CA2843762C - Barrier coatings for films and structures - Google Patents
Barrier coatings for films and structures Download PDFInfo
- Publication number
- CA2843762C CA2843762C CA2843762A CA2843762A CA2843762C CA 2843762 C CA2843762 C CA 2843762C CA 2843762 A CA2843762 A CA 2843762A CA 2843762 A CA2843762 A CA 2843762A CA 2843762 C CA2843762 C CA 2843762C
- Authority
- CA
- Canada
- Prior art keywords
- lithium
- coating
- film
- ammonium
- vermiculite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 238000000576 coating method Methods 0.000 title claims abstract description 179
- 230000004888 barrier function Effects 0.000 title abstract description 82
- 239000011248 coating agent Substances 0.000 claims abstract description 154
- -1 allyl ammonium Chemical compound 0.000 claims abstract description 106
- 229920000642 polymer Polymers 0.000 claims abstract description 86
- 239000010455 vermiculite Substances 0.000 claims abstract description 71
- 235000019354 vermiculite Nutrition 0.000 claims abstract description 71
- 229910052902 vermiculite Inorganic materials 0.000 claims abstract description 71
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 claims abstract description 67
- 239000000126 substance Substances 0.000 claims abstract description 66
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims abstract description 64
- 239000000203 mixture Substances 0.000 claims abstract description 59
- 229910052744 lithium Inorganic materials 0.000 claims abstract description 58
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims abstract description 55
- 238000000034 method Methods 0.000 claims abstract description 52
- 239000003381 stabilizer Substances 0.000 claims abstract description 48
- 239000000463 material Substances 0.000 claims abstract description 46
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims abstract description 42
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 40
- 229910003002 lithium salt Inorganic materials 0.000 claims abstract description 24
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 23
- 150000001735 carboxylic acids Chemical class 0.000 claims abstract description 23
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 23
- 159000000002 lithium salts Chemical class 0.000 claims abstract description 23
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 22
- 229930195729 fatty acid Natural products 0.000 claims abstract description 22
- 239000000194 fatty acid Substances 0.000 claims abstract description 22
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 22
- OBMBYGXRLQQDHH-KVVVOXFISA-N morpholin-4-ium;(z)-octadec-9-enoate Chemical compound C1COCCN1.CCCCCCCC\C=C/CCCCCCCC(O)=O OBMBYGXRLQQDHH-KVVVOXFISA-N 0.000 claims abstract description 21
- 150000001450 anions Chemical class 0.000 claims abstract description 19
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 18
- 125000002091 cationic group Chemical group 0.000 claims abstract description 17
- 239000002738 chelating agent Substances 0.000 claims abstract description 17
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims abstract description 17
- 150000003009 phosphonic acids Chemical class 0.000 claims abstract description 16
- 150000003016 phosphoric acids Chemical class 0.000 claims abstract description 16
- 150000003460 sulfonic acids Chemical class 0.000 claims abstract description 16
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 claims description 41
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 41
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 35
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 35
- 239000001301 oxygen Substances 0.000 claims description 35
- 229910052760 oxygen Inorganic materials 0.000 claims description 35
- 229940071264 lithium citrate Drugs 0.000 claims description 24
- WJSIUCDMWSDDCE-UHFFFAOYSA-K lithium citrate (anhydrous) Chemical compound [Li+].[Li+].[Li+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O WJSIUCDMWSDDCE-UHFFFAOYSA-K 0.000 claims description 24
- 239000000123 paper Substances 0.000 claims description 24
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 20
- 230000005540 biological transmission Effects 0.000 claims description 19
- 239000000565 sealant Substances 0.000 claims description 19
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 claims description 18
- 150000001875 compounds Chemical class 0.000 claims description 18
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 17
- 239000006185 dispersion Substances 0.000 claims description 17
- 229920000728 polyester Polymers 0.000 claims description 17
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 17
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 17
- 229940015043 glyoxal Drugs 0.000 claims description 16
- 239000012298 atmosphere Substances 0.000 claims description 15
- 239000000796 flavoring agent Substances 0.000 claims description 13
- 239000004698 Polyethylene Substances 0.000 claims description 12
- 239000005014 poly(hydroxyalkanoate) Substances 0.000 claims description 12
- 239000005033 polyvinylidene chloride Substances 0.000 claims description 12
- 239000000725 suspension Substances 0.000 claims description 12
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 claims description 11
- 229920001328 Polyvinylidene chloride Polymers 0.000 claims description 11
- 235000019634 flavors Nutrition 0.000 claims description 11
- 229920000747 poly(lactic acid) Polymers 0.000 claims description 11
- 230000008569 process Effects 0.000 claims description 11
- 239000002131 composite material Substances 0.000 claims description 10
- 229920000573 polyethylene Polymers 0.000 claims description 10
- 229920000903 polyhydroxyalkanoate Polymers 0.000 claims description 10
- 239000004626 polylactic acid Substances 0.000 claims description 10
- 235000010350 erythorbic acid Nutrition 0.000 claims description 9
- 239000004715 ethylene vinyl alcohol Substances 0.000 claims description 9
- 239000004677 Nylon Substances 0.000 claims description 8
- 229920001577 copolymer Polymers 0.000 claims description 8
- 229920001778 nylon Polymers 0.000 claims description 8
- 239000011127 biaxially oriented polypropylene Substances 0.000 claims description 7
- 229920006378 biaxially oriented polypropylene Polymers 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 229940026231 erythorbate Drugs 0.000 claims description 7
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 7
- 239000011118 polyvinyl acetate Substances 0.000 claims description 7
- 239000004800 polyvinyl chloride Substances 0.000 claims description 7
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 7
- HGPXWXLYXNVULB-UHFFFAOYSA-M lithium stearate Chemical compound [Li+].CCCCCCCCCCCCCCCCCC([O-])=O HGPXWXLYXNVULB-UHFFFAOYSA-M 0.000 claims description 6
- 239000004793 Polystyrene Substances 0.000 claims description 5
- 239000003963 antioxidant agent Substances 0.000 claims description 5
- 235000016213 coffee Nutrition 0.000 claims description 5
- 235000013353 coffee beverage Nutrition 0.000 claims description 5
- 229920000058 polyacrylate Polymers 0.000 claims description 5
- XMGQYMWWDOXHJM-JTQLQIEISA-N (+)-α-limonene Chemical compound CC(=C)[C@@H]1CCC(C)=CC1 XMGQYMWWDOXHJM-JTQLQIEISA-N 0.000 claims description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 4
- 125000005210 alkyl ammonium group Chemical group 0.000 claims description 4
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 4
- 239000005025 cast polypropylene Substances 0.000 claims description 4
- WTWBUQJHJGUZCY-UHFFFAOYSA-N cuminaldehyde Chemical compound CC(C)C1=CC=C(C=O)C=C1 WTWBUQJHJGUZCY-UHFFFAOYSA-N 0.000 claims description 4
- RRAFCDWBNXTKKO-UHFFFAOYSA-N eugenol Chemical compound COC1=CC(CC=C)=CC=C1O RRAFCDWBNXTKKO-UHFFFAOYSA-N 0.000 claims description 4
- 239000001307 helium Substances 0.000 claims description 4
- 229910052734 helium Inorganic materials 0.000 claims description 4
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 claims description 4
- 125000000623 heterocyclic group Chemical group 0.000 claims description 4
- 239000005026 oriented polypropylene Substances 0.000 claims description 4
- 229920002223 polystyrene Polymers 0.000 claims description 4
- 238000012545 processing Methods 0.000 claims description 4
- ZMGMDXCADSRNCX-UHFFFAOYSA-N 5,6-dihydroxy-1,3-diazepan-2-one Chemical compound OC1CNC(=O)NCC1O ZMGMDXCADSRNCX-UHFFFAOYSA-N 0.000 claims description 3
- 235000019219 chocolate Nutrition 0.000 claims description 3
- 239000003921 oil Substances 0.000 claims description 3
- 239000012748 slip agent Substances 0.000 claims description 3
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 claims description 2
- NPBVQXIMTZKSBA-UHFFFAOYSA-N Chavibetol Natural products COC1=CC=C(CC=C)C=C1O NPBVQXIMTZKSBA-UHFFFAOYSA-N 0.000 claims description 2
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 claims description 2
- 239000005770 Eugenol Substances 0.000 claims description 2
- UVMRYBDEERADNV-UHFFFAOYSA-N Pseudoeugenol Natural products COC1=CC(C(C)=C)=CC=C1O UVMRYBDEERADNV-UHFFFAOYSA-N 0.000 claims description 2
- 229960002217 eugenol Drugs 0.000 claims description 2
- 229940041616 menthol Drugs 0.000 claims description 2
- 239000003607 modifier Substances 0.000 claims description 2
- 229920005644 polyethylene terephthalate glycol copolymer Polymers 0.000 claims description 2
- 239000000080 wetting agent Substances 0.000 claims description 2
- 230000003078 antioxidant effect Effects 0.000 claims 1
- 239000013530 defoamer Substances 0.000 claims 1
- UFRKOOWSQGXVKV-UHFFFAOYSA-N ethene;ethenol Chemical compound C=C.OC=C UFRKOOWSQGXVKV-UHFFFAOYSA-N 0.000 claims 1
- 230000007704 transition Effects 0.000 claims 1
- 150000001412 amines Chemical class 0.000 abstract description 13
- 239000000758 substrate Substances 0.000 abstract description 10
- 239000000243 solution Substances 0.000 description 77
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 35
- 239000000047 product Substances 0.000 description 23
- 238000012360 testing method Methods 0.000 description 22
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- 239000004033 plastic Substances 0.000 description 14
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 13
- 239000002245 particle Substances 0.000 description 12
- 229920005989 resin Polymers 0.000 description 12
- 239000011347 resin Substances 0.000 description 12
- 239000008199 coating composition Substances 0.000 description 11
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- 229920002799 BoPET Polymers 0.000 description 8
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- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 8
- 239000002987 primer (paints) Substances 0.000 description 8
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- 238000001125 extrusion Methods 0.000 description 7
- 235000019645 odor Nutrition 0.000 description 7
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 238000009792 diffusion process Methods 0.000 description 6
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- 229910052708 sodium Inorganic materials 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- 244000223014 Syzygium aromaticum Species 0.000 description 5
- 235000016639 Syzygium aromaticum Nutrition 0.000 description 5
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- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 4
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- 238000011109 contamination Methods 0.000 description 4
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Classifications
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
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- C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
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- C08J2429/02—Homopolymers or copolymers of unsaturated alcohols
- C08J2429/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
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- C—CHEMISTRY; METALLURGY
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K2003/2203—Oxides; Hydroxides of metals of lithium
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- C—CHEMISTRY; METALLURGY
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
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- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
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- C—CHEMISTRY; METALLURGY
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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Landscapes
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- Inorganic Chemistry (AREA)
- Laminated Bodies (AREA)
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- Wrappers (AREA)
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Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161513853P | 2011-08-01 | 2011-08-01 | |
| US61/513,853 | 2011-08-01 | ||
| PCT/US2012/049109 WO2013019833A1 (en) | 2011-08-01 | 2012-08-01 | Barrier coatings for films and structures |
Publications (2)
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| CA2843762A1 CA2843762A1 (en) | 2013-02-07 |
| CA2843762C true CA2843762C (en) | 2019-12-24 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2843762A Active CA2843762C (en) | 2011-08-01 | 2012-08-01 | Barrier coatings for films and structures |
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|---|---|
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| EP (1) | EP2739674B1 (enExample) |
| JP (1) | JP6360647B2 (enExample) |
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| RU (1) | RU2014107901A (enExample) |
| WO (1) | WO2013019833A1 (enExample) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103717650B (zh) | 2011-08-01 | 2017-09-26 | 纳米包装公司 | 用于薄膜和结构的屏障涂层 |
| SG11201401159XA (en) | 2011-10-06 | 2014-04-28 | Agency Science Tech & Res | A layered silicate/polymer composite and a method of forming the same |
| CN105431591B (zh) | 2013-07-22 | 2019-05-10 | 爱适瑞运营法国公司 | 包含活性剂的纤维素纤维料幅和用于制造包含活性剂的纤维素纤维料幅的方法 |
| GB2502241B (en) * | 2013-09-19 | 2014-04-30 | Rockwell Solutions Ltd | Packaging material and methods for manufacturing the same |
| WO2015164093A1 (en) * | 2014-04-21 | 2015-10-29 | Nanopack, Inc. | Vermiculite-containing adhesive compositions |
| EP3020652A1 (de) * | 2014-11-14 | 2016-05-18 | Reno de Medici S.p.A. | Verpackungsmaterial |
| AU2015369929B2 (en) | 2014-12-22 | 2020-08-20 | Nutrition & Biosciences USA 4, Inc. | Polymeric blend containing poly alpha-1,3-glucan |
| KR102745257B1 (ko) | 2015-10-26 | 2024-12-23 | 뉴트리션 앤드 바이오사이언시스 유에스에이 4, 인크. | 종이용 다당류 코팅 |
| KR102746152B1 (ko) | 2015-10-26 | 2024-12-26 | 뉴트리션 앤드 바이오사이언시스 유에스에이 4, 인크. | 수불용성 알파-(1,3-글루칸) 조성물 |
| KR101742708B1 (ko) * | 2016-08-23 | 2017-06-01 | (주)에버켐텍 | 천연물을 이용한 식품포장재용 코팅 조성물 및 이의 제조방법 |
| US20180079556A1 (en) * | 2016-09-22 | 2018-03-22 | Tia Bodington | Reusable labeled coffee bean bag and method of operation |
| US11814229B2 (en) * | 2017-03-31 | 2023-11-14 | Amcor Flexibles North America, Inc. | Packaging and packaging film having differential barrier properties |
| TWI701198B (zh) * | 2018-05-04 | 2020-08-11 | 黃廖全 | 一種防潮單元之製造方法及其用於生化感測試片容器防潮結構 |
| DE102020114527B4 (de) * | 2020-05-29 | 2023-11-30 | Infineon Technologies Ag | Chipgehäuse und verfahren zum bilden eines chipgehäuses |
| ES2955784T3 (es) * | 2020-10-14 | 2023-12-07 | Hannes Bichsel | Granos biogranulados espumados |
| CN116376081B (zh) * | 2021-12-23 | 2025-09-09 | 江阴纳力新材料科技有限公司 | 改性聚合物膜及其制备方法、金属化聚合物膜与应用 |
| US20230356517A1 (en) * | 2022-05-06 | 2023-11-09 | Meredian, Inc. | Pha-based retort food pouch |
| US20230365828A1 (en) * | 2022-05-11 | 2023-11-16 | Sonoco Development, Inc. | Barrier coating with high aspect ratio particles |
| WO2024086222A1 (en) | 2022-10-18 | 2024-04-25 | Braskem S.A. | High-barrier multilayer film and packaging container made therefrom |
| CN120265844A (zh) * | 2022-12-08 | 2025-07-04 | 菲利普莫里斯生产公司 | 不含金属层的内衬片材材料 |
| EP4411064A1 (en) | 2023-02-06 | 2024-08-07 | Huhtamäki Oyj | A process of forming an open container for dairy, plant-based food and/or frozen food |
| KR102718263B1 (ko) * | 2023-06-26 | 2024-10-17 | 에이치비페이퍼 주식회사 | 산소차단 및 투습방지와 해리성이 개선된 적층 코팅지 및 이의 제조방법 |
| CN116922902B (zh) * | 2023-07-21 | 2025-12-09 | 长虹美菱股份有限公司 | 压缩机防护盖、冰箱及制备方法 |
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| US4801403A (en) | 1987-07-17 | 1989-01-31 | Hercules Incorporated | Aqueous mineral dispersions |
| US4885330A (en) | 1987-11-20 | 1989-12-05 | Hercules Incorporated | Non-dispersible vermiculite products |
| GB9102374D0 (en) * | 1991-02-04 | 1991-03-20 | Ici Plc | Polymeric film |
| GB9112827D0 (en) * | 1991-06-14 | 1991-07-31 | Ici Plc | Polymeric film |
| US5326500A (en) | 1993-06-14 | 1994-07-05 | W.R. Grace & Co.-Conn. | Vermiculite composition with improved chemical exfoliation |
| US5496649A (en) | 1994-07-21 | 1996-03-05 | Mobil Oil Corp. | Cross-linked PVOH coatings having enhanced barrier characteristics |
| US6444750B1 (en) | 1995-03-06 | 2002-09-03 | Exxonmobil Oil Corp. | PVOH-based coating solutions |
| DE19631530C2 (de) | 1996-07-23 | 2000-03-09 | Inst Chemo Biosensorik | Ionenselektiver Sensor |
| US6232389B1 (en) * | 1997-06-09 | 2001-05-15 | Inmat, Llc | Barrier coating of an elastomer and a dispersed layered filler in a liquid carrier and coated articles |
| JP4775921B2 (ja) | 1997-06-09 | 2011-09-21 | インマット・インコーポレーテツド | 液状担体中に分散している層状充填材と弾性重合体から作られたバリヤーコーティングおよび被覆された構成物、特にタイヤ |
| JP3726569B2 (ja) | 1999-07-26 | 2005-12-14 | セイコーエプソン株式会社 | 半透過反射型及び反射型液晶装置並びにこれらを用いた電子機器 |
| US8063119B2 (en) * | 2003-08-29 | 2011-11-22 | Inmat Inc. | Barrier coating of a non-elastomeric polymer and a dispersed layered filler in a liquid carrier and coated articles |
| JP2005126301A (ja) | 2003-10-27 | 2005-05-19 | Hojun:Kk | ゲル状粘土及びゲル状粘土の製造方法並びにゲル状粘土で生成されてなる極性有機溶剤及び極性有機溶剤中で分散し増粘させてなるゲル状粘土組成物 |
| US7119138B1 (en) * | 2003-12-19 | 2006-10-10 | Inmat Inc. | Barrier coating of a mixture of cured and uncured elastomeric polymers and a dispersed layered filler in a liquid carrier and coated articles |
| DE602007006179D1 (de) * | 2006-05-01 | 2010-06-10 | Nanopack Inc | Barriereschichten für filme und strukturen |
| US20090098395A1 (en) * | 2007-10-15 | 2009-04-16 | Pang Chia Lu | Barrier coating for thermoplastic films |
| WO2010117900A1 (en) | 2009-04-08 | 2010-10-14 | Nanopack, Inc. | Aroma barrier films and structures |
| CN103717650B (zh) | 2011-08-01 | 2017-09-26 | 纳米包装公司 | 用于薄膜和结构的屏障涂层 |
-
2012
- 2012-08-01 CN CN201280038704.7A patent/CN103717650B/zh active Active
- 2012-08-01 EP EP12747957.4A patent/EP2739674B1/en active Active
- 2012-08-01 RU RU2014107901/05A patent/RU2014107901A/ru not_active Application Discontinuation
- 2012-08-01 JP JP2014524041A patent/JP6360647B2/ja active Active
- 2012-08-01 WO PCT/US2012/049109 patent/WO2013019833A1/en not_active Ceased
- 2012-08-01 CA CA2843762A patent/CA2843762C/en active Active
- 2012-08-01 US US14/236,170 patent/US10851259B2/en active Active - Reinstated
- 2012-08-01 BR BR112014002447A patent/BR112014002447A2/pt not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| US20140377545A1 (en) | 2014-12-25 |
| BR112014002447A2 (pt) | 2017-02-21 |
| US10851259B2 (en) | 2020-12-01 |
| EP2739674A1 (en) | 2014-06-11 |
| CN103717650A (zh) | 2014-04-09 |
| CA2843762A1 (en) | 2013-02-07 |
| JP6360647B2 (ja) | 2018-07-18 |
| CN103717650B (zh) | 2017-09-26 |
| JP2014524489A (ja) | 2014-09-22 |
| RU2014107901A (ru) | 2015-09-10 |
| EP2739674B1 (en) | 2019-02-13 |
| WO2013019833A1 (en) | 2013-02-07 |
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