CA2585376C - Elastomeric compositions with improved resistance to necking for high speed sheet extrusion applications - Google Patents
Elastomeric compositions with improved resistance to necking for high speed sheet extrusion applications Download PDFInfo
- Publication number
- CA2585376C CA2585376C CA2585376A CA2585376A CA2585376C CA 2585376 C CA2585376 C CA 2585376C CA 2585376 A CA2585376 A CA 2585376A CA 2585376 A CA2585376 A CA 2585376A CA 2585376 C CA2585376 C CA 2585376C
- Authority
- CA
- Canada
- Prior art keywords
- polymer
- composition
- astm
- melt
- ethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 128
- 238000001125 extrusion Methods 0.000 title abstract description 27
- 229920000642 polymer Polymers 0.000 claims abstract description 161
- 239000000463 material Substances 0.000 claims abstract description 95
- 229920001155 polypropylene Polymers 0.000 claims abstract description 81
- 239000004743 Polypropylene Substances 0.000 claims abstract description 79
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 66
- 239000005977 Ethylene Substances 0.000 claims abstract description 66
- -1 polypropylene Polymers 0.000 claims abstract description 53
- 229920000098 polyolefin Polymers 0.000 claims abstract description 28
- 238000000518 rheometry Methods 0.000 claims abstract description 20
- 239000000155 melt Substances 0.000 claims description 42
- 238000000034 method Methods 0.000 claims description 28
- 230000008569 process Effects 0.000 claims description 25
- 239000006260 foam Substances 0.000 claims description 11
- 125000004432 carbon atom Chemical group C* 0.000 claims description 9
- 150000002978 peroxides Chemical class 0.000 claims description 9
- 150000001993 dienes Chemical class 0.000 claims description 8
- OJOWICOBYCXEKR-APPZFPTMSA-N (1S,4R)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound CC=C1C[C@@H]2C[C@@H]1C=C2 OJOWICOBYCXEKR-APPZFPTMSA-N 0.000 claims description 3
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 claims description 3
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical group C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 claims description 3
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 claims description 3
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 125000002872 norbornadienyl group Chemical group C12=C(C=C(CC1)C2)* 0.000 claims 1
- 230000000052 comparative effect Effects 0.000 description 28
- 229920001577 copolymer Polymers 0.000 description 28
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 20
- 229920002397 thermoplastic olefin Polymers 0.000 description 16
- 229920000573 polyethylene Polymers 0.000 description 14
- 239000000178 monomer Substances 0.000 description 13
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 13
- 229920005604 random copolymer Polymers 0.000 description 13
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 12
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 10
- 229920005989 resin Polymers 0.000 description 10
- 239000011347 resin Substances 0.000 description 10
- 239000004698 Polyethylene Substances 0.000 description 9
- 238000009826 distribution Methods 0.000 description 9
- 229920001519 homopolymer Polymers 0.000 description 8
- 239000012528 membrane Substances 0.000 description 8
- 239000010408 film Substances 0.000 description 7
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 7
- 239000003054 catalyst Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 6
- 230000004044 response Effects 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 5
- 230000007423 decrease Effects 0.000 description 5
- 238000000113 differential scanning calorimetry Methods 0.000 description 5
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 5
- 238000002844 melting Methods 0.000 description 5
- 230000004048 modification Effects 0.000 description 5
- 238000012986 modification Methods 0.000 description 5
- 229920005606 polypropylene copolymer Polymers 0.000 description 5
- 239000004711 α-olefin Substances 0.000 description 5
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 4
- 238000013329 compounding Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 238000010348 incorporation Methods 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 229920001897 terpolymer Polymers 0.000 description 4
- 239000004708 Very-low-density polyethylene Substances 0.000 description 3
- HEAMQYHBJQWOSS-UHFFFAOYSA-N ethene;oct-1-ene Chemical compound C=C.CCCCCCC=C HEAMQYHBJQWOSS-UHFFFAOYSA-N 0.000 description 3
- 229920001038 ethylene copolymer Polymers 0.000 description 3
- 230000010355 oscillation Effects 0.000 description 3
- 229920002959 polymer blend Polymers 0.000 description 3
- 229920002725 thermoplastic elastomer Polymers 0.000 description 3
- 229920001866 very low density polyethylene Polymers 0.000 description 3
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 2
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 229920001400 block copolymer Polymers 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 239000000806 elastomer Substances 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 230000004927 fusion Effects 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- SJYNFBVQFBRSIB-UHFFFAOYSA-N norbornadiene Chemical compound C1=CC2C=CC1C2 SJYNFBVQFBRSIB-UHFFFAOYSA-N 0.000 description 2
- 239000002667 nucleating agent Substances 0.000 description 2
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 150000004291 polyenes Chemical class 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 229920005672 polyolefin resin Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000011342 resin composition Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000004611 spectroscopical analysis Methods 0.000 description 2
- QEOSCXACXNFJCY-AKHDSKFASA-N (2R,3R,4S,5R)-6-benzyl-7-phenylheptane-1,2,3,4,5,6-hexol Chemical compound C(C1=CC=CC=C1)C(O)([C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO)CC1=CC=CC=C1 QEOSCXACXNFJCY-AKHDSKFASA-N 0.000 description 1
- OKTJSMMVPCPJKN-OUBTZVSYSA-N Carbon-13 Chemical compound [13C] OKTJSMMVPCPJKN-OUBTZVSYSA-N 0.000 description 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- 229920000181 Ethylene propylene rubber Polymers 0.000 description 1
- 241001441571 Hiodontidae Species 0.000 description 1
- 238000005481 NMR spectroscopy Methods 0.000 description 1
- 229920000034 Plastomer Polymers 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229920006125 amorphous polymer Polymers 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 150000001540 azides Chemical class 0.000 description 1
- 230000002902 bimodal effect Effects 0.000 description 1
- 235000013877 carbamide Nutrition 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 1
- 239000012990 dithiocarbamate Substances 0.000 description 1
- 150000004659 dithiocarbamates Chemical class 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011067 equilibration Methods 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 150000002357 guanidines Chemical class 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 229920004889 linear high-density polyethylene Polymers 0.000 description 1
- 229920000092 linear low density polyethylene Polymers 0.000 description 1
- 239000004707 linear low-density polyethylene Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000003446 memory effect Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- 239000003348 petrochemical agent Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 229920006124 polyolefin elastomer Polymers 0.000 description 1
- 229920005629 polypropylene homopolymer Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000003303 reheating Methods 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 230000024042 response to gravity Effects 0.000 description 1
- 239000006254 rheological additive Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000004826 seaming Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229920006029 tetra-polymer Polymers 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 150000003557 thiazoles Chemical class 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 1
- 238000004627 transmission electron microscopy Methods 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 239000012991 xanthate Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
- C08L2666/06—Homopolymers or copolymers of unsaturated hydrocarbons; Derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Laminated Bodies (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US62840504P | 2004-11-16 | 2004-11-16 | |
| US60/628,405 | 2004-11-16 | ||
| PCT/US2005/041562 WO2006055650A1 (en) | 2004-11-16 | 2005-11-16 | Elastomeric compositions with improved resistance to necking for high speed sheet extrusion applications |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2585376A1 CA2585376A1 (en) | 2006-05-26 |
| CA2585376C true CA2585376C (en) | 2013-06-25 |
Family
ID=35986249
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2585376A Expired - Fee Related CA2585376C (en) | 2004-11-16 | 2005-11-16 | Elastomeric compositions with improved resistance to necking for high speed sheet extrusion applications |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US20080132595A1 (enExample) |
| EP (1) | EP1814942B1 (enExample) |
| JP (1) | JP5301835B2 (enExample) |
| KR (1) | KR101215809B1 (enExample) |
| CN (1) | CN101061172B (enExample) |
| AT (1) | ATE437202T1 (enExample) |
| AU (1) | AU2005307750B2 (enExample) |
| BR (1) | BRPI0516806B1 (enExample) |
| CA (1) | CA2585376C (enExample) |
| DE (1) | DE602005015613D1 (enExample) |
| ES (1) | ES2326676T3 (enExample) |
| MX (1) | MX2007005826A (enExample) |
| WO (1) | WO2006055650A1 (enExample) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007002436A1 (en) * | 2005-06-24 | 2007-01-04 | Dow Global Technologies Inc. | Filled tpo compositions, methods of making the same, and articles prepared from the same |
| EP2190918B1 (en) * | 2007-09-07 | 2011-06-15 | Dow Global Technologies LLC | Filled tpo compositions with good low temperature ductility |
| JP5538092B2 (ja) * | 2010-06-28 | 2014-07-02 | 日本ポリエチレン株式会社 | 太陽電池封止材用組成物及びそれからなる封止材ならびにそれを用いた太陽電池モジュール |
| JP5542547B2 (ja) * | 2010-06-29 | 2014-07-09 | 日本ポリエチレン株式会社 | 太陽電池モジュール、太陽電池封止材用組成物及びそれからなる太陽電池封止材 |
| BR112013017815B1 (pt) | 2011-01-12 | 2020-05-12 | Compagnie Chomarat | Estruturas de compósito laminado e métodos para fabricar e usar as mesmas |
| JP2015527472A (ja) * | 2012-09-11 | 2015-09-17 | シーカ・テクノロジー・アーゲー | 高い柔軟性及び高い融点を有する熱可塑性混合物 |
| MX2020011726A (es) * | 2018-05-04 | 2021-02-26 | Braskem Sa | Composiciones de poliolefina con propiedades de tacto suave mejoradas. |
| WO2020214453A1 (en) * | 2019-04-17 | 2020-10-22 | Dow Global Technologies Llc | Thermoplastic olefin composition |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4598128A (en) * | 1983-03-14 | 1986-07-01 | Phillips Petroleum Company | Polymer composition and preparation method |
| US6316546B1 (en) * | 1991-03-06 | 2001-11-13 | Exxonmobil Oil Corporation | Ethylene polymer film resins |
| US5278272A (en) * | 1991-10-15 | 1994-01-11 | The Dow Chemical Company | Elastic substantialy linear olefin polymers |
| EP0575123B2 (en) * | 1992-06-17 | 2008-02-13 | Mitsui Chemicals, Inc. | Ethylene copolymer composition |
| JPH06136195A (ja) * | 1992-09-08 | 1994-05-17 | Mitsui Petrochem Ind Ltd | エチレン系共重合体組成物 |
| US6448341B1 (en) * | 1993-01-29 | 2002-09-10 | The Dow Chemical Company | Ethylene interpolymer blend compositions |
| IL115911A0 (en) * | 1994-11-14 | 1996-01-31 | Dow Chemical Co | Extrusion compositions having high drawdown and substantially reduced neck-in |
| DE19629050B4 (de) * | 1995-07-21 | 2009-05-07 | Toyoda Gosei Co., Ltd. | Polyolefin-Elastomer-Zusammensetzung |
| JPH09188788A (ja) * | 1995-11-07 | 1997-07-22 | Mitsui Petrochem Ind Ltd | ポリプロピレン組成物 |
| EP0887378B1 (en) * | 1996-03-15 | 2004-08-04 | Sumitomo Chemical Company Limited | Thermoplastic elastomer composition and powder and molded article thereof |
| US6485662B1 (en) * | 1996-12-03 | 2002-11-26 | Union Carbide Chemicals & Plastics Technology Corporation | Process for preparing a simulated in situ polyethylene blend |
| US6506842B1 (en) * | 1997-01-29 | 2003-01-14 | Dupont Dow Elastomers L.L.C. | Rheology-modified thermoplastic elastomer compositions and articles fabricated therefrom |
| DE19833858C2 (de) * | 1998-07-28 | 2000-06-08 | Elenac Gmbh | Geruchsarme Polyethylen-Blends |
| CN1142973C (zh) * | 1998-11-03 | 2004-03-24 | 蒙特克美国有限公司 | 刚性与冲击强度高度平衡的聚烯烃组合物 |
| US6541105B1 (en) | 1999-09-16 | 2003-04-01 | Dow Global Technologies Inc. | Acoustical open-cell polylefins and process for making |
| ES2257397T3 (es) * | 2000-03-17 | 2006-08-01 | Dow Global Technologies Inc. | Espuma poliolefinica macrocelular que tiene una alta temperatura de servicio para aplicaciones acusticas. |
| US6926820B2 (en) * | 2002-09-20 | 2005-08-09 | G.E. Betz, Inc. | Inhibition of viscosity increase and fouling in hydrocarbon streams including unsaturation |
| US7846552B2 (en) * | 2002-09-23 | 2010-12-07 | Dow Global Technologies Inc. | Polymer compositions for extrusion coating |
| JP4651275B2 (ja) * | 2003-11-04 | 2011-03-16 | 三井化学株式会社 | エチレン系共重合体樹脂組成物とその用途 |
-
2005
- 2005-11-16 CN CN2005800392168A patent/CN101061172B/zh not_active Expired - Lifetime
- 2005-11-16 AT AT05846330T patent/ATE437202T1/de not_active IP Right Cessation
- 2005-11-16 MX MX2007005826A patent/MX2007005826A/es active IP Right Grant
- 2005-11-16 JP JP2007541467A patent/JP5301835B2/ja not_active Expired - Lifetime
- 2005-11-16 CA CA2585376A patent/CA2585376C/en not_active Expired - Fee Related
- 2005-11-16 US US11/666,530 patent/US20080132595A1/en not_active Abandoned
- 2005-11-16 DE DE602005015613T patent/DE602005015613D1/de not_active Expired - Lifetime
- 2005-11-16 AU AU2005307750A patent/AU2005307750B2/en not_active Ceased
- 2005-11-16 BR BRPI0516806A patent/BRPI0516806B1/pt active IP Right Grant
- 2005-11-16 WO PCT/US2005/041562 patent/WO2006055650A1/en not_active Ceased
- 2005-11-16 ES ES05846330T patent/ES2326676T3/es not_active Expired - Lifetime
- 2005-11-16 KR KR1020077011015A patent/KR101215809B1/ko not_active Expired - Lifetime
- 2005-11-16 EP EP05846330A patent/EP1814942B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JP5301835B2 (ja) | 2013-09-25 |
| BRPI0516806B1 (pt) | 2019-08-13 |
| ATE437202T1 (de) | 2009-08-15 |
| US20080132595A1 (en) | 2008-06-05 |
| CN101061172B (zh) | 2010-12-15 |
| MX2007005826A (es) | 2007-07-20 |
| KR20070085368A (ko) | 2007-08-27 |
| DE602005015613D1 (de) | 2009-09-03 |
| JP2008520769A (ja) | 2008-06-19 |
| AU2005307750B2 (en) | 2011-09-01 |
| EP1814942A1 (en) | 2007-08-08 |
| EP1814942B1 (en) | 2009-07-22 |
| WO2006055650A1 (en) | 2006-05-26 |
| KR101215809B1 (ko) | 2012-12-27 |
| CN101061172A (zh) | 2007-10-24 |
| AU2005307750A1 (en) | 2006-05-26 |
| ES2326676T3 (es) | 2009-10-16 |
| BRPI0516806A2 (pt) | 2008-11-25 |
| CA2585376A1 (en) | 2006-05-26 |
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