CA2371835C - Stereorigid, bridged metallocene catalysts for polyolefin production - Google Patents

Stereorigid, bridged metallocene catalysts for polyolefin production Download PDF

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Publication number
CA2371835C
CA2371835C CA2371835A CA2371835A CA2371835C CA 2371835 C CA2371835 C CA 2371835C CA 2371835 A CA2371835 A CA 2371835A CA 2371835 A CA2371835 A CA 2371835A CA 2371835 C CA2371835 C CA 2371835C
Authority
CA
Canada
Prior art keywords
use according
polyolefin
substituent
hydrogen
chosen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA2371835A
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English (en)
French (fr)
Other versions
CA2371835A1 (en
Inventor
Abbas Razavi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TotalEnergies One Tech Belgium SA
Original Assignee
Atofina Research SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Atofina Research SA filed Critical Atofina Research SA
Publication of CA2371835A1 publication Critical patent/CA2371835A1/en
Application granted granted Critical
Publication of CA2371835C publication Critical patent/CA2371835C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/15Isotactic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
  • Organic Insulating Materials (AREA)
CA2371835A 1999-02-19 2000-02-18 Stereorigid, bridged metallocene catalysts for polyolefin production Expired - Fee Related CA2371835C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
PCT/EP1999/001094 WO2000049029A1 (en) 1999-02-19 1999-02-19 Polyolefin production
EPPCT/EP99/01094 1999-02-19
PCT/EP2000/001378 WO2000049056A1 (en) 1999-02-19 2000-02-18 Polyolefin production

Publications (2)

Publication Number Publication Date
CA2371835A1 CA2371835A1 (en) 2000-08-24
CA2371835C true CA2371835C (en) 2010-07-27

Family

ID=8167219

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2371835A Expired - Fee Related CA2371835C (en) 1999-02-19 2000-02-18 Stereorigid, bridged metallocene catalysts for polyolefin production

Country Status (11)

Country Link
JP (1) JP4864176B2 (pt)
KR (1) KR100663788B1 (pt)
CN (1) CN1152056C (pt)
AT (1) ATE271071T1 (pt)
AU (2) AU3141199A (pt)
BR (1) BR0008312B1 (pt)
CA (1) CA2371835C (pt)
DE (1) DE60012166T2 (pt)
ES (1) ES2223460T3 (pt)
RU (1) RU2244721C2 (pt)
WO (2) WO2000049029A1 (pt)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6469188B1 (en) * 1999-01-20 2002-10-22 California Institute Of Technology Catalyst system for the polymerization of alkenes to polyolefins
CN100434433C (zh) * 1999-10-08 2008-11-19 三井化学株式会社 茂金属化合物及制备方法、烯烃聚合催化剂、聚烯烃及制备方法
ES2243196T3 (es) 2000-08-07 2005-12-01 Total Petrochemicals Research Feluy Produccion de poliolefinas.
KR100541582B1 (ko) * 2001-03-15 2007-04-16 미쓰이 가가쿠 가부시키가이샤 폴리프로필렌 수지 조성물로 되는 자동차 부품
DE60331613D1 (de) * 2003-03-28 2010-04-15 Mitsui Chemicals Inc Propylen-Copolymer, Polypropylen-Zusammensetzung, Verwendung davon, Übergangsmetallverbindungen und Katalysatoren zur Olefin-Polymerisation
EP1493759A1 (en) * 2003-07-04 2005-01-05 Total Petrochemicals Research Feluy Polymerisation process
EP1493778A1 (en) * 2003-07-04 2005-01-05 Total Petrochemicals Research Feluy Polyolefin production
EP1493760A1 (en) * 2003-07-04 2005-01-05 Total Petrochemicals Research Feluy Styrene copolymerisation process
EP1496070A1 (en) * 2003-07-09 2005-01-12 Total Petrochemicals Research Feluy A polyolefin having internal double bonds and a method for making the same
CN101010350B (zh) 2004-08-30 2013-01-02 三井化学株式会社 丙烯系聚合物的制造方法
WO2006126610A1 (ja) * 2005-05-25 2006-11-30 Mitsui Chemicals, Inc. 遷移金属化合物、オレフィン重合用触媒およびオレフィン系重合体の製造方法
EP1734059A1 (en) * 2005-06-13 2006-12-20 Total Petrochemicals Research Feluy Carbon-bridged cyclopentadienyl-fluorenyl ligands
EP1734058A1 (en) * 2005-06-13 2006-12-20 Total Petrochemicals Research Feluy Ethylene and alpha-olefins polymerisation catalyst system based on fluorenyl ligand
JPWO2008059974A1 (ja) 2006-11-17 2010-03-04 三井化学株式会社 シンジオタクティックプロピレン系重合体の製造方法
EP2108665B1 (en) * 2007-01-18 2018-05-16 Prime Polymer Co., Ltd. Propylene homopolymer for stress-resistant molded object, composition containing the polymer, and stress-resistant molded object obtained from the same
US8119553B2 (en) * 2007-09-28 2012-02-21 Chevron Phillips Chemical Company Lp Polymerization catalysts for producing polymers with low melt elasticity
CN105330771B (zh) * 2014-12-03 2018-12-14 亚培烯科技(杭州)有限公司 一种茂金属线性低密度聚乙烯催化剂及其制备方法和应用
CN115677879B (zh) * 2021-07-31 2024-07-30 华为技术有限公司 环烯烃共聚物制备用催化剂、环烯烃共聚物的制备方法、环烯烃共聚物及其应用

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2030532C (en) * 1989-04-18 1995-08-01 Tadashi Asanuma Syndiotactic polypropylene resin composition
DE69116814T2 (de) * 1990-11-20 1996-09-26 Mitsubishi Chem Corp Funktionalisierte Olefinpolymere
US5710222A (en) * 1992-06-22 1998-01-20 Fina Technology, Inc. Method for controlling the melting points and molecular weights of syndiotactic polyolefins using metallocene catalyst systems
JPH08325327A (ja) * 1995-06-02 1996-12-10 Chisso Corp 高立体規則性ポリプロピレン
ATE225359T1 (de) * 1995-12-18 2002-10-15 Basell Polyolefine Gmbh Verfahren zur abreicherung von nebenprodukten in produktgemischen
DE59712644D1 (de) * 1996-08-13 2006-06-14 Basell Polyolefine Gmbh Geträgerte chemische Verbindung
EP0881236A1 (en) * 1997-05-26 1998-12-02 Fina Research S.A. Metallocene catalyst component for use in producing isotactic polyolefins

Also Published As

Publication number Publication date
CN1152056C (zh) 2004-06-02
AU3141199A (en) 2000-09-04
BR0008312B1 (pt) 2011-06-14
JP2002510358A (ja) 2002-04-02
CA2371835A1 (en) 2000-08-24
RU2244721C2 (ru) 2005-01-20
ATE271071T1 (de) 2004-07-15
KR20020002471A (ko) 2002-01-09
CN1346373A (zh) 2002-04-24
DE60012166T2 (de) 2005-09-08
KR100663788B1 (ko) 2007-01-03
AU2806200A (en) 2000-09-04
WO2000049029A1 (en) 2000-08-24
ES2223460T3 (es) 2005-03-01
DE60012166D1 (de) 2004-08-19
JP4864176B2 (ja) 2012-02-01
BR0008312A (pt) 2002-01-22
WO2000049056A1 (en) 2000-08-24

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