CA2533118C - Procede de fabrication de composants en alliage a base de nickel et composants ainsi fabriques - Google Patents
Procede de fabrication de composants en alliage a base de nickel et composants ainsi fabriques Download PDFInfo
- Publication number
- CA2533118C CA2533118C CA2533118A CA2533118A CA2533118C CA 2533118 C CA2533118 C CA 2533118C CA 2533118 A CA2533118 A CA 2533118A CA 2533118 A CA2533118 A CA 2533118A CA 2533118 C CA2533118 C CA 2533118C
- Authority
- CA
- Canada
- Prior art keywords
- nickel
- substrate core
- coated
- metal powder
- foam body
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title claims abstract description 134
- 229910052759 nickel Inorganic materials 0.000 title claims abstract description 67
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 50
- 239000000956 alloy Substances 0.000 title claims abstract description 50
- 238000000034 method Methods 0.000 title claims abstract description 37
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 18
- 239000000758 substrate Substances 0.000 claims abstract description 63
- 239000000843 powder Substances 0.000 claims abstract description 48
- 229910052751 metal Inorganic materials 0.000 claims abstract description 45
- 239000002184 metal Substances 0.000 claims abstract description 45
- 238000000576 coating method Methods 0.000 claims abstract description 33
- 239000011230 binding agent Substances 0.000 claims abstract description 32
- 239000011248 coating agent Substances 0.000 claims abstract description 27
- 238000007669 thermal treatment Methods 0.000 claims abstract description 21
- 238000005245 sintering Methods 0.000 claims abstract description 13
- 239000007787 solid Substances 0.000 claims abstract description 4
- 239000006260 foam Substances 0.000 claims description 32
- 239000000203 mixture Substances 0.000 claims description 21
- 239000000725 suspension Substances 0.000 claims description 16
- 239000006185 dispersion Substances 0.000 claims description 15
- 230000001070 adhesive effect Effects 0.000 claims description 10
- 239000000853 adhesive Substances 0.000 claims description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 8
- 229910052799 carbon Inorganic materials 0.000 claims description 7
- 239000011148 porous material Substances 0.000 claims description 7
- 239000012298 atmosphere Substances 0.000 claims description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 4
- 229910017052 cobalt Inorganic materials 0.000 claims description 4
- 239000010941 cobalt Substances 0.000 claims description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 4
- 238000000151 deposition Methods 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 238000005304 joining Methods 0.000 claims description 4
- 229910052750 molybdenum Inorganic materials 0.000 claims description 4
- 239000011733 molybdenum Substances 0.000 claims description 4
- 229910052758 niobium Inorganic materials 0.000 claims description 4
- 239000010955 niobium Substances 0.000 claims description 4
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
- 239000004411 aluminium Substances 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 229910052796 boron Inorganic materials 0.000 claims description 3
- 239000011651 chromium Substances 0.000 claims description 3
- 229910052804 chromium Inorganic materials 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 229910052746 lanthanum Inorganic materials 0.000 claims description 3
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims description 3
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 3
- 239000010936 titanium Substances 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- 229910052845 zircon Inorganic materials 0.000 claims description 3
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims description 3
- 238000005275 alloying Methods 0.000 abstract 1
- 239000011162 core material Substances 0.000 description 46
- 239000000243 solution Substances 0.000 description 6
- 239000002131 composite material Substances 0.000 description 4
- 238000007493 shaping process Methods 0.000 description 4
- NPXOKRUENSOPAO-UHFFFAOYSA-N Raney nickel Chemical compound [Al].[Ni] NPXOKRUENSOPAO-UHFFFAOYSA-N 0.000 description 3
- 238000005452 bending Methods 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000003754 machining Methods 0.000 description 2
- 229910000907 nickel aluminide Inorganic materials 0.000 description 2
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 2
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000009827 uniform distribution Methods 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910000943 NiAl Inorganic materials 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910001119 inconels 625 Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000011265 semifinished product Substances 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F7/00—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression
- B22F7/002—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of porous nature
- B22F7/004—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of porous nature comprising at least one non-porous part
- B22F7/006—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of porous nature comprising at least one non-porous part the porous part being obtained by foaming
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F7/00—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/02—Making metallic powder or suspensions thereof using physical processes
- B22F9/04—Making metallic powder or suspensions thereof using physical processes starting from solid material, e.g. by crushing, grinding or milling
- B22F2009/041—Making metallic powder or suspensions thereof using physical processes starting from solid material, e.g. by crushing, grinding or milling by mechanical alloying, e.g. blending, milling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
- B22F2998/10—Processes characterised by the sequence of their steps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F7/00—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression
- B22F7/02—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of composite layers
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Composite Materials (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Powder Metallurgy (AREA)
Abstract
L'invention concerne un procédé de fabrication de composants en alliage à base de nickel et des composants ainsi fabriqués, qui ont en particulier des propriétés mécaniques améliorées par rapport aux solutions classiques. On peut produire ces composants sous la forme la plus différenciée. Dans la production, un noyau de substrat en nickel ou en alliage à base de nickel (au moins 20 % de nickel, en poids) reçoit un revêtement de surface avec un agent de liaison et une poudre métallique (au moins 20 % de nickel) ainsi que d'autres éléments de formation d'alliage. On conduit ensuite un traitement thermique par échelons, dans lequel l'agent de liaison est expulsé en premier, puis on conduit un frittage de la poudre métallique réalisant l'alliage pour le noyau considéré et/ou donnant un revêtement de surface solide en alliage à base de nickel.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10346281A DE10346281B4 (de) | 2003-09-30 | 2003-09-30 | Verfahren zur Herstellung von Bauteilen mit einer Nickel-Basislegierung sowie damit hergestellte Bauteile |
DE10346281.3 | 2003-09-30 | ||
PCT/EP2004/010894 WO2005037467A2 (fr) | 2003-09-30 | 2004-09-29 | Procede de fabrication de composants en alliage a base de nickel et composants ainsi fabriques |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2533118A1 CA2533118A1 (fr) | 2005-04-28 |
CA2533118C true CA2533118C (fr) | 2015-07-07 |
Family
ID=34399275
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA2533118A Expired - Lifetime CA2533118C (fr) | 2003-09-30 | 2004-09-29 | Procede de fabrication de composants en alliage a base de nickel et composants ainsi fabriques |
Country Status (9)
Country | Link |
---|---|
US (1) | US20060280637A1 (fr) |
EP (1) | EP1667808B1 (fr) |
JP (1) | JP4647604B2 (fr) |
KR (1) | KR100741613B1 (fr) |
CN (2) | CN1842387A (fr) |
CA (1) | CA2533118C (fr) |
DE (1) | DE10346281B4 (fr) |
ES (1) | ES2612730T3 (fr) |
WO (1) | WO2005037467A2 (fr) |
Families Citing this family (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102005010248B4 (de) * | 2005-02-28 | 2006-10-26 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verfahren zur Herstellung eines offenporigen Metallschaumkörpers, ein so hergestellter Metallschaumkörper sowie seine Verwendungen |
US7467467B2 (en) * | 2005-09-30 | 2008-12-23 | Pratt & Whitney Canada Corp. | Method for manufacturing a foam core heat exchanger |
GR1005904B (el) | 2005-10-31 | 2008-05-15 | ΑΡΙΣΤΟΤΕΛΕΙΟ ΠΑΝΕΠΙΣΤΗΜΙΟ ΘΕΣΣΑΛΟΝΙΚΗΣ-ΕΙΔΙΚΟΣ ΛΟΓΑΡΙΑΣΜΟΣ ΑΞΙΟΠΟΙΗΣΗΣ ΚΟΝΔΥΛΙΩΝ ΕΡΕΥΝΑΣ (κατά ποσοστό 40%) | Καταλυτικο φιλτρο μεταλλικου αφρου για το καυσαεριο των κινητηρων ντηζελ. |
GR1005756B (el) | 2006-09-20 | 2007-12-20 | (������� 30%) ��������� | Διαταξη επεξεργασιας αεριων |
US8230673B2 (en) | 2006-12-04 | 2012-07-31 | Firestar Engineering, Llc | Rocket engine injectorhead with flashback barrier |
US8572946B2 (en) | 2006-12-04 | 2013-11-05 | Firestar Engineering, Llc | Microfluidic flame barrier |
US8230672B2 (en) | 2006-12-04 | 2012-07-31 | Firestar Engineering, Llc | Spark-integrated propellant injector head with flashback barrier |
EP2452064A4 (fr) | 2009-07-07 | 2014-11-19 | Firestar Engineering Llc | Eléments de suppression de retour de flamme à porosité échelonnée pour systèmes au monergol ou au diergol prémélangé |
DE102009034390B4 (de) * | 2009-07-23 | 2019-08-22 | Alantum Europe Gmbh | Verfahren zur Herstellung von in Gehäuse integrierten Metallschaumkörpern |
KR101212786B1 (ko) * | 2010-08-10 | 2012-12-14 | 프라운호퍼-게젤샤프트 츄어 푀르더룽 데어 안게반텐 포르슝에.파우. | 개방-다공성 금속폼 및 그의 제조방법 |
WO2012087409A2 (fr) | 2010-10-12 | 2012-06-28 | The Regents Of The University Of Michigan | Supercondensateurs asymétriques à haute performance à base de carbure et nitrure et borure de métal de transition |
WO2012051326A1 (fr) | 2010-10-12 | 2012-04-19 | The Regents Of The University Of Michigan | Supercondensateurs à base de carbure, nitrure ou borure de métaux de transition, comprenant un substrat alvéolaire d'électrode métallique |
KR101483039B1 (ko) * | 2013-04-02 | 2015-01-19 | 한국기계연구원 | 스폰지 티타늄을 이용한 금속 다공체의 표면 합금화 방법 |
WO2018038791A1 (fr) * | 2016-08-24 | 2018-03-01 | Wal-Mart Stores, Inc. | Système d'inventaire de chariot et procédés associés |
US10675686B2 (en) * | 2017-03-29 | 2020-06-09 | General Electric Company | Hybrid component with multiple cores and method for treating a component |
CN107119248A (zh) * | 2017-05-23 | 2017-09-01 | 哈尔滨工业大学 | 一种分级多孔结构泡沫金属的制备方法 |
DE102017216569A1 (de) * | 2017-09-19 | 2019-03-21 | Alantum Europe Gmbh | Verfahren zur Herstellung eines offenporösen Formkörpers, der mit einem Metall gebildet ist und einen mit dem Verfahren hergestellten Formkörper |
DE102017216566A1 (de) * | 2017-09-19 | 2019-03-21 | Alantum Europe Gmbh | Verfahren zur Herstellung eines offenporösen Formkörpers mit modifizierter Oberfläche, der mit einem Metall gebildet ist und einen mit dem Verfahren hergestellten Formkörper |
CN111906301A (zh) * | 2020-08-13 | 2020-11-10 | 合肥工业大学 | 一种铜基石墨自润滑梯度功能材料及其制备方法 |
KR102552389B1 (ko) * | 2021-08-03 | 2023-07-07 | 주식회사 화승알앤에이 | 굽힘 가공 시스템 |
Family Cites Families (18)
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FR2029930A5 (en) * | 1969-01-31 | 1970-10-23 | Union Carbide Corp | Manufacturing sintered, porous sheet - metal |
DE2206567C1 (de) * | 1971-02-12 | 2000-12-07 | Commissariat Energie Atomique | Verfahren zur Herstellung von porösen Membranen für die Ultrafiltration und nach diesem Verfahren hergestellte Membranen |
CA941643A (en) * | 1971-03-25 | 1974-02-12 | Union Carbide Corporation | Metal porous abradable seals |
DE3729126A1 (de) * | 1987-09-01 | 1989-04-06 | Mototech Motoren Umweltschutz | Dieselruss-partikelfilter und verfahren zu seiner herstellung |
DE3731889A1 (de) * | 1987-09-01 | 1989-06-29 | Mototech Motoren Umweltschutz | Dieselruss-partikelfilter und verfahren zu seiner herstellung |
JPH09176702A (ja) * | 1995-12-26 | 1997-07-08 | Toyota Motor Corp | 被覆層を備えた焼結複合部材の製造方法 |
WO1998045009A2 (fr) * | 1997-04-04 | 1998-10-15 | Oiltools International B.V. | Filtre a usage souterrain |
JPH10317016A (ja) * | 1997-05-22 | 1998-12-02 | Asahi Tec Corp | 金属製物体の接合方法 |
US5951791A (en) * | 1997-12-01 | 1999-09-14 | Inco Limited | Method of preparing porous nickel-aluminum structures |
US5967400A (en) * | 1997-12-01 | 1999-10-19 | Inco Limited | Method of forming metal matrix fiber composites |
JP2000133278A (ja) * | 1998-10-29 | 2000-05-12 | Matsushita Electric Ind Co Ltd | アルカリ蓄電池用焼結基板の製造方法 |
JP2000192109A (ja) * | 1998-12-28 | 2000-07-11 | Daido Steel Co Ltd | 難加工性合金薄板の製造方法 |
US6533875B1 (en) * | 2000-10-20 | 2003-03-18 | General Electric Co. | Protecting a surface of a nickel-based article with a corrosion-resistant aluminum-alloy layer |
JP2002346719A (ja) * | 2001-05-30 | 2002-12-04 | Toshiba Mach Co Ltd | ダイカストマシン用射出スリーブ |
DE10150948C1 (de) * | 2001-10-11 | 2003-05-28 | Fraunhofer Ges Forschung | Verfahren zur Herstellung gesinterter poröser Körper |
US6551551B1 (en) * | 2001-11-16 | 2003-04-22 | Caterpillar Inc | Sinter bonding using a bonding agent |
US7458991B2 (en) * | 2002-02-08 | 2008-12-02 | Howmedica Osteonics Corp. | Porous metallic scaffold for tissue ingrowth |
DE10316929B3 (de) * | 2003-04-07 | 2004-09-16 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verfahren zur Herstellung eines offenporigen Formkörpers ein solcher Formkörper sowie dessen Verwendung |
-
2003
- 2003-09-30 DE DE10346281A patent/DE10346281B4/de not_active Expired - Lifetime
-
2004
- 2004-09-29 CN CNA2004800244941A patent/CN1842387A/zh active Pending
- 2004-09-29 US US10/570,984 patent/US20060280637A1/en not_active Abandoned
- 2004-09-29 CN CN201210023200XA patent/CN102653001A/zh active Pending
- 2004-09-29 JP JP2006523621A patent/JP4647604B2/ja not_active Expired - Lifetime
- 2004-09-29 EP EP04765692.1A patent/EP1667808B1/fr not_active Expired - Lifetime
- 2004-09-29 WO PCT/EP2004/010894 patent/WO2005037467A2/fr active Application Filing
- 2004-09-29 KR KR1020067002219A patent/KR100741613B1/ko active IP Right Grant
- 2004-09-29 ES ES04765692.1T patent/ES2612730T3/es not_active Expired - Lifetime
- 2004-09-29 CA CA2533118A patent/CA2533118C/fr not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
ES2612730T3 (es) | 2017-05-18 |
JP2007502368A (ja) | 2007-02-08 |
US20060280637A1 (en) | 2006-12-14 |
CN102653001A (zh) | 2012-09-05 |
EP1667808A2 (fr) | 2006-06-14 |
JP4647604B2 (ja) | 2011-03-09 |
CA2533118A1 (fr) | 2005-04-28 |
WO2005037467A2 (fr) | 2005-04-28 |
CN1842387A (zh) | 2006-10-04 |
EP1667808B1 (fr) | 2016-11-09 |
DE10346281A1 (de) | 2005-05-04 |
KR20060035789A (ko) | 2006-04-26 |
WO2005037467A3 (fr) | 2005-10-27 |
KR100741613B1 (ko) | 2007-07-23 |
DE10346281B4 (de) | 2006-06-22 |
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