CA2586205A1 - Pigment composition in the form of aqueous dispersion - Google Patents
Pigment composition in the form of aqueous dispersion Download PDFInfo
- Publication number
- CA2586205A1 CA2586205A1 CA002586205A CA2586205A CA2586205A1 CA 2586205 A1 CA2586205 A1 CA 2586205A1 CA 002586205 A CA002586205 A CA 002586205A CA 2586205 A CA2586205 A CA 2586205A CA 2586205 A1 CA2586205 A1 CA 2586205A1
- Authority
- CA
- Canada
- Prior art keywords
- composition
- particles
- silica
- aluminosilicate
- pigment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract 27
- 239000000049 pigment Substances 0.000 title claims abstract 17
- 239000006185 dispersion Substances 0.000 title claims abstract 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract 20
- 239000002245 particle Substances 0.000 claims abstract 16
- 229910000323 aluminium silicate Inorganic materials 0.000 claims abstract 10
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract 9
- 239000011087 paperboard Substances 0.000 claims abstract 8
- 238000000034 method Methods 0.000 claims abstract 7
- 229910002029 synthetic silica gel Inorganic materials 0.000 claims abstract 7
- 229910000329 aluminium sulfate Inorganic materials 0.000 claims abstract 6
- 239000000123 paper Substances 0.000 claims abstract 6
- 159000000013 aluminium salts Chemical class 0.000 claims abstract 5
- 229920006317 cationic polymer Polymers 0.000 claims abstract 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract 5
- 239000011248 coating agent Substances 0.000 claims abstract 3
- 238000000576 coating method Methods 0.000 claims abstract 3
- 238000004519 manufacturing process Methods 0.000 claims abstract 3
- 239000000377 silicon dioxide Substances 0.000 claims 5
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims 3
- 229910021485 fumed silica Inorganic materials 0.000 claims 2
- 229920002401 polyacrylamide Polymers 0.000 claims 2
- 239000011164 primary particle Substances 0.000 claims 2
- 239000005995 Aluminium silicate Substances 0.000 claims 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims 1
- 238000004220 aggregation Methods 0.000 claims 1
- 230000002776 aggregation Effects 0.000 claims 1
- 229910052910 alkali metal silicate Inorganic materials 0.000 claims 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 1
- PZZYQPZGQPZBDN-UHFFFAOYSA-N aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 claims 1
- 235000012211 aluminium silicate Nutrition 0.000 claims 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims 1
- 235000011128 aluminium sulphate Nutrition 0.000 claims 1
- 229910000019 calcium carbonate Inorganic materials 0.000 claims 1
- 229910052593 corundum Inorganic materials 0.000 claims 1
- 150000004676 glycans Chemical class 0.000 claims 1
- 229910052500 inorganic mineral Inorganic materials 0.000 claims 1
- 238000005342 ion exchange Methods 0.000 claims 1
- 239000011707 mineral Substances 0.000 claims 1
- 230000020477 pH reduction Effects 0.000 claims 1
- 229920000083 poly(allylamine) Polymers 0.000 claims 1
- 229920000371 poly(diallyldimethylammonium chloride) polymer Polymers 0.000 claims 1
- 229920000768 polyamine Polymers 0.000 claims 1
- 239000005017 polysaccharide Substances 0.000 claims 1
- 229920001282 polysaccharide Polymers 0.000 claims 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 claims 1
- 238000001556 precipitation Methods 0.000 claims 1
- 229910001845 yogo sapphire Inorganic materials 0.000 claims 1
- XJUNLJFOHNHSAR-UHFFFAOYSA-J zirconium(4+);dicarbonate Chemical class [Zr+4].[O-]C([O-])=O.[O-]C([O-])=O XJUNLJFOHNHSAR-UHFFFAOYSA-J 0.000 claims 1
- MFFVROSEPLMJAP-UHFFFAOYSA-J zirconium(4+);tetraacetate Chemical class [Zr+4].CC([O-])=O.CC([O-])=O.CC([O-])=O.CC([O-])=O MFFVROSEPLMJAP-UHFFFAOYSA-J 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D17/00—Pigment pastes, e.g. for mixing in paints
- C09D17/004—Pigment pastes, e.g. for mixing in paints containing an inorganic pigment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D17/00—Pigment pastes, e.g. for mixing in paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Paper (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Paints Or Removers (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
- Ink Jet (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The present invention relates to a pigment composition in the form of an aqueous dispersion comprising: (a) pigment particles of synthetic amorphous silica or aluminosilicate; (b) at least one water soluble aluminium salt; and, (c) at least one cationic polymer having a molecular weight from about 2000 t about 1000000 and a charge density from about 0.2 to about 12 meq/g. The invention further relates to a process for its production, use thereof, a process for coating paper or paper board and paper or paper board obtainable by the process.
Claims (17)
1. Pigment composition in the form of an aqueous dispersion comprising:
(a) pigment particles of synthetic amorphous silica or aluminosilicate;
(b) at least one water soluble aluminium salt; and, (c) at least one cationic polymer having a molecular weight from about 2000 to about 1000000 and a charge density from about 0.2 to about 12 meq/g.
(a) pigment particles of synthetic amorphous silica or aluminosilicate;
(b) at least one water soluble aluminium salt; and, (c) at least one cationic polymer having a molecular weight from about 2000 to about 1000000 and a charge density from about 0.2 to about 12 meq/g.
2. Composition as claimed in claim 1, wherein the particles of synthetic amorphous silica or aluminosilicate are selected from the group consisting of precipitated silica, gel-type silica, fumed silica, colloidal primary particles of silica, aluminosilicate or a mixture thereof, porous aggregates formed by aggregation of colloidal primary particles of silica, aluminosilicate or a mixture thereof in an aqueous sol, and a mixture of one or more of the above kinds of particles.
3. Composition as claimed in any one of the claims 1-2, wherein the pigment particles of synthetic amorphous silica or aluminosilicate have a mean diameter from about 0.005 µm to about 25 µm.
4. Composition as claimed in any one of the claims 1-3, wherein the net surface charge of the pigment particles in the composition is positive.
5. Composition as claimed in any one of the claims 1-4, wherein pigment particles of synthetic amorphous silica or aluminosilicate have a surface area from about 30 to about 600 m2/g.
6. Composition as claimed in any one of the claims 1-5, wherein the pigment particles of synthetic amorphous silica or aluminosilicate is a mixture of colloidal particles in a sol prepared from alkali metal silicate by ion exchange or pH-reduction, optionally partially or fully aggregated, with particles of one or more of precipitated silica, gel-type silica or fumed silica.
7. Composition as claimed in any one of the claims 1-6, wherein the at least one water soluble aluminium salt is selected from the group consisting of aluminium chloride, poly aluminium chloride, poly aluminium silicate sulfate, aluminium sulfate, zirconium carbonates, zirconium acetates, and mixtures thereof.
8. Composition as claimed in any one of the claims 1-7, wherein the at least one water soluble aluminium salt is present in an amount from about 0.1 wt% to about 30 wt%, calculated as wt% Al2O3 on dry pigment particles.
9. Composition as claimed in any one of the claims 1-8, wherein the at least one cationic polymer is selected from the group consisting of PAM
(polyacrylamides), polyDADMAC (poly diallyl dimethyl ammoniumchloride), polyallyl amines, polyamines, polysaccharides and mixtures thereof.
(polyacrylamides), polyDADMAC (poly diallyl dimethyl ammoniumchloride), polyallyl amines, polyamines, polysaccharides and mixtures thereof.
10. Composition as claimed in any one of the claims 1-9, wherein the at least one cationic polymer is present in an amount from about 0.1 wt% to about 30 wt%, based on the amount of dry pigment particles.
11. Composition as claimed in any one of the claims 1-10, wherein the pigment composition further comprises other kinds of pigment particles.
12. Composition as claimed in claim 11, wherein the other kinds of pigment particles are selected from the group consisting of kaolinites, smectites, talcites, calcium carbonate minerals, precipitated calcium carbonate, and mixtures thereof.
13. A process for the production of a pigment composition according to any one of the claims 1-12 comprising mixing particles of synthetic amorphous silica or aluminosilicate, a water soluble aluminium salt and a cationic polymer having a molecular weight from about 2000 to about 1000000 and a charge density from about 0.2 meq/g to about 12 meq/g to an aqueous dispersion in a way so substantial gelling or precipitation is avoided.
14. Use of a composition according to any one of the claims 1-12 for coating a web of paper or paper board.
15. A process for the production of coated paper or paperboard comprising a step of applying a composition according to any one of the claims 1-12 to at least one side of a paper or paperboard web.
16. A process as claimed in claim 15, wherein the coating is applied in an amount sufficient to yield from about 0.4 g/m2 to about 40 g/m2 of pigment particles from the pigment composition per coated side of the paper or paper board web.
17. Paper or paper board obtainable by a process according to any one of the claims 15-16.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP04105595 | 2004-11-08 | ||
EP04105595.5 | 2004-11-08 | ||
PCT/SE2005/001523 WO2006049546A1 (en) | 2004-11-08 | 2005-10-13 | Pigment composition in the form of aqueous dispersion |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2586205A1 true CA2586205A1 (en) | 2006-05-11 |
CA2586205C CA2586205C (en) | 2010-05-25 |
Family
ID=34929820
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA2586202A Expired - Fee Related CA2586202C (en) | 2004-11-08 | 2005-10-13 | Pigment composition in the form of aqueous dispersion |
CA2586205A Expired - Fee Related CA2586205C (en) | 2004-11-08 | 2005-10-13 | Pigment composition in the form of aqueous dispersion |
CA2586207A Expired - Fee Related CA2586207C (en) | 2004-11-08 | 2005-10-13 | A process for the production of coated paper |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA2586202A Expired - Fee Related CA2586202C (en) | 2004-11-08 | 2005-10-13 | Pigment composition in the form of aqueous dispersion |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA2586207A Expired - Fee Related CA2586207C (en) | 2004-11-08 | 2005-10-13 | A process for the production of coated paper |
Country Status (16)
Country | Link |
---|---|
EP (3) | EP1809710A1 (en) |
JP (3) | JP4897694B2 (en) |
KR (3) | KR100948121B1 (en) |
CN (3) | CN101056956B (en) |
AR (3) | AR051756A1 (en) |
AU (3) | AU2005301350B2 (en) |
BR (3) | BRPI0517258A (en) |
CA (3) | CA2586202C (en) |
MX (3) | MX2007004959A (en) |
MY (3) | MY145665A (en) |
NO (3) | NO20072908L (en) |
NZ (1) | NZ554297A (en) |
RU (3) | RU2392223C2 (en) |
TW (3) | TWI308583B (en) |
WO (3) | WO2006049547A1 (en) |
ZA (3) | ZA200704417B (en) |
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JP4102771B2 (en) * | 2004-03-25 | 2008-06-18 | 富士フイルム株式会社 | Inkjet recording medium |
JP4250121B2 (en) * | 2004-07-02 | 2009-04-08 | 富士フイルム株式会社 | Inkjet recording medium |
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2005
- 2005-10-13 ZA ZA200704417A patent/ZA200704417B/en unknown
- 2005-10-13 CN CN200580038064XA patent/CN101056956B/en not_active Expired - Fee Related
- 2005-10-13 JP JP2007540279A patent/JP4897694B2/en not_active Expired - Fee Related
- 2005-10-13 MX MX2007004959A patent/MX2007004959A/en active IP Right Grant
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- 2005-10-13 RU RU2007121446/15A patent/RU2392223C2/en not_active IP Right Cessation
- 2005-10-13 KR KR1020077012914A patent/KR100948121B1/en not_active IP Right Cessation
- 2005-10-13 RU RU2007121413/04A patent/RU2375397C2/en not_active IP Right Cessation
- 2005-10-13 WO PCT/SE2005/001524 patent/WO2006049547A1/en active Application Filing
- 2005-10-13 CN CN2005800358612A patent/CN101426865B/en not_active Expired - Fee Related
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- 2005-10-13 EP EP05793317A patent/EP1809710A1/en not_active Withdrawn
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- 2005-10-13 AU AU2005301351A patent/AU2005301351B2/en not_active Ceased
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- 2005-10-13 JP JP2007540281A patent/JP2008519178A/en active Pending
- 2005-10-13 KR KR1020077012912A patent/KR100855144B1/en not_active IP Right Cessation
- 2005-10-13 MX MX2007004438A patent/MX2007004438A/en unknown
- 2005-10-13 CA CA2586205A patent/CA2586205C/en not_active Expired - Fee Related
- 2005-10-13 MX MX2007003617A patent/MX2007003617A/en active IP Right Grant
- 2005-10-13 ZA ZA200704415A patent/ZA200704415B/en unknown
- 2005-10-13 WO PCT/SE2005/001522 patent/WO2006049545A1/en active Application Filing
- 2005-10-13 EP EP05793349A patent/EP1809711A1/en not_active Withdrawn
- 2005-10-13 EP EP05794244A patent/EP1809712A1/en not_active Withdrawn
- 2005-10-13 ZA ZA200704420A patent/ZA200704420B/en unknown
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- 2005-10-13 WO PCT/SE2005/001523 patent/WO2006049546A1/en active Application Filing
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- 2005-10-13 JP JP2007540280A patent/JP5159312B2/en not_active Expired - Fee Related
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- 2005-10-13 CA CA2586207A patent/CA2586207C/en not_active Expired - Fee Related
- 2005-10-13 AU AU2005301349A patent/AU2005301349B2/en not_active Ceased
- 2005-10-17 TW TW094136124A patent/TWI308583B/en not_active IP Right Cessation
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- 2005-10-17 TW TW094136125A patent/TWI298081B/en not_active IP Right Cessation
- 2005-10-25 MY MYPI20055015A patent/MY145665A/en unknown
- 2005-10-25 MY MYPI20055014A patent/MY145836A/en unknown
- 2005-10-25 MY MYPI20055017A patent/MY145100A/en unknown
- 2005-11-03 AR ARP050104602A patent/AR051756A1/en unknown
- 2005-11-03 AR ARP050104600A patent/AR055816A1/en active IP Right Grant
- 2005-11-03 AR ARP050104601A patent/AR051614A1/en active IP Right Grant
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2007
- 2007-06-07 NO NO20072908A patent/NO20072908L/en not_active Application Discontinuation
- 2007-06-07 NO NO20072903A patent/NO20072903L/en not_active Application Discontinuation
- 2007-06-07 NO NO20072909A patent/NO20072909L/en not_active Application Discontinuation
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