CA2604552C - Catalysts for olefin polymerization - Google Patents

Catalysts for olefin polymerization Download PDF

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Publication number
CA2604552C
CA2604552C CA2604552A CA2604552A CA2604552C CA 2604552 C CA2604552 C CA 2604552C CA 2604552 A CA2604552 A CA 2604552A CA 2604552 A CA2604552 A CA 2604552A CA 2604552 C CA2604552 C CA 2604552C
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Canada
Prior art keywords
group
alumina
solid oxide
catalyst composition
compound
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Active
Application number
CA2604552A
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English (en)
French (fr)
Other versions
CA2604552A1 (en
Inventor
Kumudini C. Jayaratne
Michael D. Jensen
Matthew G. Thorn
Max P. Mcdaniel
Paul Barbee
Qing Yang
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Chevron Phillips Chemical Co LP
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Chevron Phillips Chemical Co LP
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Publication of CA2604552A1 publication Critical patent/CA2604552A1/en
Application granted granted Critical
Publication of CA2604552C publication Critical patent/CA2604552C/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/07Catalyst support treated by an anion, e.g. Cl-, F-, SO42-
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CA2604552A 2005-04-13 2006-04-11 Catalysts for olefin polymerization Active CA2604552C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US11/105,770 2005-04-13
US11/105,770 US7247594B2 (en) 2005-04-13 2005-04-13 Catalysts for olefin polymerization
PCT/US2006/013657 WO2006113272A1 (en) 2005-04-13 2006-04-11 Catalysts for olefin polymerization

Publications (2)

Publication Number Publication Date
CA2604552A1 CA2604552A1 (en) 2006-10-26
CA2604552C true CA2604552C (en) 2014-08-05

Family

ID=36808351

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2604552A Active CA2604552C (en) 2005-04-13 2006-04-11 Catalysts for olefin polymerization

Country Status (12)

Country Link
US (1) US7247594B2 (pt)
EP (1) EP1874828B1 (pt)
CN (1) CN101184782B (pt)
AT (1) ATE485311T1 (pt)
AU (1) AU2006236780A1 (pt)
BR (1) BRPI0610610B1 (pt)
CA (1) CA2604552C (pt)
DE (1) DE602006017679D1 (pt)
HK (1) HK1113583A1 (pt)
MX (1) MX2007012751A (pt)
RU (1) RU2007141927A (pt)
WO (1) WO2006113272A1 (pt)

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EP1749842A1 (en) * 2005-08-03 2007-02-07 Total Petrochemicals Research Feluy Transition metal complexes supported on activating fluorinated support
US7534842B2 (en) * 2005-11-16 2009-05-19 Chevron Phillips Chemical Company, Lp Catalysts for olefin polymerization
US7947814B2 (en) * 2006-04-25 2011-05-24 Air Products And Chemicals, Inc. Metal complexes of polydentate beta-ketoiminates
US11208514B2 (en) 2008-03-20 2021-12-28 Chevron Phillips Chemical Company Lp Silica-coated alumina activator-supports for metallocene catalyst compositions
US7884163B2 (en) * 2008-03-20 2011-02-08 Chevron Phillips Chemical Company Lp Silica-coated alumina activator-supports for metallocene catalyst compositions
US8309485B2 (en) * 2009-03-09 2012-11-13 Chevron Phillips Chemical Company Lp Methods for producing metal-containing sulfated activator-supports
US9289739B2 (en) * 2009-06-23 2016-03-22 Chevron Philips Chemical Company Lp Continuous preparation of calcined chemically-treated solid oxides
US8399580B2 (en) 2010-08-11 2013-03-19 Chevron Philips Chemical Company Lp Additives to chromium catalyst mix tank
US20120116034A1 (en) 2010-11-08 2012-05-10 Dow Global Technologies, Inc. Solution polymerization process and procatalyst carrier systems useful therein
US8618229B2 (en) 2011-03-08 2013-12-31 Chevron Phillips Chemical Company Lp Catalyst compositions containing transition metal complexes with thiolate ligands
CN102311539B (zh) * 2011-07-09 2012-07-25 山西大学 三核有机锌催化剂及其制备方法和应用
WO2013077944A1 (en) * 2011-11-21 2013-05-30 Exxonmobil Chemical Patents Inc. Amidinate catalyst compounds, process for their use and polymers produced therefrom
US8791217B2 (en) 2011-12-28 2014-07-29 Chevron Phillips Chemical Company Lp Catalyst systems for production of alpha olefin oligomers and polymers
US8785576B2 (en) 2011-12-28 2014-07-22 Chevron Phillips Chemical Company Lp Catalyst compositions for the polymerization of olefins
CN103183624B (zh) * 2011-12-30 2017-04-19 中国科学院上海有机化学研究所 烯烃聚合或共聚合催化剂及其制备方法
CN102614909B (zh) * 2012-03-02 2014-04-16 山西盛驰科技有限公司 可脱除煤焦油含氮化合物的加氢脱氮催化剂及其制备方法和应用
CN102688772B (zh) * 2012-06-14 2014-04-23 山西盛驰科技有限公司 一种脱除中低温煤焦油中含硫化合物的加氢脱硫催化剂及其应用
US8937139B2 (en) 2012-10-25 2015-01-20 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US8895679B2 (en) * 2012-10-25 2014-11-25 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
EP2948757B1 (en) * 2013-01-25 2017-04-26 Hewlett-Packard Development Company, L.P. Chemical sensing device
US9034991B2 (en) 2013-01-29 2015-05-19 Chevron Phillips Chemical Company Lp Polymer compositions and methods of making and using same
US8877672B2 (en) 2013-01-29 2014-11-04 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US9145492B1 (en) * 2014-04-01 2015-09-29 King Fahd University Of Petroleum And Minerals Method to produce ultra-high molecular weight polyethylene
CN104014373A (zh) * 2014-06-09 2014-09-03 浙江科技学院 一种丙烯二聚合成2,3-二甲基丁烯的负载型催化剂及其制备方法
BR112017003306B1 (pt) * 2014-08-19 2022-03-03 Univation Technologies, Llc Método para preparar um suporte de catalisador fluorado e sistema de catalisador
CA2957809C (en) * 2014-08-19 2023-01-03 Univation Technologies, Llc Fluorinated catalyst supports and catalyst systems
CN106794455B (zh) * 2014-08-19 2020-09-04 尤尼威蒂恩技术有限责任公司 氟化催化剂载体和催化剂系统
CN104307572B (zh) * 2014-10-16 2016-06-22 山西大学 一种脒基铝金属催化剂及其制备方法
US9861955B2 (en) 2015-06-11 2018-01-09 Chevron Phillips Chemical Company, Lp Treater regeneration
US9289748B1 (en) 2015-06-11 2016-03-22 Chevron Phillips Chemical Company Lp Treater regeneration
US9707549B1 (en) 2016-05-26 2017-07-18 Chevron Phillips Chemical Company Lp Ethylene oligomerization catalyst systems using chemically-treated solid oxides
US10662268B2 (en) 2016-09-23 2020-05-26 China Petroleum & Chemical Corporation Catalyst component for olefin polymerization, catalyst, and use thereof
WO2018203928A1 (en) 2017-05-03 2018-11-08 Chevron Phillips Chemical Company Lp Regeneration of a desiccant in an off-line treater of a polyolefin production process
CN107812519B (zh) * 2017-11-09 2020-08-07 南京大学(苏州)高新技术研究院 一种粉末催化材料、含SiO2气凝胶复合多孔纳米催化材料的制备及应用
WO2019156968A1 (en) * 2018-02-07 2019-08-15 Exxonmobil Chemical Patents Inc. Supported catalysts systems and polymerization processes for using the same
US10792609B2 (en) 2018-05-07 2020-10-06 Chevron Phillips Chemical Company Lp Nitrogen conservation in polymerization processes
GB201903452D0 (en) * 2019-03-13 2019-04-24 Lucite Int Uk Ltd A catalyst and a process for the production of ethylenically unsaturated carboxylic acids for esters
TW202224768A (zh) * 2020-08-26 2022-07-01 美商先進精鍊科技有限公司 在氫加工催化劑中併入硼、所獲得之催化劑、及其用途

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US6015917A (en) * 1998-01-23 2000-01-18 Advanced Technology Materials, Inc. Tantalum amide precursors for deposition of tantalum nitride on a substrate
US6511936B1 (en) * 1998-02-12 2003-01-28 University Of Delaware Catalyst compounds with β-diminate anionic ligands and processes for polymerizing olefins
DE69908147T2 (de) * 1998-08-26 2004-02-19 Exxonmobil Chemical Patents Inc., Baytown Hochwirksame geträgerte katalysatorzusammensetzungen
MXPA02003999A (es) 1999-10-22 2002-10-23 Univation Tech Llc Composiciones catalizadoras, metodos de polimerizacion, y polimeros a partir de ellos.
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CA2416197A1 (en) 2000-07-17 2002-01-24 David E. Gindelberger A catalyst system and its use in a polymerization process
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US6919467B2 (en) * 2001-12-18 2005-07-19 Univation Technologies, Llc Imino-amide catalyst compositions for the polymerization of olefins
US7410927B2 (en) * 2005-04-13 2008-08-12 Chevron Phillips Chemical Company, Lp Catalysts for olefin polymerization

Also Published As

Publication number Publication date
RU2007141927A (ru) 2009-05-20
CN101184782B (zh) 2012-06-27
AU2006236780A1 (en) 2006-10-26
EP1874828B1 (en) 2010-10-20
CA2604552A1 (en) 2006-10-26
ATE485311T1 (de) 2010-11-15
BRPI0610610B1 (pt) 2017-06-06
MX2007012751A (es) 2008-01-11
WO2006113272A1 (en) 2006-10-26
BRPI0610610A2 (pt) 2010-07-13
US20060234857A1 (en) 2006-10-19
DE602006017679D1 (pt) 2010-12-02
US7247594B2 (en) 2007-07-24
EP1874828A1 (en) 2008-01-09
HK1113583A1 (en) 2008-10-10
CN101184782A (zh) 2008-05-21

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