CA2485665A1 - Passivation de catalyseur d'hydroconversion sulfure - Google Patents

Passivation de catalyseur d'hydroconversion sulfure Download PDF

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Publication number
CA2485665A1
CA2485665A1 CA002485665A CA2485665A CA2485665A1 CA 2485665 A1 CA2485665 A1 CA 2485665A1 CA 002485665 A CA002485665 A CA 002485665A CA 2485665 A CA2485665 A CA 2485665A CA 2485665 A1 CA2485665 A1 CA 2485665A1
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catalyst
contact
gas flow
organic liquid
oxygen
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CA2485665C (fr
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Pierre Dufresne
Franck Labruyere
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Europeene de Retraitement de Catalysateurs EURECAT
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/20—Sulfiding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/883—Molybdenum and nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/06—Washing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/12—Oxidising
    • B01J37/14—Oxidising with gases containing free oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
    • C10G49/02—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J33/00—Protection of catalysts, e.g. by coating
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • C10G2300/1014—Biomass of vegetal origin
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • C10G2300/1018—Biomass of animal origin
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/1048—Middle distillates
    • C10G2300/1051—Kerosene having a boiling range of about 180 - 230 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/1048—Middle distillates
    • C10G2300/1059—Gasoil having a boiling range of about 330 - 427 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1074—Vacuum distillates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/30—Physical properties of feedstocks or products
    • C10G2300/301—Boiling range
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/70—Catalyst aspects
    • C10G2300/705—Passivation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

La présente invention concerne un procédé de passivation oxydante hors site des catalyseurs d'hydroconversion d'hydrocarbures et notamment d'hydrotraitement dans leurs états sulfures, dans lequel le catalyseur sulfu ré est soumis à 2 traitements : mise en contact avec un flux gazeux oxydant, et mise en contact avec un liquide organique (hydrocarbure par exemple) qui remplit partiellement sa porosité.

Claims (14)

1. Procédé de passivation oxydante hors-site d'un catalyseur d'hydroconversion d'hydrocarbures caractérisé en ce que ledit catalyseur sulfuré est soumis à au moins deux traitements : mise en contact avec au moins un flux gazeux oxydant, et mise en contact avec au moins un liquide organique de point d'ébullition initial supérieur à
120°C qui remplit au moins partiellement la porosité du catalyseur.
2. Procédé selon la revendication 1 dans lequel ledit catalyseur sulfuré est dans une première étape mis en contact avec au moins un flux gazeux oxydant et dans une deuxième étape mis au contact dudit liquide organique.
3. Procédé selon la revendication 1 dans lequel ledit catalyseur sulfuré est dans une première étape mis au contact dudit liquide organique et dans une deuxième étape mis en contact avec au moins un flux gazeux oxydant.
4. Procédé selon l'une des revendications 1 à 3 dans lequel la mise en contact avec ledit flux gazeux est effectuée en deux temps, le premier sous une pression partielle d'oxygène inférieure à 8 kPa, le second, sous une pression partielle en oxygène supérieure à celle du premier temps et au plus à 21.3kPa.
5. Procédé selon la revendication 4 dans lequel le deuxième temps de la première étape est effectué sous air.
6. Procédé selon la revendication 1 dans lequel la mise en contact avec ledit flux gazeux est effectuée en un ou plusieurs temps avec un ou des flux gazeux ayant tous une pression partielle en oxygène supérieure à 8 kPa.
7. Procédé selon la revendication 6 dans lequel ce ou ces flux sont de l'air.
8. Procédé selon l'une des revendications précédentes dans lequel le catalyseur est en mouvement.
9. Procédé selon la revendication 8 dans lequel le catalyseur est en lit mobile.
10. Procédé selon la revendication 9 mis en oeuvre dans un four rotatif, un four à lit fluide, un four à bande, un four à lit croulant ou un dispositif à lit ascendant.
11. Procédé selon l'une des revendications précédentes dans lequel ledit liquide organique utilisé en deuxième étape est choisi dans le groupe constitué par le kérosène, le gasoil, les distillats sous vide, une base huileuse, les cires et les paraffines de point d'ébullition initial supérieure à 180°C.
12. Procédé selon l'une des revendications précédentes dans lequel ledit composé organique contient au moins un hétéroatome choisi parmi l'oxygène, le soufre et l'azote.
13. Procédé selon la revendication 12 dans lequel ledit composé organique est choisi parmi les alcools, aldéhydes, cétones, esters, amines, amides, mereaptans, sulfures et sulfones.
14. Procédé selon la revendication 13 dans lequel le composé organique est un ester choisi de préférence parmi les huiles végétales ou animales, les triglycérides d' acides gras partiellement insaturés.
CA2485665A 2003-02-11 2004-02-06 Passivation de catalyseur d'hydroconversion sulfure Expired - Lifetime CA2485665C (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR03/01634 2003-02-11
FR0301634A FR2850882B1 (fr) 2003-02-11 2003-02-11 Passivation de catalyseur d'hydroconversion sulfure
PCT/FR2004/000272 WO2004071655A1 (fr) 2003-02-11 2004-02-06 Passivation de catalyseur d'hydroconversion sulfure

Publications (2)

Publication Number Publication Date
CA2485665A1 true CA2485665A1 (fr) 2004-08-26
CA2485665C CA2485665C (fr) 2011-09-27

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ID=32731959

Family Applications (1)

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CA2485665A Expired - Lifetime CA2485665C (fr) 2003-02-11 2004-02-06 Passivation de catalyseur d'hydroconversion sulfure

Country Status (7)

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US (1) US7582587B2 (fr)
JP (1) JP5016918B2 (fr)
CA (1) CA2485665C (fr)
DE (1) DE112004000001B4 (fr)
FR (1) FR2850882B1 (fr)
LU (1) LU91102B1 (fr)
WO (1) WO2004071655A1 (fr)

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US7407909B2 (en) * 2004-10-01 2008-08-05 Exxonmobil Research And Engineering Company Ex-situ reduction and dry passivation of noble metal catalysts
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FR2915908B1 (fr) * 2007-05-10 2010-09-03 Eurecat Sa Procede de sulfuration ou presulfuration de particules solides d'un catalyseur ou d'un adsorbant
US8519379B2 (en) 2009-12-08 2013-08-27 Zena Technologies, Inc. Nanowire structured photodiode with a surrounding epitaxially grown P or N layer
US8889455B2 (en) 2009-12-08 2014-11-18 Zena Technologies, Inc. Manufacturing nanowire photo-detector grown on a back-side illuminated image sensor
US8890271B2 (en) 2010-06-30 2014-11-18 Zena Technologies, Inc. Silicon nitride light pipes for image sensors
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US8748799B2 (en) 2010-12-14 2014-06-10 Zena Technologies, Inc. Full color single pixel including doublet or quadruplet si nanowires for image sensors
US8735797B2 (en) 2009-12-08 2014-05-27 Zena Technologies, Inc. Nanowire photo-detector grown on a back-side illuminated image sensor
US9515218B2 (en) 2008-09-04 2016-12-06 Zena Technologies, Inc. Vertical pillar structured photovoltaic devices with mirrors and optical claddings
US9299866B2 (en) 2010-12-30 2016-03-29 Zena Technologies, Inc. Nanowire array based solar energy harvesting device
US8299472B2 (en) 2009-12-08 2012-10-30 Young-June Yu Active pixel sensor with nanowire structured photodetectors
CA2742549C (fr) 2008-11-10 2017-07-04 Institut National De La Recherche Scientifique Precurseurs de catalyseurs, catalyseurs et leurs procedes de production
MY166873A (en) * 2011-12-16 2018-07-24 Basf Corp Protected reduced metal catalyst
FR2994394B1 (fr) * 2012-08-09 2015-08-21 Eurecat Sa Procede de passivation par un compose azote d'un catalyseur zeolitique, en particulier d'un catalyseur d'hydrocraquage
CN113083376A (zh) * 2019-12-23 2021-07-09 内蒙古伊泰煤基新材料研究院有限公司 一种加氢裂化催化剂的钝化方法
GB202100248D0 (en) * 2021-01-08 2021-02-24 Johnson Matthey Plc Catalyst passivation method

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Also Published As

Publication number Publication date
LU91102B1 (fr) 2006-02-28
FR2850882A1 (fr) 2004-08-13
US7582587B2 (en) 2009-09-01
JP5016918B2 (ja) 2012-09-05
FR2850882B1 (fr) 2005-03-18
JP2006517467A (ja) 2006-07-27
WO2004071655A1 (fr) 2004-08-26
US20060154812A1 (en) 2006-07-13
DE112004000001T5 (de) 2005-05-25
DE112004000001B4 (de) 2021-12-02
CA2485665C (fr) 2011-09-27

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