CA2825284A1 - Methods of removing rust from a ferrous metal-containing surface - Google Patents
Methods of removing rust from a ferrous metal-containing surface Download PDFInfo
- Publication number
- CA2825284A1 CA2825284A1 CA2825284A CA2825284A CA2825284A1 CA 2825284 A1 CA2825284 A1 CA 2825284A1 CA 2825284 A CA2825284 A CA 2825284A CA 2825284 A CA2825284 A CA 2825284A CA 2825284 A1 CA2825284 A1 CA 2825284A1
- Authority
- CA
- Canada
- Prior art keywords
- composition
- acid
- weight
- containing surface
- ferrous metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 238000000034 method Methods 0.000 title claims abstract description 59
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 title claims abstract description 41
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 30
- 239000002184 metal Substances 0.000 title claims abstract description 30
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 title claims abstract description 21
- 239000000203 mixture Substances 0.000 claims abstract description 66
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 30
- 229910001868 water Inorganic materials 0.000 claims abstract description 26
- 239000004927 clay Substances 0.000 claims abstract description 15
- AZJYLVAUMGUUBL-UHFFFAOYSA-A u1qj22mc8e Chemical compound [F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[F-].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].O=[Si]=O.O=[Si]=O.O=[Si]=O.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3 AZJYLVAUMGUUBL-UHFFFAOYSA-A 0.000 claims abstract description 13
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 40
- 239000002253 acid Substances 0.000 claims description 13
- 229910000831 Steel Inorganic materials 0.000 claims description 11
- 239000010959 steel Substances 0.000 claims description 11
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 9
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 8
- -1 aliphatic hydroxy acid Chemical class 0.000 claims description 7
- 150000001735 carboxylic acids Chemical class 0.000 claims description 6
- 229910001209 Low-carbon steel Inorganic materials 0.000 claims description 5
- 239000007921 spray Substances 0.000 claims description 5
- NCNCGGDMXMBVIA-UHFFFAOYSA-L iron(ii) hydroxide Chemical compound [OH-].[OH-].[Fe+2] NCNCGGDMXMBVIA-UHFFFAOYSA-L 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
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- 235000014413 iron hydroxide Nutrition 0.000 claims 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract description 7
- 238000003756 stirring Methods 0.000 description 15
- 229940094522 laponite Drugs 0.000 description 14
- XCOBTUNSZUJCDH-UHFFFAOYSA-B lithium magnesium sodium silicate Chemical compound [Li+].[Li+].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Na+].[Na+].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3 XCOBTUNSZUJCDH-UHFFFAOYSA-B 0.000 description 14
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- 239000008367 deionised water Substances 0.000 description 7
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 7
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- 229910021641 deionized water Inorganic materials 0.000 description 6
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- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 4
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
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- 229910021506 iron(II) hydroxide Inorganic materials 0.000 description 4
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- 230000009974 thixotropic effect Effects 0.000 description 4
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- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
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- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
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- 238000012360 testing method Methods 0.000 description 3
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/265—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/16—Metals
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Mechanical Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Emergency Medicine (AREA)
- Health & Medical Sciences (AREA)
- Detergent Compositions (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US13/011,151 | 2011-01-21 | ||
US13/011,151 US20120189485A1 (en) | 2011-01-21 | 2011-01-21 | Methods of removing rust from a ferrous metal-containing surface |
PCT/US2012/022004 WO2012100146A1 (en) | 2011-01-21 | 2012-01-20 | Methods of removing rust from a ferrous metal-containing surface |
Publications (1)
Publication Number | Publication Date |
---|---|
CA2825284A1 true CA2825284A1 (en) | 2012-07-26 |
Family
ID=45771882
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA2825284A Abandoned CA2825284A1 (en) | 2011-01-21 | 2012-01-20 | Methods of removing rust from a ferrous metal-containing surface |
Country Status (14)
Country | Link |
---|---|
US (1) | US20120189485A1 (pt) |
EP (1) | EP2665845B1 (pt) |
JP (1) | JP5693754B2 (pt) |
KR (1) | KR20130117853A (pt) |
CN (1) | CN103415651B (pt) |
AU (1) | AU2012207164B2 (pt) |
BR (1) | BR112013018680A2 (pt) |
CA (1) | CA2825284A1 (pt) |
ES (1) | ES2666452T3 (pt) |
MX (1) | MX2013008465A (pt) |
PL (1) | PL2665845T3 (pt) |
SG (1) | SG192055A1 (pt) |
TR (1) | TR201807940T4 (pt) |
WO (1) | WO2012100146A1 (pt) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8852357B2 (en) | 2011-09-30 | 2014-10-07 | Ppg Industries Ohio, Inc | Rheology modified pretreatment compositions and associated methods of use |
CN103898529B (zh) * | 2014-04-22 | 2017-02-15 | 东北大学 | 一种除锈方法 |
JP6727019B2 (ja) * | 2016-04-22 | 2020-07-22 | ショーボンド建設株式会社 | 鋼材の下地処理方法、および下地処理剤 |
CN109628940B (zh) * | 2019-01-21 | 2021-11-12 | 常熟理工学院 | 一种多羟基苯甲酸型水基中性除锈剂 |
KR102166122B1 (ko) | 2020-04-13 | 2020-10-15 | 케이알건설 주식회사 | 강 교량의 녹 또는 페인트 제거방법 |
JP2023529937A (ja) * | 2020-06-10 | 2023-07-12 | ケメタル ゲゼルシャフト ミット ベシュレンクテル ハフツング | ホスホネートを含まない水性酸洗い組成物及びその使用方法 |
JP7426641B1 (ja) | 2023-09-18 | 2024-02-02 | スズカファイン株式会社 | 既設鋼材の錆の除去方法 |
Family Cites Families (13)
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NL283747A (pt) * | 1961-09-28 | |||
CN1070957A (zh) * | 1992-09-29 | 1993-04-14 | 王光宇 | 安全酸洗液 |
US20020037822A1 (en) * | 2000-07-19 | 2002-03-28 | Foley Peter Robert | Cleaning composition |
US6514350B1 (en) * | 2000-09-15 | 2003-02-04 | Ashland Inc. | Process for removing rust from metal surfaces |
GB2385597B (en) * | 2002-02-21 | 2004-05-12 | Reckitt Benckiser Inc | Hard surface cleaning compositions |
US20040149311A1 (en) * | 2002-11-15 | 2004-08-05 | The Procter & Gamble Company | Method for cleaning cookware and tableware with film-forming liquid dishwashing compositions, and compositions therefore |
US20060079424A1 (en) * | 2004-09-23 | 2006-04-13 | Perry Stephen C | Buffered acid cleaner and method of production |
US20060076299A1 (en) * | 2004-10-08 | 2006-04-13 | The Hong Kong University Of Science And Technology | Synthesis of bentonite clay-based iron nanocomposite and its use as a heterogeneous photo fenton catalyst |
CN100532649C (zh) * | 2006-02-27 | 2009-08-26 | 徐州正菱涂装有限公司 | 一种钢铁构件涂装的前处理工艺 |
WO2008015381A1 (en) * | 2006-07-31 | 2008-02-07 | Reckitt Benckiser (Uk) Limited | Improved hard surface cleaning compositions |
DE102007039652A1 (de) * | 2006-12-05 | 2008-06-12 | Henkel Kgaa | Mittel zur Behandlung harter Oberflächen |
WO2009100226A1 (en) * | 2008-02-05 | 2009-08-13 | Amcol International Corporation | Drip resistant acidic cleaning compositions for sprayable and non-sprayable applications |
EP2166075A1 (en) * | 2008-09-23 | 2010-03-24 | The Procter and Gamble Company | Cleaning composition |
-
2011
- 2011-01-21 US US13/011,151 patent/US20120189485A1/en not_active Abandoned
-
2012
- 2012-01-20 AU AU2012207164A patent/AU2012207164B2/en not_active Ceased
- 2012-01-20 EP EP12706349.3A patent/EP2665845B1/en not_active Not-in-force
- 2012-01-20 CA CA2825284A patent/CA2825284A1/en not_active Abandoned
- 2012-01-20 PL PL12706349T patent/PL2665845T3/pl unknown
- 2012-01-20 BR BR112013018680A patent/BR112013018680A2/pt not_active Application Discontinuation
- 2012-01-20 ES ES12706349.3T patent/ES2666452T3/es active Active
- 2012-01-20 SG SG2013055413A patent/SG192055A1/en unknown
- 2012-01-20 TR TR2018/07940T patent/TR201807940T4/tr unknown
- 2012-01-20 KR KR1020137021700A patent/KR20130117853A/ko not_active Application Discontinuation
- 2012-01-20 JP JP2013550611A patent/JP5693754B2/ja not_active Expired - Fee Related
- 2012-01-20 MX MX2013008465A patent/MX2013008465A/es unknown
- 2012-01-20 WO PCT/US2012/022004 patent/WO2012100146A1/en active Application Filing
- 2012-01-20 CN CN201280010699.9A patent/CN103415651B/zh not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
US20120189485A1 (en) | 2012-07-26 |
NZ613553A (en) | 2015-11-27 |
CN103415651A (zh) | 2013-11-27 |
JP5693754B2 (ja) | 2015-04-01 |
CN103415651B (zh) | 2016-10-26 |
MX2013008465A (es) | 2013-12-06 |
WO2012100146A1 (en) | 2012-07-26 |
EP2665845B1 (en) | 2018-03-07 |
AU2012207164B2 (en) | 2015-08-20 |
KR20130117853A (ko) | 2013-10-28 |
JP2014508220A (ja) | 2014-04-03 |
BR112013018680A2 (pt) | 2016-10-18 |
PL2665845T3 (pl) | 2018-08-31 |
SG192055A1 (en) | 2013-08-30 |
EP2665845A1 (en) | 2013-11-27 |
TR201807940T4 (tr) | 2018-06-21 |
ES2666452T3 (es) | 2018-05-04 |
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EEER | Examination request |
Effective date: 20130719 |
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FZDE | Discontinued |
Effective date: 20171109 |