CA2624384C - Polyamides and polyesters blended with a lithium salt interfacial tension reducing agent - Google Patents
Polyamides and polyesters blended with a lithium salt interfacial tension reducing agent Download PDFInfo
- Publication number
- CA2624384C CA2624384C CA2624384A CA2624384A CA2624384C CA 2624384 C CA2624384 C CA 2624384C CA 2624384 A CA2624384 A CA 2624384A CA 2624384 A CA2624384 A CA 2624384A CA 2624384 C CA2624384 C CA 2624384C
- Authority
- CA
- Canada
- Prior art keywords
- polyester
- acid
- mole percent
- moles
- lithium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920000728 polyester Polymers 0.000 title claims abstract description 142
- 239000004952 Polyamide Substances 0.000 title claims abstract description 97
- 229920002647 polyamide Polymers 0.000 title claims abstract description 97
- 239000003638 chemical reducing agent Substances 0.000 title claims abstract description 69
- 229910003002 lithium salt Inorganic materials 0.000 title description 21
- 159000000002 lithium salts Chemical class 0.000 title description 20
- 239000000203 mixture Substances 0.000 claims abstract description 76
- YESSCOKKOLMTNS-UHFFFAOYSA-L dilithium;2-sulfobenzene-1,3-dicarboxylate Chemical group [Li+].[Li+].OS(=O)(=O)C1=C(C([O-])=O)C=CC=C1C([O-])=O YESSCOKKOLMTNS-UHFFFAOYSA-L 0.000 claims description 82
- 239000002253 acid Substances 0.000 claims description 68
- 239000002245 particle Substances 0.000 claims description 63
- 101000576320 Homo sapiens Max-binding protein MNT Proteins 0.000 claims description 55
- 229920006121 Polyxylylene adipamide Polymers 0.000 claims description 55
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 55
- -1 lithium sulfonates Chemical class 0.000 claims description 45
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims description 32
- 229910052744 lithium Inorganic materials 0.000 claims description 30
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 26
- 229920001778 nylon Polymers 0.000 claims description 22
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 22
- 239000004677 Nylon Substances 0.000 claims description 21
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 18
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 15
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 claims description 12
- 238000006243 chemical reaction Methods 0.000 claims description 10
- 239000007795 chemical reaction product Substances 0.000 claims description 10
- OJURWUUOVGOHJZ-UHFFFAOYSA-N methyl 2-[(2-acetyloxyphenyl)methyl-[2-[(2-acetyloxyphenyl)methyl-(2-methoxy-2-oxoethyl)amino]ethyl]amino]acetate Chemical compound C=1C=CC=C(OC(C)=O)C=1CN(CC(=O)OC)CCN(CC(=O)OC)CC1=CC=CC=C1OC(C)=O OJURWUUOVGOHJZ-UHFFFAOYSA-N 0.000 claims description 10
- 239000001361 adipic acid Substances 0.000 claims description 9
- 235000011037 adipic acid Nutrition 0.000 claims description 9
- 150000004985 diamines Chemical class 0.000 claims description 9
- SLXKOJJOQWFEFD-UHFFFAOYSA-N 6-aminohexanoic acid Chemical compound NCCCCCC(O)=O SLXKOJJOQWFEFD-UHFFFAOYSA-N 0.000 claims description 7
- FDLQZKYLHJJBHD-UHFFFAOYSA-N [3-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=CC(CN)=C1 FDLQZKYLHJJBHD-UHFFFAOYSA-N 0.000 claims description 7
- 229960002684 aminocaproic acid Drugs 0.000 claims description 6
- KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical compound C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 claims description 6
- PXGZQGDTEZPERC-UHFFFAOYSA-N 1,4-cyclohexanedicarboxylic acid Chemical compound OC(=O)C1CCC(C(O)=O)CC1 PXGZQGDTEZPERC-UHFFFAOYSA-N 0.000 claims description 5
- YWJNJZBDYHRABW-UHFFFAOYSA-N 2,4-dihydroxybenzene-1,3-dicarboxylic acid Chemical compound OC(=O)C1=CC=C(O)C(C(O)=O)=C1O YWJNJZBDYHRABW-UHFFFAOYSA-N 0.000 claims description 5
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 5
- OXIKYYJDTWKERT-UHFFFAOYSA-N [4-(aminomethyl)cyclohexyl]methanamine Chemical compound NCC1CCC(CN)CC1 OXIKYYJDTWKERT-UHFFFAOYSA-N 0.000 claims description 5
- ISKQADXMHQSTHK-UHFFFAOYSA-N [4-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=C(CN)C=C1 ISKQADXMHQSTHK-UHFFFAOYSA-N 0.000 claims description 5
- 150000001869 cobalt compounds Chemical class 0.000 claims description 5
- 125000003118 aryl group Chemical group 0.000 claims description 4
- SOTMTGOXKALQPI-UHFFFAOYSA-N lithium;2-sulfobenzoic acid Chemical compound [Li].OC(=O)C1=CC=CC=C1S(O)(=O)=O SOTMTGOXKALQPI-UHFFFAOYSA-N 0.000 claims description 3
- 239000011342 resin composition Substances 0.000 claims 1
- 229920006012 semi-aromatic polyamide Polymers 0.000 claims 1
- 239000011800 void material Substances 0.000 claims 1
- 229920000642 polymer Polymers 0.000 abstract description 111
- 150000001868 cobalt Chemical class 0.000 abstract description 11
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 75
- 229920000139 polyethylene terephthalate Polymers 0.000 description 47
- 239000005020 polyethylene terephthalate Substances 0.000 description 47
- 238000000034 method Methods 0.000 description 40
- 239000000463 material Substances 0.000 description 30
- 229920001577 copolymer Polymers 0.000 description 23
- ZJSXTJPARZJENS-UHFFFAOYSA-N lithium;2-sulfobenzene-1,3-dicarboxylic acid Chemical compound [Li].OC(=O)C1=CC=CC(C(O)=O)=C1S(O)(=O)=O ZJSXTJPARZJENS-UHFFFAOYSA-N 0.000 description 23
- 238000006116 polymerization reaction Methods 0.000 description 23
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 19
- 150000002009 diols Chemical class 0.000 description 19
- 239000000178 monomer Substances 0.000 description 18
- 229910017052 cobalt Inorganic materials 0.000 description 17
- 239000010941 cobalt Substances 0.000 description 17
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 17
- 239000008188 pellet Substances 0.000 description 17
- 230000008569 process Effects 0.000 description 17
- 230000008859 change Effects 0.000 description 16
- 239000011159 matrix material Substances 0.000 description 16
- 229920002292 Nylon 6 Polymers 0.000 description 15
- 239000006185 dispersion Substances 0.000 description 15
- 238000002347 injection Methods 0.000 description 13
- 239000007924 injection Substances 0.000 description 13
- 239000012071 phase Substances 0.000 description 13
- VVTXSHLLIKXMPY-UHFFFAOYSA-L disodium;2-sulfobenzene-1,3-dicarboxylate Chemical compound [Na+].[Na+].OS(=O)(=O)C1=C(C([O-])=O)C=CC=C1C([O-])=O VVTXSHLLIKXMPY-UHFFFAOYSA-L 0.000 description 12
- 238000004519 manufacturing process Methods 0.000 description 12
- 150000003839 salts Chemical class 0.000 description 12
- 239000007790 solid phase Substances 0.000 description 12
- MMEDJBFVJUFIDD-UHFFFAOYSA-N 2-[2-(carboxymethyl)phenyl]acetic acid Chemical compound OC(=O)CC1=CC=CC=C1CC(O)=O MMEDJBFVJUFIDD-UHFFFAOYSA-N 0.000 description 11
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 11
- 150000001875 compounds Chemical class 0.000 description 11
- 150000002148 esters Chemical class 0.000 description 11
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 11
- 229920006149 polyester-amide block copolymer Polymers 0.000 description 11
- QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 description 10
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 10
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 10
- 238000009826 distribution Methods 0.000 description 10
- 238000001125 extrusion Methods 0.000 description 10
- 239000010410 layer Substances 0.000 description 10
- 239000000155 melt Substances 0.000 description 10
- 229910052751 metal Inorganic materials 0.000 description 10
- 239000002184 metal Substances 0.000 description 10
- 239000011734 sodium Substances 0.000 description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 238000004626 scanning electron microscopy Methods 0.000 description 9
- 229910052708 sodium Inorganic materials 0.000 description 9
- YZTJKOLMWJNVFH-UHFFFAOYSA-N 2-sulfobenzene-1,3-dicarboxylic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1S(O)(=O)=O YZTJKOLMWJNVFH-UHFFFAOYSA-N 0.000 description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 8
- 239000003054 catalyst Substances 0.000 description 8
- 239000001301 oxygen Substances 0.000 description 8
- 229910052760 oxygen Inorganic materials 0.000 description 8
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 230000004888 barrier function Effects 0.000 description 7
- 150000001991 dicarboxylic acids Chemical class 0.000 description 7
- 150000005690 diesters Chemical class 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 7
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- 238000004458 analytical method Methods 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 238000005259 measurement Methods 0.000 description 6
- 239000002356 single layer Substances 0.000 description 6
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 5
- 150000007513 acids Chemical class 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 150000001732 carboxylic acid derivatives Chemical group 0.000 description 5
- 229940011182 cobalt acetate Drugs 0.000 description 5
- QAHREYKOYSIQPH-UHFFFAOYSA-L cobalt(II) acetate Chemical compound [Co+2].CC([O-])=O.CC([O-])=O QAHREYKOYSIQPH-UHFFFAOYSA-L 0.000 description 5
- 238000002425 crystallisation Methods 0.000 description 5
- 230000008025 crystallization Effects 0.000 description 5
- 235000019253 formic acid Nutrition 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 229960003742 phenol Drugs 0.000 description 5
- 229920000570 polyether Polymers 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 239000010936 titanium Substances 0.000 description 5
- 229910052719 titanium Inorganic materials 0.000 description 5
- 238000002834 transmittance Methods 0.000 description 5
- 239000004593 Epoxy Chemical group 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
- DTQVDTLACAAQTR-UHFFFAOYSA-N Trifluoroacetic acid Chemical compound OC(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 239000003086 colorant Substances 0.000 description 4
- 238000013461 design Methods 0.000 description 4
- 125000000524 functional group Chemical group 0.000 description 4
- 150000002334 glycols Chemical class 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 239000000543 intermediate Substances 0.000 description 4
- 229920002215 polytrimethylene terephthalate Polymers 0.000 description 4
- IBBQVGDGTMTZRA-UHFFFAOYSA-N sodium;2-sulfobenzene-1,3-dicarboxylic acid Chemical compound [Na].OC(=O)C1=CC=CC(C(O)=O)=C1S(O)(=O)=O IBBQVGDGTMTZRA-UHFFFAOYSA-N 0.000 description 4
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 3
- 229940035437 1,3-propanediol Drugs 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 229920000007 Nylon MXD6 Polymers 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 229910006145 SO3Li Inorganic materials 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 229910000410 antimony oxide Inorganic materials 0.000 description 3
- 150000001735 carboxylic acids Chemical class 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000011258 core-shell material Substances 0.000 description 3
- GZCKIUIIYCBICZ-UHFFFAOYSA-L disodium;benzene-1,3-dicarboxylate Chemical compound [Na+].[Na+].[O-]C(=O)C1=CC=CC(C([O-])=O)=C1 GZCKIUIIYCBICZ-UHFFFAOYSA-L 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 229920001519 homopolymer Polymers 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 229920000554 ionomer Polymers 0.000 description 3
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 3
- 229920001225 polyester resin Polymers 0.000 description 3
- 239000004645 polyester resin Substances 0.000 description 3
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 230000002000 scavenging effect Effects 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 241000894007 species Species 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- VLDPXPPHXDGHEW-UHFFFAOYSA-N 1-chloro-2-dichlorophosphoryloxybenzene Chemical compound ClC1=CC=CC=C1OP(Cl)(Cl)=O VLDPXPPHXDGHEW-UHFFFAOYSA-N 0.000 description 2
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 2
- AHYFYYVVAXRMKB-UHFFFAOYSA-N 3-(1h-indol-3-yl)-2-(phenylmethoxycarbonylamino)propanoic acid Chemical compound C=1NC2=CC=CC=C2C=1CC(C(=O)O)NC(=O)OCC1=CC=CC=C1 AHYFYYVVAXRMKB-UHFFFAOYSA-N 0.000 description 2
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 2
- 229920001817 Agar Polymers 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- 229940123973 Oxygen scavenger Drugs 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 230000003213 activating effect Effects 0.000 description 2
- 239000008272 agar Substances 0.000 description 2
- 125000005907 alkyl ester group Chemical group 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 2
- 229910052787 antimony Inorganic materials 0.000 description 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
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- 238000007334 copolymerization reaction Methods 0.000 description 2
- 150000003950 cyclic amides Chemical class 0.000 description 2
- QYQADNCHXSEGJT-UHFFFAOYSA-N cyclohexane-1,1-dicarboxylate;hydron Chemical compound OC(=O)C1(C(O)=O)CCCCC1 QYQADNCHXSEGJT-UHFFFAOYSA-N 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 2
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical class [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- SUMDYPCJJOFFON-UHFFFAOYSA-N isethionic acid Chemical compound OCCS(O)(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
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- 125000005487 naphthalate group Chemical group 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 238000005453 pelletization Methods 0.000 description 2
- WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 description 2
- 229920001467 poly(styrenesulfonates) Polymers 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 229920005604 random copolymer Polymers 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 239000001632 sodium acetate Substances 0.000 description 2
- 235000017281 sodium acetate Nutrition 0.000 description 2
- TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 2
- 229920001897 terpolymer Polymers 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 150000003608 titanium Chemical class 0.000 description 2
- 150000003609 titanium compounds Chemical class 0.000 description 2
- 238000001429 visible spectrum Methods 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
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- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1334—Nonself-supporting tubular film or bag [e.g., pouch, envelope, packet, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
- Y10T428/1355—Elemental metal containing [e.g., substrate, foil, film, coating, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
- Y10T428/139—Open-ended, self-supporting conduit, cylinder, or tube-type article
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
- Y10T428/139—Open-ended, self-supporting conduit, cylinder, or tube-type article
- Y10T428/1393—Multilayer [continuous layer]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
- Y10T428/1397—Single layer [continuous layer]
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyesters Or Polycarbonates (AREA)
- Polyamides (AREA)
- Containers Having Bodies Formed In One Piece (AREA)
- Laminated Bodies (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US72508505P | 2005-10-07 | 2005-10-07 | |
| US60/725,085 | 2005-10-07 | ||
| US82714706P | 2006-09-27 | 2006-09-27 | |
| US60/827,147 | 2006-09-27 | ||
| PCT/EP2006/009705 WO2007042230A1 (en) | 2005-10-07 | 2006-10-06 | Polyamides and polyesters blended with a lithium salt interfacial tension reducing agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2624384A1 CA2624384A1 (en) | 2007-04-19 |
| CA2624384C true CA2624384C (en) | 2013-07-23 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2624384A Expired - Fee Related CA2624384C (en) | 2005-10-07 | 2006-10-06 | Polyamides and polyesters blended with a lithium salt interfacial tension reducing agent |
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| CA (1) | CA2624384C (enExample) |
| DK (1) | DK2366734T3 (enExample) |
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| RU (1) | RU2414494C2 (enExample) |
| WO (1) | WO2007042230A1 (enExample) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2323229C2 (ru) | 2003-01-31 | 2008-04-27 | М Энд Г Полимери Италия С.П.А. | Изделие, включающее светопоглощающую композицию для маскировки оптической мутности, и способы его получения |
| US20080009574A1 (en) * | 2005-01-24 | 2008-01-10 | Wellman, Inc. | Polyamide-Polyester Polymer Blends and Methods of Making the Same |
| US8465818B2 (en) * | 2005-10-07 | 2013-06-18 | M & G Usa Corporation | Polyamides and polyesters blended with a lithium salt interfacial tension reducing agent |
| WO2007049233A1 (en) * | 2005-10-25 | 2007-05-03 | M & G Polimeri Italia S.P.A. | Stable polyamides for simultaneous solid phase polymerization of polyesters and polyamides |
| PL2181158T3 (pl) * | 2007-08-23 | 2017-10-31 | M & G Usa Corp | Mieszanki poliestrowo-poliamidowe zachowujące prawidłowe zabarwienie pod wpływem obróbki termicznej |
| US20090054567A1 (en) * | 2007-08-23 | 2009-02-26 | Heater Paul Lewis | Phosphite stabilizers for ionomeric polyester compounds |
| US8178648B2 (en) * | 2007-12-18 | 2012-05-15 | Future Fuel Chemical Company | Diaminium bis-3,5-dicarboxybenzensulfonate and tri-diaminium bis-3,5-dicarboxybenzensulfonate and methods for producing same |
| WO2010099532A2 (en) * | 2009-02-27 | 2010-09-02 | Futurefuel Chemical Company | Purification of 5-sulfoisophthalic acid by the use of an acetic acid wash on a crude cake |
| WO2010128526A2 (en) | 2009-05-07 | 2010-11-11 | Reliance Industries Limited | Oxygen scavenging polyester composition |
| US9381709B2 (en) | 2009-05-07 | 2016-07-05 | Reliance Industries Limited | Oxygen scavenging polyester composition |
| US8409680B2 (en) * | 2009-06-11 | 2013-04-02 | M&G Usa Corporation | Polyamide-polydiene blends with improved oxygen reactivity |
| WO2011049940A2 (en) | 2009-10-20 | 2011-04-28 | Futurefuel Chemical Company | Use of an acetic acid/water solvent mixture for the preparation of low-sulfate 5-sulfoisophthalic acid, mono-lithium salt from 5-sulfoisophthalic acid |
| WO2011110890A1 (en) * | 2010-03-11 | 2011-09-15 | Sa Des Eaux Minerales D'evian Saeme | Method for producing plastic containers by stretch blow molding, preform, container and use of such a container |
| CA2815049A1 (en) * | 2010-10-19 | 2012-04-26 | Future Fuel Chemical Company | Use of an acetic acid wash to prepare low-sulfate 5-sulfoisophthalic acid, mono-lithium salt |
| US8884045B2 (en) | 2010-10-19 | 2014-11-11 | Future Fuel Chemical Company | Use of an acetic acid wash to prepare low-sulfate 5-sulfoisophthalic acid, mono-lithium salt |
| EP2681225A4 (en) | 2011-03-02 | 2014-08-06 | Futurefuel Chemical Co | METALLIC SALTS OF SULFO-5-ISOPHTHALIC ACID DIALKYL ESTER AND PROCESS FOR PRODUCTION THEREOF |
| US8920914B2 (en) | 2011-08-25 | 2014-12-30 | Jindal Films Americas Llc | Enhanced processing oriented polypropylene films |
| US8809565B2 (en) | 2011-08-29 | 2014-08-19 | Futurefuel Chemical Company | 5-sulfoisophthalic acid salts and process for the preparation thereof |
| US10322528B2 (en) | 2011-11-16 | 2019-06-18 | APG Polytech, LLC | Color control of polyester-cobalt compounds and polyester-cobalt compositions |
| JP6028343B2 (ja) * | 2012-03-09 | 2016-11-16 | 三菱瓦斯化学株式会社 | ポリエステル系樹脂組成物 |
| JP6476186B2 (ja) * | 2013-08-30 | 2019-02-27 | ディスクマ アクチェンゲゼルシャフト | 容器用高変性ポリエステル |
| AU2016205389B2 (en) | 2015-01-06 | 2019-09-12 | Lawter, Inc. | Polyamide resins for coating of sand or ceramic proppants used in hydraulic fracturing |
| KR102529151B1 (ko) | 2016-01-27 | 2023-05-08 | 삼성전자주식회사 | 폴리이미드 또는 폴리(아미드-이미드) 코폴리머를 포함하는 성형품 제조용 조성물, 상기 조성물로부터 얻어지는 성형품, 및 상기 성형품을 포함하는 디스플레이 장치 |
| US11235521B2 (en) | 2017-07-14 | 2022-02-01 | Hewlett-Packard Development, L.P. | 3-D printing |
| US10800897B2 (en) | 2018-04-30 | 2020-10-13 | Skc Inc. | Heat shrinkable film and method for reproducing polyester container using same |
Family Cites Families (58)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3018272A (en) * | 1955-06-30 | 1962-01-23 | Du Pont | Sulfonate containing polyesters dyeable with basic dyes |
| NL302928A (enExample) | 1963-01-03 | 1900-01-01 | ||
| DE1769231A1 (de) | 1968-04-24 | 1972-03-02 | Hoechst Ag | Thermoplastische Formmassen aus Polyestern und Polyamiden |
| US3936389A (en) * | 1973-06-14 | 1976-02-03 | Monsanto Company | Bis glycol ester of sodium sulfo isophthalic acid from its dimethyl ester |
| US3899470A (en) * | 1973-08-01 | 1975-08-12 | Monsanto Co | Continuous process for preparation of basic dyeable polyester |
| US3922250A (en) * | 1974-09-03 | 1975-11-25 | Phillips Petroleum Co | Late addition of alkali metal sulfonate dye receptivity additive in polyesterification process |
| US4421804A (en) * | 1981-09-11 | 1983-12-20 | Japan Crown Cork Co., Ltd. | Bottle for carbonated drink |
| JPH0611797B2 (ja) | 1987-02-27 | 1994-02-16 | 東洋紡績株式会社 | ポリエステル中空成形体 |
| EP0301719A1 (en) * | 1987-07-27 | 1989-02-01 | CarnaudMetalbox plc | Improvements in and relating to packaging |
| GB2207439B (en) * | 1987-07-27 | 1992-02-12 | Metal Box Plc | Improvements in and relating to packaging |
| CA1324329C (en) * | 1988-03-12 | 1993-11-16 | Rickworth Folland | Packaging |
| IN172789B (enExample) | 1988-07-01 | 1993-11-27 | Sir Padampat Research Centre | |
| JP2663578B2 (ja) | 1988-11-17 | 1997-10-15 | 東洋紡績株式会社 | ポリエステル中空成形体 |
| US5239016A (en) * | 1989-01-26 | 1993-08-24 | Cmb Packaging (Uk) Limited | Process for production of a wall for a package |
| US5166311A (en) * | 1989-05-22 | 1992-11-24 | Hoechst Celanese Corporation | Catalyst system and process for preparing high clarity, colorless polyethylene terephthalate |
| JP2864595B2 (ja) | 1989-12-22 | 1999-03-03 | 東洋紡績株式会社 | 色調の改善されたポリエステル中空成形体 |
| US5077111A (en) * | 1990-01-12 | 1991-12-31 | Continental Pet Technologies, Inc. | Recyclable multilayer plastic preform and container blown therefrom |
| US20030134966A1 (en) | 1990-01-31 | 2003-07-17 | Kim Yong Joo | Barrier compositions and articles made therefrom |
| US5314987A (en) | 1990-01-31 | 1994-05-24 | American National Can Company | Barrier compositions and film made therefrom having improved optical and oxygen barrier properties |
| JPH03281246A (ja) | 1990-03-29 | 1991-12-11 | Kuraray Co Ltd | 多層構造体およびそれに用いる組成物 |
| EP0503664A3 (en) | 1991-03-14 | 1993-02-03 | Kao Corporation | Process for producing cationic dye-dyeable polyester fiber with high strenght and polyester resin composition used therefor |
| JP2766405B2 (ja) * | 1991-06-14 | 1998-06-18 | ポリプラスチックス株式会社 | ポリエステル樹脂組成物 |
| US5300572A (en) | 1991-06-14 | 1994-04-05 | Polyplastics Co., Ltd. | Moldable polyester resin compositions and molded articles formed of the same |
| US5266413A (en) | 1992-05-18 | 1993-11-30 | Eastman Kodak Company | Copolyester/polyamide blend having improved flavor retaining property and clarity |
| US5348832A (en) * | 1993-06-01 | 1994-09-20 | Xerox Corporation | Toner compositions |
| JPH08208950A (ja) | 1995-02-06 | 1996-08-13 | Unitika Ltd | ２軸配向ポリエステルフイルムおよびその製造方法 |
| US5627218A (en) | 1995-03-20 | 1997-05-06 | Bradt; Rexford H. | Compartmented thermoplastic pellets |
| US5559205A (en) * | 1995-05-18 | 1996-09-24 | E. I. Du Pont De Nemours And Company | Sulfonate-containing polyesters dyeable with basic dyes |
| US6537475B1 (en) * | 1995-08-31 | 2003-03-25 | Prisma Fibers, Inc. | Melt extrusion spinning polyamide fibers with sulfonated reagent |
| JP3674650B2 (ja) | 1996-06-25 | 2005-07-20 | 三菱瓦斯化学株式会社 | 樹脂組成物 |
| US5820982A (en) * | 1996-12-03 | 1998-10-13 | Seydel Companies, Inc. | Sulfoaryl modified water-soluble or water-dispersible resins from polyethylene terephthalate or terephthalates |
| USH1760H (en) * | 1997-01-08 | 1998-11-03 | Hoechst Celanese Corporation | Process for glycol esters of an alkali metal salt of 5-sulfoisophthalic acid |
| US5985389A (en) | 1997-06-17 | 1999-11-16 | Eastman Chemical Company | Polyester and optical brightener blend having improved properties |
| US6254803B1 (en) * | 1998-03-25 | 2001-07-03 | Cryovac, Inc. | Oxygen scavengers with reduced oxidation products for use in plastic films |
| IT1301690B1 (it) | 1998-06-11 | 2000-07-07 | Sinco Ricerche Spa | Miscele di resine poliestere aventi elevate proprieta' di barriera aigas. |
| US6300405B2 (en) * | 1998-06-30 | 2001-10-09 | General Electric Company | Polyester molding composition |
| US6239233B1 (en) | 1998-10-09 | 2001-05-29 | Eastman Chemical Company | Polyester/polyamide blends with improved color |
| WO2000058404A1 (fr) | 1999-03-31 | 2000-10-05 | Toyo Boseki Kabusiki Kaisya | Materiau absorbant l'oxygene et objet moule a partir de ce materiau |
| ATE479531T1 (de) | 1999-06-25 | 2010-09-15 | Sumika Color Company Ltd | Mehrschichtige pellets und verfahren zur herstellung dieser mehrschichtigen pellets |
| BR0012815A (pt) | 1999-07-30 | 2002-05-07 | Eastman Chem Co | Mistura de polìmero, artigo, e, método para reduzir a permeabilidade a gás de poliéster |
| AU7420600A (en) * | 1999-09-27 | 2001-04-30 | Ciba Specialty Chemicals Holding Inc. | Polyester compositions of low residual aldehyde content |
| US6495079B1 (en) * | 2000-06-28 | 2002-12-17 | Prisma Fibers, Inc. | Process to prepare polymeric fibers with improved color and appearance |
| US6500895B1 (en) | 2000-10-13 | 2002-12-31 | General Electric Company | Thermoplastic blend comprising poly(arylene ether) and polyamide |
| US6479619B1 (en) * | 2001-03-15 | 2002-11-12 | E. I. Du Pont De Nemours And Company | Sulfoisophthalic acid solution process therewith |
| US6407194B1 (en) * | 2001-07-17 | 2002-06-18 | E. I. Du Pont De Nemours And Company | Temporarily crosslinked polyester polymers |
| WO2003080731A2 (en) | 2002-03-21 | 2003-10-02 | Advanced Plastics Technologies, Ltd. | Compatibilized polyester/polyamide blends |
| JP2003285879A (ja) * | 2002-03-28 | 2003-10-07 | Yoshino Kogyosho Co Ltd | ポリエチレンテレフタレート系樹脂製容器 |
| UA81055C2 (uk) | 2003-08-26 | 2007-11-26 | Інвіста Технолоджіс С.А.Р.Л. | Композиція для ємностей та преформа або ємність |
| US6872451B2 (en) * | 2003-08-28 | 2005-03-29 | Cryovac, Inc. | Ionomeric oxygen scavenger compositions |
| US7491359B2 (en) * | 2003-10-16 | 2009-02-17 | Graham Packaging Pet Technologies Inc. | Delamination-resistant multilayer container, preform, article and method of manufacture |
| US20050153084A1 (en) * | 2004-01-09 | 2005-07-14 | Yu Shi | PET with stress cracking resistance, preform and container made therewith and method |
| CA2565922C (en) | 2004-05-18 | 2013-02-19 | M & G Polimeri Italia S.P.A. | Compartmentalized resin pellets |
| US7375154B2 (en) | 2004-12-06 | 2008-05-20 | Eastman Chemical Company | Polyester/polyamide blend having improved flavor retaining property and clarity |
| BRPI0518849A2 (pt) * | 2004-12-06 | 2008-12-09 | Eastman Chem Co | concentrado sàlido, processos para a produÇço de uma prÉ-forma, e para a secagem de partÍculas, e, concentrado de polÍmero de poliÉster |
| WO2006079044A2 (en) | 2005-01-24 | 2006-07-27 | Wellman, Inc. | Improved polyamide-polyester polymer blends and methods of making the same |
| US8465818B2 (en) * | 2005-10-07 | 2013-06-18 | M & G Usa Corporation | Polyamides and polyesters blended with a lithium salt interfacial tension reducing agent |
| CN101460567B (zh) * | 2006-06-02 | 2011-11-23 | 东洋纺织株式会社 | 聚酯组合物及由该聚酯组合物构成的聚酯成形体 |
| US9610506B2 (en) | 2011-03-28 | 2017-04-04 | Brian M. Dugan | Systems and methods for fitness and video games |
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- 2006-10-06 KR KR1020087010983A patent/KR101309108B1/ko not_active Expired - Fee Related
- 2006-10-06 EP EP11170053.0A patent/EP2366734B9/en active Active
- 2006-10-06 AT AT06792394T patent/ATE517940T1/de not_active IP Right Cessation
- 2006-10-06 ES ES11170053.0T patent/ES2623835T3/es active Active
- 2006-10-06 AU AU2006301554A patent/AU2006301554B2/en not_active Ceased
- 2006-10-06 HU HUE11170053A patent/HUE031584T2/en unknown
- 2006-10-06 PL PL11170053T patent/PL2366734T3/pl unknown
- 2006-10-06 JP JP2008533948A patent/JP5435950B2/ja not_active Expired - Fee Related
- 2006-10-06 MX MX2016005234A patent/MX389301B/es unknown
- 2006-10-06 BR BRPI0617993-2A patent/BRPI0617993B1/pt not_active IP Right Cessation
- 2006-10-06 LT LTEP11170053.0T patent/LT2366734T/lt unknown
- 2006-10-06 RU RU2008118137/05A patent/RU2414494C2/ru active
- 2006-10-06 CA CA2624384A patent/CA2624384C/en not_active Expired - Fee Related
- 2006-10-06 WO PCT/EP2006/009705 patent/WO2007042230A1/en not_active Ceased
- 2006-10-06 DK DK11170053.0T patent/DK2366734T3/en active
- 2006-10-06 US US11/539,234 patent/US20070088133A1/en not_active Abandoned
- 2006-10-06 EP EP06792394A patent/EP1931727B1/en not_active Revoked
- 2006-10-06 PL PL06792394T patent/PL1931727T3/pl unknown
-
2013
- 2013-06-17 US US13/919,422 patent/US20140371402A1/en not_active Abandoned
-
2015
- 2015-10-19 US US14/886,143 patent/US20160040007A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| EP1931727A1 (en) | 2008-06-18 |
| WO2007042230A1 (en) | 2007-04-19 |
| US20160040007A1 (en) | 2016-02-11 |
| US20140371402A1 (en) | 2014-12-18 |
| US20070082157A1 (en) | 2007-04-12 |
| BRPI0617993A2 (pt) | 2011-08-16 |
| HUE031584T2 (en) | 2017-07-28 |
| RU2008118137A (ru) | 2009-11-20 |
| ES2623835T3 (es) | 2017-07-12 |
| PL2366734T3 (pl) | 2017-07-31 |
| ATE517940T1 (de) | 2011-08-15 |
| DK2366734T3 (en) | 2017-04-18 |
| KR101309108B1 (ko) | 2013-09-17 |
| RU2414494C2 (ru) | 2011-03-20 |
| EP2366734B9 (en) | 2017-08-16 |
| EP1931727B1 (en) | 2011-07-27 |
| MX389301B (es) | 2025-03-20 |
| EP2366734A1 (en) | 2011-09-21 |
| AU2006301554A1 (en) | 2007-04-19 |
| ES2623835T9 (es) | 2017-12-12 |
| JP5435950B2 (ja) | 2014-03-05 |
| JP2009510242A (ja) | 2009-03-12 |
| EP2366734B1 (en) | 2017-02-01 |
| US20070088133A1 (en) | 2007-04-19 |
| LT2366734T (lt) | 2017-06-26 |
| BRPI0617993B1 (pt) | 2018-01-16 |
| PL1931727T3 (pl) | 2011-12-30 |
| KR20080068693A (ko) | 2008-07-23 |
| CA2624384A1 (en) | 2007-04-19 |
| US8465818B2 (en) | 2013-06-18 |
| AU2006301554B2 (en) | 2011-05-12 |
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