CA2573975A1 - 1-butene polymers composition - Google Patents
1-butene polymers composition Download PDFInfo
- Publication number
- CA2573975A1 CA2573975A1 CA002573975A CA2573975A CA2573975A1 CA 2573975 A1 CA2573975 A1 CA 2573975A1 CA 002573975 A CA002573975 A CA 002573975A CA 2573975 A CA2573975 A CA 2573975A CA 2573975 A1 CA2573975 A1 CA 2573975A1
- Authority
- CA
- Canada
- Prior art keywords
- butene
- weight
- isotactic
- component
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 title claims abstract description 190
- 239000000203 mixture Substances 0.000 title claims abstract description 76
- 229920000642 polymer Polymers 0.000 title claims abstract description 76
- 238000009826 distribution Methods 0.000 claims abstract description 19
- 238000002844 melting Methods 0.000 claims abstract description 13
- 230000008018 melting Effects 0.000 claims abstract description 13
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 claims abstract description 8
- 230000004927 fusion Effects 0.000 claims abstract description 3
- 150000001875 compounds Chemical class 0.000 claims description 50
- -1 ethylene, propylene Chemical group 0.000 claims description 42
- 239000003054 catalyst Substances 0.000 claims description 38
- 230000000737 periodic effect Effects 0.000 claims description 36
- 238000000034 method Methods 0.000 claims description 30
- 125000005842 heteroatom Chemical group 0.000 claims description 29
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 26
- 239000004215 Carbon black (E152) Substances 0.000 claims description 22
- 229930195733 hydrocarbon Natural products 0.000 claims description 22
- 238000006116 polymerization reaction Methods 0.000 claims description 22
- 239000004711 α-olefin Substances 0.000 claims description 21
- 229920001577 copolymer Polymers 0.000 claims description 20
- 125000004122 cyclic group Chemical group 0.000 claims description 19
- 230000008569 process Effects 0.000 claims description 19
- 125000002015 acyclic group Chemical group 0.000 claims description 18
- 125000004429 atom Chemical group 0.000 claims description 16
- 125000000304 alkynyl group Chemical group 0.000 claims description 15
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 claims description 15
- 125000003342 alkenyl group Chemical group 0.000 claims description 14
- 229910052782 aluminium Inorganic materials 0.000 claims description 14
- 229920001519 homopolymer Polymers 0.000 claims description 14
- 229910052723 transition metal Inorganic materials 0.000 claims description 14
- 150000003624 transition metals Chemical group 0.000 claims description 14
- 125000000217 alkyl group Chemical group 0.000 claims description 12
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 8
- 239000000178 monomer Substances 0.000 claims description 6
- 229910052710 silicon Inorganic materials 0.000 claims description 6
- 150000001768 cations Chemical class 0.000 claims description 5
- 125000005843 halogen group Chemical group 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 4
- 239000005977 Ethylene Substances 0.000 claims description 4
- 150000004646 arylidenes Chemical group 0.000 claims description 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 4
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 4
- 150000001255 actinides Chemical group 0.000 claims description 3
- 125000001118 alkylidene group Chemical group 0.000 claims description 3
- 230000003647 oxidation Effects 0.000 claims description 3
- 238000007254 oxidation reaction Methods 0.000 claims description 3
- 230000000379 polymerizing effect Effects 0.000 claims description 3
- 229910052747 lanthanoid Inorganic materials 0.000 claims description 2
- 150000002602 lanthanoids Chemical class 0.000 claims description 2
- 125000002827 triflate group Chemical group FC(S(=O)(=O)O*)(F)F 0.000 claims 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 26
- 150000003254 radicals Chemical class 0.000 description 20
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 19
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 19
- 239000000243 solution Substances 0.000 description 18
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 14
- 229910052757 nitrogen Inorganic materials 0.000 description 13
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 11
- 239000007983 Tris buffer Substances 0.000 description 10
- 239000004411 aluminium Substances 0.000 description 10
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 9
- 239000010936 titanium Substances 0.000 description 9
- AQZWEFBJYQSQEH-UHFFFAOYSA-N 2-methyloxaluminane Chemical compound C[Al]1CCCCO1 AQZWEFBJYQSQEH-UHFFFAOYSA-N 0.000 description 8
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 8
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 8
- 125000001424 substituent group Chemical group 0.000 description 8
- 229910052719 titanium Inorganic materials 0.000 description 8
- 229910052726 zirconium Inorganic materials 0.000 description 8
- 239000002904 solvent Substances 0.000 description 7
- 229910001220 stainless steel Inorganic materials 0.000 description 7
- 239000010935 stainless steel Substances 0.000 description 7
- 229910000831 Steel Inorganic materials 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 6
- 229920006395 saturated elastomer Polymers 0.000 description 6
- 239000010959 steel Substances 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 150000004645 aluminates Chemical class 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- 238000012512 characterization method Methods 0.000 description 5
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 5
- 239000008096 xylene Substances 0.000 description 5
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical group [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 4
- 150000001450 anions Chemical class 0.000 description 4
- 238000001704 evaporation Methods 0.000 description 4
- 230000008020 evaporation Effects 0.000 description 4
- 238000001914 filtration Methods 0.000 description 4
- 229920001748 polybutylene Polymers 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- XOJVVFBFDXDTEG-UHFFFAOYSA-N pristane Chemical compound CC(C)CCCC(C)CCCC(C)CCCC(C)C XOJVVFBFDXDTEG-UHFFFAOYSA-N 0.000 description 4
- PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical compound ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 3
- 125000003358 C2-C20 alkenyl group Chemical group 0.000 description 3
- 101100238304 Mus musculus Morc1 gene Proteins 0.000 description 3
- 238000005481 NMR spectroscopy Methods 0.000 description 3
- 239000004793 Polystyrene Substances 0.000 description 3
- 125000001309 chloro group Chemical group Cl* 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- QUPDWYMUPZLYJZ-UHFFFAOYSA-N ethyl Chemical group C[CH2] QUPDWYMUPZLYJZ-UHFFFAOYSA-N 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229920002223 polystyrene Polymers 0.000 description 3
- VPGLGRNSAYHXPY-UHFFFAOYSA-L zirconium(2+);dichloride Chemical compound Cl[Zr]Cl VPGLGRNSAYHXPY-UHFFFAOYSA-L 0.000 description 3
- 125000006736 (C6-C20) aryl group Chemical group 0.000 description 2
- RELMFMZEBKVZJC-UHFFFAOYSA-N 1,2,3-trichlorobenzene Chemical compound ClC1=CC=CC(Cl)=C1Cl RELMFMZEBKVZJC-UHFFFAOYSA-N 0.000 description 2
- 229910018516 Al—O Inorganic materials 0.000 description 2
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- XMIJDTGORVPYLW-UHFFFAOYSA-N [SiH2] Chemical compound [SiH2] XMIJDTGORVPYLW-UHFFFAOYSA-N 0.000 description 2
- 150000001399 aluminium compounds Chemical class 0.000 description 2
- 229940077746 antacid containing aluminium compound Drugs 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 150000001639 boron compounds Chemical class 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 150000001923 cyclic compounds Chemical class 0.000 description 2
- IPZJQDSFZGZEOY-UHFFFAOYSA-N dimethylmethylene Chemical compound C[C]C IPZJQDSFZGZEOY-UHFFFAOYSA-N 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 238000005194 fractionation Methods 0.000 description 2
- 229910052735 hafnium Chemical group 0.000 description 2
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical group [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- 229920002521 macromolecule Polymers 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 229940078552 o-xylene Drugs 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 150000003623 transition metal compounds Chemical class 0.000 description 2
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 2
- HKVFGFGPRISDFM-UHFFFAOYSA-N tris(2,3,3-trimethylbutyl)alumane Chemical compound CC(C)(C)C(C)C[Al](CC(C)C(C)(C)C)CC(C)C(C)(C)C HKVFGFGPRISDFM-UHFFFAOYSA-N 0.000 description 2
- SSEXLBWMXFFGTD-UHFFFAOYSA-N tris(2,3-dimethylbutyl)alumane Chemical compound CC(C)C(C)C[Al](CC(C)C(C)C)CC(C)C(C)C SSEXLBWMXFFGTD-UHFFFAOYSA-N 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- QPFMBZIOSGYJDE-QDNHWIQGSA-N 1,1,2,2-tetrachlorethane-d2 Chemical compound [2H]C(Cl)(Cl)C([2H])(Cl)Cl QPFMBZIOSGYJDE-QDNHWIQGSA-N 0.000 description 1
- KAESVJOAVNADME-UHFFFAOYSA-N 1H-pyrrole Natural products C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 102000020897 Formins Human genes 0.000 description 1
- 108091022623 Formins Proteins 0.000 description 1
- NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 1
- 241000446313 Lamella Species 0.000 description 1
- 238000000944 Soxhlet extraction Methods 0.000 description 1
- 230000009102 absorption Effects 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000000862 absorption spectrum Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 150000005840 aryl radicals Chemical class 0.000 description 1
- 238000010009 beating Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 238000011088 calibration curve Methods 0.000 description 1
- 238000001460 carbon-13 nuclear magnetic resonance spectrum Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical group [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000002899 organoaluminium compounds Chemical class 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 125000000538 pentafluorophenyl group Chemical group FC1=C(F)C(F)=C(*)C(F)=C1F 0.000 description 1
- DOIRQSBPFJWKBE-UHFFFAOYSA-N phthalic acid di-n-butyl ester Natural products CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000012925 reference material Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 101150115956 slc25a26 gene Proteins 0.000 description 1
- 239000007779 soft material Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 238000000935 solvent evaporation Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 230000000707 stereoselective effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- INNUJJCMHIUXQQ-UHFFFAOYSA-N tris(2,2-diphenylethyl)alumane Chemical compound C=1C=CC=CC=1C(C=1C=CC=CC=1)C[Al](CC(C=1C=CC=CC=1)C=1C=CC=CC=1)CC(C=1C=CC=CC=1)C1=CC=CC=C1 INNUJJCMHIUXQQ-UHFFFAOYSA-N 0.000 description 1
- PUGPVAUOXDRYSP-UHFFFAOYSA-N tris(2,3,3-trimethylhexyl)alumane Chemical compound CCCC(C)(C)C(C)C[Al](CC(C)C(C)(C)CCC)CC(C)C(C)(C)CCC PUGPVAUOXDRYSP-UHFFFAOYSA-N 0.000 description 1
- RXTYCDSTJDDMRJ-UHFFFAOYSA-N tris(2,3,3-trimethylpentyl)alumane Chemical compound CCC(C)(C)C(C)C[Al](CC(C)C(C)(C)CC)CC(C)C(C)(C)CC RXTYCDSTJDDMRJ-UHFFFAOYSA-N 0.000 description 1
- WRZKUDJYHWOMSC-UHFFFAOYSA-N tris(2,3-diethylpentyl)alumane Chemical compound CCC(CC)C(CC)C[Al](CC(CC)C(CC)CC)CC(CC)C(CC)CC WRZKUDJYHWOMSC-UHFFFAOYSA-N 0.000 description 1
- IBAAQZWRANCYLH-UHFFFAOYSA-N tris(2,3-dimethyl-3-phenylbutyl)alumane Chemical compound C=1C=CC=CC=1C(C)(C)C(C)C[Al](CC(C)C(C)(C)C=1C=CC=CC=1)CC(C)C(C)(C)C1=CC=CC=C1 IBAAQZWRANCYLH-UHFFFAOYSA-N 0.000 description 1
- BENYMJNPVWYYES-UHFFFAOYSA-N tris(2,3-dimethylpentyl)alumane Chemical compound CCC(C)C(C)C[Al](CC(C)C(C)CC)CC(C)C(C)CC BENYMJNPVWYYES-UHFFFAOYSA-N 0.000 description 1
- XZIKSWMNFLIAQP-UHFFFAOYSA-N tris(2,4,4-trimethylpentyl)alumane Chemical compound CC(C)(C)CC(C)C[Al](CC(C)CC(C)(C)C)CC(C)CC(C)(C)C XZIKSWMNFLIAQP-UHFFFAOYSA-N 0.000 description 1
- WXUZTGFTOYFKIR-UHFFFAOYSA-N tris(2-ethyl-3,3-dimethylbutyl)alumane Chemical compound CCC(C(C)(C)C)C[Al](CC(CC)C(C)(C)C)CC(CC)C(C)(C)C WXUZTGFTOYFKIR-UHFFFAOYSA-N 0.000 description 1
- IDEILWZYRDEEGQ-UHFFFAOYSA-N tris(2-ethyl-3,3-dimethylpentyl)alumane Chemical compound CCC(C)(C)C(CC)C[Al](CC(CC)C(C)(C)CC)CC(CC)C(C)(C)CC IDEILWZYRDEEGQ-UHFFFAOYSA-N 0.000 description 1
- FEJNOSHLGDRZDX-UHFFFAOYSA-N tris(2-ethyl-3-methylbutyl)alumane Chemical compound CCC(C(C)C)C[Al](CC(CC)C(C)C)CC(CC)C(C)C FEJNOSHLGDRZDX-UHFFFAOYSA-N 0.000 description 1
- JAFSWBPCWFKGBY-UHFFFAOYSA-N tris(2-ethyl-3-methylpentyl)alumane Chemical compound CCC(C)C(CC)C[Al](CC(CC)C(C)CC)CC(CC)C(C)CC JAFSWBPCWFKGBY-UHFFFAOYSA-N 0.000 description 1
- ZMFQGYOUXPHLOA-UHFFFAOYSA-N tris(2-methyl-3-phenylbutyl)alumane Chemical compound C=1C=CC=CC=1C(C)C(C)C[Al](CC(C)C(C)C=1C=CC=CC=1)CC(C)C(C)C1=CC=CC=C1 ZMFQGYOUXPHLOA-UHFFFAOYSA-N 0.000 description 1
- JHKHTIUZAWUYBF-UHFFFAOYSA-N tris(2-methyl-3-propylhexyl)alumane Chemical compound CCCC(CCC)C(C)C[Al](CC(C)C(CCC)CCC)CC(C)C(CCC)CCC JHKHTIUZAWUYBF-UHFFFAOYSA-N 0.000 description 1
- VJEKKLDXDUTOAK-UHFFFAOYSA-N tris(2-phenylpropyl)alumane Chemical compound C=1C=CC=CC=1C(C)C[Al](CC(C)C=1C=CC=CC=1)CC(C)C1=CC=CC=C1 VJEKKLDXDUTOAK-UHFFFAOYSA-N 0.000 description 1
- NEKKHOCWHFUARF-UHFFFAOYSA-N tris(2-propan-2-ylpentyl)alumane Chemical compound CCCC(C(C)C)C[Al](CC(CCC)C(C)C)CC(CCC)C(C)C NEKKHOCWHFUARF-UHFFFAOYSA-N 0.000 description 1
- NWZXKGHKCZTEHC-UHFFFAOYSA-N tris(3-ethyl-2-methylheptyl)alumane Chemical compound CCCCC(CC)C(C)C[Al](CC(C)C(CC)CCCC)CC(C)C(CC)CCCC NWZXKGHKCZTEHC-UHFFFAOYSA-N 0.000 description 1
- PZHDFOMROGHRBA-UHFFFAOYSA-N tris(3-ethyl-2-methylhexyl)alumane Chemical compound CCCC(CC)C(C)C[Al](CC(C)C(CC)CCC)CC(C)C(CC)CCC PZHDFOMROGHRBA-UHFFFAOYSA-N 0.000 description 1
- VIDMRZMJMLMHSP-UHFFFAOYSA-N tris(3-methyl-2-propan-2-ylbutyl)alumane Chemical compound CC(C)C(C(C)C)C[Al](CC(C(C)C)C(C)C)CC(C(C)C)C(C)C VIDMRZMJMLMHSP-UHFFFAOYSA-N 0.000 description 1
- KFXLMHSDDUANFS-UHFFFAOYSA-N tris[2-(2,3,4,5,6-pentafluorophenyl)propyl]alumane Chemical compound FC=1C(F)=C(F)C(F)=C(F)C=1C(C)C[Al](CC(C)C=1C(=C(F)C(F)=C(F)C=1F)F)CC(C)C1=C(F)C(F)=C(F)C(F)=C1F KFXLMHSDDUANFS-UHFFFAOYSA-N 0.000 description 1
- ASSHEQWDGOTJRP-UHFFFAOYSA-N tris[2-(4-chlorophenyl)propyl]alumane Chemical compound C=1C=C(Cl)C=CC=1C(C)C[Al](CC(C)C=1C=CC(Cl)=CC=1)CC(C)C1=CC=C(Cl)C=C1 ASSHEQWDGOTJRP-UHFFFAOYSA-N 0.000 description 1
- ZCLZBCAKWSHDJL-UHFFFAOYSA-N tris[2-(4-fluorophenyl)propyl]alumane Chemical compound C=1C=C(F)C=CC=1C(C)C[Al](CC(C)C=1C=CC(F)=CC=1)CC(C)C1=CC=C(F)C=C1 ZCLZBCAKWSHDJL-UHFFFAOYSA-N 0.000 description 1
- AETKXSGBGBBCGA-UHFFFAOYSA-N tris[3-methyl-2-(2-methylpropyl)pentyl]alumane Chemical compound CCC(C)C(CC(C)C)C[Al](CC(CC(C)C)C(C)CC)CC(CC(C)C)C(C)CC AETKXSGBGBBCGA-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/08—Butenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP04103525 | 2004-07-22 | ||
| EP04103525.4 | 2004-07-22 | ||
| US59234604P | 2004-07-28 | 2004-07-28 | |
| US60/592,346 | 2004-07-28 | ||
| PCT/EP2005/052688 WO2006008211A1 (en) | 2004-07-22 | 2005-06-10 | 1-butene polymers composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2573975A1 true CA2573975A1 (en) | 2006-01-26 |
Family
ID=38185425
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002573975A Abandoned CA2573975A1 (en) | 2004-07-22 | 2005-06-10 | 1-butene polymers composition |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US7799871B2 (https=) |
| EP (1) | EP1769030B1 (https=) |
| JP (1) | JP2008506824A (https=) |
| KR (1) | KR20070043800A (https=) |
| CN (2) | CN100567338C (https=) |
| AT (1) | ATE388994T1 (https=) |
| AU (1) | AU2005263670A1 (https=) |
| BR (1) | BRPI0513109A (https=) |
| CA (1) | CA2573975A1 (https=) |
| DE (1) | DE602005005334T2 (https=) |
| ES (1) | ES2303260T3 (https=) |
| PL (1) | PL1769030T3 (https=) |
| RU (2) | RU2371459C2 (https=) |
| TW (1) | TW200613418A (https=) |
| WO (1) | WO2006008211A1 (https=) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4897670B2 (ja) | 2004-05-04 | 2012-03-14 | バーゼル・ポリオレフィン・ゲーエムベーハー | アタクチック１−ブテンポリマー類の製造方法 |
| EP1769009A1 (en) | 2004-07-22 | 2007-04-04 | Basell Polyolefine GmbH | Process for producing fractionable 1-butene polymers |
| WO2007122097A1 (en) | 2006-04-21 | 2007-11-01 | Basell Polyolefine Gmbh | Process for the preparation of ethylene propylene copolymers |
| EP2010580B1 (en) | 2006-04-21 | 2016-07-13 | Basell Polyolefine GmbH | Process for the preparation of ethylene copolymers |
| US8097681B2 (en) | 2006-08-30 | 2012-01-17 | Basell Polyolefine Gmbh | 1-butene propylene copolymer compositions |
| KR101423946B1 (ko) | 2006-08-30 | 2014-08-01 | 바젤 폴리올레핀 게엠베하 | 1-부텐 프로필렌 공중합체 조성물 |
| DE102008005947A1 (de) * | 2008-01-24 | 2009-07-30 | Evonik Degussa Gmbh | Polyolefine mit Ataktischen Strukturelementen, Verfahren zu deren Herstellung und deren Verwendung |
| JP5346075B2 (ja) * | 2008-04-22 | 2013-11-20 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | １−ブテンターポリマー |
| CN101337997B (zh) * | 2008-08-13 | 2012-09-05 | 中国科学院化学研究所 | 一种载体型双金属复合催化剂及其制备方法 |
| CN101891856B (zh) * | 2010-07-09 | 2011-10-19 | 锦州康泰润滑油添加剂有限公司 | 一种利用工业废碳四中烯烃制备正丁烯聚合物的方法 |
| US9505958B2 (en) | 2012-09-14 | 2016-11-29 | Mitsui Chemicals, Inc. | 1-butene α-olefin copolymer composition |
| PT3266825T (pt) * | 2016-07-07 | 2022-04-11 | Basell Poliolefine Italia Srl | Composição polimérica de buteno-1 tendo um índice de fluidez elevado |
| EP3266824B1 (en) * | 2016-07-07 | 2022-03-09 | Basell Poliolefine Italia S.r.l. | Butene-1 polymer composition having a high melt flow rate |
| JP7034252B2 (ja) * | 2017-08-04 | 2022-03-11 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | 高い溶融流量を有するブテン－１重合体組成物 |
| WO2019025585A1 (en) * | 2017-08-04 | 2019-02-07 | Basell Poliolefine Italia S.R.L. | BUTENE-1 POLYMER COMPOSITION WITH HIGH FLUIDITY INDEX |
| CN115991804A (zh) * | 2021-10-20 | 2023-04-21 | 中国石油化工股份有限公司 | 聚1-丁烯及其制备方法 |
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| DE1915061B2 (de) * | 1969-03-25 | 1972-03-23 | Chemische Werke Hüls AG, 4370 Mari | Leitfaehige kunststoffmasse fuer den kabelsektor |
| DE2254128C3 (de) * | 1972-11-04 | 1975-08-14 | Chemische Werke Huels Ag, 4370 Marl | Thermoplastische Formmasse aus Polybuten-I |
| US4298722A (en) | 1980-03-11 | 1981-11-03 | E. I. Du Pont De Nemours And Company | Fractionable, elastomeric poly (1-butene) |
| ATE38044T1 (de) | 1984-08-30 | 1988-11-15 | Mitsui Petrochemical Ind | Buten-1-polymer und seine verwendung. |
| IL95278A0 (en) | 1989-08-03 | 1991-06-30 | Exxon Chemical Patents Inc | Very high molecular weight polyethylene |
| RU2118203C1 (ru) | 1990-06-22 | 1998-08-27 | Экксон Кэмикал Пейтентс Инк. | Каталитическая система для получения полиолефинов и композиция, используемая для полимеризации олефинов |
| IT1243430B (it) * | 1990-09-28 | 1994-06-10 | Himont Inc | Composizioni di polimeri cristallini del propilene aventi bassa temperatura |
| ES2128371T3 (es) * | 1992-08-15 | 1999-05-16 | Targor Gmbh | Procedimiento para la obtencion de poliolefinas. |
| IT1256259B (it) | 1992-12-30 | 1995-11-29 | Montecatini Tecnologie Srl | Composti mettallocenici aventi leganti di tipo fluorenilico |
| ATE223929T1 (de) * | 1995-05-16 | 2002-09-15 | Univation Tech Llc | Herstellung von polyethylen unter verwendung eines stereoisomeren metallocens |
| EP0930320A1 (en) * | 1997-07-22 | 1999-07-21 | Mitsui Chemicals, Inc. | Ethylene/alpha-olefin copolymers, compositions, and processes for the preparation of the copolymers and the compositions |
| IT1295052B1 (it) * | 1997-09-24 | 1999-04-27 | Montell North America Inc | Miscele poliolefiniche elastomeriche parzialmente reticolate |
| US6559252B1 (en) | 1997-10-29 | 2003-05-06 | Basell Technology Company Bv | Catalysts and processes for the polymerization of olefins |
| KR19990067851A (ko) * | 1998-01-14 | 1999-08-25 | 고오사이 아끼오 | 올레핀 중합체, 올레핀 중합 촉매 및 올레핀 중합체의 제조 방법 |
| DE69910511T2 (de) | 1998-03-05 | 2004-06-17 | Basell Poliolefine Italia S.P.A. | Polybutene-1 (co)polymere und verfahren zu ihrer herstellung |
| US6900343B1 (en) | 1998-11-25 | 2005-05-31 | Basell Polyolefine Gmbh | Method for the purification of metallocenes |
| BR0014616A (pt) | 1999-09-22 | 2002-06-18 | Basell Technology Co Bv | Sistema catalìtico e processo para a polimerização de olefinas |
| US6444833B1 (en) | 1999-12-15 | 2002-09-03 | Basell Technology Company Bv | Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins |
| DE19962814A1 (de) | 1999-12-23 | 2001-06-28 | Targor Gmbh | Neues Katalysatorsystem und dessen Verwendung |
| DE19962910A1 (de) | 1999-12-23 | 2001-07-05 | Targor Gmbh | Chemische Verbindung, Verfahren zu deren Herstellung und deren Verwendung in Katalysatorsystemen zur Herstellung von Polyolefinen |
| DE60103702T2 (de) | 2000-02-24 | 2005-06-23 | Basell Polyolefine Gmbh | Organometallische Verbindungen die als Cokatalysator bei der Polymerisation von Olefinen verwendet ist |
| WO2002002576A1 (en) | 2000-06-30 | 2002-01-10 | Exxonmobil Chemical Patents Inc. | Bridged bis (indenyl) metallocene compounds |
| US20020123538A1 (en) * | 2000-12-29 | 2002-09-05 | Peiguang Zhou | Hot-melt adhesive based on blend of amorphous and crystalline polymers for multilayer bonding |
| JP2002348343A (ja) * | 2001-05-28 | 2002-12-04 | Idemitsu Petrochem Co Ltd | オレフィン系重合体、その製造方法及び該重合体を含む熱可塑性樹脂組成物 |
| WO2002100908A1 (en) | 2001-06-12 | 2002-12-19 | Basell Polyolefine Gmbh | Process for the polymerization of 1-butene |
| JP4332029B2 (ja) | 2001-06-12 | 2009-09-16 | バーゼル・ポリオレフィン・ゲーエムベーハー | １−ブテンの重合方法 |
| DE60208683T2 (de) | 2001-08-01 | 2006-11-02 | Basell Polyolefine Gmbh | Verfahren zur herstellung von heterocyclischen pentalen derivaten |
| JP2003096135A (ja) * | 2001-09-21 | 2003-04-03 | Idemitsu Petrochem Co Ltd | ポリ（ブテン−１）とその製造方法および成形体 |
| US7141637B2 (en) | 2001-11-30 | 2006-11-28 | Basell Polyolefine Gmbh | Metallocene compounds and process for the preparation of propylene polymers |
| EP1507806B1 (en) | 2002-05-29 | 2006-10-11 | Basell Poliolefine Italia S.r.l. | Butene-1 (co)polymers and process for their preparation |
| DE60329523D1 (de) * | 2002-12-04 | 2009-11-12 | Basell Polyolefine Gmbh | 1-Buten-Copolymere und Herstellungsverfahren dafür |
| AU2003296585A1 (en) | 2002-12-04 | 2004-06-23 | Basell Polyolefine Gmbh | 1-buten copolymers and process for preparing them |
| KR101060985B1 (ko) | 2003-05-12 | 2011-08-31 | 바젤 폴리올레핀 게엠베하 | 1-부텐의 중합 방법 |
| US20060252637A1 (en) | 2003-05-28 | 2006-11-09 | Basell Polyolefine Gmbh | Bisindenyl zirconium complexes for use in the polymerization of olefins |
| DE10324541A1 (de) | 2003-05-28 | 2004-12-16 | Basell Polyolefine Gmbh | Organoübergangsmetallverbindung mit einem speziellen Substitutionsmuster, Biscyclopentadienylligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen |
| BRPI0508155A (pt) | 2004-03-12 | 2007-08-07 | Basell Polyolefine Gmbh | sistema catalìtico para a polimerização de olefinas |
| JP4897670B2 (ja) | 2004-05-04 | 2012-03-14 | バーゼル・ポリオレフィン・ゲーエムベーハー | アタクチック１−ブテンポリマー類の製造方法 |
| EP1769009A1 (en) | 2004-07-22 | 2007-04-04 | Basell Polyolefine GmbH | Process for producing fractionable 1-butene polymers |
-
2005
- 2005-06-10 CA CA002573975A patent/CA2573975A1/en not_active Abandoned
- 2005-06-10 RU RU2007106715/02A patent/RU2371459C2/ru not_active IP Right Cessation
- 2005-06-10 JP JP2007521929A patent/JP2008506824A/ja active Pending
- 2005-06-10 KR KR1020077001564A patent/KR20070043800A/ko not_active Withdrawn
- 2005-06-10 DE DE602005005334T patent/DE602005005334T2/de not_active Expired - Lifetime
- 2005-06-10 AU AU2005263670A patent/AU2005263670A1/en not_active Abandoned
- 2005-06-10 BR BRPI0513109-0A patent/BRPI0513109A/pt not_active IP Right Cessation
- 2005-06-10 EP EP05760920A patent/EP1769030B1/en not_active Expired - Lifetime
- 2005-06-10 RU RU2007106716/04A patent/RU2007106716A/ru not_active Application Discontinuation
- 2005-06-10 CN CNB2005800244626A patent/CN100567338C/zh not_active Expired - Fee Related
- 2005-06-10 WO PCT/EP2005/052688 patent/WO2006008211A1/en not_active Ceased
- 2005-06-10 PL PL05760920T patent/PL1769030T3/pl unknown
- 2005-06-10 AT AT05760920T patent/ATE388994T1/de not_active IP Right Cessation
- 2005-06-10 US US11/632,616 patent/US7799871B2/en not_active Expired - Fee Related
- 2005-06-10 ES ES05760920T patent/ES2303260T3/es not_active Expired - Lifetime
- 2005-06-10 CN CNB2005800245277A patent/CN100567387C/zh not_active Expired - Fee Related
- 2005-06-21 TW TW094120585A patent/TW200613418A/zh unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CN100567387C (zh) | 2009-12-09 |
| RU2007106716A (ru) | 2008-08-27 |
| US7799871B2 (en) | 2010-09-21 |
| EP1769030B1 (en) | 2008-03-12 |
| AU2005263670A1 (en) | 2006-01-26 |
| PL1769030T3 (pl) | 2008-08-29 |
| EP1769030A1 (en) | 2007-04-04 |
| KR20070043800A (ko) | 2007-04-25 |
| TW200613418A (en) | 2006-05-01 |
| US20080319135A1 (en) | 2008-12-25 |
| CN1989199A (zh) | 2007-06-27 |
| CN1989159A (zh) | 2007-06-27 |
| CN100567338C (zh) | 2009-12-09 |
| ATE388994T1 (de) | 2008-03-15 |
| JP2008506824A (ja) | 2008-03-06 |
| WO2006008211A1 (en) | 2006-01-26 |
| RU2371459C2 (ru) | 2009-10-27 |
| DE602005005334T2 (de) | 2009-03-26 |
| ES2303260T3 (es) | 2008-08-01 |
| DE602005005334D1 (de) | 2008-04-24 |
| BRPI0513109A (pt) | 2008-04-29 |
| RU2007106715A (ru) | 2008-08-27 |
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| Date | Code | Title | Description |
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| FZDE | Discontinued | ||
| FZDE | Discontinued |
Effective date: 20110610 |