * | 2003-07-09 | 2011-09-06 | Ezaki Glico Co., Ltd. | Molded object comprising α-1,4-glucans and/or modifications thereof and process for producing the same |
| DE10357260A1 (de) | 2003-12-08 | 2005-06-30 | Degussa Food Ingredients Gmbh | Polysaccharid-Derivate, deren Herstellung und Verwendung |
| US8642757B2 (en) * | 2011-09-09 | 2014-02-04 | E I Du Pont De Nemours And Company | High titer production of highly linear poly (α 1,3 glucan) |
| TWI565801B (zh) * | 2011-10-05 | 2017-01-11 | 杜邦股份有限公司 | 用於製備多醣纖維之新穎組成物 |
| WO2013052730A1 (en) * | 2011-10-05 | 2013-04-11 | E. I. Du Pont De Nemours And Company | Novel composition for preparing polysaccharide fibers |
| WO2013096502A1 (en) * | 2011-12-19 | 2013-06-27 | E. I. Du Pont De Nemours And Company | INCREASED POLY (α 1, 3 GLUCAN) YIELD USING BORIC ACID |
| US9334584B2 (en) * | 2011-12-21 | 2016-05-10 | E I Du Pont De Nemours And Company | Process for preparing polysaccharide fibers from aqueous alkali metal hydroxide solution |
| SG11201403710RA (en) * | 2011-12-30 | 2014-07-30 | Du Pont | Fiber composition comprising 1,3-glucan and a method of preparing same |
| US9034092B2 (en) * | 2012-05-24 | 2015-05-19 | E I Du Pont De Nemours And Company | Composition for preparing polysaccharide fibers |
| EP2900828B1 (en) * | 2012-09-25 | 2023-04-19 | Nutrition & Biosciences USA 4, Inc. | Glucosyltransferase enzymes for production of glucan polymers |
-
2012
- 2012-05-24 US US13/479,990 patent/US9034092B2/en active Active
-
2013
- 2013-05-23 WO PCT/US2013/042329 patent/WO2013177348A1/en not_active Ceased
- 2013-05-23 MY MYPI2014002990A patent/MY166348A/en unknown
- 2013-05-23 JP JP2015514170A patent/JP6167172B2/ja active Active
- 2013-05-23 SG SG11201407488SA patent/SG11201407488SA/en unknown
- 2013-05-23 BR BR112014028870-4A patent/BR112014028870B1/pt active IP Right Grant
- 2013-05-23 CN CN201380027081.8A patent/CN104379607B/zh active Active
- 2013-05-23 AU AU2013266331A patent/AU2013266331B2/en active Active
- 2013-05-23 KR KR1020147035559A patent/KR102049792B1/ko not_active Expired - Fee Related
- 2013-05-23 NZ NZ701241A patent/NZ701241A/en not_active IP Right Cessation
- 2013-05-23 CA CA2873322A patent/CA2873322A1/en not_active Abandoned
- 2013-05-23 EP EP13726657.3A patent/EP2855536B1/en active Active
-
2014
- 2014-10-24 IN IN8909DEN2014 patent/IN2014DN08909A/en unknown
- 2014-11-21 PH PH12014502607A patent/PH12014502607B1/en unknown
-
2015
- 2015-04-16 US US14/688,801 patent/US9540747B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| WO2013177348A1 (en) | 2013-11-28 |
| KR102049792B1 (ko) | 2019-11-28 |
| US20150225877A1 (en) | 2015-08-13 |
| MY166348A (en) | 2018-06-25 |
| SG11201407488SA (en) | 2014-12-30 |
| AU2013266331A1 (en) | 2014-11-13 |
| AU2013266331B2 (en) | 2016-10-27 |
| BR112014028870B1 (pt) | 2020-12-29 |
| US20130313737A1 (en) | 2013-11-28 |
| CN104379607B (zh) | 2016-11-09 |
| JP2015518926A (ja) | 2015-07-06 |
| EP2855536B1 (en) | 2016-12-21 |
| PH12014502607A1 (en) | 2015-01-21 |
| KR20150021053A (ko) | 2015-02-27 |
| US9034092B2 (en) | 2015-05-19 |
| PH12014502607B1 (en) | 2015-01-21 |
| JP6167172B2 (ja) | 2017-07-19 |
| BR112014028870A2 (pt) | 2017-06-27 |
| EP2855536A1 (en) | 2015-04-08 |
| US9540747B2 (en) | 2017-01-10 |
| CN104379607A (zh) | 2015-02-25 |
| NZ701241A (en) | 2016-01-29 |
| IN2014DN08909A (enExample) | 2015-05-22 |
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