CA2382023A1 - Stable formulation components, compositions and laundry methods employing same - Google Patents
Stable formulation components, compositions and laundry methods employing same Download PDFInfo
- Publication number
- CA2382023A1 CA2382023A1 CA002382023A CA2382023A CA2382023A1 CA 2382023 A1 CA2382023 A1 CA 2382023A1 CA 002382023 A CA002382023 A CA 002382023A CA 2382023 A CA2382023 A CA 2382023A CA 2382023 A1 CA2382023 A1 CA 2382023A1
- Authority
- CA
- Canada
- Prior art keywords
- group
- substituted
- aryl
- heterocyclic ring
- unsubstituted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 335
- 238000000034 method Methods 0.000 title claims abstract description 57
- 238000009472 formulation Methods 0.000 title claims abstract description 30
- 239000003054 catalyst Substances 0.000 claims abstract description 238
- 150000001875 compounds Chemical class 0.000 claims abstract description 170
- 238000004061 bleaching Methods 0.000 claims abstract description 166
- 239000007844 bleaching agent Substances 0.000 claims abstract description 96
- 150000001412 amines Chemical class 0.000 claims abstract description 41
- SJGALSBBFTYSBA-UHFFFAOYSA-N oxaziridine Chemical group C1NO1 SJGALSBBFTYSBA-UHFFFAOYSA-N 0.000 claims abstract description 16
- 230000001965 increasing effect Effects 0.000 claims abstract description 15
- 150000002466 imines Chemical group 0.000 claims abstract description 4
- 125000003118 aryl group Chemical group 0.000 claims description 154
- 125000000217 alkyl group Chemical group 0.000 claims description 151
- 125000000623 heterocyclic group Chemical group 0.000 claims description 147
- -1 oxaziridinium cations Chemical class 0.000 claims description 121
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 113
- 125000003545 alkoxy group Chemical group 0.000 claims description 91
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 90
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 90
- 229910052739 hydrogen Inorganic materials 0.000 claims description 82
- 239000004744 fabric Substances 0.000 claims description 70
- 229930194542 Keto Natural products 0.000 claims description 57
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 57
- 125000000468 ketone group Chemical group 0.000 claims description 57
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 57
- 239000003599 detergent Substances 0.000 claims description 55
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 claims description 52
- 102000004190 Enzymes Human genes 0.000 claims description 49
- 108090000790 Enzymes Proteins 0.000 claims description 49
- 239000002253 acid Substances 0.000 claims description 49
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 44
- 150000003839 salts Chemical class 0.000 claims description 43
- 239000012190 activator Substances 0.000 claims description 42
- 239000004094 surface-active agent Substances 0.000 claims description 40
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 claims description 39
- 229920006395 saturated elastomer Polymers 0.000 claims description 38
- 239000003795 chemical substances by application Substances 0.000 claims description 37
- 125000001424 substituent group Chemical group 0.000 claims description 36
- 125000002947 alkylene group Chemical group 0.000 claims description 33
- 239000000975 dye Substances 0.000 claims description 30
- 229910052760 oxygen Inorganic materials 0.000 claims description 29
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 28
- 239000001301 oxygen Substances 0.000 claims description 28
- 150000007513 acids Chemical class 0.000 claims description 24
- 125000003368 amide group Chemical group 0.000 claims description 24
- 125000005129 aryl carbonyl group Chemical group 0.000 claims description 24
- 125000004181 carboxyalkyl group Chemical group 0.000 claims description 24
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 24
- 125000002837 carbocyclic group Chemical group 0.000 claims description 23
- 239000002304 perfume Substances 0.000 claims description 22
- 239000002689 soil Substances 0.000 claims description 21
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical class [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 claims description 19
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 18
- 239000000654 additive Substances 0.000 claims description 17
- 229920000831 ionic polymer Polymers 0.000 claims description 16
- 230000000996 additive effect Effects 0.000 claims description 15
- 125000002091 cationic group Chemical group 0.000 claims description 15
- 125000000129 anionic group Chemical group 0.000 claims description 14
- 150000001768 cations Chemical class 0.000 claims description 14
- 239000002270 dispersing agent Substances 0.000 claims description 14
- 238000004900 laundering Methods 0.000 claims description 13
- 238000012546 transfer Methods 0.000 claims description 12
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 9
- 230000002401 inhibitory effect Effects 0.000 claims description 8
- 125000004417 unsaturated alkyl group Chemical group 0.000 claims description 8
- 239000004927 clay Substances 0.000 claims description 7
- 125000005342 perphosphate group Chemical group 0.000 claims description 7
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 7
- 150000002148 esters Chemical class 0.000 claims description 6
- 239000002904 solvent Substances 0.000 claims description 6
- 125000004400 (C1-C12) alkyl group Chemical group 0.000 claims description 5
- FAGGUIDTQQXDSJ-UHFFFAOYSA-N 3-benzoylazepan-2-one Chemical compound C=1C=CC=CC=1C(=O)C1CCCCNC1=O FAGGUIDTQQXDSJ-UHFFFAOYSA-N 0.000 claims description 5
- 239000000872 buffer Substances 0.000 claims description 4
- 150000004968 peroxymonosulfuric acids Chemical class 0.000 claims description 4
- FCJSHPDYVMKCHI-UHFFFAOYSA-N phenyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OC1=CC=CC=C1 FCJSHPDYVMKCHI-UHFFFAOYSA-N 0.000 claims description 4
- 239000003381 stabilizer Substances 0.000 claims description 4
- CDWQJRGVYJQAIT-UHFFFAOYSA-N 3-benzoylpiperidin-2-one Chemical compound C=1C=CC=CC=1C(=O)C1CCCNC1=O CDWQJRGVYJQAIT-UHFFFAOYSA-N 0.000 claims description 3
- KYVZSRPVPDAAKQ-UHFFFAOYSA-N 2-benzoyloxybenzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1OC(=O)C1=CC=CC=C1 KYVZSRPVPDAAKQ-UHFFFAOYSA-N 0.000 claims description 2
- GGAVUMZUOHJGGM-UHFFFAOYSA-N 2-decanoyloxybenzenesulfonic acid Chemical compound CCCCCCCCCC(=O)OC1=CC=CC=C1S(O)(=O)=O GGAVUMZUOHJGGM-UHFFFAOYSA-N 0.000 claims description 2
- GZFRVDZZXXKIGR-UHFFFAOYSA-N 2-decanoyloxybenzoic acid Chemical compound CCCCCCCCCC(=O)OC1=CC=CC=C1C(O)=O GZFRVDZZXXKIGR-UHFFFAOYSA-N 0.000 claims description 2
- ZDKYIHHSXJTDKX-UHFFFAOYSA-N 2-dodecanoyloxybenzenesulfonic acid Chemical compound CCCCCCCCCCCC(=O)OC1=CC=CC=C1S(O)(=O)=O ZDKYIHHSXJTDKX-UHFFFAOYSA-N 0.000 claims description 2
- MQWCVVYEJGQDEL-UHFFFAOYSA-N 3-(4-nitrobenzoyl)azepan-2-one Chemical compound C1=CC([N+](=O)[O-])=CC=C1C(=O)C1C(=O)NCCCC1 MQWCVVYEJGQDEL-UHFFFAOYSA-N 0.000 claims description 2
- JNIYAMTYWPMEGP-UHFFFAOYSA-N ClC1=CC=CC(C(=O)C2C(NCCCC2)=O)=C1 Chemical compound ClC1=CC=CC(C(=O)C2C(NCCCC2)=O)=C1 JNIYAMTYWPMEGP-UHFFFAOYSA-N 0.000 claims description 2
- 239000002979 fabric softener Substances 0.000 claims description 2
- MAZNCWGRSPCNGO-UHFFFAOYSA-M sodium;4-[6-(nonanoylamino)hexanoyloxy]benzenesulfonate Chemical compound [Na+].CCCCCCCCC(=O)NCCCCCC(=O)OC1=CC=C(S([O-])(=O)=O)C=C1 MAZNCWGRSPCNGO-UHFFFAOYSA-M 0.000 claims description 2
- 125000001475 halogen functional group Chemical group 0.000 claims 34
- 125000004356 hydroxy functional group Chemical group O* 0.000 claims 2
- FRPJTGXMTIIFIT-UHFFFAOYSA-N tetraacetylethylenediamine Chemical compound CC(=O)C(N)(C(C)=O)C(N)(C(C)=O)C(C)=O FRPJTGXMTIIFIT-UHFFFAOYSA-N 0.000 claims 2
- MJYRIHYNDGNHTJ-UHFFFAOYSA-N benzenesulfonyl undec-10-eneperoxoate Chemical compound C=CCCCCCCCCC(=O)OOS(=O)(=O)C1=CC=CC=C1 MJYRIHYNDGNHTJ-UHFFFAOYSA-N 0.000 claims 1
- 150000003254 radicals Chemical class 0.000 description 79
- 239000000243 solution Substances 0.000 description 67
- 238000004140 cleaning Methods 0.000 description 53
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 51
- 229940088598 enzyme Drugs 0.000 description 47
- 239000000463 material Substances 0.000 description 47
- 229910001868 water Inorganic materials 0.000 description 45
- 239000000047 product Substances 0.000 description 35
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 33
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 30
- 239000007788 liquid Substances 0.000 description 30
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical class [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 26
- 125000005843 halogen group Chemical group 0.000 description 23
- 239000002736 nonionic surfactant Substances 0.000 description 23
- 239000010457 zeolite Substances 0.000 description 23
- 108091005804 Peptidases Proteins 0.000 description 21
- 239000004365 Protease Substances 0.000 description 21
- 229910021536 Zeolite Inorganic materials 0.000 description 21
- 150000004965 peroxy acids Chemical class 0.000 description 21
- 229920000642 polymer Polymers 0.000 description 21
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 20
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 19
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 19
- BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 19
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 18
- 241000228215 Aspergillus aculeatus Species 0.000 description 18
- 238000002360 preparation method Methods 0.000 description 17
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 16
- 229910000323 aluminium silicate Inorganic materials 0.000 description 16
- 229920001577 copolymer Polymers 0.000 description 16
- 238000000354 decomposition reaction Methods 0.000 description 16
- 108010065511 Amylases Proteins 0.000 description 15
- 102000013142 Amylases Human genes 0.000 description 15
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 15
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical class [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 15
- 235000019418 amylase Nutrition 0.000 description 15
- 229910000029 sodium carbonate Inorganic materials 0.000 description 15
- 241000894007 species Species 0.000 description 15
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical class [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 14
- 238000004851 dishwashing Methods 0.000 description 14
- 239000004615 ingredient Substances 0.000 description 14
- 229910052751 metal Inorganic materials 0.000 description 14
- 239000002184 metal Substances 0.000 description 14
- 238000012360 testing method Methods 0.000 description 14
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 13
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 12
- 239000003945 anionic surfactant Substances 0.000 description 12
- 125000004432 carbon atom Chemical group C* 0.000 description 12
- 239000007859 condensation product Substances 0.000 description 12
- 239000000945 filler Substances 0.000 description 12
- 239000011734 sodium Substances 0.000 description 12
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical class [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 11
- 239000004115 Sodium Silicate Substances 0.000 description 11
- 238000002835 absorbance Methods 0.000 description 11
- 229940025131 amylases Drugs 0.000 description 11
- 150000004760 silicates Chemical class 0.000 description 11
- 239000004382 Amylase Substances 0.000 description 10
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 10
- 230000015572 biosynthetic process Effects 0.000 description 10
- 229940106157 cellulase Drugs 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 10
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 10
- 150000002678 macrocyclic compounds Chemical class 0.000 description 10
- 229910052708 sodium Inorganic materials 0.000 description 10
- 238000005406 washing Methods 0.000 description 10
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 9
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 9
- 108010059892 Cellulase Proteins 0.000 description 9
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Natural products OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 9
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 9
- 239000002738 chelating agent Substances 0.000 description 9
- 239000008367 deionised water Substances 0.000 description 9
- 229910021641 deionized water Inorganic materials 0.000 description 9
- 230000000694 effects Effects 0.000 description 9
- 230000008569 process Effects 0.000 description 9
- 235000019832 sodium triphosphate Nutrition 0.000 description 9
- 229910052723 transition metal Inorganic materials 0.000 description 9
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 150000001450 anions Chemical class 0.000 description 8
- 239000002585 base Substances 0.000 description 8
- 229910017052 cobalt Inorganic materials 0.000 description 8
- 239000010941 cobalt Substances 0.000 description 8
- 239000011572 manganese Substances 0.000 description 8
- 239000007787 solid Substances 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 239000000758 substrate Substances 0.000 description 8
- 150000003624 transition metals Chemical class 0.000 description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 7
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 7
- 239000004367 Lipase Substances 0.000 description 7
- 102000004882 Lipase Human genes 0.000 description 7
- 108090001060 Lipase Proteins 0.000 description 7
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 7
- 229910019142 PO4 Inorganic materials 0.000 description 7
- 239000004902 Softening Agent Substances 0.000 description 7
- 150000004996 alkyl benzenes Chemical class 0.000 description 7
- 229960004106 citric acid Drugs 0.000 description 7
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 7
- 239000003446 ligand Substances 0.000 description 7
- 235000019421 lipase Nutrition 0.000 description 7
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 7
- 235000021317 phosphate Nutrition 0.000 description 7
- 229920005646 polycarboxylate Polymers 0.000 description 7
- 229920001223 polyethylene glycol Polymers 0.000 description 7
- 235000017557 sodium bicarbonate Nutrition 0.000 description 7
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 7
- 229910052911 sodium silicate Inorganic materials 0.000 description 7
- 239000003826 tablet Substances 0.000 description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 6
- 235000019270 ammonium chloride Nutrition 0.000 description 6
- 230000008901 benefit Effects 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 6
- 239000003093 cationic surfactant Substances 0.000 description 6
- 229920006037 cross link polymer Polymers 0.000 description 6
- 235000014113 dietary fatty acids Nutrition 0.000 description 6
- 239000000194 fatty acid Substances 0.000 description 6
- 229930195729 fatty acid Natural products 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 6
- 229920001296 polysiloxane Polymers 0.000 description 6
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 6
- 229940045872 sodium percarbonate Drugs 0.000 description 6
- 238000006467 substitution reaction Methods 0.000 description 6
- 229910021653 sulphate ion Inorganic materials 0.000 description 6
- 238000003786 synthesis reaction Methods 0.000 description 6
- MHKLKWCYGIBEQF-UHFFFAOYSA-N 4-(1,3-benzothiazol-2-ylsulfanyl)morpholine Chemical compound C1COCCN1SC1=NC2=CC=CC=C2S1 MHKLKWCYGIBEQF-UHFFFAOYSA-N 0.000 description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical group CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 5
- 244000060011 Cocos nucifera Species 0.000 description 5
- 235000013162 Cocos nucifera Nutrition 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 5
- 239000002202 Polyethylene glycol Substances 0.000 description 5
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical group [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 5
- 229920002125 Sokalan® Polymers 0.000 description 5
- 150000008051 alkyl sulfates Chemical class 0.000 description 5
- 239000001768 carboxy methyl cellulose Substances 0.000 description 5
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 5
- 239000013522 chelant Substances 0.000 description 5
- 150000004665 fatty acids Chemical class 0.000 description 5
- 239000000499 gel Substances 0.000 description 5
- 239000008187 granular material Substances 0.000 description 5
- 125000001183 hydrocarbyl group Chemical group 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 230000002209 hydrophobic effect Effects 0.000 description 5
- 229910052748 manganese Inorganic materials 0.000 description 5
- 150000004682 monohydrates Chemical class 0.000 description 5
- 239000012188 paraffin wax Substances 0.000 description 5
- 239000010452 phosphate Substances 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- ROSDSFDQCJNGOL-UHFFFAOYSA-N protonated dimethyl amine Natural products CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 5
- 229960001922 sodium perborate Drugs 0.000 description 5
- 239000012418 sodium perborate tetrahydrate Substances 0.000 description 5
- IBDSNZLUHYKHQP-UHFFFAOYSA-N sodium;3-oxidodioxaborirane;tetrahydrate Chemical compound O.O.O.O.[Na+].[O-]B1OO1 IBDSNZLUHYKHQP-UHFFFAOYSA-N 0.000 description 5
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 5
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 5
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 5
- VKZRWSNIWNFCIQ-WDSKDSINSA-N (2s)-2-[2-[[(1s)-1,2-dicarboxyethyl]amino]ethylamino]butanedioic acid Chemical compound OC(=O)C[C@@H](C(O)=O)NCCN[C@H](C(O)=O)CC(O)=O VKZRWSNIWNFCIQ-WDSKDSINSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 4
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 description 4
- 101710194948 Protein phosphatase PhpP Proteins 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 230000002378 acidificating effect Effects 0.000 description 4
- 125000001931 aliphatic group Chemical group 0.000 description 4
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 4
- 125000005907 alkyl ester group Chemical group 0.000 description 4
- 229940077388 benzenesulfonate Drugs 0.000 description 4
- OWBTYPJTUOEWEK-UHFFFAOYSA-N butane-2,3-diol Chemical compound CC(O)C(C)O OWBTYPJTUOEWEK-UHFFFAOYSA-N 0.000 description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 4
- 230000003197 catalytic effect Effects 0.000 description 4
- 239000011651 chromium Substances 0.000 description 4
- 239000003086 colorant Substances 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
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- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- HNEGQIOMVPPMNR-NSCUHMNNSA-N mesaconic acid Chemical compound OC(=O)C(/C)=C/C(O)=O HNEGQIOMVPPMNR-NSCUHMNNSA-N 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 125000005341 metaphosphate group Chemical group 0.000 description 1
- TWXDDNPPQUTEOV-FVGYRXGTSA-N methamphetamine hydrochloride Chemical compound Cl.CN[C@@H](C)CC1=CC=CC=C1 TWXDDNPPQUTEOV-FVGYRXGTSA-N 0.000 description 1
- 229940050176 methyl chloride Drugs 0.000 description 1
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 1
- VXBSKVAMQMBCCA-UHFFFAOYSA-M methyl sulfate;trimethyl(tetradecyl)azanium Chemical compound COS([O-])(=O)=O.CCCCCCCCCCCCCC[N+](C)(C)C VXBSKVAMQMBCCA-UHFFFAOYSA-M 0.000 description 1
- 150000005451 methyl sulfates Chemical class 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- HNEGQIOMVPPMNR-UHFFFAOYSA-N methylfumaric acid Natural products OC(=O)C(C)=CC(O)=O HNEGQIOMVPPMNR-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- 229940051866 mouthwash Drugs 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- IQZPDFORWZTSKT-UHFFFAOYSA-N nitrosulphonic acid Chemical compound OS(=O)(=O)[N+]([O-])=O IQZPDFORWZTSKT-UHFFFAOYSA-N 0.000 description 1
- FJDUDHYHRVPMJZ-UHFFFAOYSA-N nonan-1-amine Chemical compound CCCCCCCCCN FJDUDHYHRVPMJZ-UHFFFAOYSA-N 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 150000004967 organic peroxy acids Chemical class 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical class [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 1
- WXHIJDCHNDBCNY-UHFFFAOYSA-N palladium dihydride Chemical compound [PdH2] WXHIJDCHNDBCNY-UHFFFAOYSA-N 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 229940055076 parasympathomimetics choline ester Drugs 0.000 description 1
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
- 108040007629 peroxidase activity proteins Proteins 0.000 description 1
- 125000000864 peroxy group Chemical group O(O*)* 0.000 description 1
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 235000002949 phytic acid Nutrition 0.000 description 1
- 239000000467 phytic acid Substances 0.000 description 1
- 229940068041 phytic acid Drugs 0.000 description 1
- 239000006187 pill Substances 0.000 description 1
- 229920000075 poly(4-vinylpyridine) Polymers 0.000 description 1
- 229920002006 poly(N-vinylimidazole) polymer Polymers 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical compound CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 229940024999 proteolytic enzymes for treatment of wounds and ulcers Drugs 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 150000003248 quinolines Chemical class 0.000 description 1
- 238000006268 reductive amination reaction Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 238000002390 rotary evaporation Methods 0.000 description 1
- 102200047299 rs764232985 Human genes 0.000 description 1
- AJTVWPGZWVJMEA-UHFFFAOYSA-N ruthenium tungsten Chemical compound [Ru].[Ru].[W].[W].[W] AJTVWPGZWVJMEA-UHFFFAOYSA-N 0.000 description 1
- BIXNGBXQRRXPLM-UHFFFAOYSA-K ruthenium(3+);trichloride;hydrate Chemical compound O.Cl[Ru](Cl)Cl BIXNGBXQRRXPLM-UHFFFAOYSA-K 0.000 description 1
- 238000011012 sanitization Methods 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- COEZWFYORILMOM-UHFFFAOYSA-M sodium 4-[(2,4-dihydroxyphenyl)diazenyl]benzenesulfonate Chemical compound [Na+].OC1=CC(O)=CC=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 COEZWFYORILMOM-UHFFFAOYSA-M 0.000 description 1
- 235000012217 sodium aluminium silicate Nutrition 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- DZCAZXAJPZCSCU-UHFFFAOYSA-K sodium nitrilotriacetate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CC([O-])=O DZCAZXAJPZCSCU-UHFFFAOYSA-K 0.000 description 1
- PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 description 1
- 229940048086 sodium pyrophosphate Drugs 0.000 description 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 125000005156 substituted alkylene group Chemical group 0.000 description 1
- 125000005650 substituted phenylene group Chemical group 0.000 description 1
- IIACRCGMVDHOTQ-UHFFFAOYSA-N sulfamic acid Chemical compound NS(O)(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-N 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 239000000271 synthetic detergent Substances 0.000 description 1
- 239000003784 tall oil Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- QEMXHQIAXOOASZ-UHFFFAOYSA-N tetramethylammonium Chemical compound C[N+](C)(C)C QEMXHQIAXOOASZ-UHFFFAOYSA-N 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- MSLRPWGRFCKNIZ-UHFFFAOYSA-J tetrasodium;hydrogen peroxide;dicarbonate Chemical compound [Na+].[Na+].[Na+].[Na+].OO.OO.OO.[O-]C([O-])=O.[O-]C([O-])=O MSLRPWGRFCKNIZ-UHFFFAOYSA-J 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 239000000606 toothpaste Substances 0.000 description 1
- 229940034610 toothpaste Drugs 0.000 description 1
- GTZCVFVGUGFEME-UHFFFAOYSA-N trans-aconitic acid Natural products OC(=O)CC(C(O)=O)=CC(O)=O GTZCVFVGUGFEME-UHFFFAOYSA-N 0.000 description 1
- 229910001428 transition metal ion Inorganic materials 0.000 description 1
- 125000005208 trialkylammonium group Chemical group 0.000 description 1
- RSJKGSCJYJTIGS-UHFFFAOYSA-N undecane Chemical compound CCCCCCCCCCC RSJKGSCJYJTIGS-UHFFFAOYSA-N 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3907—Organic compounds
- C11D3/3917—Nitrogen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3907—Organic compounds
- C11D3/3917—Nitrogen-containing compounds
- C11D3/392—Heterocyclic compounds, e.g. cyclic imides or lactames
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US15117699P | 1999-08-27 | 1999-08-27 | |
| US60/151,176 | 1999-08-27 | ||
| PCT/US2000/023317 WO2001016274A1 (en) | 1999-08-27 | 2000-08-25 | Stable formulation components, compositions and laundry methods employing same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2382023A1 true CA2382023A1 (en) | 2001-03-08 |
Family
ID=22537634
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002382023A Abandoned CA2382023A1 (en) | 1999-08-27 | 2000-08-25 | Stable formulation components, compositions and laundry methods employing same |
Country Status (16)
| Country | Link |
|---|---|
| EP (1) | EP1206519B1 (de) |
| JP (1) | JP2003508585A (de) |
| CN (1) | CN1384868A (de) |
| AR (1) | AR027846A1 (de) |
| AT (1) | ATE311432T1 (de) |
| AU (1) | AU7072100A (de) |
| BR (1) | BR0014151A (de) |
| CA (1) | CA2382023A1 (de) |
| CZ (1) | CZ2002722A3 (de) |
| DE (1) | DE60024463T2 (de) |
| EG (1) | EG22867A (de) |
| ES (1) | ES2252054T3 (de) |
| MA (1) | MA25602A1 (de) |
| MX (1) | MXPA02002128A (de) |
| TR (1) | TR200200471T2 (de) |
| WO (1) | WO2001016274A1 (de) |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7557076B2 (en) | 2002-06-06 | 2009-07-07 | The Procter & Gamble Company | Organic catalyst with enhanced enzyme compatibility |
| US7169744B2 (en) | 2002-06-06 | 2007-01-30 | Procter & Gamble Company | Organic catalyst with enhanced solubility |
| AR051659A1 (es) | 2005-06-17 | 2007-01-31 | Procter & Gamble | Una composicion que comprende un catalizador organico con compatibilidada enzimatica mejorada |
| EP1896561A2 (de) | 2005-06-17 | 2008-03-12 | Basf Se | Verfahren zur herstellung von bleichaktivatoren |
| ES2415872T3 (es) * | 2005-08-19 | 2013-07-29 | The Procter & Gamble Company | Composición detergente para lavado de ropa, sólida que comprende un tensioactivo detersivo aniónico y una tecnología de potenciación del calcio |
| US20070123440A1 (en) * | 2005-11-28 | 2007-05-31 | Loughnane Brian J | Stable odorant systems |
| CN101370921B (zh) | 2006-01-23 | 2014-08-13 | 宝洁公司 | 包含脂肪酶和漂白催化剂的组合物 |
| EP1811014B1 (de) | 2006-01-23 | 2010-04-21 | The Procter and Gamble Company | Zusammensetzung enthaltend vorgeformte Persäure und einen Bleichmittelkatalysator |
| WO2007087258A2 (en) | 2006-01-23 | 2007-08-02 | The Procter & Gamble Company | A composition comprising a lipase and a bleach catalyst |
| PH12009500020A1 (en) | 2006-07-07 | 2008-01-17 | Procter & Gamble | A composition comprising a cellulose and a bleach catalyst |
| KR20120034666A (ko) | 2009-05-22 | 2012-04-12 | 엑셀리시스, 인코포레이티드 | 증식성 질환에 대한 벤족사제핀 기반 ｐ１３ｋ／ｍｔ０ｒ의 억제제 |
| AU2010254200A1 (en) | 2009-05-26 | 2011-12-08 | Exelixis, Inc. | Benzoxazepines as inhibitors of PI3K/m TOR and methods of their use and manufacture |
| DK2464645T3 (en) | 2009-07-27 | 2017-10-23 | Gilead Sciences Inc | CONDENSED, HETEROCYCLIC COMPOUNDS AS IRON CHANNEL MODULATORS |
| US20110240510A1 (en) * | 2010-04-06 | 2011-10-06 | Johan Maurice Theo De Poortere | Optimized release of bleaching systems in laundry detergents |
| CN103096977B (zh) | 2010-07-02 | 2017-02-15 | 吉利德科学公司 | 作为离子通道调节剂的稠杂环化合物 |
| WO2012154760A1 (en) | 2011-05-10 | 2012-11-15 | Gilead Sciences, Inc. | Fused heterocyclic compounds as sodium channel modulators |
| TWI549944B (zh) | 2011-07-01 | 2016-09-21 | 吉李德科學股份有限公司 | 作為離子通道調節劑之稠合雜環化合物 |
| NO3175985T3 (de) | 2011-07-01 | 2018-04-28 | ||
| CN104394936B (zh) * | 2012-05-30 | 2017-08-25 | 科莱恩金融(Bvi)有限公司 | N‑甲基‑n‑酰基葡糖胺作为表面活性剂溶液中的低温稳定剂的用途 |
| JP6188199B2 (ja) * | 2013-05-20 | 2017-08-30 | ライオン株式会社 | 食器洗い機用洗浄剤 |
| WO2017182295A1 (en) * | 2016-04-18 | 2017-10-26 | Basf Se | Liquid cleaning compositions |
| EP3249034B1 (de) * | 2016-05-26 | 2019-03-20 | The Procter and Gamble Company | Wasserlöslicher einheitsdosisartikel mit einer pulverzusammensetzung |
| DE102016015660A1 (de) * | 2016-12-31 | 2018-07-05 | Weylchem Wiesbaden Gmbh | Granulate, deren Verwendung und Wasch- und Reinigungsmittel enthaltend diese |
| WO2024068248A1 (en) * | 2022-09-29 | 2024-04-04 | Unilever Ip Holdings B.V. | A solid cleaning and disinfection composition |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4194987A (en) * | 1978-12-26 | 1980-03-25 | Fmc Corporation | Peroxygen bleaching and compositions therefor |
| CA2176227C (en) * | 1993-11-12 | 2006-08-15 | Stephen Alan Madison | Imine quaternary salts as bleach catalysts |
| AU8106694A (en) * | 1993-11-12 | 1995-05-29 | Unilever Plc | Activation of bleach precursors with imine quaternary salts |
| US5370826A (en) * | 1993-11-12 | 1994-12-06 | Lever Brothers Company, Division Of Conopco, Inc. | Quaternay oxaziridinium salts as bleaching compounds |
| US5576282A (en) * | 1995-09-11 | 1996-11-19 | The Procter & Gamble Company | Color-safe bleach boosters, compositions and laundry methods employing same |
| US5817614A (en) * | 1996-08-29 | 1998-10-06 | Procter & Gamble Company | Color-safe bleach boosters, compositions and laundry methods employing same |
| DE19746290A1 (de) * | 1997-10-20 | 1999-04-22 | Clariant Gmbh | Verwendung von Aminonitril-N-oxiden als Bleichaktivatoren |
-
2000
- 2000-08-25 JP JP2001520822A patent/JP2003508585A/ja not_active Withdrawn
- 2000-08-25 CA CA002382023A patent/CA2382023A1/en not_active Abandoned
- 2000-08-25 EP EP00959387A patent/EP1206519B1/de not_active Expired - Lifetime
- 2000-08-25 DE DE60024463T patent/DE60024463T2/de not_active Expired - Lifetime
- 2000-08-25 AU AU70721/00A patent/AU7072100A/en not_active Abandoned
- 2000-08-25 AT AT00959387T patent/ATE311432T1/de not_active IP Right Cessation
- 2000-08-25 BR BR0014151-8A patent/BR0014151A/pt not_active Application Discontinuation
- 2000-08-25 TR TR2002/00471T patent/TR200200471T2/xx unknown
- 2000-08-25 CN CN00814999.2A patent/CN1384868A/zh active Pending
- 2000-08-25 MX MXPA02002128A patent/MXPA02002128A/es active IP Right Grant
- 2000-08-25 CZ CZ2002722A patent/CZ2002722A3/cs unknown
- 2000-08-25 ES ES00959387T patent/ES2252054T3/es not_active Expired - Lifetime
- 2000-08-25 WO PCT/US2000/023317 patent/WO2001016274A1/en active IP Right Grant
- 2000-08-27 EG EG20001108A patent/EG22867A/xx active
- 2000-08-28 AR ARP000104455A patent/AR027846A1/es active IP Right Grant
-
2002
- 2002-02-27 MA MA26531A patent/MA25602A1/fr unknown
Also Published As
| Publication number | Publication date |
|---|---|
| WO2001016274A1 (en) | 2001-03-08 |
| DE60024463T2 (de) | 2006-08-17 |
| EP1206519B1 (de) | 2005-11-30 |
| DE60024463D1 (de) | 2006-01-05 |
| CN1384868A (zh) | 2002-12-11 |
| AR027846A1 (es) | 2003-04-16 |
| EG22867A (en) | 2003-09-30 |
| ES2252054T3 (es) | 2006-05-16 |
| WO2001016274A9 (en) | 2007-06-14 |
| ATE311432T1 (de) | 2005-12-15 |
| TR200200471T2 (tr) | 2002-05-21 |
| MXPA02002128A (es) | 2002-09-02 |
| MA25602A1 (fr) | 2002-12-31 |
| EP1206519A1 (de) | 2002-05-22 |
| JP2003508585A (ja) | 2003-03-04 |
| CZ2002722A3 (cs) | 2002-10-16 |
| AU7072100A (en) | 2001-03-26 |
| BR0014151A (pt) | 2002-05-07 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| FZDE | Discontinued |