CA2371835C - Stereorigid, bridged metallocene catalysts for polyolefin production - Google Patents

Stereorigid, bridged metallocene catalysts for polyolefin production Download PDF

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Publication number
CA2371835C
CA2371835C CA2371835A CA2371835A CA2371835C CA 2371835 C CA2371835 C CA 2371835C CA 2371835 A CA2371835 A CA 2371835A CA 2371835 A CA2371835 A CA 2371835A CA 2371835 C CA2371835 C CA 2371835C
Authority
CA
Canada
Prior art keywords
use according
polyolefin
substituent
hydrogen
chosen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA2371835A
Other languages
English (en)
French (fr)
Other versions
CA2371835A1 (en
Inventor
Abbas Razavi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TotalEnergies Onetech Belgium SA
Original Assignee
Atofina Research SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Atofina Research SA filed Critical Atofina Research SA
Publication of CA2371835A1 publication Critical patent/CA2371835A1/en
Application granted granted Critical
Publication of CA2371835C publication Critical patent/CA2371835C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/15—Isotactic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
  • Organic Insulating Materials (AREA)
CA2371835A 1999-02-19 2000-02-18 Stereorigid, bridged metallocene catalysts for polyolefin production Expired - Fee Related CA2371835C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EPPCT/EP99/01094 1999-02-19
PCT/EP1999/001094 WO2000049029A1 (en) 1999-02-19 1999-02-19 Polyolefin production
PCT/EP2000/001378 WO2000049056A1 (en) 1999-02-19 2000-02-18 Polyolefin production

Publications (2)

Publication Number Publication Date
CA2371835A1 CA2371835A1 (en) 2000-08-24
CA2371835C true CA2371835C (en) 2010-07-27

Family

ID=8167219

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2371835A Expired - Fee Related CA2371835C (en) 1999-02-19 2000-02-18 Stereorigid, bridged metallocene catalysts for polyolefin production

Country Status (11)

Country Link
JP (1) JP4864176B2 (https=)
KR (1) KR100663788B1 (https=)
CN (1) CN1152056C (https=)
AT (1) ATE271071T1 (https=)
AU (2) AU3141199A (https=)
BR (1) BR0008312B1 (https=)
CA (1) CA2371835C (https=)
DE (1) DE60012166T2 (https=)
ES (1) ES2223460T3 (https=)
RU (1) RU2244721C2 (https=)
WO (2) WO2000049029A1 (https=)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6469188B1 (en) 1999-01-20 2002-10-22 California Institute Of Technology Catalyst system for the polymerization of alkenes to polyolefins
DE60034308T2 (de) * 1999-10-08 2007-12-20 Mitsui Chemicals, Inc. Metallocene, ein Verfahren zur deren Herstellung, Olefinpolymerisationskatalysator, und ein Verfahren zur Herstellung von Polyolefinen
ES2243196T3 (es) * 2000-08-07 2005-12-01 Total Petrochemicals Research Feluy Produccion de poliolefinas.
DE60211444T2 (de) * 2001-03-15 2006-11-30 Mitsui Chemicals, Inc. Automobilteile aus einer polypropylenharzzusammensetzung
TWI296270B (en) * 2002-07-19 2008-05-01 Mitsui Chemicals Inc Propylene copolymer, polypropylene composition and its usage, and transition metal compound, catalyst for olefinic polymerization
PL374508A1 (en) * 2002-08-01 2005-10-31 Basell Poliolefine Italia S.P.A. Highly stereoregular polypropylene with improved properties
EP1493778A1 (en) * 2003-07-04 2005-01-05 Total Petrochemicals Research Feluy Polyolefin production
EP1493760A1 (en) * 2003-07-04 2005-01-05 Total Petrochemicals Research Feluy Styrene copolymerisation process
EP1493759A1 (en) * 2003-07-04 2005-01-05 Total Petrochemicals Research Feluy Polymerisation process
EP1496070A1 (en) * 2003-07-09 2005-01-12 Total Petrochemicals Research Feluy A polyolefin having internal double bonds and a method for making the same
US7879960B2 (en) 2004-08-30 2011-02-01 Mitsui Chemicals, Inc. Process for producing propylene polymer
EP1900744A4 (en) * 2005-05-25 2010-10-20 Mitsui Chemicals Inc TRANSITION METAL COMPOUND, OLEFIN POLYMERIZATION CATALYST, AND PROCESS FOR PRODUCING OLEFIN POLYMER
EP1734058A1 (en) * 2005-06-13 2006-12-20 Total Petrochemicals Research Feluy Ethylene and alpha-olefins polymerisation catalyst system based on fluorenyl ligand
EP1734059A1 (en) * 2005-06-13 2006-12-20 Total Petrochemicals Research Feluy Carbon-bridged cyclopentadienyl-fluorenyl ligands
WO2008059974A1 (en) 2006-11-17 2008-05-22 Mitsui Chemicals, Inc. Method for producing syndiotactic propylene polymer
CN101600743B (zh) 2007-01-18 2012-08-29 普瑞曼聚合物株式会社 应力耐久成型体用丙烯均聚物和包含该聚合物的组合物、以及由它们得到的应力耐久成型体
US8119553B2 (en) * 2007-09-28 2012-02-21 Chevron Phillips Chemical Company Lp Polymerization catalysts for producing polymers with low melt elasticity
CN105330771B (zh) * 2014-12-03 2018-12-14 亚培烯科技（杭州）有限公司 一种茂金属线性低密度聚乙烯催化剂及其制备方法和应用
CN115677879B (zh) * 2021-07-31 2024-07-30 华为技术有限公司 环烯烃共聚物制备用催化剂、环烯烃共聚物的制备方法、环烯烃共聚物及其应用

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0419677B1 (en) * 1989-04-18 1995-12-27 MITSUI TOATSU CHEMICALS, Inc. Syndiotactic polypropylene resin composition
DE69116814T2 (de) * 1990-11-20 1996-09-26 Mitsubishi Chem Corp Funktionalisierte Olefinpolymere
JP3371118B2 (ja) * 1991-11-30 2003-01-27 バーゼル・ポリオレフィン・ゲゼルシャフト・ミト・ベシュレンクテル・ハフツング 配位子としてベンゼン融合したインデニル誘導体を持つメタロセン、その製造方法および触媒としてのその用途
US5710222A (en) * 1992-06-22 1998-01-20 Fina Technology, Inc. Method for controlling the melting points and molecular weights of syndiotactic polyolefins using metallocene catalyst systems
DE19519370A1 (de) * 1995-05-26 1996-11-28 Philips Patentverwaltung Schaltungsanordnung zum Speisen eines Zweiphasen-Asynchronmotors
JPH08325327A (ja) * 1995-06-02 1996-12-10 Chisso Corp 高立体規則性ポリプロピレン
ATE225359T1 (de) * 1995-12-18 2002-10-15 Basell Polyolefine Gmbh Verfahren zur abreicherung von nebenprodukten in produktgemischen
DE59712644D1 (de) * 1996-08-13 2006-06-14 Basell Polyolefine Gmbh Geträgerte chemische Verbindung
EP0881236A1 (en) * 1997-05-26 1998-12-02 Fina Research S.A. Metallocene catalyst component for use in producing isotactic polyolefins

Also Published As

Publication number Publication date
CN1152056C (zh) 2004-06-02
JP2002510358A (ja) 2002-04-02
BR0008312A (pt) 2002-01-22
DE60012166T2 (de) 2005-09-08
KR100663788B1 (ko) 2007-01-03
DE60012166D1 (de) 2004-08-19
WO2000049029A1 (en) 2000-08-24
CN1346373A (zh) 2002-04-24
JP4864176B2 (ja) 2012-02-01
ES2223460T3 (es) 2005-03-01
WO2000049056A1 (en) 2000-08-24
RU2244721C2 (ru) 2005-01-20
AU2806200A (en) 2000-09-04
AU3141199A (en) 2000-09-04
KR20020002471A (ko) 2002-01-09
CA2371835A1 (en) 2000-08-24
BR0008312B1 (pt) 2011-06-14
ATE271071T1 (de) 2004-07-15

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Effective date: 20150218