CA2586202A1 - Pigment composition in the form of aqueous dispersion - Google Patents
Pigment composition in the form of aqueous dispersion Download PDFInfo
- Publication number
- CA2586202A1 CA2586202A1 CA002586202A CA2586202A CA2586202A1 CA 2586202 A1 CA2586202 A1 CA 2586202A1 CA 002586202 A CA002586202 A CA 002586202A CA 2586202 A CA2586202 A CA 2586202A CA 2586202 A1 CA2586202 A1 CA 2586202A1
- Authority
- CA
- Canada
- Prior art keywords
- porous aggregates
- particles
- silica
- paper
- extender particles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract 19
- 239000000049 pigment Substances 0.000 title claims abstract 8
- 239000006185 dispersion Substances 0.000 title claims abstract 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract 17
- 239000004606 Fillers/Extenders Substances 0.000 claims abstract 14
- 239000002245 particle Substances 0.000 claims abstract 14
- 238000000034 method Methods 0.000 claims abstract 10
- 239000011087 paperboard Substances 0.000 claims abstract 9
- 239000000377 silicon dioxide Substances 0.000 claims abstract 8
- 229910000323 aluminium silicate Inorganic materials 0.000 claims abstract 7
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract 7
- 239000000123 paper Substances 0.000 claims abstract 7
- 239000011164 primary particle Substances 0.000 claims abstract 7
- 238000004519 manufacturing process Methods 0.000 claims abstract 6
- 239000011248 coating agent Substances 0.000 claims abstract 4
- 238000000576 coating method Methods 0.000 claims abstract 4
- 238000004220 aggregation Methods 0.000 claims abstract 3
- 230000002776 aggregation Effects 0.000 claims abstract 3
- 239000011230 binding agent Substances 0.000 claims 4
- 239000008199 coating composition Substances 0.000 claims 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims 3
- 229910052910 alkali metal silicate Inorganic materials 0.000 claims 2
- 229920000881 Modified starch Polymers 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 230000004931 aggregating effect Effects 0.000 claims 1
- 229910001413 alkali metal ion Inorganic materials 0.000 claims 1
- 239000007864 aqueous solution Substances 0.000 claims 1
- 229910000019 calcium carbonate Inorganic materials 0.000 claims 1
- 229910021485 fumed silica Inorganic materials 0.000 claims 1
- 229910052500 inorganic mineral Inorganic materials 0.000 claims 1
- 238000005342 ion exchange Methods 0.000 claims 1
- 229920000126 latex Polymers 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- 239000011707 mineral Substances 0.000 claims 1
- 235000019426 modified starch Nutrition 0.000 claims 1
- 229920002451 polyvinyl alcohol Polymers 0.000 claims 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 claims 1
- 102000004169 proteins and genes Human genes 0.000 claims 1
- 108090000623 proteins and genes Proteins 0.000 claims 1
- 239000002002 slurry Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D17/00—Pigment pastes, e.g. for mixing in paints
- C09D17/004—Pigment pastes, e.g. for mixing in paints containing an inorganic pigment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D17/00—Pigment pastes, e.g. for mixing in paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Paper (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Paints Or Removers (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Ink Jet (AREA)
Abstract
The invention relates to a pigment composition in the form of an aqueous dispersion or slurry comprising: (a) porous aggregates formed by aggregation of colloidal primary particles of silica, aluminosilicate or a mixture thereof in an aqueous sol, said porous aggregates having a mean diameter from about 0.03 to about 25 ~m, and, (b) extender particles where the mean size of at least one dimension is larger than the mean diameter of the porous aggregates, wherein the weight ratio of porous aggregates to extender particles is from about 0.01:1 to about 3:1. The invention further relates to a process for its production, a compositionfor coating paper or paper board and a process for its production, and a process for coating paper or paper board and paper or paper board obtainable by the process.
Claims (14)
1. Pigment composition in the form of an aqueous dispersion comprising:
(a) porous aggregates formed by aggregation of colloidal primary particles of silica, aluminosilicate or a mixture thereof in an aqueous sol, said porous aggregates having a mean diameter from about 0.03 to about 25 µm, and, (b) extender particles where the mean size of at least one dimension is larger than the mean diameter of the porous aggregates, wherein the weight ratio of porous aggregates to extender particles is from about 0.01:1 to about 3:1.
(a) porous aggregates formed by aggregation of colloidal primary particles of silica, aluminosilicate or a mixture thereof in an aqueous sol, said porous aggregates having a mean diameter from about 0.03 to about 25 µm, and, (b) extender particles where the mean size of at least one dimension is larger than the mean diameter of the porous aggregates, wherein the weight ratio of porous aggregates to extender particles is from about 0.01:1 to about 3:1.
2. Composition as claimed in claim 1, wherein the colloidal primary particles of silica or aluminosilicate have been formed from an aqueous solution of alkali metal silicate where alkali metal ions are removed through an ion exchange process or where the alkali metal silicate has been neutralised by the addition of an acid.
3. Composition as claimed in any one of the claims 1-2, wherein at least some of the porous aggregates are attached to extender particles.
4. Composition as claimed in any one of the claims 1-3, wherein the porous aggregates and the extender particles have opposite net charges.
5. Composition as claimed in any one of the claims 1-4, wherein the extender particles are of a material selected from the group consisting of kaolinites, smectites, talcites, calcium carbonate minerals, precipitated silica, gel-type silica, fumed silica, precipitated calcium carbonate, and mixtures thereof.
6. Composition as claimed in any one of the claims 1-5, wherein total content of porous aggregates and extender particles in the composition is from about 1 to about 60 wt%.
7. A process for the production of a pigment composition according to any one of the claims 1-6 comprising a step of mixing (a) an aqueous dispersion of porous aggregates formed by aggregation of colloidal primary particles of silica, aluminosilicate or a mixture thereof in an aqueous sol, said porous aggregates having a mean diameter from about 0.03 to about 25 µm, and, (b) extender particles where the mean size of at least one dimension is larger than the mean diameter of the porous aggregates, wherein the weight ratio of porous aggregates to extender particles is from about 0.01:1 to about 3.1.
8. A process for the production of a pigment composition according to any one of the claims 1-6 comprising the steps:
(a) mixing an aqueous sol comprising colloidal primary particles of silica or aluminosilicate and extender particles in a weight ratio primary particles of silica or aluminosilicate to extender particles from about 0.01:1 to about 3:1; and, (b) aggregating the colloidal primary particles of silica or aluminosilicate to form porous aggregates having a mean diameter from about 0.03 µm to about 25 µm, but not exceeding the mean size of the largest dimension of the extender particles.
(a) mixing an aqueous sol comprising colloidal primary particles of silica or aluminosilicate and extender particles in a weight ratio primary particles of silica or aluminosilicate to extender particles from about 0.01:1 to about 3:1; and, (b) aggregating the colloidal primary particles of silica or aluminosilicate to form porous aggregates having a mean diameter from about 0.03 µm to about 25 µm, but not exceeding the mean size of the largest dimension of the extender particles.
9. Coating composition suitable for coating paper or paper board comprising a binder and a pigment composition according to any one of the claims 1-6.
10. Coating composition as claimed in claim 9, wherein the binder is selected from the group consisting of polyvinyl alcohols, optionally modified starches, gums, protein binders, latices and mixtures thereof.
11. A process for the production of a coating composition comprising a step of mixing a binder with a pigment composition according to any one of the claims 1-6.
12. A process for the production of coated paper or paperboard comprising a step of applying a coating composition according to any one of the claims 9-10 to at least one side of a paper or paperboard web.
13. A process as claimed in claim 12, wherein the coating is applied in an amount sufficient to yield from about 0.4 g/m2 to about 40 g/m2, of porous aggregates and extender particles from the pigment composition per coated side of the paper or paper board.
14. Paper or paper board obtainable by the process according to any one of the claims 12-13.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP04105595 | 2004-11-08 | ||
EP04105595.5 | 2004-11-08 | ||
PCT/SE2005/001522 WO2006049545A1 (en) | 2004-11-08 | 2005-10-13 | Pigment composition in the form of aqueous dispersion |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2586202A1 true CA2586202A1 (en) | 2006-05-11 |
CA2586202C CA2586202C (en) | 2011-01-25 |
Family
ID=34929820
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA2586207A Expired - Fee Related CA2586207C (en) | 2004-11-08 | 2005-10-13 | A process for the production of coated paper |
CA2586202A Expired - Fee Related CA2586202C (en) | 2004-11-08 | 2005-10-13 | Pigment composition in the form of aqueous dispersion |
CA2586205A Expired - Fee Related CA2586205C (en) | 2004-11-08 | 2005-10-13 | Pigment composition in the form of aqueous dispersion |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA2586207A Expired - Fee Related CA2586207C (en) | 2004-11-08 | 2005-10-13 | A process for the production of coated paper |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA2586205A Expired - Fee Related CA2586205C (en) | 2004-11-08 | 2005-10-13 | Pigment composition in the form of aqueous dispersion |
Country Status (16)
Country | Link |
---|---|
EP (3) | EP1809710A1 (en) |
JP (3) | JP4897694B2 (en) |
KR (3) | KR100948121B1 (en) |
CN (3) | CN101426865B (en) |
AR (3) | AR051756A1 (en) |
AU (3) | AU2005301351B2 (en) |
BR (3) | BRPI0517264A (en) |
CA (3) | CA2586207C (en) |
MX (3) | MX2007004959A (en) |
MY (3) | MY145100A (en) |
NO (3) | NO20072909L (en) |
NZ (1) | NZ554297A (en) |
RU (3) | RU2392223C2 (en) |
TW (3) | TWI298081B (en) |
WO (3) | WO2006049547A1 (en) |
ZA (3) | ZA200704420B (en) |
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CN101415882B (en) | 2006-02-28 | 2011-12-28 | 赢创德固赛公司 | Colored paper and substrates coated for enhanced printing performance |
BRPI0717292A2 (en) * | 2006-09-26 | 2013-01-22 | Evonik Degussa Corp | multifunction paper for increased printing performance |
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US20100021662A1 (en) * | 2007-02-06 | 2010-01-28 | Roland Stephan | Method for the preparation of coating formulations and papers coated therewith |
JP2010519380A (en) * | 2007-02-26 | 2010-06-03 | アクゾ ノーベル ナムローゼ フェンノートシャップ | Pigment composition |
CL2008002019A1 (en) | 2007-07-16 | 2009-01-16 | Akzo Nobel Chemicals Int Bv | A filler composition comprising a filler, a cationic inorganic compound, a cationic organic compound, and an anionic polysaccharide; method of preparing said composition; use as an additive for an aqueous cellulosic suspension; procedure for producing paper; and paper. |
CA2710804C (en) | 2007-12-26 | 2013-07-02 | International Paper Company | A paper substrate containing a wetting agent and having improved print mottle |
ES2689849T3 (en) | 2008-03-31 | 2018-11-16 | International Paper Company | Registration sheet with improved print quality at low additive levels |
WO2009146416A1 (en) * | 2008-05-29 | 2009-12-03 | International Paper Company | Fast dry coated inkjet paper |
US8460511B2 (en) | 2008-10-01 | 2013-06-11 | International Paper Company | Paper substrate containing a wetting agent and having improved printability |
FR2944034B1 (en) * | 2009-04-01 | 2011-06-03 | Arjo Wiggins Fine Papers Ltd | IMPRIMABLE MATT FINE PAPER AND PROCESS FOR PREPARING THE SAME |
US20120107533A1 (en) | 2009-06-26 | 2012-05-03 | Akzo Nobel Chemicals International B.V. | Coated substrate and method for the preparation thereof |
CA2772385C (en) * | 2009-08-31 | 2017-03-14 | Newpage Corporation | Paper substrate with inkjet-receptive coating comprising cationic porous silica |
US8652593B2 (en) | 2009-12-17 | 2014-02-18 | International Paper Company | Printable substrates with improved brightness from OBAs in presence of multivalent metal salts |
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US8608908B2 (en) | 2010-04-02 | 2013-12-17 | International Paper Company | Method and system using low fatty acid starches in paper sizing composition to inhibit deposition of multivalent fatty acid salts |
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FI126543B (en) * | 2013-05-17 | 2017-02-15 | Fp-Pigments Oy | A process for the preparation of an aqueous pigment-containing cationic high solids dispersion, an aqueous pigment dispersion and its use |
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-
2005
- 2005-10-13 KR KR1020077012914A patent/KR100948121B1/en not_active IP Right Cessation
- 2005-10-13 AU AU2005301351A patent/AU2005301351B2/en not_active Ceased
- 2005-10-13 CN CN2005800358612A patent/CN101426865B/en not_active Expired - Fee Related
- 2005-10-13 JP JP2007540279A patent/JP4897694B2/en not_active Expired - Fee Related
- 2005-10-13 WO PCT/SE2005/001524 patent/WO2006049547A1/en active Application Filing
- 2005-10-13 KR KR1020077012897A patent/KR100887002B1/en not_active IP Right Cessation
- 2005-10-13 BR BRPI0517264-0A patent/BRPI0517264A/en not_active IP Right Cessation
- 2005-10-13 AU AU2005301350A patent/AU2005301350B2/en not_active Ceased
- 2005-10-13 JP JP2007540280A patent/JP5159312B2/en not_active Expired - Fee Related
- 2005-10-13 EP EP05793317A patent/EP1809710A1/en not_active Withdrawn
- 2005-10-13 ZA ZA200704420A patent/ZA200704420B/en unknown
- 2005-10-13 CN CN2005800380118A patent/CN101056955B/en not_active Expired - Fee Related
- 2005-10-13 RU RU2007121446/15A patent/RU2392223C2/en not_active IP Right Cessation
- 2005-10-13 JP JP2007540281A patent/JP2008519178A/en active Pending
- 2005-10-13 RU RU2007121473/12A patent/RU2346098C1/en not_active IP Right Cessation
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