CN108914687A - A kind of micro- painting technique of papermaking nanometer and nano coating offset printing paper - Google Patents

A kind of micro- painting technique of papermaking nanometer and nano coating offset printing paper Download PDF

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Publication number
CN108914687A
CN108914687A CN201810897825.6A CN201810897825A CN108914687A CN 108914687 A CN108914687 A CN 108914687A CN 201810897825 A CN201810897825 A CN 201810897825A CN 108914687 A CN108914687 A CN 108914687A
Authority
CN
China
Prior art keywords
papermaking
micro
nanometer
paper
coating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810897825.6A
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Chinese (zh)
Inventor
刘春景
刘成良
李丹
姜云
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Yueyang Forest & Paper Co Ltd
Original Assignee
Yueyang Forest & Paper Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Yueyang Forest & Paper Co Ltd filed Critical Yueyang Forest & Paper Co Ltd
Priority to CN201810897825.6A priority Critical patent/CN108914687A/en
Publication of CN108914687A publication Critical patent/CN108914687A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/38Coatings with pigments characterised by the pigments
    • D21H19/40Coatings with pigments characterised by the pigments siliceous, e.g. clays
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/44Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/54Starch

Abstract

The invention discloses a kind of micro- painting techniques of papermaking nanometer, and following coating are applied on the paper machine with size press, and formulation for coating material includes:Nanoparticle, starch, styrene-acrylic latex, calcium stearate series lubricant agent, brightening agent.A kind of micro- painting technique of papermaking nanometer is provided, lid ability is weak, printing color reduction shortcoming to overcome the problems, such as conventional surface sizing, while improving paper surface exquisiteness, improves paper sense of touch, to improve paper product class.

Description

A kind of micro- painting technique of papermaking nanometer and nano coating offset printing paper
Technical field
The present invention relates to pulp technology for making paper, in particular to the present invention relates to a kind of micro- painting technologies of papermaking nanometer.
Background technique
As China's living standard improves, requirement of the user to hectograph paper product is also higher and higher, and emphasis is to want among these Improve paper printing effect, improves paper sense of touch and reading comfort.Offset paper production in China's often uses starch surface sizing, But traditional starch surface sizing covering power is weak, when printing, ink penetration is excessive, causes print gloss low, printing color Color reducing property is poor, and realizes high-quality printing effect, and paper surface generally requires to be coated with, and coating needs special painting to lay Standby, domestic culture paper is containing the few of coating apparatus.In addition, domestic coating Cultural Paper(Such as art paper, lightweight paper), because of glossiness Excessively high, tightness is too big, and smell is too dense, tends not to the print request for meeting high-end books.Exploitation nanometer is glued in conventional surface Coating technology is exactly to solve the problems, such as that conventional surface sizing covering power is weak, restoring shortcoming.
Summary of the invention
It is an object of the present invention to provide a kind of micro- painting techniques of papermaking nanometer, and to overcome, conventional surface sizing lid ability is weak, prints Brush color rendition is short of problem, while improving paper surface exquisiteness, improves paper sense of touch, to improve paper product class.
In order to achieve the above object, the technical solution adopted by the present invention is that:A kind of micro- painting technique of papermaking nanometer, feature exist In using following coating on the paper machine with size press, formulation for coating material includes:Nanoparticle:5-20 parts, starch:70- 90 parts, styrene-acrylic latex:5-10 parts, calcium stearate series lubricant agent:0.5-1.5 parts, brightening agent OBA:1-2 parts.
Preferably, the coating ph value is adjusted to 8.0-8.5, solid content 10-15%, viscosity:4-10cpas.
Preferably, resin added or coating weight:4-6g/m2.
Preferably, nanoparticle is the nano inorganic particles of bigger serface, porous structure.
Preferably, nanoparticle is porous silicate nanometer particle.
A kind of nano coating offset printing paper is made of the micro- painting technique of above-mentioned papermaking nanometer.
Beneficial effects of the present invention:Overcoming the problems, such as conventional surface sizing, lid ability is weak, printing color reduction shortcoming, changes simultaneously Kind paper surface exquisiteness, improves paper sense of touch, to improve paper product class:
1, compounding 5-20% nano inorganic particles can largely adsorb print due to its great specific surface area, porous structure Brush ink, so that ink is made to be retained in paper surface as far as possible, meanwhile, porous structure is conducive to solvent components in ink and penetrates into, from And improve drying property when printing.
2, nano material is introduced in top sizing, due to this nano particle large specific surface area, the requirement to adhesive is high, Otherwise it is low to be also easy to produce surface strength, prints Discussion of Picking, for this purpose, using the styrene-acrylic latex and 70- of 5-10% in coating 90% starch is as adhesive, and to improve surface strength, and emission of bad smell is effectively reduced in the presence of nano particle, and reading can be improved Comfort.
3, nanoparticle exists as colloidal form, and brightening agent and traditional helps strong type anionic surface sizing agent It is compatible that the brightening agent of 1-2% can be compounded in coating very well, meanwhile, using the coating formula of nanometer, viscosity of the coating specific surface is applied The viscous decline 31.8% of amylopectin liquid, paper machine size press roller roll surface film forming is more preferable, meanwhile, nanoparticle is compatible with brightening agent (OBA) Property is also very good.
4, the calcium stearate series lubricant agent that 0.5-1.5% is compounded in coating, can improve the rheological characteristic of coating, reduce paper Coefficient of friction improves paper feel.
5, product major parameter produced by the present invention is quantitative 50-120g/m2, to improve paper printing effect, in hectograph The indignant thought of print gloss is introduced in paper production, to improve paper feel, introduces the indignant thought of coefficient of friction, wherein print gloss >= 20%, static friction coefficient is lower than 0.4, moves mill coefficient of friction and is lower than 0.3;Surface strength >=1.0m/s;Smoothness >=40s;Blotting Property:30-40%.After being formulated using nano coating, compared with general surface sizing, paper roughness decline, smoothness rises, and moves Frictional decrease, in the consistent situation of sheet gloss degree, print gloss is higher, in addition ink absorption, surface strength difference Less.This guarantees the sheet gloss of customer requirement is low(Protect eyes), while printing color reduction preferably requires, simultaneously It can guarantee high speed rotary printing again(Without drying equipment)Not set-off, the requirement not lost powder.
Specific embodiment
In order to make those skilled in the art more fully understand technical solution of the present invention, the present invention is retouched in detail below State, the description of this part be only it is exemplary and explanatory, should not have any restriction effect to protection scope of the present invention.
Embodiment 1:
Size press is had in 5280mm(Film transfer sizing)Long mesh paper making machine on apply nano coating technology, wet end speed 1350m/min, production paper kind are 100g/m2 offset printing paper.Formulation for coating material and coating property are under:
Nano coating formula, coating property
It is quantitative 99.2g/m2, print gloss 30%, static friction coefficient 0.32, dynamic mill coefficient of friction that product major parameter, which is made, 0.25;Surface strength 1.2m/s;Smoothness 45s;Absorbency:35%.
Embodiment 2
Size press is had in 6400mm(Film transfer sizing)Foudrinier on apply nano coating technology, wet end speed 1400m/min, production paper kind are 55g/m2 offset printing paper.Formulation for coating material and coating property are under:
Nano coating formula, coating property
It is quantitative 55.5g/m2, print gloss 35%, static friction coefficient 0.33, dynamic mill coefficient of friction that product major parameter, which is made, Lower than 0.21;Surface strength 1.3m/s;Smoothness 48s;Absorbency:33%.
Embodiment 3
It is that quantitatively 111g/m2, print gloss 35%, static friction coefficient 0.33, dynamic mill coefficient of friction are low that product major parameter, which is made, In 0.21;Surface strength 1.3m/s;Smoothness 48s;Absorbency:34%.
Embodiment 4
It is that quantitatively 75g/m2, print gloss 35%, static friction coefficient 0.36, dynamic mill coefficient of friction are low that product major parameter, which is made, In 0.22;Surface strength 1.4m/s;Smoothness 49s;Absorbency:33%.
It should be noted that, in this document, the terms "include", "comprise" or its any other variant are intended to non-row His property includes, so that the process, method, article or equipment for including a series of elements not only includes those elements, and And further include other elements that are not explicitly listed, or further include for this process, method, article or equipment institute it is intrinsic Element.
Used herein a specific example illustrates the principle and implementation of the invention, the explanation of above example It is merely used to help understand method and its core concept of the invention.The above is only a preferred embodiment of the present invention, it answers When pointing out due to the finiteness of literal expression, and objectively there is unlimited specific structure, for the common skill of the art For art personnel, without departing from the principle of the present invention, several improvement, retouching or variation can also be made, can also incited somebody to action Above-mentioned technical characteristic is combined in the right way;These improve retouching, variation or combination, or the not improved structure by invention Think and technical solution directly applies to other occasions, is regarded as protection scope of the present invention.

Claims (6)

1. a kind of micro- painting technique of papermaking nanometer, which is characterized in that apply following coating on the paper machine with size press, apply Material formula includes:Nanoparticle:5-20 parts, starch:70-90 parts, styrene-acrylic latex:5-10 parts, calcium stearate series lubricant agent:0.5- 1.5 part, brightening agent OBA:1-2 parts.
2. the micro- painting technique of a kind of papermaking nanometer according to claim 1, which is characterized in that the coating ph value is adjusted to 8.0-8.5 solid content 10-15%, viscosity:4-10cpas.
3. the micro- painting technique of a kind of papermaking nanometer according to claim 1, which is characterized in that resin added or coating weight:4-6g/ m2。
4. the micro- painting technique of a kind of papermaking nanometer according to claim 1, which is characterized in that nanoparticle is Large ratio surface The nano inorganic particles of product, porous structure.
5. the micro- painting technique of a kind of papermaking nanometer according to claim 1 or 4, which is characterized in that nanoparticle is porous silicon Silicate nanometer particle.
6. a kind of nano coating offset printing paper, which is characterized in that using the micro- painting of papermaking nanometer described in the claims 1-5 Technique is made.
CN201810897825.6A 2018-08-08 2018-08-08 A kind of micro- painting technique of papermaking nanometer and nano coating offset printing paper Pending CN108914687A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810897825.6A CN108914687A (en) 2018-08-08 2018-08-08 A kind of micro- painting technique of papermaking nanometer and nano coating offset printing paper

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810897825.6A CN108914687A (en) 2018-08-08 2018-08-08 A kind of micro- painting technique of papermaking nanometer and nano coating offset printing paper

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Publication Number Publication Date
CN108914687A true CN108914687A (en) 2018-11-30

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112609503A (en) * 2020-12-10 2021-04-06 岳阳林纸股份有限公司 Surface sizing solution for electrostatic copying paper and application

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1369529A (en) * 2002-03-12 2002-09-18 深圳市尊业纳米材料有限公司 Microporous nano composite paint
CN101056955A (en) * 2004-11-08 2007-10-17 阿克佐诺贝尔公司 Pigment composition in the form of aqueous dispersion
CN101835939A (en) * 2007-10-26 2010-09-15 赛佩荷兰服务有限公司 Coating formulation for an offset paper and paper coated therewith
CN103590282A (en) * 2012-08-14 2014-02-19 金东纸业(江苏)股份有限公司 Coating and coating used coated paper
CN104672959A (en) * 2015-02-11 2015-06-03 常州君合科技股份有限公司 Nano ceramic micro-coating anticorrosive coating solution and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1369529A (en) * 2002-03-12 2002-09-18 深圳市尊业纳米材料有限公司 Microporous nano composite paint
CN101056955A (en) * 2004-11-08 2007-10-17 阿克佐诺贝尔公司 Pigment composition in the form of aqueous dispersion
CN101835939A (en) * 2007-10-26 2010-09-15 赛佩荷兰服务有限公司 Coating formulation for an offset paper and paper coated therewith
CN103590282A (en) * 2012-08-14 2014-02-19 金东纸业(江苏)股份有限公司 Coating and coating used coated paper
CN104672959A (en) * 2015-02-11 2015-06-03 常州君合科技股份有限公司 Nano ceramic micro-coating anticorrosive coating solution and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112609503A (en) * 2020-12-10 2021-04-06 岳阳林纸股份有限公司 Surface sizing solution for electrostatic copying paper and application

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Application publication date: 20181130

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