CA2489731C - Radiation-curing coating compositions - Google Patents

Radiation-curing coating compositions Download PDF

Info

Publication number
CA2489731C
CA2489731C CA 2489731 CA2489731A CA2489731C CA 2489731 C CA2489731 C CA 2489731C CA 2489731 CA2489731 CA 2489731 CA 2489731 A CA2489731 A CA 2489731A CA 2489731 C CA2489731 C CA 2489731C
Authority
CA
Canada
Prior art keywords
polyisocyanate
groups
coating compositions
aqueous coating
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA 2489731
Other languages
English (en)
French (fr)
Other versions
CA2489731A1 (en
Inventor
Jan Weikard
Erhard Luehmann
Christoph Irle
Thorsten Rische
Karin Naujoks
Thomas Feller
Jan Mazanek
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Covestro Deutschland AG
Original Assignee
Bayer MaterialScience AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer MaterialScience AG filed Critical Bayer MaterialScience AG
Publication of CA2489731A1 publication Critical patent/CA2489731A1/en
Application granted granted Critical
Publication of CA2489731C publication Critical patent/CA2489731C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
    • C09D175/16—Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
    • C08G18/0823—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing carboxylate salt groups or groups forming them
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
    • C08G18/0828—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing sulfonate groups or groups forming them
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
    • C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
    • C08G18/622—Polymers of esters of alpha-beta ethylenically unsaturated carboxylic acids
    • C08G18/6225—Polymers of esters of acrylic or methacrylic acid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/68—Unsaturated polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/703—Isocyanates or isothiocyanates transformed in a latent form by physical means
    • C08G18/705—Dispersions of isocyanates or isothiocyanates in a liquid medium
    • C08G18/706—Dispersions of isocyanates or isothiocyanates in a liquid medium the liquid medium being water
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/80—Masked polyisocyanates
    • C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
    • C08G18/807—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with nitrogen containing compounds
    • C08G18/8077—Oximes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Dispersion Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Paints Or Removers (AREA)
  • Sealing Material Composition (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
CA 2489731 2002-06-17 2003-06-04 Radiation-curing coating compositions Expired - Fee Related CA2489731C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10226932.7 2002-06-17
DE2002126932 DE10226932A1 (de) 2002-06-17 2002-06-17 Strahlenhärtende Beschichtungsmittel
PCT/EP2003/005825 WO2003106577A1 (de) 2002-06-17 2003-06-04 Strahlenhärtende beschichtungsmittel

Publications (2)

Publication Number Publication Date
CA2489731A1 CA2489731A1 (en) 2003-12-24
CA2489731C true CA2489731C (en) 2012-09-04

Family

ID=29594581

Family Applications (1)

Application Number Title Priority Date Filing Date
CA 2489731 Expired - Fee Related CA2489731C (en) 2002-06-17 2003-06-04 Radiation-curing coating compositions

Country Status (13)

Country Link
US (1) US6960639B2 (enExample)
EP (1) EP1516025B1 (enExample)
JP (1) JP2005530006A (enExample)
KR (1) KR101034067B1 (enExample)
CN (1) CN100392033C (enExample)
AU (1) AU2003236685A1 (enExample)
CA (1) CA2489731C (enExample)
DE (1) DE10226932A1 (enExample)
ES (1) ES2603177T3 (enExample)
MX (1) MX250140B (enExample)
RU (1) RU2324718C2 (enExample)
TW (1) TWI292775B (enExample)
WO (1) WO2003106577A1 (enExample)

Families Citing this family (50)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MY164523A (en) 2000-05-23 2017-12-29 Univ Degli Studi Cagliari Methods and compositions for treating hepatitis c virus
KR20080021797A (ko) 2000-05-26 2008-03-07 이데닉스(케이만)리미티드 플라비바이러스 및 페스티바이러스의 치료방법 및 조성물
JP2005533824A (ja) 2002-06-28 2005-11-10 イデニクス（ケイマン）リミテツド フラビウイルス科感染の治療のための２’−ｃ−メチル−３’−ｏ−ｌ−バリンエステルリボフラノシルシチジン
NZ537662A (en) 2002-06-28 2007-10-26 Idenix Cayman Ltd 2'-C-methyl-3'-O-L-valine ester ribofuranosyl cytidine for treatment of flaviviridae infections
US7824851B2 (en) 2002-11-15 2010-11-02 Idenix Pharmaceuticals, Inc. 2′-branched nucleosides and Flaviviridae mutation
EP1585529A4 (en) 2002-12-12 2008-05-28 Idenix Cayman Ltd PROCESS FOR PREPARING 2'-BRANCHED NUCLEOSIDES
US20050129882A1 (en) * 2003-12-16 2005-06-16 Snow Larry G. Processes for preparing printable and printed articles
US20050215654A1 (en) * 2004-03-29 2005-09-29 Rebecca Wright Ultraviolet-curable waterborne coating
KR101251244B1 (ko) * 2005-02-24 2013-04-08 바스프 에스이 방사선 경화성 수성 폴리우레탄 분산액
DE102005019430A1 (de) * 2005-04-25 2006-10-26 Bayer Materialscience Ag N-Methylpyrrolidon-freie Polyurethan-Dispersionen auf Basis von Dimethylolpropionsäure
US20060293484A1 (en) * 2005-06-24 2006-12-28 Bayer Materialscience Llc Low viscosity, ethylenically-unsaturated polyurethanes
DE102005057683A1 (de) * 2005-12-01 2007-06-06 Basf Ag Strahlungshärtbare wasserelmulgierbare Polyisocyanate
DE102005057682A1 (de) * 2005-12-01 2007-06-06 Basf Ag Strahlungshärtbare wasserelmulgierbare Polyisocyanate
DE102006017385A1 (de) * 2006-04-11 2007-10-25 Bayer Materialscience Ag Wässrige Polyurethandispersionen mit verbesserter Lagerstabilität
DE102006038940A1 (de) * 2006-08-18 2008-02-21 Bayer Materialscience Ag Dispersionen von Nanoharnstoffen, enthaltend Wirkstoffe
DE102006049764A1 (de) * 2006-10-21 2008-04-24 Bayer Materialscience Ag UV-härtbare Polyurethan-Dispersionen
DE102006058202A1 (de) * 2006-12-11 2008-06-12 Merck Patent Gmbh Verfahren zur Herstellung von Dispersionen
DE102007006492A1 (de) * 2007-02-09 2008-08-14 Bayer Materialscience Ag UV-härtbare Dispersionen auf Basis von Polyisocyanaten
US7547105B2 (en) * 2007-07-16 2009-06-16 3M Innovative Properties Company Prismatic retroreflective article with cross-linked image layer and method of making same
PL2113527T3 (pl) * 2008-04-28 2014-10-31 Bayer Ip Gmbh Odkształcalna folia z powłoką utwardzalną radiacyjnie i wykonane z niej kształtki
EP2130846A1 (en) * 2008-06-06 2009-12-09 Cytec Surface Specialties, S.A. Aqueous radiation curable polyurethane compositions
WO2010056182A1 (en) * 2008-11-17 2010-05-20 Bwe I Malmö Ab Method for coating a floor
WO2010077475A2 (en) * 2008-12-08 2010-07-08 3M Innovative Properties Company Protective overlay bearing a graphic and retroreflective articles comprising the overlay
EP2361396A4 (en) * 2008-12-08 2018-01-24 3M Innovative Properties Company Prismatic retroreflective article bearing a graphic and method of making same
DE102009008950A1 (de) 2009-02-13 2010-08-19 Bayer Materialscience Ag Wässrige Beschichtungssysteme auf Basis physikalisch trocknender Urethanacrylate
RU2539444C1 (ru) * 2009-10-09 2015-01-20 ДСМ Ай Пи ЭССЕТС Б.В. Отверждаемые облучением суперпокрытия для одномодового оптического волокна
DK2316867T3 (da) * 2009-10-31 2012-08-27 Bayer Materialscience Ag Tin-fri, vandige polyurethandispersioner
JP5638866B2 (ja) * 2009-12-09 2014-12-10 日本化薬株式会社 ポリウレタン化合物、それを含有する活性エネルギー線硬化型樹脂組成物及びその用途
US20110138753A1 (en) * 2009-12-11 2011-06-16 International Paper Company Container with Repulpable Moisture Resistant Barrier
WO2011073116A2 (de) * 2009-12-19 2011-06-23 Bayer Materialscience Ag Niedrigviskose polyurethanacrylatdispersionen
DE102010009896A1 (de) 2010-03-02 2011-09-08 Bayer Materialscience Ag Wässrige Polyurethandispersionen
US9365980B2 (en) 2010-11-05 2016-06-14 International Paper Company Packaging material having moisture barrier and methods for preparing same
US9358576B2 (en) 2010-11-05 2016-06-07 International Paper Company Packaging material having moisture barrier and methods for preparing same
US8647471B2 (en) * 2010-12-22 2014-02-11 Bayer Materialscience Llc Process for the production of sized and/or wet-strength papers, paperboards and cardboards
US8772375B2 (en) * 2011-02-19 2014-07-08 Ling Tan Composition of polyacrylate, epoxy and polyamine
WO2013006606A2 (en) * 2011-07-06 2013-01-10 Bayer Materialscience Llc Free radical curable waterborne glass coating compositions
JP5977014B2 (ja) * 2011-10-20 2016-08-24 大日精化工業株式会社 塗料及び該塗料を用いた積層型フィルム
US20130295346A1 (en) * 2012-05-07 2013-11-07 Renewable Technology Holdings, Inc. Decorative monolithic, functionally bonded composite surface overlayment system and application process
US9296907B2 (en) 2012-05-30 2016-03-29 Basf Se Radiation-curable compounds
EP2687552A1 (en) * 2012-07-17 2014-01-22 Huntsman International Llc Use of polyurea nanoparticles as performance modifiers in polyurethane materials
JP6436996B2 (ja) * 2013-08-26 2018-12-12 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 放射線硬化性で水分散性のポリウレタン（メタ）アクリレート
EP2980110A1 (en) 2014-07-31 2016-02-03 ALLNEX AUSTRIA GmbH Aqueous polyurethane-vinyl polymer hybrid dispersions
JP6477407B2 (ja) * 2015-10-15 2019-03-06 信越化学工業株式会社 レジスト材料及びパターン形成方法
TWI682976B (zh) 2016-03-02 2020-01-21 阿科瑪法國公司 雙固化型軟觸感塗層
WO2017211702A1 (de) * 2016-06-06 2017-12-14 Basf Se Neue verfahren zur herstellung vom verbundmaterialien
JP6843371B2 (ja) * 2017-07-31 2021-03-17 日油株式会社 活性エネルギー線硬化型樹脂組成物
CN112126330A (zh) * 2019-06-24 2020-12-25 科思创德国股份有限公司 一种水性白漆
CN110511658B (zh) * 2019-08-22 2021-06-22 湖南松井新材料股份有限公司 双重固化型水性primer涂料及其制备方法、应用
CN111171696A (zh) * 2020-03-02 2020-05-19 上海立邦长润发涂料有限公司 一种水性双组分哑光白面漆及其制备方法
CN115627115B (zh) * 2022-11-14 2023-11-17 福耀玻璃工业集团股份有限公司 一种涂料、具有涂层的基材及其制备方法

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4021126C2 (de) * 1990-07-03 1998-01-29 Basf Lacke & Farben Lacke und Verwendung der Lacke zur Lackierung von Automobilkarosserien
KR100311244B1 (ko) 1993-02-22 2001-12-15 가지와라 야스시 에틸렌/α-올레핀공중합체의제조방법
DE19736083A1 (de) * 1997-08-20 1999-02-25 Basf Coatings Ag Mehrschichtlackierungen und Verfahren zu deren Herstellung
DE19750186A1 (de) * 1997-11-13 1999-05-20 Bayer Ag Hydrophilierungsmittel, ein Verfahren zu dessen Herstellung sowie dessen Verwendung als Dispergator für wäßrige Polyurethan-Dispersionen
DE19818312A1 (de) * 1998-04-23 1999-10-28 Bayer Ag Wäßriges Beschichtungssytem aus UV-härtenden Isocyanatgruppen aufweisenden Urethan(meth)acrylatisocyanaten
DE19855146A1 (de) * 1998-11-30 2000-05-31 Basf Coatings Ag Aus mindestens drei Komponenten bestehendes Beschichtungsmittel, Verfahren zu seiner Herstellung sowie seine Verwendung
JP3796552B2 (ja) * 1998-12-25 2006-07-12 日本ポリウレタン工業株式会社 自己乳化性ポリイソシアネート、並びにこれを用いた水系塗料及び水系接着剤
JP2000256615A (ja) * 1999-03-05 2000-09-19 Kansai Paint Co Ltd ポットライフを可視化した２液型水性塗料組成物
DE19914896A1 (de) * 1999-04-01 2000-10-05 Basf Coatings Ag Thermisch und/oder mit aktinischer Strahlung härtbarer wäßriger Beschichtungsstoff und seine Verwendung
JP4278265B2 (ja) * 1999-04-30 2009-06-10 日本ペイント株式会社 熱硬化性水性塗料組成物およびこれを用いた塗膜形成方法、ならびに、複層塗膜形成方法
DE50014951D1 (de) * 1999-09-30 2008-03-20 Basf Ag Mit uv-strahlung und thermisch härtbare wässrige polyurethandispersionen sowie deren verwendung
AU2001260325B2 (en) * 2000-05-26 2005-03-10 Akzo Nobel N.V. Photoactivatable coating composition
DE10043433A1 (de) * 2000-09-04 2002-03-21 Bayer Ag Wäßrige 2-K-PUR-Systeme
DE10054933A1 (de) * 2000-11-06 2002-05-08 Bayer Ag Verfahren zur Beschichtung von Substraten
DE10056163A1 (de) * 2000-11-13 2002-05-23 Basf Ag Hydrophil modifizierte Polyisocyanate und Polyurethane zur Antiknitterausrüstung von cellulosehaltigen Textilien
DE10115605A1 (de) * 2001-03-29 2002-10-24 Basf Coatings Ag Thermisch und mit aktinischer Strahlung härtbare Pulverslurries, Verfahren zu ihrer Herstellung und ihre Verwendung

Also Published As

Publication number Publication date
TWI292775B (en) 2008-01-21
CN1675325A (zh) 2005-09-28
CN100392033C (zh) 2008-06-04
ES2603177T3 (es) 2017-02-24
RU2005100956A (ru) 2005-10-10
KR101034067B1 (ko) 2011-05-12
TW200404874A (en) 2004-04-01
US6960639B2 (en) 2005-11-01
CA2489731A1 (en) 2003-12-24
MX250140B (es) 2007-10-10
RU2324718C2 (ru) 2008-05-20
US20040006152A1 (en) 2004-01-08
AU2003236685A1 (en) 2003-12-31
JP2005530006A (ja) 2005-10-06
MXPA04012362A (es) 2005-02-25
EP1516025B1 (de) 2016-08-24
WO2003106577A1 (de) 2003-12-24
DE10226932A1 (de) 2003-12-24
KR20050021013A (ko) 2005-03-04
EP1516025A1 (de) 2005-03-23

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