CA2501390A1 - Ceinture de pneumatique a base d'une charge inorganique et d'un silane-polysulfure - Google Patents
Ceinture de pneumatique a base d'une charge inorganique et d'un silane-polysulfure Download PDFInfo
- Publication number
- CA2501390A1 CA2501390A1 CA002501390A CA2501390A CA2501390A1 CA 2501390 A1 CA2501390 A1 CA 2501390A1 CA 002501390 A CA002501390 A CA 002501390A CA 2501390 A CA2501390 A CA 2501390A CA 2501390 A1 CA2501390 A1 CA 2501390A1
- Authority
- CA
- Canada
- Prior art keywords
- silane
- tire belt
- chosen
- belt according
- tire
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 229920001021 polysulfide Polymers 0.000 title claims abstract description 73
- 239000011256 inorganic filler Substances 0.000 title claims abstract description 50
- 229910003475 inorganic filler Inorganic materials 0.000 title claims abstract description 49
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 title abstract description 7
- 229910000077 silane Inorganic materials 0.000 title abstract description 5
- 239000000203 mixture Substances 0.000 claims abstract description 96
- 230000003014 reinforcing effect Effects 0.000 claims abstract description 59
- 150000008117 polysulfides Polymers 0.000 claims abstract description 46
- 239000005077 polysulfide Substances 0.000 claims abstract description 45
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 20
- 229920003049 isoprene rubber Polymers 0.000 claims abstract description 17
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 12
- 150000002430 hydrocarbons Chemical group 0.000 claims abstract description 12
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 10
- 239000001257 hydrogen Substances 0.000 claims abstract description 10
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 6
- CIUQDSCDWFSTQR-UHFFFAOYSA-N [C]1=CC=CC=C1 Chemical compound [C]1=CC=CC=C1 CIUQDSCDWFSTQR-UHFFFAOYSA-N 0.000 claims abstract description 6
- 125000004183 alkoxy alkyl group Chemical group 0.000 claims abstract description 6
- 125000005647 linker group Chemical group 0.000 claims abstract description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 58
- 229920001971 elastomer Polymers 0.000 claims description 49
- 239000005060 rubber Substances 0.000 claims description 32
- 239000007822 coupling agent Substances 0.000 claims description 26
- 239000000377 silicon dioxide Substances 0.000 claims description 25
- 238000004073 vulcanization Methods 0.000 claims description 24
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 22
- 230000002787 reinforcement Effects 0.000 claims description 21
- 239000006229 carbon black Substances 0.000 claims description 17
- 239000000806 elastomer Substances 0.000 claims description 17
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 16
- 238000004519 manufacturing process Methods 0.000 claims description 14
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 14
- 238000003490 calendering Methods 0.000 claims description 13
- 244000043261 Hevea brasiliensis Species 0.000 claims description 11
- 238000002156 mixing Methods 0.000 claims description 11
- 229920003052 natural elastomer Polymers 0.000 claims description 11
- 229920001194 natural rubber Polymers 0.000 claims description 11
- 239000004215 Carbon black (E152) Substances 0.000 claims description 10
- 229910052799 carbon Inorganic materials 0.000 claims description 10
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 10
- 229930195733 hydrocarbon Natural products 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 9
- 239000004753 textile Substances 0.000 claims description 7
- 125000002947 alkylene group Chemical group 0.000 claims description 6
- 125000004429 atom Chemical group 0.000 claims description 6
- 239000000945 filler Substances 0.000 claims description 5
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 4
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 4
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 3
- IYABWNGZIDDRAK-UHFFFAOYSA-N allene Chemical group C=C=C IYABWNGZIDDRAK-UHFFFAOYSA-N 0.000 claims description 2
- 229920001195 polyisoprene Polymers 0.000 claims description 2
- 150000002431 hydrogen Chemical class 0.000 claims 2
- AJUWFXDHBFMLFT-UHFFFAOYSA-N [3-[(3-dimethylsilyl-3-ethoxypropyl)disulfanyl]-1-ethoxypropyl]-dimethylsilane Chemical class C(C)OC(CCSSCCC([SiH](C)C)OCC)[SiH](C)C AJUWFXDHBFMLFT-UHFFFAOYSA-N 0.000 claims 1
- 229910010272 inorganic material Inorganic materials 0.000 claims 1
- 239000011147 inorganic material Substances 0.000 claims 1
- 239000012744 reinforcing agent Substances 0.000 claims 1
- 229920003244 diene elastomer Polymers 0.000 description 20
- 235000019241 carbon black Nutrition 0.000 description 15
- 238000012360 testing method Methods 0.000 description 11
- 239000003795 chemical substances by application Substances 0.000 description 10
- 238000010411 cooking Methods 0.000 description 10
- 229910052717 sulfur Inorganic materials 0.000 description 10
- 150000001993 dienes Chemical class 0.000 description 9
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 8
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 8
- 239000011593 sulfur Substances 0.000 description 8
- 241001441571 Hiodontidae Species 0.000 description 7
- 239000011324 bead Substances 0.000 description 7
- 229920001577 copolymer Polymers 0.000 description 7
- 239000011159 matrix material Substances 0.000 description 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 230000008878 coupling Effects 0.000 description 6
- 238000010168 coupling process Methods 0.000 description 6
- 238000005859 coupling reaction Methods 0.000 description 6
- 238000005259 measurement Methods 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 239000012763 reinforcing filler Substances 0.000 description 6
- 238000005096 rolling process Methods 0.000 description 6
- 229920003048 styrene butadiene rubber Polymers 0.000 description 6
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 5
- 239000002174 Styrene-butadiene Substances 0.000 description 5
- 239000000470 constituent Substances 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 230000000930 thermomechanical effect Effects 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 229910052786 argon Inorganic materials 0.000 description 4
- 238000004132 cross linking Methods 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 239000012429 reaction media Substances 0.000 description 4
- 230000002829 reductive effect Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- -1 triethoxysilylpropyl Chemical group 0.000 description 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 238000005520 cutting process Methods 0.000 description 3
- 230000001627 detrimental effect Effects 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 125000000524 functional group Chemical group 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 230000001681 protective effect Effects 0.000 description 3
- 238000005728 strengthening Methods 0.000 description 3
- QAZLUNIWYYOJPC-UHFFFAOYSA-M sulfenamide Chemical compound [Cl-].COC1=C(C)C=[N+]2C3=NC4=CC=C(OC)C=C4N3SCC2=C1C QAZLUNIWYYOJPC-UHFFFAOYSA-M 0.000 description 3
- 125000004434 sulfur atom Chemical group 0.000 description 3
- 229920003051 synthetic elastomer Polymers 0.000 description 3
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- SCPNGMKCUAZZOO-UHFFFAOYSA-N [3-[(3-dimethylsilyl-3-ethoxypropyl)tetrasulfanyl]-1-ethoxypropyl]-dimethylsilane Chemical compound CCOC([SiH](C)C)CCSSSSCCC([SiH](C)C)OCC SCPNGMKCUAZZOO-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000012190 activator Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 235000006708 antioxidants Nutrition 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000001588 bifunctional effect Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000003738 black carbon Substances 0.000 description 2
- 229920005549 butyl rubber Polymers 0.000 description 2
- 238000012512 characterization method Methods 0.000 description 2
- 238000003776 cleavage reaction Methods 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 2
- 230000006698 induction Effects 0.000 description 2
- MSRJTTSHWYDFIU-UHFFFAOYSA-N octyltriethoxysilane Chemical compound CCCCCCCC[Si](OCC)(OCC)OCC MSRJTTSHWYDFIU-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 230000002572 peristaltic effect Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 230000007017 scission Effects 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- OWRCNXZUPFZXOS-UHFFFAOYSA-N 1,3-diphenylguanidine Chemical compound C=1C=CC=CC=1NC(=N)NC1=CC=CC=C1 OWRCNXZUPFZXOS-UHFFFAOYSA-N 0.000 description 1
- 238000005160 1H NMR spectroscopy Methods 0.000 description 1
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 1
- ROGIWVXWXZRRMZ-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1 ROGIWVXWXZRRMZ-UHFFFAOYSA-N 0.000 description 1
- SAPGIBGZGRMCFZ-UHFFFAOYSA-N 3-[(2,5-dioxopyrrol-3-yl)methyl]pyrrole-2,5-dione Chemical class O=C1NC(=O)C(CC=2C(NC(=O)C=2)=O)=C1 SAPGIBGZGRMCFZ-UHFFFAOYSA-N 0.000 description 1
- ZZMVLMVFYMGSMY-UHFFFAOYSA-N 4-n-(4-methylpentan-2-yl)-1-n-phenylbenzene-1,4-diamine Chemical compound C1=CC(NC(C)CC(C)C)=CC=C1NC1=CC=CC=C1 ZZMVLMVFYMGSMY-UHFFFAOYSA-N 0.000 description 1
- 206010001488 Aggression Diseases 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 241000640882 Condea Species 0.000 description 1
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 1
- 239000006237 Intermediate SAF Substances 0.000 description 1
- VHOQXEIFYTTXJU-UHFFFAOYSA-N Isobutylene-isoprene copolymer Chemical compound CC(C)=C.CC(=C)C=C VHOQXEIFYTTXJU-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 241000872198 Serjania polyphylla Species 0.000 description 1
- 229910008051 Si-OH Inorganic materials 0.000 description 1
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- 229910006358 Si—OH Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000006750 UV protection Effects 0.000 description 1
- 239000000370 acceptor Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000016571 aggressive behavior Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000005370 alkoxysilyl group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000002929 anti-fatigue Effects 0.000 description 1
- 125000000732 arylene group Chemical group 0.000 description 1
- 239000011805 ball Substances 0.000 description 1
- 230000006399 behavior Effects 0.000 description 1
- 239000007767 bonding agent Substances 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- VLLYOYVKQDKAHN-UHFFFAOYSA-N buta-1,3-diene;2-methylbuta-1,3-diene Chemical compound C=CC=C.CC(=C)C=C VLLYOYVKQDKAHN-UHFFFAOYSA-N 0.000 description 1
- RTACIUYXLGWTAE-UHFFFAOYSA-N buta-1,3-diene;2-methylbuta-1,3-diene;styrene Chemical compound C=CC=C.CC(=C)C=C.C=CC1=CC=CC=C1 RTACIUYXLGWTAE-UHFFFAOYSA-N 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 230000008094 contradictory effect Effects 0.000 description 1
- 239000004148 curcumin Substances 0.000 description 1
- 125000002993 cycloalkylene group Chemical group 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 125000002897 diene group Chemical group 0.000 description 1
- ZLCCLBKPLLUIJC-UHFFFAOYSA-L disodium tetrasulfane-1,4-diide Chemical compound [Na+].[Na+].[S-]SS[S-] ZLCCLBKPLLUIJC-UHFFFAOYSA-L 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 235000021384 green leafy vegetables Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 239000011325 microbead Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000012764 mineral filler Substances 0.000 description 1
- CMAUJSNXENPPOF-UHFFFAOYSA-N n-(1,3-benzothiazol-2-ylsulfanyl)-n-cyclohexylcyclohexanamine Chemical compound C1CCCCC1N(C1CCCCC1)SC1=NC2=CC=CC=C2S1 CMAUJSNXENPPOF-UHFFFAOYSA-N 0.000 description 1
- DEQZTKGFXNUBJL-UHFFFAOYSA-N n-(1,3-benzothiazol-2-ylsulfanyl)cyclohexanamine Chemical compound C1CCCCC1NSC1=NC2=CC=CC=C2S1 DEQZTKGFXNUBJL-UHFFFAOYSA-N 0.000 description 1
- 150000001282 organosilanes Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000019612 pigmentation Effects 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920002589 poly(vinylethylene) polymer Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000004224 protection Effects 0.000 description 1
- 239000003223 protective agent Substances 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 239000003507 refrigerant Substances 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 150000004819 silanols Chemical class 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- QDRKDTQENPPHOJ-UHFFFAOYSA-N sodium ethoxide Chemical compound [Na+].CC[O-] QDRKDTQENPPHOJ-UHFFFAOYSA-N 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 239000012936 vulcanization activator Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- 238000004876 x-ray fluorescence Methods 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/548—Silicon-containing compounds containing sulfur
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C9/00—Reinforcements or ply arrangement of pneumatic tyres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L21/00—Compositions of unspecified rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T152/00—Resilient tires and wheels
- Y10T152/10—Tires, resilient
- Y10T152/10495—Pneumatic tire or inner tube
- Y10T152/10765—Characterized by belt or breaker structure
- Y10T152/1081—Breaker or belt characterized by the chemical composition or physical properties of elastomer or the like
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR02/12818 | 2002-10-11 | ||
| FR0212818 | 2002-10-11 | ||
| PCT/EP2003/011074 WO2004033548A1 (fr) | 2002-10-11 | 2003-10-07 | Ceinture de pneumatique a base dune charge inorganique et d'un silane-polysulfure |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2501390A1 true CA2501390A1 (fr) | 2004-04-22 |
Family
ID=32088182
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002501390A Abandoned CA2501390A1 (fr) | 2002-10-11 | 2003-10-07 | Ceinture de pneumatique a base d'une charge inorganique et d'un silane-polysulfure |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US20040129360A1 (https=) |
| EP (1) | EP1560880B1 (https=) |
| JP (1) | JP4738811B2 (https=) |
| KR (1) | KR20050065588A (https=) |
| CN (1) | CN100519640C (https=) |
| AU (1) | AU2003271695A1 (https=) |
| CA (1) | CA2501390A1 (https=) |
| RU (1) | RU2005113875A (https=) |
| WO (1) | WO2004033548A1 (https=) |
Families Citing this family (65)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE602005027575D1 (de) | 2004-07-29 | 2011-06-01 | Michelin Soc Tech | Zinkfreie oder praktisch zinkfreie kautschukzusammensetzung |
| FR2873707B1 (fr) * | 2004-07-29 | 2007-08-10 | Michelin Soc Tech | Composition de caoutchouc depourvue de zinc |
| JP4860162B2 (ja) * | 2005-02-14 | 2012-01-25 | 住友ゴム工業株式会社 | ゴム組成物およびそれからなるタイヤ |
| FR2886304B1 (fr) * | 2005-05-26 | 2007-08-10 | Michelin Soc Tech | Composition de caoutchouc pour pneumatique comportant un systeme de couplage organosilicique |
| JP4895583B2 (ja) * | 2005-11-24 | 2012-03-14 | 住友ゴム工業株式会社 | カーカスコード被覆用ゴム組成物およびそれを用いたカーカスを有するタイヤ |
| FR2900156B1 (fr) * | 2006-04-20 | 2008-07-04 | Michelin Soc Tech | Ceinture de pneumatique incorporant un agent antioxydant. |
| JP5172114B2 (ja) * | 2006-07-26 | 2013-03-27 | 住友ゴム工業株式会社 | コード被覆用ゴム組成物、ならびにそれを用いたカーカスプライおよび／またはベルトを有するタイヤ |
| US7968634B2 (en) * | 2006-12-28 | 2011-06-28 | Continental Ag | Tire compositions and components containing silated core polysulfides |
| US7968636B2 (en) | 2006-12-28 | 2011-06-28 | Continental Ag | Tire compositions and components containing silated cyclic core polysulfides |
| US8592506B2 (en) * | 2006-12-28 | 2013-11-26 | Continental Ag | Tire compositions and components containing blocked mercaptosilane coupling agent |
| US7968633B2 (en) * | 2006-12-28 | 2011-06-28 | Continental Ag | Tire compositions and components containing free-flowing filler compositions |
| US7968635B2 (en) * | 2006-12-28 | 2011-06-28 | Continental Ag | Tire compositions and components containing free-flowing filler compositions |
| FR2931158B1 (fr) * | 2008-05-15 | 2010-07-30 | Michelin Soc Tech | Composition de caoutchouc pour pneumatique incorporant un nouveau systeme anti-oxydant |
| FR2940300B1 (fr) | 2008-12-22 | 2010-12-31 | Michelin Soc Tech | Composition de caoutchouc depourvue ou quasiment depourvue de zinc |
| FR2944227B1 (fr) | 2009-04-09 | 2013-08-16 | Soc Tech Michelin | Stratifie multicouches pour bandage pneumatique |
| FR2947274B1 (fr) | 2009-06-24 | 2013-02-08 | Michelin Soc Tech | Composition de caoutchouc pour pneumatique comportant un compose acetylacetonate |
| FR2950564B1 (fr) | 2009-09-30 | 2014-11-07 | Michelin Soc Tech | Pneumatique comportant un reservoir d'antioxydant |
| FR2954332B1 (fr) | 2009-12-22 | 2012-01-13 | Michelin Soc Tech | Article notamment pneumatique avec melange de caoutchouc externe comportant un sel de lanthanide |
| EP2807040B1 (en) * | 2012-01-25 | 2016-06-29 | Bridgestone Corporation | Rubber tyre compound with improved crack propagation resistance |
| FR2987310B1 (fr) | 2012-02-29 | 2014-03-21 | Michelin & Cie | Stratifie multicouche utilisable pour le renforcement d'une ceinture de pneumatique |
| FR2991916B1 (fr) * | 2012-06-18 | 2014-07-11 | Michelin & Cie | Pneumatique pour vehicule a forte charge |
| KR101433164B1 (ko) * | 2012-09-03 | 2014-08-22 | 한국타이어 주식회사 | 타이어 벨트 토핑용 고무 조성물 및 이를 이용하여 제조된 타이어 |
| EP3469022B1 (en) | 2016-06-09 | 2020-09-23 | Compagnie Générale des Etablissements Michelin | A tire comprising a tread |
| JP6789061B2 (ja) * | 2016-10-20 | 2020-11-25 | 住友ゴム工業株式会社 | タイヤ用ゴム組成物及び空気入りタイヤ |
| EP3532312B1 (en) | 2016-10-31 | 2020-10-07 | Compagnie Générale des Etablissements Michelin | A tire comprising a tread |
| WO2018079801A1 (en) | 2016-10-31 | 2018-05-03 | Compagnie Generale Des Etablissements Michelin | A tire comprising a tread |
| EP3532311B1 (en) | 2016-10-31 | 2023-06-14 | Compagnie Générale des Etablissements Michelin | A tire comprising a tread |
| WO2018079802A1 (en) | 2016-10-31 | 2018-05-03 | Compagnie Generale Des Etablissements Michelin | A tire comprising a tread |
| WO2018079800A1 (en) | 2016-10-31 | 2018-05-03 | Compagnie Generale Des Etablissements Michelin | A tire comprising a tread |
| US20200094622A1 (en) | 2016-12-15 | 2020-03-26 | Compagnie Generale Des Etablissements Michelin | A tire comprising a tread |
| EP3577143A1 (en) | 2017-01-31 | 2019-12-11 | Compagnie Générale des Etablissements Michelin | A tire comprising a rubber composition |
| WO2018151305A1 (en) | 2017-02-20 | 2018-08-23 | Compagnie Generale Des Etablissements Michelin | A tire comprising a tread |
| US11241912B2 (en) | 2017-03-21 | 2022-02-08 | Compagnie Generale Des Etablissements Michelin | Tire comprising a tread |
| WO2018221630A1 (en) | 2017-05-31 | 2018-12-06 | Compagnie Generale Des Etablissements Michelin | A tire comprising a tread |
| WO2019004411A1 (en) | 2017-06-30 | 2019-01-03 | Compagnie Generale Des Etablissements Michelin | TIRE COMPRISING A TREAD |
| WO2019064407A1 (en) | 2017-09-28 | 2019-04-04 | Compagnie Generale Des Etablissements Michelin | PNEUMATIC COMPRISING A RUBBER COMPOSITION |
| JP2021519725A (ja) | 2018-03-30 | 2021-08-12 | コンパニー ゼネラール デ エタブリッスマン ミシュラン | トレッドを含むタイヤ |
| WO2019239568A1 (en) | 2018-06-15 | 2019-12-19 | Compagnie Generale Des Etablissements Michelin | A rubber composition for a tire tread |
| WO2020039535A1 (en) | 2018-08-23 | 2020-02-27 | Compagnie Generale Des Etablissements Michelin | A rubber composition |
| WO2020039536A1 (en) | 2018-08-23 | 2020-02-27 | Compagnie Generale Des Etablissements Michelin | A rubber composition |
| FR3086296B1 (fr) | 2018-09-21 | 2020-09-25 | Michelin & Cie | Composition de caoutchouc comprenant un elastomere epoxyde et un compose polyphenolique |
| EP3877166B1 (en) | 2018-11-08 | 2023-01-04 | Compagnie Generale Des Etablissements Michelin | An article, in particular a tire |
| WO2020096027A1 (en) | 2018-11-08 | 2020-05-14 | Compagnie Generale Des Etablissements Michelin | An article, in particular a tire |
| WO2020122255A1 (en) | 2018-12-14 | 2020-06-18 | Compagnie Generale Des Etablissements Michelin | An article, in particular a tire |
| WO2020122256A1 (en) | 2018-12-14 | 2020-06-18 | Compagnie Generale Des Etablissements Michelin | An article, in particular a tire |
| WO2020158695A1 (en) | 2019-01-28 | 2020-08-06 | Compagnie Generale Des Etablissements Michelin | A laminate |
| WO2020158694A1 (en) | 2019-01-28 | 2020-08-06 | Compagnie Generale Des Etablissements Michelin | An article |
| WO2020217370A1 (en) | 2019-04-25 | 2020-10-29 | Compagnie Generale Des Etablissements Michelin | A rubber composition |
| WO2020218601A1 (en) | 2019-04-25 | 2020-10-29 | Compagnie Generale Des Etablissements Michelin | A rubber composition |
| FR3097549A1 (fr) | 2019-06-19 | 2020-12-25 | Compagnie Generale Des Etablissements Michelin | composition de caoutchouc |
| EP3996915A1 (en) | 2019-07-09 | 2022-05-18 | Compagnie Generale Des Etablissements Michelin | A rubber composition |
| WO2021005718A1 (en) | 2019-07-09 | 2021-01-14 | Compagnie Generale Des Etablissements Michelin | A laminate |
| WO2021019708A1 (en) | 2019-07-31 | 2021-02-04 | Compagnie Generale Des Etablissements Michelin | A laminate |
| WO2021019709A1 (en) | 2019-07-31 | 2021-02-04 | Compagnie Generale Des Etablissements Michelin | A laminate |
| DE102019213978A1 (de) * | 2019-09-13 | 2021-03-18 | Continental Reifen Deutschland Gmbh | Schwefelvernetzbare Kautschukmischung, Vulkanisat und Fahrzeugreifen |
| BR112022014395A2 (pt) | 2020-01-28 | 2023-02-23 | Michelin & Cie | Composição de borracha |
| WO2021166166A1 (en) | 2020-02-20 | 2021-08-26 | Compagnie Generale Des Etablissements Michelin | A rubber composition |
| WO2021166165A1 (en) | 2020-02-20 | 2021-08-26 | Compagnie Generale Des Etablissements Michelin | A rubber composition |
| WO2021193901A1 (en) | 2020-03-27 | 2021-09-30 | Compagnie Generale Des Etablissements Michelin | An article intended to come into contact with the ground, in particular a tire |
| DE102020215465A1 (de) * | 2020-12-08 | 2022-06-09 | Continental Reifen Deutschland Gmbh | Schwefelvernetzbare Kautschukmischung, Vulkanisat und Fahrzeugreifen |
| JP7686759B2 (ja) | 2021-01-28 | 2025-06-02 | コンパニー ゼネラール デ エタブリッスマン ミシュラン | 物品、特にタイヤ |
| FR3138352B1 (fr) | 2022-07-29 | 2025-04-25 | Michelin & Cie | Pneumatique à armature de carcasse radiale |
| FR3138351B1 (fr) | 2022-07-29 | 2025-04-25 | Michelin & Cie | Pneumatique à armature de carcasse radiale |
| FR3138350B1 (fr) | 2022-07-29 | 2025-04-18 | Michelin & Cie | Pneumatique à armature de carcasse radiale |
| FR3146476B1 (fr) | 2023-03-09 | 2025-02-14 | Michelin & Cie | Une composition de caoutchouc |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US132880A (en) * | 1872-11-05 | Improvement in milk-coolers | ||
| US51210A (en) * | 1865-11-28 | Improved buckle | ||
| US92647A (en) * | 1869-07-13 | Improvement in spindle-bolsters | ||
| DE3639142A1 (de) * | 1986-11-15 | 1988-05-19 | Uniroyal Englebert Gmbh | Fahrzeugluftreifen |
| JPH07102115A (ja) * | 1993-10-08 | 1995-04-18 | Bridgestone Corp | ゴム組成物 |
| DE4415658A1 (de) * | 1994-05-04 | 1995-11-09 | Bayer Ag | Schwefelhaltige Organosiliciumverbindungen enthaltende Kautschukmischungen |
| FR2729671B1 (fr) * | 1995-01-20 | 1997-04-18 | Michelin & Cie | Enveloppe de pneumatique a base de silice precipitee presentant une resistance au roulement amelioree |
| US5674932A (en) * | 1995-03-14 | 1997-10-07 | The Goodyear Tire & Rubber Company | Silica reinforced rubber composition and use in tires |
| US5580919A (en) * | 1995-03-14 | 1996-12-03 | The Goodyear Tire & Rubber Company | Silica reinforced rubber composition and use in tires |
| US5914364A (en) * | 1996-03-11 | 1999-06-22 | The Goodyear Tire & Rubber Company | Silica reinforced rubber composition and tire with tread |
| JP3445080B2 (ja) * | 1996-12-27 | 2003-09-08 | 株式会社ブリヂストン | ゴム組成物及びそのゴム組成物を使用した空気入りタイヤ |
| JP3996696B2 (ja) * | 1998-03-20 | 2007-10-24 | 住友ゴム工業株式会社 | ゴム組成物 |
| DE19915281A1 (de) * | 1999-04-03 | 2000-10-05 | Degussa | Kautschukmischungen |
| FR2804121A1 (fr) * | 2000-01-24 | 2001-07-27 | Michelin Soc Tech | Composition de caoutchouc pour pneumatique comportant une charge blanche renforcante et un systeme de couplage ( charge blanche/elastomere) |
| FR2804120A1 (fr) * | 2000-01-24 | 2001-07-27 | Michelin Soc Tech | Composition de caoutchouc pour pneumatique comportant une charge blanche renforcante et un systeme de couplage (charge blanche/elstomere) |
| US6218561B1 (en) * | 2000-06-26 | 2001-04-17 | The Goodyear Tire & Rubber Company | Process for the preparation of bis organosilicon disulfide compounds |
| WO2002031041A1 (fr) * | 2000-10-13 | 2002-04-18 | Societe De Technologie Michelin | Composition de caoutchouc comportant a titre d'agent de couplage un organosilane polyfonctionnel |
| KR100776926B1 (ko) * | 2000-10-13 | 2007-11-20 | 소시에떼 드 테크놀로지 미쉐린 | 커플링제로서 사용하기 위한 다관능성 오가노실란 및 이의제조방법 |
| EP1349983A1 (fr) * | 2001-01-04 | 2003-10-08 | Société de Technologie Michelin | Cable d'acier multicouches pour armature de sommet de pneumatique |
| FR2823215B1 (fr) * | 2001-04-10 | 2005-04-08 | Michelin Soc Tech | Pneumatique et bande de roulement de pneumatique comportant a titre d'agent de couplage un tetrasulfure de bis-alkoxysilane |
| FR2823210B1 (fr) * | 2001-04-10 | 2005-04-01 | Rhodia Chimie Sa | Organoxysilanes polysulfures utilisables notamment en tant qu'agent de couplage, compositions d'elastomere(s) les contenant et articles en elastomere(s) prepares a partir de telles compositions |
| KR100821872B1 (ko) * | 2001-05-16 | 2008-04-16 | 소시에떼 드 테크놀로지 미쉐린 | 이력이 감소된 고무 조성물을 포함하는 크라운 강화재를 갖는 타이어 |
-
2003
- 2003-10-07 AU AU2003271695A patent/AU2003271695A1/en not_active Abandoned
- 2003-10-07 RU RU2005113875/04A patent/RU2005113875A/ru not_active Application Discontinuation
- 2003-10-07 JP JP2004542446A patent/JP4738811B2/ja not_active Expired - Fee Related
- 2003-10-07 CA CA002501390A patent/CA2501390A1/fr not_active Abandoned
- 2003-10-07 KR KR1020057006191A patent/KR20050065588A/ko not_active Withdrawn
- 2003-10-07 EP EP03753519.2A patent/EP1560880B1/fr not_active Expired - Lifetime
- 2003-10-07 CN CNB2003801012190A patent/CN100519640C/zh not_active Expired - Fee Related
- 2003-10-07 WO PCT/EP2003/011074 patent/WO2004033548A1/fr not_active Ceased
- 2003-10-08 US US10/681,802 patent/US20040129360A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| CN100519640C (zh) | 2009-07-29 |
| JP4738811B2 (ja) | 2011-08-03 |
| JP2006502270A (ja) | 2006-01-19 |
| RU2005113875A (ru) | 2005-11-10 |
| WO2004033548A1 (fr) | 2004-04-22 |
| KR20050065588A (ko) | 2005-06-29 |
| US20040129360A1 (en) | 2004-07-08 |
| EP1560880B1 (fr) | 2014-08-27 |
| EP1560880A1 (fr) | 2005-08-10 |
| CN1703454A (zh) | 2005-11-30 |
| AU2003271695A1 (en) | 2004-05-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP1560880B1 (fr) | Ceinture de pneumatique a base dune charge inorganique et d'un silane-polysulfure | |
| EP2285886B1 (fr) | Composition de caoutchouc pour pneumatique incorporant un nouveau systeme anti-oxydant | |
| EP2092010B1 (fr) | Composition de caoutchouc pour pneumatique incorporant un nouveau systeme anti-oxydant | |
| EP1392769B1 (fr) | Pneumatique et bande de roulement comportant comme agent de couplage un tetrasulfure de bis-alkoxysilane | |
| EP1265955B1 (fr) | Composition de caoutchouc pour pneumatique comportant un agent de couplage (charge blanche/elastomere) a fonction ester | |
| EP1773938B1 (fr) | Composition de caoutchouc depourvue ou pratiquement depourvue de zinc | |
| EP2013038A1 (fr) | Ceinture de pneumatique incorporant un agent antioxydant | |
| EP1320569B1 (fr) | Composition de caoutchouc pour pneumatique comportant un citraconimido-alkoxysilane a titre d'agent de couplage | |
| WO2009062733A2 (fr) | Composition de caoutchouc pour pneumatique comportant un agent de recouvrement hydroxysilane | |
| EP2432826A1 (fr) | Composition de caoutchouc pour pneumatique comportant un compose acetylacetonate | |
| WO2013189820A1 (fr) | Pneumatique pour vehicule a forte charge | |
| WO2011076619A1 (fr) | Article notamment pneumatique avec melange de caoutchouc externe comportant un sel de lanthanide | |
| EP2999741A1 (fr) | Melange interne pour pneumatique a resistance a la fissuration amelioree | |
| EP3083814B1 (fr) | Composition de caoutchouc comprenant une resine de polyphenylene ether comme plastifiant | |
| WO2015091921A1 (fr) | Composition de caoutchouc comprenant une resine de polyphenylene ether comme plastifiant | |
| WO2010149580A1 (fr) | Composition de caoutchouc pour pneumatique comportant un composé acétylacétonate | |
| FR2873707A1 (fr) | Composition de caoutchouc depourvue de zinc | |
| EP2379631B1 (fr) | Composition de caoutchouc depourvue ou quasiment depourvue de zinc |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FZDE | Discontinued |