CA2696199C - Method for the cleaning of off-gas - Google Patents
Method for the cleaning of off-gas Download PDFInfo
- Publication number
- CA2696199C CA2696199C CA2696199A CA2696199A CA2696199C CA 2696199 C CA2696199 C CA 2696199C CA 2696199 A CA2696199 A CA 2696199A CA 2696199 A CA2696199 A CA 2696199A CA 2696199 C CA2696199 C CA 2696199C
- Authority
- CA
- Canada
- Prior art keywords
- scrubber
- scrubber stage
- stage
- gas
- value
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000000034 method Methods 0.000 title claims abstract description 52
- 238000004140 cleaning Methods 0.000 title claims abstract description 12
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 110
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims abstract description 109
- 239000004291 sulphur dioxide Substances 0.000 claims abstract description 54
- 235000010269 sulphur dioxide Nutrition 0.000 claims abstract description 54
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 39
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 24
- 235000011149 sulphuric acid Nutrition 0.000 claims abstract description 24
- 239000001117 sulphuric acid Substances 0.000 claims abstract description 22
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims abstract description 14
- 235000011130 ammonium sulphate Nutrition 0.000 claims abstract description 14
- 239000001166 ammonium sulphate Substances 0.000 claims abstract description 12
- 150000003868 ammonium compounds Chemical class 0.000 claims abstract description 5
- 239000007789 gas Substances 0.000 claims description 71
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 51
- 238000000926 separation method Methods 0.000 claims description 36
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 30
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims description 26
- 229960002163 hydrogen peroxide Drugs 0.000 claims description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 19
- 239000000243 solution Substances 0.000 claims description 14
- 238000010791 quenching Methods 0.000 claims description 11
- 230000003647 oxidation Effects 0.000 claims description 8
- 238000007254 oxidation reaction Methods 0.000 claims description 8
- 239000000428 dust Substances 0.000 claims description 7
- 239000010881 fly ash Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 239000007864 aqueous solution Substances 0.000 claims description 4
- 230000000171 quenching effect Effects 0.000 claims description 2
- 230000004907 flux Effects 0.000 claims 3
- 238000002347 injection Methods 0.000 claims 1
- 239000007924 injection Substances 0.000 claims 1
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 13
- 239000007800 oxidant agent Substances 0.000 description 13
- 239000000779 smoke Substances 0.000 description 8
- 230000007423 decrease Effects 0.000 description 7
- PQUCIEFHOVEZAU-UHFFFAOYSA-N Diammonium sulfite Chemical compound [NH4+].[NH4+].[O-]S([O-])=O PQUCIEFHOVEZAU-UHFFFAOYSA-N 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 239000002699 waste material Substances 0.000 description 5
- 230000001276 controlling effect Effects 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 239000003546 flue gas Substances 0.000 description 4
- 238000012856 packing Methods 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical class [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 235000011114 ammonium hydroxide Nutrition 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000000443 aerosol Substances 0.000 description 2
- 230000033228 biological regulation Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- XXQBEVHPUKOQEO-UHFFFAOYSA-N potassium superoxide Chemical compound [K+].[K+].[O-][O-] XXQBEVHPUKOQEO-UHFFFAOYSA-N 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 229910021653 sulphate ion Inorganic materials 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 239000000159 acid neutralizing agent Substances 0.000 description 1
- 239000001099 ammonium carbonate Substances 0.000 description 1
- 235000012501 ammonium carbonate Nutrition 0.000 description 1
- ZETCGWYACBNPIH-UHFFFAOYSA-N azane;sulfurous acid Chemical compound N.OS(O)=O ZETCGWYACBNPIH-UHFFFAOYSA-N 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 235000011116 calcium hydroxide Nutrition 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- AWADHHRPTLLUKK-UHFFFAOYSA-N diazanium sulfuric acid sulfate Chemical group [NH4+].[NH4+].OS(O)(=O)=O.[O-]S([O-])(=O)=O AWADHHRPTLLUKK-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000013505 freshwater Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000004868 gas analysis Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
- 238000004056 waste incineration Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides
- B01D53/501—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
- B01D53/502—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound characterised by a specific solution or suspension
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/38—Removing components of undefined structure
- B01D53/40—Acidic components
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/64—Heavy metals or compounds thereof, e.g. mercury
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/68—Halogens or halogen compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/75—Multi-step processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/10—Oxidants
- B01D2251/106—Peroxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/20—Reductants
- B01D2251/206—Ammonium compounds
- B01D2251/2062—Ammonia
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/60—Inorganic bases or salts
- B01D2251/604—Hydroxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/20—Halogens or halogen compounds
- B01D2257/204—Inorganic halogen compounds
- B01D2257/2045—Hydrochloric acid
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/20—Halogens or halogen compounds
- B01D2257/204—Inorganic halogen compounds
- B01D2257/2047—Hydrofluoric acid
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/30—Sulfur compounds
- B01D2257/302—Sulfur oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/60—Heavy metals or heavy metal compounds
- B01D2257/602—Mercury or mercury compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/30—Capture or disposal of greenhouse gases of perfluorocarbons [PFC], hydrofluorocarbons [HFC] or sulfur hexafluoride [SF6]
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treating Waste Gases (AREA)
- Cleaning Or Drying Semiconductors (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102007039926.1 | 2007-08-23 | ||
| DE102007039926A DE102007039926B4 (de) | 2007-08-23 | 2007-08-23 | Verfahren und Vorrichtung zur Abgasreinigung |
| PCT/EP2008/061013 WO2009024612A1 (en) | 2007-08-23 | 2008-08-22 | Method for the cleaning of off-gas |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2696199A1 CA2696199A1 (en) | 2009-02-26 |
| CA2696199C true CA2696199C (en) | 2016-03-22 |
Family
ID=40202995
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2696199A Expired - Fee Related CA2696199C (en) | 2007-08-23 | 2008-08-22 | Method for the cleaning of off-gas |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US8048392B2 (enExample) |
| EP (1) | EP2180938B1 (enExample) |
| JP (1) | JP5455907B2 (enExample) |
| KR (1) | KR101535280B1 (enExample) |
| CN (1) | CN101842147B (enExample) |
| CA (1) | CA2696199C (enExample) |
| DE (1) | DE102007039926B4 (enExample) |
| DK (1) | DK2180938T3 (enExample) |
| PL (1) | PL2180938T3 (enExample) |
| RU (1) | RU2488431C2 (enExample) |
| WO (1) | WO2009024612A1 (enExample) |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102011005525B3 (de) * | 2011-03-14 | 2012-04-05 | Untha Recyclingtechnik Gmbh | Verfahren und Anlage zur Behandlung von Kältemittel aufweisenden Fluiden |
| WO2012123223A1 (de) | 2011-03-14 | 2012-09-20 | Untha Recyclingtechnik Gmbh | Verfahren und anlage zur behandlung von kältemittel und/oder treibmittel aufweisenden fluiden |
| DE102011005523B3 (de) * | 2011-03-14 | 2012-04-05 | Untha Recyclingtechnik Gmbh | Verfahren und Anlage zur Behandlung von Kältemittel aufweisenden Fluiden |
| DE102011005522B3 (de) * | 2011-03-14 | 2012-04-05 | Untha Recyclingtechnik Gmbh | Verfahren und Anlage zur Behandlung von Kältemittel aufweisenden Fluiden |
| CN102205204B (zh) * | 2011-06-02 | 2013-08-28 | 上海大学 | 冷热态出料的湿式氨法脱硫浓缩工艺 |
| KR101349974B1 (ko) * | 2011-08-03 | 2014-01-23 | 주식회사 그린솔루스 | 가스상 황화수소 처리 방법 |
| CN102614735A (zh) * | 2012-04-13 | 2012-08-01 | 大连华氏流体设备有限公司 | 一种烟气脱硫与废弃物回收再利用的装置和方法 |
| CN102949926B (zh) * | 2012-11-16 | 2014-10-01 | 昆明理工大学 | 一种冶炼烟气中so2和重金属回收利用的方法 |
| FI126178B (en) | 2014-01-28 | 2016-07-29 | Outotec Finland Oy | METHOD FOR ELIMINATING THE GASEOUS ELEMENTAL MERCURY FROM THE GAS FLOW |
| TWI633923B (zh) * | 2014-02-10 | 2018-09-01 | 中國石油化工科技開發有限公司 | 一種處理酸性氣體的方法及裝置 |
| CN105457463A (zh) * | 2014-09-09 | 2016-04-06 | 江苏澄天环保科技有限公司 | 一种含硫尾气深度减排的方法及装置 |
| CN104474872A (zh) * | 2014-12-12 | 2015-04-01 | 秦皇岛杰伯特环境科技有限公司 | 脱硫系统 |
| CN105107354B (zh) * | 2015-07-16 | 2017-05-31 | 刘国忠 | 一种利用烟道节能同时节省资金的氨法脱硫工艺 |
| CN105148700B (zh) * | 2015-08-27 | 2018-05-08 | 北京市环境保护科学研究院 | 一种氧化吸收处理天然气锅炉烟气中污染物的方法及装置 |
| DE102017203251A1 (de) * | 2017-02-28 | 2018-08-30 | Thyssenkrupp Ag | Verfahren zur Reinigung der Abluft einer Granulierungsanlage zur Herstellung eines harnstoffhaltigen Granulats |
| CN106823730B (zh) * | 2017-03-21 | 2023-09-26 | 宁波工程学院 | 一种防止氨逃逸的氨法脱硫系统 |
| CN107213769B (zh) * | 2017-05-25 | 2019-09-20 | 江苏新世纪江南环保股份有限公司 | 一种分室加氨的氨法脱硫方法及装置 |
| CN107469602A (zh) * | 2017-08-07 | 2017-12-15 | 山东胜星化工有限公司 | 一种回收含硫尾气达标排放技术 |
| AT16120U1 (de) * | 2018-01-19 | 2019-02-15 | Scheuch Gmbh | Vorrichtung zur Reinigung von mit Staub und organischen als auch anorganischen Verbindungen belasteten Abgasen aus der holzverarbeitenden Industrie |
| EA036807B1 (ru) * | 2018-10-11 | 2020-12-23 | Юрий Петрович Шаповалов | Система и способ очистки отходящих газов от органических соединений |
| CN109569251B (zh) * | 2019-01-17 | 2020-12-11 | 北京化工大学 | 一种利用含so2烟气制稀硫酸的装置及方法 |
| CN110433630B (zh) * | 2019-08-15 | 2022-03-01 | 湖南株冶环保科技有限公司 | 一种铅锌冶炼烟气中汞深度净化和汞回收工艺 |
| CN112107983A (zh) * | 2020-08-17 | 2020-12-22 | 南京汇仁化工设备有限公司 | 一种双氧水脱硫工艺 |
| JP7230940B2 (ja) * | 2021-02-10 | 2023-03-01 | 栗田工業株式会社 | 排ガス処理設備 |
| KR20230096964A (ko) * | 2020-10-30 | 2023-06-30 | 쿠리타 고교 가부시키가이샤 | 배기 가스 처리 설비 |
| CN113908675A (zh) * | 2021-11-01 | 2022-01-11 | 大连理工大学 | 一种湿法烟气脱氯提升石膏品质的方法 |
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|---|---|---|---|---|
| US3760061A (en) | 1971-03-02 | 1973-09-18 | Du Pont | High-strength acid containing h2o2 to scrub so2 |
| JPS4989675A (enExample) * | 1972-12-27 | 1974-08-27 | ||
| JPS5513770B2 (enExample) * | 1973-09-26 | 1980-04-11 | ||
| JPS5322936B2 (enExample) * | 1974-01-23 | 1978-07-12 | ||
| JPS5227068A (en) * | 1975-08-27 | 1977-03-01 | Kureha Chem Ind Co Ltd | Exhaust gas desulfurization process |
| SU1212518A1 (ru) * | 1984-01-11 | 1986-02-23 | Ленинградский Ордена Октябрьской Революции И Ордена Трудового Красного Знамени Технологический Институт Им.Ленсовета | Способ очистки газов от сернистого ангидрида |
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| DE3507718A1 (de) * | 1985-03-05 | 1986-09-11 | Nukem Gmbh, 6450 Hanau | Verfahren zur reinigung von rauchgasen |
| US4690807A (en) | 1985-08-15 | 1987-09-01 | General Electric Environmental Services, Inc. | Process for the simultaneous absorption of sulfur oxides and production of ammonium sulfate |
| DE3733319A1 (de) | 1987-10-02 | 1989-04-13 | Krupp Koppers Gmbh | Verfahren zur entfernung von schwefeldioxid aus rauchgasen |
| JPH03275125A (ja) * | 1990-03-23 | 1991-12-05 | Ishikawajima Harima Heavy Ind Co Ltd | 硫酸塩回収装置 |
| DE4036899C2 (de) | 1990-11-20 | 2001-10-25 | Degussa | Verfahren zur Entschwefelung von SO¶2¶ enthaltenden feuchten Abgasen und Vorrichtung zur Durchführung des Verfahrens |
| IT1251334B (it) * | 1991-09-19 | 1995-05-08 | Ente Naz Energia Elettrica | Metodo per rimuovere inquinanti da un gas di combustione e impianto per attuare il metodo |
| DE59509540D1 (de) | 1995-12-06 | 2001-09-27 | Lurgi Lentjes Bischoff Gmbh | Anlage zur Reinigung von Rauchgasen mit unterschiedlichen Gehalten an sauren Komponenten und Verfahren zum Betrieb der Anlage |
| NL1003151C2 (nl) * | 1996-05-17 | 1997-11-18 | Avira Afvalverwerking Nv | Werkwijze en inrichting ter verwijdering van schadelijke stoffen, in het bijzonder dioxine. |
| DE19731062C2 (de) | 1997-07-19 | 2001-07-12 | Lurgi Lentjes Bischoff Gmbh | Verfahren zur Entfernung von sauren Gasen aus Rauchgasen, insbesondere aus Kraftwerksabgasen und Abgasen von Müllverbrennungsanlagen |
| JPH11137959A (ja) * | 1997-11-07 | 1999-05-25 | Mitsubishi Materials Corp | 窒素酸化物の除去方法とその装置 |
| JP3786786B2 (ja) * | 1998-08-27 | 2006-06-14 | 千代田化工建設株式会社 | 排煙脱硫方法 |
| US6221325B1 (en) * | 1998-09-08 | 2001-04-24 | Marsulex Environmental Technologies, Llc | Process for controlling ammonia slip in the reduction of sulfur dioxide emission |
| US6531104B1 (en) | 2000-11-21 | 2003-03-11 | Alstom (Schweiz) Ag | Process for the absorption of sulfur oxides and the production of ammonium sulfate |
| US20040062697A1 (en) * | 2002-10-01 | 2004-04-01 | Airborne Pollution Control Inc. | Flue gas purification method |
| ES2300632T3 (es) * | 2002-12-21 | 2008-06-16 | Haldor Topsoe A/S | Procedimiento para la eliminacion de so2 de gases de escape por reaccion con h202. |
| RU2256603C1 (ru) * | 2004-04-13 | 2005-07-20 | Открытое Акционерное Общество "Всероссийский теплотехнический научно-исследовательский институт" (ОАО "ВТИ") | Способ очистки дымовых газов от диоксида серы |
| DE102005041794A1 (de) * | 2005-09-02 | 2007-03-08 | Basf Ag | Verfahren und Vorrichtung zum Entfernen von Schwefeldioxid aus einem trockenen Gasstrom |
| US20070154374A1 (en) * | 2006-01-05 | 2007-07-05 | Envirosolv Energy Llc | Method for removing sulfur dioxide and other acid gases, mercury, and nitrogen oxides from a gas stream with the optional production of ammonia based fertilizers |
| CN100463847C (zh) * | 2006-06-23 | 2009-02-25 | 李开春 | 以烟道气制备硫酸的方法 |
-
2007
- 2007-08-23 DE DE102007039926A patent/DE102007039926B4/de not_active Expired - Fee Related
-
2008
- 2008-08-22 PL PL08827917T patent/PL2180938T3/pl unknown
- 2008-08-22 EP EP08827917.9A patent/EP2180938B1/en active Active
- 2008-08-22 JP JP2010521439A patent/JP5455907B2/ja not_active Expired - Fee Related
- 2008-08-22 KR KR1020107006362A patent/KR101535280B1/ko not_active Expired - Fee Related
- 2008-08-22 RU RU2010110637/05A patent/RU2488431C2/ru active
- 2008-08-22 DK DK08827917.9T patent/DK2180938T3/da active
- 2008-08-22 US US12/733,314 patent/US8048392B2/en not_active Expired - Fee Related
- 2008-08-22 CN CN200880104087XA patent/CN101842147B/zh not_active Expired - Fee Related
- 2008-08-22 CA CA2696199A patent/CA2696199C/en not_active Expired - Fee Related
- 2008-08-22 WO PCT/EP2008/061013 patent/WO2009024612A1/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| WO2009024612A1 (en) | 2009-02-26 |
| JP5455907B2 (ja) | 2014-03-26 |
| CN101842147A (zh) | 2010-09-22 |
| KR20100061812A (ko) | 2010-06-09 |
| RU2010110637A (ru) | 2011-09-27 |
| CN101842147B (zh) | 2013-03-27 |
| KR101535280B1 (ko) | 2015-07-09 |
| EP2180938A1 (en) | 2010-05-05 |
| DE102007039926A1 (de) | 2009-02-26 |
| RU2488431C2 (ru) | 2013-07-27 |
| DE102007039926B4 (de) | 2012-03-22 |
| EP2180938B1 (en) | 2014-06-18 |
| US20100296993A1 (en) | 2010-11-25 |
| PL2180938T3 (pl) | 2015-04-30 |
| US8048392B2 (en) | 2011-11-01 |
| DK2180938T3 (da) | 2014-09-01 |
| CA2696199A1 (en) | 2009-02-26 |
| JP2010536549A (ja) | 2010-12-02 |
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