CA2252854A1 - Formed ultra-flexible retroreflective cube-corner composite sheeting with target optical properties and method for making same - Google Patents
Formed ultra-flexible retroreflective cube-corner composite sheeting with target optical properties and method for making same Download PDFInfo
- Publication number
- CA2252854A1 CA2252854A1 CA002252854A CA2252854A CA2252854A1 CA 2252854 A1 CA2252854 A1 CA 2252854A1 CA 002252854 A CA002252854 A CA 002252854A CA 2252854 A CA2252854 A CA 2252854A CA 2252854 A1 CA2252854 A1 CA 2252854A1
- Authority
- CA
- Canada
- Prior art keywords
- cube
- corner
- article
- corner elements
- retroreflective
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 238000000034 method Methods 0.000 title claims abstract description 49
- 230000003287 optical effect Effects 0.000 title claims abstract description 48
- 239000002131 composite material Substances 0.000 title description 10
- 238000011065 in-situ storage Methods 0.000 claims abstract description 6
- 239000000463 material Substances 0.000 claims description 39
- 238000000576 coating method Methods 0.000 claims description 12
- 239000011248 coating agent Substances 0.000 claims description 11
- 239000003086 colorant Substances 0.000 claims description 7
- 238000004049 embossing Methods 0.000 claims description 7
- 238000007666 vacuum forming Methods 0.000 claims description 5
- 229920001187 thermosetting polymer Polymers 0.000 claims description 4
- 238000003856 thermoforming Methods 0.000 claims 1
- QEMSVZNTSXPFJA-HNAYVOBHSA-N 1-[(1s,2s)-1-hydroxy-1-(4-hydroxyphenyl)propan-2-yl]-4-phenylpiperidin-4-ol Chemical compound C1([C@H](O)[C@H](C)N2CCC(O)(CC2)C=2C=CC=CC=2)=CC=C(O)C=C1 QEMSVZNTSXPFJA-HNAYVOBHSA-N 0.000 description 34
- 229920005989 resin Polymers 0.000 description 34
- 239000011347 resin Substances 0.000 description 34
- 238000007789 sealing Methods 0.000 description 18
- -1 vinyl halide Chemical class 0.000 description 18
- 239000010410 layer Substances 0.000 description 16
- 229920000642 polymer Polymers 0.000 description 16
- 239000000203 mixture Substances 0.000 description 13
- 230000005855 radiation Effects 0.000 description 13
- 238000000926 separation method Methods 0.000 description 12
- 150000001875 compounds Chemical class 0.000 description 11
- 239000000047 product Substances 0.000 description 11
- 239000011342 resin composition Substances 0.000 description 11
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 7
- YFONKFDEZLYQDH-OPQQBVKSSA-N N-[(1R,2S)-2,6-dimethyindan-1-yl]-6-[(1R)-1-fluoroethyl]-1,3,5-triazine-2,4-diamine Chemical compound C[C@@H](F)C1=NC(N)=NC(N[C@H]2C3=CC(C)=CC=C3C[C@@H]2C)=N1 YFONKFDEZLYQDH-OPQQBVKSSA-N 0.000 description 7
- 239000002253 acid Substances 0.000 description 7
- 239000003550 marker Substances 0.000 description 7
- 229920002554 vinyl polymer Polymers 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- 239000004593 Epoxy Substances 0.000 description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- 238000005065 mining Methods 0.000 description 6
- 229920000728 polyester Polymers 0.000 description 6
- 241000934653 Dero Species 0.000 description 5
- 239000004698 Polyethylene Substances 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 5
- 238000003491 array Methods 0.000 description 5
- 230000015556 catabolic process Effects 0.000 description 5
- 238000006731 degradation reaction Methods 0.000 description 5
- 125000004386 diacrylate group Chemical group 0.000 description 5
- 125000005442 diisocyanate group Chemical group 0.000 description 5
- 229920001971 elastomer Polymers 0.000 description 5
- 229920001038 ethylene copolymer Polymers 0.000 description 5
- 150000002500 ions Chemical class 0.000 description 5
- 229920000573 polyethylene Polymers 0.000 description 5
- 238000007740 vapor deposition Methods 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- 241000282320 Panthera leo Species 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 4
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 229920000647 polyepoxide Polymers 0.000 description 4
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 3
- 239000004677 Nylon Substances 0.000 description 3
- 150000001408 amides Chemical class 0.000 description 3
- 150000001735 carboxylic acids Chemical class 0.000 description 3
- 238000005266 casting Methods 0.000 description 3
- 125000003700 epoxy group Chemical group 0.000 description 3
- 239000011888 foil Substances 0.000 description 3
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 3
- 229910052753 mercury Inorganic materials 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 229920001778 nylon Polymers 0.000 description 3
- 229910052718 tin Inorganic materials 0.000 description 3
- 230000007704 transition Effects 0.000 description 3
- 238000003466 welding Methods 0.000 description 3
- LEJBBGNFPAFPKQ-UHFFFAOYSA-N 2-(2-prop-2-enoyloxyethoxy)ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOC(=O)C=C LEJBBGNFPAFPKQ-UHFFFAOYSA-N 0.000 description 2
- INQDDHNZXOAFFD-UHFFFAOYSA-N 2-[2-(2-prop-2-enoyloxyethoxy)ethoxy]ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOCCOC(=O)C=C INQDDHNZXOAFFD-UHFFFAOYSA-N 0.000 description 2
- HCLJOFJIQIJXHS-UHFFFAOYSA-N 2-[2-[2-(2-prop-2-enoyloxyethoxy)ethoxy]ethoxy]ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOCCOCCOC(=O)C=C HCLJOFJIQIJXHS-UHFFFAOYSA-N 0.000 description 2
- SZNYYWIUQFZLLT-UHFFFAOYSA-N 2-methyl-1-(2-methylpropoxy)propane Chemical compound CC(C)COCC(C)C SZNYYWIUQFZLLT-UHFFFAOYSA-N 0.000 description 2
- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- 229940123457 Free radical scavenger Drugs 0.000 description 2
- 241000428199 Mustelinae Species 0.000 description 2
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 244000028419 Styrax benzoin Species 0.000 description 2
- 235000000126 Styrax benzoin Nutrition 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 235000008411 Sumatra benzointree Nutrition 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical group C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 2
- 239000006061 abrasive grain Substances 0.000 description 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 229960002130 benzoin Drugs 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 230000009477 glass transition Effects 0.000 description 2
- 235000019382 gum benzoic Nutrition 0.000 description 2
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical group C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 238000002955 isolation Methods 0.000 description 2
- 229920001684 low density polyethylene Polymers 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000002516 radical scavenger Substances 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- MUTNCGKQJGXKEM-UHFFFAOYSA-N tamibarotene Chemical compound C=1C=C2C(C)(C)CCC(C)(C)C2=CC=1NC(=O)C1=CC=C(C(O)=O)C=C1 MUTNCGKQJGXKEM-UHFFFAOYSA-N 0.000 description 2
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- GHPYJLCQYMAXGG-WCCKRBBISA-N (2R)-2-amino-3-(2-boronoethylsulfanyl)propanoic acid hydrochloride Chemical compound Cl.N[C@@H](CSCCB(O)O)C(O)=O GHPYJLCQYMAXGG-WCCKRBBISA-N 0.000 description 1
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 1
- MYWOJODOMFBVCB-UHFFFAOYSA-N 1,2,6-trimethylphenanthrene Chemical compound CC1=CC=C2C3=CC(C)=CC=C3C=CC2=C1C MYWOJODOMFBVCB-UHFFFAOYSA-N 0.000 description 1
- RBACIKXCRWGCBB-UHFFFAOYSA-N 1,2-Epoxybutane Chemical compound CCC1CO1 RBACIKXCRWGCBB-UHFFFAOYSA-N 0.000 description 1
- PUGOMSLRUSTQGV-UHFFFAOYSA-N 2,3-di(prop-2-enoyloxy)propyl prop-2-enoate Chemical compound C=CC(=O)OCC(OC(=O)C=C)COC(=O)C=C PUGOMSLRUSTQGV-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- YIJYFLXQHDOQGW-UHFFFAOYSA-N 2-[2,4,6-trioxo-3,5-bis(2-prop-2-enoyloxyethyl)-1,3,5-triazinan-1-yl]ethyl prop-2-enoate Chemical compound C=CC(=O)OCCN1C(=O)N(CCOC(=O)C=C)C(=O)N(CCOC(=O)C=C)C1=O YIJYFLXQHDOQGW-UHFFFAOYSA-N 0.000 description 1
- KMNCBSZOIQAUFX-UHFFFAOYSA-N 2-ethoxy-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(OCC)C(=O)C1=CC=CC=C1 KMNCBSZOIQAUFX-UHFFFAOYSA-N 0.000 description 1
- RIWRBSMFKVOJMN-UHFFFAOYSA-N 2-methyl-1-phenylpropan-2-ol Chemical compound CC(C)(O)CC1=CC=CC=C1 RIWRBSMFKVOJMN-UHFFFAOYSA-N 0.000 description 1
- CFVWNXQPGQOHRJ-UHFFFAOYSA-N 2-methylpropyl prop-2-enoate Chemical compound CC(C)COC(=O)C=C CFVWNXQPGQOHRJ-UHFFFAOYSA-N 0.000 description 1
- RZVINYQDSSQUKO-UHFFFAOYSA-N 2-phenoxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC1=CC=CC=C1 RZVINYQDSSQUKO-UHFFFAOYSA-N 0.000 description 1
- WMJBVALTYVXGHW-UHFFFAOYSA-N 3,3-diphenylprop-2-enoic acid Chemical class C=1C=CC=CC=1C(=CC(=O)O)C1=CC=CC=C1 WMJBVALTYVXGHW-UHFFFAOYSA-N 0.000 description 1
- DXPPIEDUBFUSEZ-UHFFFAOYSA-N 6-methylheptyl prop-2-enoate Chemical compound CC(C)CCCCCOC(=O)C=C DXPPIEDUBFUSEZ-UHFFFAOYSA-N 0.000 description 1
- 241001136792 Alle Species 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920013683 Celanese Polymers 0.000 description 1
- VVNCNSJFMMFHPL-VKHMYHEASA-N D-penicillamine Chemical compound CC(C)(S)[C@@H](N)C(O)=O VVNCNSJFMMFHPL-VKHMYHEASA-N 0.000 description 1
- MHZGKXUYDGKKIU-UHFFFAOYSA-N Decylamine Chemical compound CCCCCCCCCCN MHZGKXUYDGKKIU-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- FMRHJJZUHUTGKE-UHFFFAOYSA-N Ethylhexyl salicylate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1O FMRHJJZUHUTGKE-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 1
- 235000004412 Jasminum grandiflorum Nutrition 0.000 description 1
- 240000005067 Jasminum grandiflorum Species 0.000 description 1
- 229920006370 Kynar Polymers 0.000 description 1
- 101100345589 Mus musculus Mical1 gene Proteins 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- SYJGKVOENHZYMQ-UHFFFAOYSA-N Penoxsulam Chemical compound N1=C2C(OC)=CN=C(OC)N2N=C1NS(=O)(=O)C1=C(OCC(F)F)C=CC=C1C(F)(F)F SYJGKVOENHZYMQ-UHFFFAOYSA-N 0.000 description 1
- 229920001054 Poly(ethylene‐co‐vinyl acetate) Polymers 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 description 1
- 239000004708 Very-low-density polyethylene Substances 0.000 description 1
- 241000271897 Viperidae Species 0.000 description 1
- HVVWZTWDBSEWIH-UHFFFAOYSA-N [2-(hydroxymethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(COC(=O)C=C)COC(=O)C=C HVVWZTWDBSEWIH-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229920003232 aliphatic polyester Polymers 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229920003180 amino resin Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- WURBFLDFSFBTLW-UHFFFAOYSA-N benzil Chemical compound C=1C=CC=CC=1C(=O)C(=O)C1=CC=CC=C1 WURBFLDFSFBTLW-UHFFFAOYSA-N 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- 229940075911 depen Drugs 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 239000003989 dielectric material Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 229920002313 fluoropolymer Polymers 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 229920001002 functional polymer Polymers 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- LNMQRPPRQDGUDR-UHFFFAOYSA-N hexyl prop-2-enoate Chemical compound CCCCCCOC(=O)C=C LNMQRPPRQDGUDR-UHFFFAOYSA-N 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- LDHQCZJRKDOVOX-IHWYPQMZSA-N isocrotonic acid Chemical compound C\C=C/C(O)=O LDHQCZJRKDOVOX-IHWYPQMZSA-N 0.000 description 1
- 239000012948 isocyanate Chemical class 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 238000009740 moulding (composite fabrication) Methods 0.000 description 1
- 229940088644 n,n-dimethylacrylamide Drugs 0.000 description 1
- YLGYACDQVQQZSW-UHFFFAOYSA-N n,n-dimethylprop-2-enamide Chemical compound CN(C)C(=O)C=C YLGYACDQVQQZSW-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- ANISOHQJBAQUQP-UHFFFAOYSA-N octyl prop-2-enoate Chemical compound CCCCCCCCOC(=O)C=C ANISOHQJBAQUQP-UHFFFAOYSA-N 0.000 description 1
- YNXCGLKMOXLBOD-UHFFFAOYSA-N oxolan-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CCCO1 YNXCGLKMOXLBOD-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 239000002952 polymeric resin Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000131 polyvinylidene Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 208000006379 syphilis Diseases 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- BSYVTEYKTMYBMK-UHFFFAOYSA-N tetrahydrofurfuryl alcohol Chemical compound OCC1CCCO1 BSYVTEYKTMYBMK-UHFFFAOYSA-N 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 125000005409 triarylsulfonium group Chemical group 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 229940071865 urelle Drugs 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
- 229920001866 very low density polyethylene Polymers 0.000 description 1
- 229960000834 vinyl ether Drugs 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical class [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/12—Reflex reflectors
- G02B5/122—Reflex reflectors cube corner, trihedral or triple reflector type
- G02B5/124—Reflex reflectors cube corner, trihedral or triple reflector type plural reflecting elements forming part of a unitary plate or sheet
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T156/00—Adhesive bonding and miscellaneous chemical manufacture
- Y10T156/10—Methods of surface bonding and/or assembly therefor
- Y10T156/1002—Methods of surface bonding and/or assembly therefor with permanent bending or reshaping or surface deformation of self sustaining lamina
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T156/00—Adhesive bonding and miscellaneous chemical manufacture
- Y10T156/10—Methods of surface bonding and/or assembly therefor
- Y10T156/1002—Methods of surface bonding and/or assembly therefor with permanent bending or reshaping or surface deformation of self sustaining lamina
- Y10T156/1007—Running or continuous length work
- Y10T156/1023—Surface deformation only [e.g., embossing]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T156/00—Adhesive bonding and miscellaneous chemical manufacture
- Y10T156/10—Methods of surface bonding and/or assembly therefor
- Y10T156/1002—Methods of surface bonding and/or assembly therefor with permanent bending or reshaping or surface deformation of self sustaining lamina
- Y10T156/1028—Methods of surface bonding and/or assembly therefor with permanent bending or reshaping or surface deformation of self sustaining lamina by bending, drawing or stretch forming sheet to assume shape of configured lamina while in contact therewith
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
- Y10T428/24364—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.] with transparent or protective coating
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24479—Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24479—Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness
- Y10T428/24612—Composite web or sheet
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24777—Edge feature
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Optical Elements Other Than Lenses (AREA)
- Laminated Bodies (AREA)
- Road Signs Or Road Markings (AREA)
- Illuminated Signs And Luminous Advertising (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/641126 | 1996-04-30 | ||
| US08/641,126 US5763049A (en) | 1996-04-30 | 1996-04-30 | Formed ultra-flexible retroreflective cube-corner composite sheeting with target optical properties and method for making same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2252854A1 true CA2252854A1 (en) | 1997-11-06 |
Family
ID=24571039
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002252854A Abandoned CA2252854A1 (en) | 1996-04-30 | 1996-08-28 | Formed ultra-flexible retroreflective cube-corner composite sheeting with target optical properties and method for making same |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US5763049A (enExample) |
| EP (1) | EP0896682B1 (enExample) |
| JP (1) | JP2000509165A (enExample) |
| KR (1) | KR100400910B1 (enExample) |
| CN (1) | CN1129010C (enExample) |
| AT (1) | ATE208047T1 (enExample) |
| AU (1) | AU706087B2 (enExample) |
| BR (1) | BR9612603A (enExample) |
| CA (1) | CA2252854A1 (enExample) |
| DE (1) | DE69616601T2 (enExample) |
| WO (1) | WO1997041463A1 (enExample) |
Families Citing this family (71)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6703108B1 (en) | 1995-06-29 | 2004-03-09 | 3M Innovative Properties Company | Wet retroreflective marking material |
| US6303058B1 (en) * | 1996-06-27 | 2001-10-16 | 3M Innovative Properties Company | Method of making profiled retroreflective marking material |
| SE507095C2 (sv) * | 1996-07-01 | 1998-03-30 | Tetra Laval Holdings & Finance | Biglinjeförsett förpackningslaminat jämte sätt att förse ett förpackningslaminat med biglinjer, samt av laminatet framställda förpackningsbehållare |
| US6080526A (en) * | 1997-03-24 | 2000-06-27 | Alliedsignal Inc. | Integration of low-k polymers into interlevel dielectrics using controlled electron-beam radiation |
| JPH1115415A (ja) * | 1997-06-16 | 1999-01-22 | Minnesota Mining & Mfg Co <3M> | 自発光可能な再帰性反射シートおよびその製造方法 |
| USD444953S1 (en) | 1997-10-31 | 2001-07-17 | 3M Innovative Properties Company | Glittering cube-corner retroreflective sheeting |
| USD446946S1 (en) | 1997-10-31 | 2001-08-28 | 3M Innovative Properties Company | Glittering retroreflective sheeting |
| US6120636A (en) * | 1998-01-26 | 2000-09-19 | Reflexite Corporation | Apparatus and method for producing retroreflective material having printed patterns thereon |
| US6119751A (en) * | 1998-01-26 | 2000-09-19 | Reflexite Corporation | Apparatus and method for producing retroreflective material having printed patterns thereon |
| US6096247A (en) * | 1998-07-31 | 2000-08-01 | 3M Innovative Properties Company | Embossed optical polymer films |
| US6280822B1 (en) * | 1999-01-11 | 2001-08-28 | 3M Innovative Properties Company | Cube corner cavity based retroeflectors with transparent fill material |
| US6224792B1 (en) | 1999-04-13 | 2001-05-01 | 3M Innovative Properties Company | Cutting and edge sealing cellular retroreflective sheeting |
| US6246428B1 (en) | 1999-05-11 | 2001-06-12 | 3M Innovoative Properties Company | Method and system for thermal mass transfer printing |
| EP1221060B1 (en) | 1999-10-04 | 2005-01-05 | 3M Innovative Properties Company | Improved continuous process for making glittering cube corner sheeting |
| US6375776B1 (en) | 2000-01-24 | 2002-04-23 | Avery Dennison Corporation | Method for forming multi-layer laminates with microstructures |
| US6699567B2 (en) * | 2000-03-09 | 2004-03-02 | Reflexite Corporation | Stain resistant film construction |
| US6325515B1 (en) | 2000-03-21 | 2001-12-04 | 3M Innovative Properties Company | Cube corner retroreflective article with enhanced pigmentation |
| US6898623B1 (en) | 2000-06-16 | 2005-05-24 | Hewlett-Packard Development Company L.P. | Simplified configuration of an internet-enabled device |
| JP2002278490A (ja) | 2001-03-08 | 2002-09-27 | Three M Innovative Properties Co | グラフィックス表示シート |
| US6931665B2 (en) | 2001-07-30 | 2005-08-23 | 3M Innovative Properties Company | Vapor permeable retroreflective garment |
| US6960275B2 (en) * | 2002-04-12 | 2005-11-01 | 3M Innovative Properties Company | Method of making a viscoelastic article by coating and curing on a reusable surface |
| JP2003315516A (ja) * | 2002-04-18 | 2003-11-06 | Three M Innovative Properties Co | 反射積層体 |
| ATE440300T1 (de) * | 2002-06-11 | 2009-09-15 | 3M Innovative Properties Co | Herstellungsverfahren für eine form und hieraus gewonnene repliken |
| US6778336B2 (en) * | 2002-08-02 | 2004-08-17 | Illinois Tool Works Inc. | Reduced visibility surface |
| DE10326585B4 (de) * | 2002-12-12 | 2005-07-21 | Imos Gubela Gmbh | Sensorikreflektor für erhöhte Temperaturbereiche |
| US6871966B2 (en) * | 2002-12-12 | 2005-03-29 | Avery Dennison Corporation | Retroreflector with controlled divergence made by the method of localized substrate stress |
| US7156527B2 (en) | 2003-03-06 | 2007-01-02 | 3M Innovative Properties Company | Lamina comprising cube corner elements and retroreflective sheeting |
| EP2442151A3 (en) * | 2003-03-06 | 2012-05-09 | 3M Innovative Properties Co. | Lamina comprising cube corner elements and retroreflective sheeting |
| US8226880B2 (en) * | 2003-07-07 | 2012-07-24 | 10X Technology, Llc | Process for fabricating precise microstructures |
| US20050008821A1 (en) * | 2003-07-07 | 2005-01-13 | Pricone Robert M. | Process and apparatus for fabricating precise microstructures and polymeric molds for making same |
| US6954315B2 (en) * | 2003-08-01 | 2005-10-11 | Illinois Tool Works Inc. | Night vision and audio signal reduction system |
| US20050031820A1 (en) * | 2003-08-04 | 2005-02-10 | Gorman Gregory Winfield | Information-bearing pavement tape |
| KR101257136B1 (ko) | 2006-01-12 | 2013-04-23 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 집광 필름 |
| US20070204953A1 (en) * | 2006-02-21 | 2007-09-06 | Ching-Bin Lin | Method for forming structured film as molded by tape die |
| US7374297B2 (en) * | 2006-03-31 | 2008-05-20 | Reflexite Corporation | Conformable retroreflective film structure |
| USD594664S1 (en) | 2006-08-02 | 2009-06-23 | 3M Innovative Properties Company | Retroreflective article |
| KR100840151B1 (ko) * | 2006-10-25 | 2008-06-23 | 미래나노텍(주) | 재귀반사필름의 제조 장치 및 그 제조 방법 |
| AU2008201903B2 (en) * | 2007-05-07 | 2013-03-28 | Viavi Solutions Inc. | Structured surfaces that exhibit color by rotation |
| KR101513287B1 (ko) * | 2007-05-07 | 2015-04-22 | 제이디에스 유니페이즈 코포레이션 | 회전에 따른 색을 보여주는 구조화된 표면들 |
| US7547105B2 (en) * | 2007-07-16 | 2009-06-16 | 3M Innovative Properties Company | Prismatic retroreflective article with cross-linked image layer and method of making same |
| US8517546B2 (en) * | 2008-03-31 | 2013-08-27 | Nippon Carbide Industries Co., Inc. | Multi-directional cube corner retroreflective article |
| USD670917S1 (en) * | 2011-02-18 | 2012-11-20 | Columbia Sportswear North America, Inc. | Heat reflective lining material |
| RU2503982C2 (ru) * | 2009-07-28 | 2014-01-10 | Шарп Кабусики Кайся | Оптическая пленка, способ ее изготовления и способ управления ее оптическими характеристиками |
| KR101741863B1 (ko) * | 2009-10-16 | 2017-05-30 | 쓰리엠 이노베이티브 프로퍼티즈 캄파니 | 적외광의 재귀반사도가 감소된 프리즘형 재귀반사성 시트류 |
| USD665584S1 (en) * | 2010-03-05 | 2012-08-21 | Orafol Europe Gmbh | Retro-reflective sheeting with a corner cube surface pattern having angular corner cube circular regions |
| ES2719199T3 (es) * | 2011-01-25 | 2019-07-09 | Avery Dennison Corp | Un método para controlar la retrorreflectividad mediante la aplicación de un patrón impreso a una película retrorreflectante y lámina producida por dicho método |
| SG195166A1 (en) | 2011-05-31 | 2013-12-30 | 3M Innovative Properties Co | Method for making microstructured tools having discontinuous topographies, articles produced therefrom |
| EP2714358B1 (en) | 2011-05-31 | 2020-02-19 | 3M Innovative Properties Company | Methods for making differentially pattern cured microstructured articles |
| EP2715415B1 (en) | 2011-05-31 | 2024-03-20 | 3M Innovative Properties Company | Retroreflective articles having composite cube-corners and methods of making |
| CN104244862B (zh) | 2012-02-27 | 2017-07-21 | 巴伊材料公司 | 牙科产品及其制作方法 |
| WO2013188690A2 (en) | 2012-06-15 | 2013-12-19 | Michael Wang | Projector based display systems and methods |
| EP2724864B1 (de) | 2012-10-24 | 2018-12-26 | Heidelberger Druckmaschinen AG | Verfahren und Vorrichtung zur Erzeugung und Übertragung diffraktiver Mikrostrukturen auf einen Bedruckstoff |
| JP2017083480A (ja) * | 2014-03-14 | 2017-05-18 | 日本カーバイド工業株式会社 | 再帰反射シート |
| EP3149543A4 (en) | 2014-05-27 | 2018-01-03 | Mirraviz Inc. | Methods for optimizing retro-reflective display systems |
| WO2016069625A1 (en) | 2014-10-27 | 2016-05-06 | Mirraviz, Inc. | Method for incident angle optimization for reflector display |
| EP3320381B1 (en) | 2015-07-07 | 2022-08-31 | 3M Innovative Properties Company | Polyurethane layer for a light directing article |
| WO2017083782A1 (en) | 2015-11-13 | 2017-05-18 | Mirraviz, Inc. | Methods for system layout optimization for retro-reflective based display systems |
| CN109154769B (zh) * | 2016-03-11 | 2021-12-21 | 米拉维兹公司 | 用于逆反射显示系统优化的定制化反射轮廓特征 |
| WO2017200862A1 (en) | 2016-05-15 | 2017-11-23 | 3M Innovative Properties Company | Light redirecting film constructions and methods of making them |
| WO2017214007A1 (en) * | 2016-06-07 | 2017-12-14 | 3M Innovative Properties Company | Acrylic polyvinyl acetal film for a light directing article |
| US10034519B2 (en) | 2016-06-16 | 2018-07-31 | Adidas Ag | UV curable lattice microstructure for footwear |
| CN109804297B (zh) | 2016-08-03 | 2021-09-07 | 米拉维兹公司 | 逆反射屏幕、显示系统和显示图像的方法 |
| TWI616697B (zh) * | 2016-10-13 | 2018-03-01 | 大立光電股份有限公司 | 環形光學元件、成像鏡組、成像裝置及電子裝置 |
| US10788743B2 (en) | 2017-04-13 | 2020-09-29 | Mirraviz, Inc. | Retroreflective display systems configured to display images using shaped light profile |
| CN110913716B (zh) | 2017-04-24 | 2022-03-18 | 耐克创新有限合伙公司 | 具有粘附至纺织品的uv辐射可固化材料的物品及制造该物品的方法 |
| US11136475B2 (en) | 2017-04-24 | 2021-10-05 | Nike, Inc. | Articles and components with UV radiation curable elastomeric materials and methods of making the same |
| EP3576919B1 (en) | 2017-04-24 | 2020-06-17 | NIKE Innovate C.V. | Transparent tooling mold and process for uv radiation curable rubber |
| DE102018101289B4 (de) * | 2018-01-22 | 2019-10-17 | Imos Gubela Gmbh | Retroreflektor mit einer gekrümmten Oberfläche, Abformwerkzeug zur Herstellung des Retroreflektors und Verfahren zur Herstellung des Abformwerkzeugs |
| CN112180672A (zh) * | 2019-07-05 | 2021-01-05 | 深圳光峰科技股份有限公司 | 一种投影屏幕 |
| US20230366642A1 (en) | 2020-11-24 | 2023-11-16 | 3M Innovative Properties Company | Radiative cooling articles including a white diffusely reflective layer and a non-white color reflective mirror |
| WO2023223114A1 (en) | 2022-05-19 | 2023-11-23 | 3M Innovative Properties Company | Light shielding articles and electromagnetic receivers and/or emitters including the same |
Family Cites Families (67)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3010845A (en) * | 1957-05-15 | 1961-11-28 | Goodrich Co B F | Method and apparatus for decorating web or sheet material with glitter |
| US3450459A (en) * | 1965-10-24 | 1969-06-17 | Walter F Haggerty | Retroreflective device |
| US3924929A (en) * | 1966-11-14 | 1975-12-09 | Minnesota Mining & Mfg | Retro-reflective sheet material |
| US3541606A (en) * | 1967-10-16 | 1970-11-17 | Amerace Esna Corp | Reflectorized vehicles and reflectors therefor |
| US3469898A (en) * | 1967-11-20 | 1969-09-30 | Gerald Altman | Reflex reflective products and processes for their manufacture |
| US3632695A (en) * | 1970-03-05 | 1972-01-04 | Reflex Corp Canada Ltd | Making a combined lens and reflector |
| US3692731A (en) * | 1970-04-29 | 1972-09-19 | Mobil Oil Corp | Metallizing coating compositions containing coated metal flakes |
| US3697070A (en) * | 1970-06-19 | 1972-10-10 | Mobil Oil Corp | Metallizing coating compositions |
| US3689346A (en) * | 1970-09-29 | 1972-09-05 | Rowland Dev Corp | Method for producing retroreflective material |
| US3684348A (en) * | 1970-09-29 | 1972-08-15 | Rowland Dev Corp | Retroreflective material |
| US3810804A (en) * | 1970-09-29 | 1974-05-14 | Rowland Dev Corp | Method of making retroreflective material |
| US3712706A (en) * | 1971-01-04 | 1973-01-23 | American Cyanamid Co | Retroreflective surface |
| US3988494A (en) * | 1972-04-10 | 1976-10-26 | Mobil Oil Corporation | Metallizing coating compositions |
| US3935359A (en) * | 1972-06-23 | 1976-01-27 | Rowland Development Corporation | Retroreflective sheeting and method and apparatus for producing same |
| US3811983A (en) * | 1972-06-23 | 1974-05-21 | Rowland Dev Corp | Method for producing retroreflective sheeting |
| US3830682A (en) * | 1972-11-06 | 1974-08-20 | Rowland Dev Corp | Retroreflecting signs and the like with novel day-night coloration |
| US3873184A (en) * | 1973-02-16 | 1975-03-25 | Amerace Esna Corp | Reflector with interspersed angled reflex elements |
| US3926402A (en) * | 1973-04-24 | 1975-12-16 | Amerace Corp | Pin having nonaligned cube axis and pin axis and bundle of such pins |
| US3923378A (en) * | 1973-04-24 | 1975-12-02 | Amerace Corp | Cube-corner reflector with non-aligned cube axes and element axes |
| US3987229A (en) * | 1973-11-19 | 1976-10-19 | Reneer Films Corporation | Calendered film/plastisol film laminate structure |
| FR2288005A1 (fr) * | 1974-10-17 | 1976-05-14 | Greenwood William | Perfectionnements apportes aux procedes de decoration de produits et produits obtenus a l'aide de ces perfectionnements |
| USRE29396E (en) * | 1975-02-18 | 1977-09-13 | Amerace Corporation | Pin having nonaligned cube axis and pin axis and bundle of such pins |
| US3992080A (en) * | 1975-06-13 | 1976-11-16 | Reflexite Corporation | Retroreflective sheet material with controlled stretch and method of making same |
| US4025159A (en) * | 1976-02-17 | 1977-05-24 | Minnesota Mining And Manufacturing Company | Cellular retroreflective sheeting |
| US4066331A (en) * | 1976-06-25 | 1978-01-03 | Beatrice Foods Co. | Cube corner type retroreflectors with improved cube corner unit relationships |
| US4349598A (en) * | 1976-12-01 | 1982-09-14 | Minnesota Mining And Manufacturing Company | High incidence angle retroreflective material |
| US4202600A (en) * | 1978-04-24 | 1980-05-13 | Avery International Corporation | Diced retroreflective sheeting |
| US4668558A (en) * | 1978-07-20 | 1987-05-26 | Minnesota Mining And Manufacturing Company | Shaped plastic articles having replicated microstructure surfaces |
| US4576850A (en) * | 1978-07-20 | 1986-03-18 | Minnesota Mining And Manufacturing Company | Shaped plastic articles having replicated microstructure surfaces |
| US4189209A (en) * | 1978-10-13 | 1980-02-19 | Ferro Corporation | Retroreflector of integrated light reflecting units of varying configurations |
| US4243618A (en) * | 1978-10-23 | 1981-01-06 | Avery International Corporation | Method for forming retroreflective sheeting |
| EP0018798B1 (en) * | 1978-11-08 | 1983-06-08 | LUCAS INDUSTRIES public limited company | Reflex reflector device |
| US4332847A (en) * | 1979-09-20 | 1982-06-01 | Relfexite Corporation | Method for compression molding of retroreflective sheeting and sheeting produced thereby |
| US4601861A (en) * | 1982-09-30 | 1986-07-22 | Amerace Corporation | Methods and apparatus for embossing a precision optical pattern in a resinous sheet or laminate |
| US4486363A (en) * | 1982-09-30 | 1984-12-04 | Amerace Corporation | Method and apparatus for embossing a precision optical pattern in a resinous sheet |
| US4588258A (en) * | 1983-09-12 | 1986-05-13 | Minnesota Mining And Manufacturing Company | Cube-corner retroreflective articles having wide angularity in multiple viewing planes |
| US4801183A (en) * | 1984-08-07 | 1989-01-31 | Pilkington P.E. Limited | Infra-red optical systems |
| US4712868A (en) * | 1985-09-23 | 1987-12-15 | Minnesota Mining And Manufacturing Company | Expanded retroreflective sheet material |
| US4775219A (en) * | 1986-11-21 | 1988-10-04 | Minnesota Mining & Manufacturing Company | Cube-corner retroreflective articles having tailored divergence profiles |
| US4938563A (en) * | 1986-11-21 | 1990-07-03 | Minnesota Mining And Manufacturing Company | High efficiency cube corner retroflective material |
| US4801193A (en) * | 1988-03-04 | 1989-01-31 | Reflexite Corporation | Retroreflective sheet material and method of making same |
| US4895428A (en) * | 1988-07-26 | 1990-01-23 | Minnesota Mining And Manufacturing Company | High efficiency retroreflective material |
| JPH03124754A (ja) * | 1989-10-09 | 1991-05-28 | Mitsubishi Rayon Co Ltd | 耐衝撃性フイルム |
| US5202180A (en) * | 1990-02-06 | 1993-04-13 | Avery Dennison Corporation | Decorative web |
| US5138488A (en) * | 1990-09-10 | 1992-08-11 | Minnesota Mining And Manufacturing Company | Retroreflective material with improved angularity |
| ZA918849B (en) * | 1990-12-06 | 1992-08-26 | Minnesota Mining & Mfg | Articles exhibiting durable fluorescence |
| US5084782A (en) * | 1990-12-20 | 1992-01-28 | Eastman Kodak Company | Decorative tape |
| US5152917B1 (en) * | 1991-02-06 | 1998-01-13 | Minnesota Mining & Mfg | Structured abrasive article |
| US5213872A (en) * | 1991-04-19 | 1993-05-25 | Stimsonite Corporation | Preprinted retroreflective highway sign and method for making the sign |
| US5276075A (en) * | 1991-10-30 | 1994-01-04 | Binney & Smith Inc. | Washable acrylic paint |
| JPH05209142A (ja) * | 1992-01-30 | 1993-08-20 | Mazda Motor Corp | 塗装用光輝材 |
| US5435816A (en) * | 1993-01-14 | 1995-07-25 | Minnesota Mining And Manufacturing Company | Method of making an abrasive article |
| US5272562A (en) * | 1993-02-05 | 1993-12-21 | Minnesota Mining And Manufacturing Company | Cube-corner retroreflective articles |
| WO1995003558A1 (en) * | 1993-07-19 | 1995-02-02 | Reflexite Corporation | Retroreflective structure |
| US5362374A (en) * | 1993-08-27 | 1994-11-08 | Chang Jung Ming | Method for making decorative stickers |
| EP0724737B1 (en) * | 1993-10-20 | 1998-07-22 | Minnesota Mining And Manufacturing Company | Ultra-flexible retroreflective cube corner composite sheetings and methods of manufacture |
| EP0724739B1 (en) * | 1993-10-20 | 1999-09-08 | Minnesota Mining And Manufacturing Company | Raised zone retroreflective cube corner article and method of manufacture |
| US5450235A (en) * | 1993-10-20 | 1995-09-12 | Minnesota Mining And Manufacturing Company | Flexible cube-corner retroreflective sheeting |
| US5454844A (en) * | 1993-10-29 | 1995-10-03 | Minnesota Mining And Manufacturing Company | Abrasive article, a process of making same, and a method of using same to finish a workpiece surface |
| USD366365S (en) | 1994-05-11 | 1996-01-23 | Minnesota Mining And Manufacturing Company | Coated abrasive sheet article |
| US5512219A (en) * | 1994-06-03 | 1996-04-30 | Reflexite Corporation | Method of casting a microstructure sheet having an array of prism elements using a reusable polycarbonate mold |
| WO1996010197A1 (en) * | 1994-09-28 | 1996-04-04 | Reflexite Corporation | Retroreflective tilted prism structure |
| US5470058A (en) * | 1994-09-30 | 1995-11-28 | Lisco, Inc. | High visibility inflated game ball |
| US5485311A (en) * | 1995-01-06 | 1996-01-16 | Mcallister; Richard | Method of increasing retroreflective brightness in a retroreflective sheet material |
| WO1996030786A1 (en) * | 1995-03-27 | 1996-10-03 | Reflexite Corporation | Retroreflective prism arrays with uniform light distribution |
| US6143224A (en) * | 1995-05-18 | 2000-11-07 | Reflexite Corporation | Method for forming a retroreflective sheeting |
| US5592330A (en) * | 1995-05-19 | 1997-01-07 | Reflexite Corporation | Retroreflective prism arrays with formed air spheres therein |
-
1996
- 1996-04-30 US US08/641,126 patent/US5763049A/en not_active Expired - Lifetime
- 1996-08-28 KR KR10-1998-0708683A patent/KR100400910B1/ko not_active Expired - Fee Related
- 1996-08-28 EP EP96930653A patent/EP0896682B1/en not_active Expired - Lifetime
- 1996-08-28 BR BR9612603A patent/BR9612603A/pt not_active Application Discontinuation
- 1996-08-28 AT AT96930653T patent/ATE208047T1/de not_active IP Right Cessation
- 1996-08-28 DE DE69616601T patent/DE69616601T2/de not_active Expired - Fee Related
- 1996-08-28 CN CN96180277A patent/CN1129010C/zh not_active Expired - Fee Related
- 1996-08-28 JP JP9538838A patent/JP2000509165A/ja not_active Ceased
- 1996-08-28 AU AU69625/96A patent/AU706087B2/en not_active Ceased
- 1996-08-28 WO PCT/US1996/014034 patent/WO1997041463A1/en not_active Ceased
- 1996-08-28 CA CA002252854A patent/CA2252854A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| BR9612603A (pt) | 1999-06-29 |
| KR20000065094A (ko) | 2000-11-06 |
| KR100400910B1 (ko) | 2003-12-24 |
| AU706087B2 (en) | 1999-06-10 |
| WO1997041463A1 (en) | 1997-11-06 |
| AU6962596A (en) | 1997-11-19 |
| CN1129010C (zh) | 2003-11-26 |
| ATE208047T1 (de) | 2001-11-15 |
| JP2000509165A (ja) | 2000-07-18 |
| DE69616601D1 (de) | 2001-12-06 |
| EP0896682A1 (en) | 1999-02-17 |
| CN1217065A (zh) | 1999-05-19 |
| EP0896682B1 (en) | 2001-10-31 |
| DE69616601T2 (de) | 2002-06-20 |
| US5763049A (en) | 1998-06-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA2252854A1 (en) | Formed ultra-flexible retroreflective cube-corner composite sheeting with target optical properties and method for making same | |
| EP0896680B1 (en) | Glittering cube-corner article | |
| AU719746B2 (en) | Glittering cube-corner retroreflective sheeting | |
| EP0896683B1 (en) | Method of making glittering cube-corner retroreflective sheeting | |
| US5814355A (en) | Mold for producing glittering cube-corner retroreflective sheeting | |
| EP0724737B1 (en) | Ultra-flexible retroreflective cube corner composite sheetings and methods of manufacture | |
| US5512219A (en) | Method of casting a microstructure sheet having an array of prism elements using a reusable polycarbonate mold | |
| CA2509055C (en) | Retroreflector with controlled divergence made by the method of localized substrate stress | |
| WO1999023516A1 (en) | Cube corner article with altered inactive areas and method of making same | |
| RU2173471C2 (ru) | Формованный сверхгибкий композитный световозвращающий листовой материал с кубическими уголковыми элементами, имеющий заданные оптические характеристики, и способ его изготовления | |
| CA2252433C (en) | Glittering cube-corner retroreflective sheeting | |
| MXPA98008962A (en) | Material in layers composed of retrorreflector cube corners, ultraflexible, conformed with optical objective properties and a method for the manufacture of the | |
| CA2521906A1 (en) | Method of making glittering cube-corner retroreflective sheeting |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FZDE | Discontinued |