CA2305193C - Amines alcoxylees et leur utilisation dans des compositions nettoyantes - Google Patents
Amines alcoxylees et leur utilisation dans des compositions nettoyantes Download PDFInfo
- Publication number
- CA2305193C CA2305193C CA2305193A CA2305193A CA2305193C CA 2305193 C CA2305193 C CA 2305193C CA 2305193 A CA2305193 A CA 2305193A CA 2305193 A CA2305193 A CA 2305193A CA 2305193 C CA2305193 C CA 2305193C
- Authority
- CA
- Canada
- Prior art keywords
- use according
- anionic surfactant
- amine
- range
- mole ratio
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 60
- 150000001412 amines Chemical class 0.000 title claims abstract description 22
- 238000004140 cleaning Methods 0.000 title claims abstract description 16
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 22
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229920006395 saturated elastomer Polymers 0.000 claims abstract description 11
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 9
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 8
- 238000007046 ethoxylation reaction Methods 0.000 claims abstract description 7
- 230000008021 deposition Effects 0.000 claims abstract description 5
- 239000002253 acid Substances 0.000 claims description 15
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 claims description 13
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 12
- 239000003752 hydrotrope Substances 0.000 claims description 12
- 239000002736 nonionic surfactant Substances 0.000 claims description 8
- IIACRCGMVDHOTQ-UHFFFAOYSA-N sulfamic acid Chemical compound NS(O)(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-N 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 5
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 claims description 4
- 150000003512 tertiary amines Chemical class 0.000 claims description 4
- 125000003342 alkenyl group Chemical group 0.000 claims description 2
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
- 230000008569 process Effects 0.000 claims description 2
- 230000000979 retarding effect Effects 0.000 claims description 2
- 125000002877 alkyl aryl group Chemical group 0.000 claims 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 239000000463 material Substances 0.000 description 19
- 230000000052 comparative effect Effects 0.000 description 8
- -1 ETHOMEEN S12) Chemical class 0.000 description 5
- 150000007513 acids Chemical class 0.000 description 5
- 150000001298 alcohols Chemical class 0.000 description 5
- 239000002304 perfume Substances 0.000 description 5
- 230000000717 retained effect Effects 0.000 description 5
- 239000002562 thickening agent Substances 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- 241000220317 Rosa Species 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 239000003899 bactericide agent Substances 0.000 description 3
- 239000003599 detergent Substances 0.000 description 3
- GIPRGFRQMWSHAK-UHFFFAOYSA-M sodium;2-propan-2-ylbenzenesulfonate Chemical group [Na+].CC(C)C1=CC=CC=C1S([O-])(=O)=O GIPRGFRQMWSHAK-UHFFFAOYSA-M 0.000 description 3
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 3
- 229920001285 xanthan gum Polymers 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- VINSUQIDKGQEND-UHFFFAOYSA-N ON(O)CCCCCCCCC=C/CCCCCCCCCC Chemical compound ON(O)CCCCCCCCC=C/CCCCCCCCCC VINSUQIDKGQEND-UHFFFAOYSA-N 0.000 description 2
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 2
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 2
- 239000000645 desinfectant Substances 0.000 description 2
- WJJMNDUMQPNECX-UHFFFAOYSA-N dipicolinic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=N1 WJJMNDUMQPNECX-UHFFFAOYSA-N 0.000 description 2
- 229960001484 edetic acid Drugs 0.000 description 2
- 239000008233 hard water Substances 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 235000011007 phosphoric acid Nutrition 0.000 description 2
- 150000003016 phosphoric acids Chemical class 0.000 description 2
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 2
- 239000002356 single layer Substances 0.000 description 2
- ODBPOHVSVJZQRX-UHFFFAOYSA-M sodium;[2-[2-[bis(phosphonomethyl)amino]ethyl-(phosphonomethyl)amino]ethyl-(phosphonomethyl)amino]methyl-hydroxyphosphinate Chemical compound [Na+].OP(=O)(O)CN(CP(O)(O)=O)CCN(CP(O)(=O)O)CCN(CP(O)(O)=O)CP(O)([O-])=O ODBPOHVSVJZQRX-UHFFFAOYSA-M 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 239000003760 tallow Substances 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- 230000008719 thickening Effects 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- BAERPNBPLZWCES-UHFFFAOYSA-N (2-hydroxy-1-phosphonoethyl)phosphonic acid Chemical compound OCC(P(O)(O)=O)P(O)(O)=O BAERPNBPLZWCES-UHFFFAOYSA-N 0.000 description 1
- BITAPBDLHJQAID-MDZDMXLPSA-N 2-[2-hydroxyethyl-[(e)-octadec-9-enyl]amino]ethanol Chemical compound CCCCCCCC\C=C\CCCCCCCCN(CCO)CCO BITAPBDLHJQAID-MDZDMXLPSA-N 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- SGHZXLIDFTYFHQ-UHFFFAOYSA-L Brilliant Blue Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 SGHZXLIDFTYFHQ-UHFFFAOYSA-L 0.000 description 1
- 229910021532 Calcite Inorganic materials 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- NSFKBZXCXCJZDQ-UHFFFAOYSA-N cumene;sodium Chemical compound [Na].CC(C)C1=CC=CC=C1 NSFKBZXCXCJZDQ-UHFFFAOYSA-N 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- DUYCTCQXNHFCSJ-UHFFFAOYSA-N dtpmp Chemical compound OP(=O)(O)CN(CP(O)(O)=O)CCN(CP(O)(=O)O)CCN(CP(O)(O)=O)CP(O)(O)=O DUYCTCQXNHFCSJ-UHFFFAOYSA-N 0.000 description 1
- NFDRPXJGHKJRLJ-UHFFFAOYSA-N edtmp Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CCN(CP(O)(O)=O)CP(O)(O)=O NFDRPXJGHKJRLJ-UHFFFAOYSA-N 0.000 description 1
- 150000004665 fatty acids Chemical group 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000003641 microbiacidal effect Effects 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- CTRXDTYTAAKVSM-UHFFFAOYSA-O n-ethyl-4-[(4-{ethyl[(3-sulfophenyl)methyl]amino}phenyl)(2-sulfophenyl)methylidene]-n-[(3-sulfophenyl)methyl]cyclohexa-2,5-dien-1-iminium Chemical compound C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S(O)(=O)=O)C=2C(=CC=CC=2)S(O)(=O)=O)C=CC=1N(CC)CC1=CC=CC(S(O)(=O)=O)=C1 CTRXDTYTAAKVSM-UHFFFAOYSA-O 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical class CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003605 opacifier Substances 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 150000004967 organic peroxy acids Chemical class 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/42—Amino alcohols or amino ethers
- C11D1/44—Ethers of polyoxyalkylenes with amino alcohols; Condensation products of epoxyalkanes with amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/042—Acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3942—Inorganic per-compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3947—Liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Cette invention a trait à une amine aliphatique alcoxylée comportant de 8 à 18 atomes de carbone et dont entre 1 et 8 moles sont éthoxylées, le rapport molaire des restes aliphatiques saturés / insaturés tombant dans la gamme s'échelonnant entre 40/60 et 80/20. Elle concerne également une composition nettoyante comportant: (a), de 0,01 à 15 % en pourcentage pondéral d'une amine aliphatique alcoxylée comportant de 8 à 18 atomes de carbone et dont entre 1 et 8 moles sont éthoxylées, le rapport molaire des restes aliphatique saturés / insaturés tombant dans la gamme s'échelonnant entre 40/60 et 80/20 et, (b), de 0,01 à 15 % en pourcentage pondéral d'un tensioactif anionique. Ces compositions nettoyantes renfermant l'amine susmentionnée témoignent d'une stabilité de viscosité améliorée lors du stockage. En présence d'une tensioactif anionique à faible pH, le dépôt de tartre sur des surfaces traitées à l'aide de la composition se trouve retardé.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB9721691.5A GB9721691D0 (en) | 1997-10-13 | 1997-10-13 | Improvements relating to acidic cleaning compositions |
| GB9721691.5 | 1997-10-13 | ||
| PCT/EP1998/006633 WO1999019431A1 (fr) | 1997-10-13 | 1998-10-09 | Amines alcoxylees et leur utilisation dans des compositions nettoyantes |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2305193A1 CA2305193A1 (fr) | 1999-04-22 |
| CA2305193C true CA2305193C (fr) | 2010-03-23 |
Family
ID=10820480
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2305193A Expired - Fee Related CA2305193C (fr) | 1997-10-13 | 1998-10-09 | Amines alcoxylees et leur utilisation dans des compositions nettoyantes |
Country Status (19)
| Country | Link |
|---|---|
| EP (1) | EP1023423B1 (fr) |
| JP (1) | JP4323093B2 (fr) |
| KR (1) | KR20010015748A (fr) |
| AR (1) | AR017315A1 (fr) |
| AU (1) | AU735924B2 (fr) |
| BR (1) | BR9813044A (fr) |
| CA (1) | CA2305193C (fr) |
| DE (1) | DE69821636T2 (fr) |
| ES (1) | ES2214747T3 (fr) |
| GB (1) | GB9721691D0 (fr) |
| HU (1) | HU224521B1 (fr) |
| ID (1) | ID24420A (fr) |
| IN (1) | IN185797B (fr) |
| MY (1) | MY123176A (fr) |
| PL (1) | PL188434B1 (fr) |
| SK (1) | SK5302000A3 (fr) |
| TR (1) | TR200000972T2 (fr) |
| WO (1) | WO1999019431A1 (fr) |
| ZA (1) | ZA989144B (fr) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6617303B1 (en) | 1999-01-11 | 2003-09-09 | Huntsman Petrochemical Corporation | Surfactant compositions containing alkoxylated amines |
| WO2003076559A1 (fr) * | 2002-03-13 | 2003-09-18 | Cognis Iberia, S.L. | Solutions de peroxyde epaissies |
| DE102004055492A1 (de) * | 2004-11-17 | 2006-07-13 | Chemische Fabrik Dr. Weigert Gmbh & Co. Kg | Klarspüler für Kunststoffteile |
| GB0804727D0 (en) * | 2008-03-14 | 2008-04-16 | Reckitt Benckiser Inc | Thickened hard surface cleaning compositions comprising fatty amine alkoxylate compounds |
| US9006286B2 (en) | 2011-05-10 | 2015-04-14 | Ecolab Usa Inc. | Couplers for medium-chain fatty acids and disinfecting compositions |
| DE102022207153A1 (de) * | 2022-07-13 | 2024-01-18 | Henkel Ag & Co. Kgaa | Waschaktive Verbindungen auf Basis einer Kombination von Anionen und Kationentensid |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2459830A1 (fr) * | 1979-06-26 | 1981-01-16 | Voreppe Ind Chimiques | Compositions nettoyantes et detartrantes a base d'acide sulfamique, ayant une viscosite stable |
| DE3603579A1 (de) * | 1986-02-06 | 1987-08-13 | Henkel Kgaa | Verwendung ethoxylierter fettamine als loesungsvermittler |
| NO170944C (no) * | 1987-01-24 | 1992-12-30 | Akzo Nv | Fortykkede, vandige preparater, samt anvendelse av slike |
-
1997
- 1997-10-13 GB GBGB9721691.5A patent/GB9721691D0/en active Pending
-
1998
- 1998-10-05 IN IN642BO1998 patent/IN185797B/en unknown
- 1998-10-07 ZA ZA9809144A patent/ZA989144B/xx unknown
- 1998-10-09 ID IDW20000660A patent/ID24420A/id unknown
- 1998-10-09 WO PCT/EP1998/006633 patent/WO1999019431A1/fr active IP Right Grant
- 1998-10-09 CA CA2305193A patent/CA2305193C/fr not_active Expired - Fee Related
- 1998-10-09 HU HU0004913A patent/HU224521B1/hu not_active IP Right Cessation
- 1998-10-09 AR ARP980105039A patent/AR017315A1/es active IP Right Grant
- 1998-10-09 SK SK530-2000A patent/SK5302000A3/sk unknown
- 1998-10-09 TR TR2000/00972T patent/TR200000972T2/xx unknown
- 1998-10-09 ES ES98955491T patent/ES2214747T3/es not_active Expired - Lifetime
- 1998-10-09 DE DE69821636T patent/DE69821636T2/de not_active Expired - Lifetime
- 1998-10-09 AU AU12298/99A patent/AU735924B2/en not_active Ceased
- 1998-10-09 KR KR1020007003926A patent/KR20010015748A/ko not_active Application Discontinuation
- 1998-10-09 EP EP98955491A patent/EP1023423B1/fr not_active Expired - Lifetime
- 1998-10-09 PL PL98339808A patent/PL188434B1/pl not_active IP Right Cessation
- 1998-10-09 BR BR9813044-7A patent/BR9813044A/pt not_active IP Right Cessation
- 1998-10-09 JP JP2000515989A patent/JP4323093B2/ja not_active Expired - Fee Related
- 1998-10-12 MY MYPI98004650A patent/MY123176A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| HUP0004913A3 (en) | 2005-06-28 |
| JP2001520259A (ja) | 2001-10-30 |
| DE69821636D1 (de) | 2004-03-18 |
| SK5302000A3 (en) | 2000-09-12 |
| EP1023423A1 (fr) | 2000-08-02 |
| GB9721691D0 (en) | 1997-12-10 |
| PL188434B1 (pl) | 2005-01-31 |
| HUP0004913A2 (hu) | 2001-05-28 |
| HU224521B1 (hu) | 2005-10-28 |
| WO1999019431A1 (fr) | 1999-04-22 |
| AU1229899A (en) | 1999-05-03 |
| AR017315A1 (es) | 2001-09-05 |
| TR200000972T2 (tr) | 2000-11-21 |
| DE69821636T2 (de) | 2004-07-29 |
| ZA989144B (en) | 2000-04-07 |
| JP4323093B2 (ja) | 2009-09-02 |
| ES2214747T3 (es) | 2004-09-16 |
| KR20010015748A (ko) | 2001-02-26 |
| PL339808A1 (en) | 2001-01-02 |
| CA2305193A1 (fr) | 1999-04-22 |
| BR9813044A (pt) | 2000-08-15 |
| AU735924B2 (en) | 2001-07-19 |
| EP1023423B1 (fr) | 2004-02-11 |
| MY123176A (en) | 2006-05-31 |
| IN185797B (fr) | 2001-05-05 |
| ID24420A (id) | 2000-07-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |
Effective date: 20151009 |