CA2218271A1 - Method of fabrication of complex alkali mental hydrides - Google Patents

Method of fabrication of complex alkali mental hydrides Download PDF

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Publication number
CA2218271A1
CA2218271A1 CA002218271A CA2218271A CA2218271A1 CA 2218271 A1 CA2218271 A1 CA 2218271A1 CA 002218271 A CA002218271 A CA 002218271A CA 2218271 A CA2218271 A CA 2218271A CA 2218271 A1 CA2218271 A1 CA 2218271A1
Authority
CA
Canada
Prior art keywords
hydride
hydrides
hydrogen
complex
alkali metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002218271A
Other languages
English (en)
French (fr)
Inventor
John O. Strom-Olsen
Leszek Zaluski
Alicja Zaluska
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
McGill University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by McGill University filed Critical McGill University
Priority to CA002218271A priority Critical patent/CA2218271A1/en
Priority to CA002305717A priority patent/CA2305717A1/en
Priority to AU93344/98A priority patent/AU9334498A/en
Priority to JP2000515828A priority patent/JP2001519312A/ja
Priority to PCT/CA1998/000927 priority patent/WO1999019250A1/en
Priority to DE69823686T priority patent/DE69823686T2/de
Priority to EP98946187A priority patent/EP1025040B1/en
Publication of CA2218271A1 publication Critical patent/CA2218271A1/en
Priority to US09/544,977 priority patent/US6251349B1/en
Abandoned legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B6/00Hydrides of metals including fully or partially hydrided metals, alloys or intermetallic compounds ; Compounds containing at least one metal-hydrogen bond, e.g. (GeH3)2S, SiH GeH; Monoborane or diborane; Addition complexes thereof
    • C01B6/24Hydrides containing at least two metals; Addition complexes thereof
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/0005Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
    • C01B3/001Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
    • C01B3/0031Intermetallic compounds; Metal alloys; Treatment thereof
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/32Hydrogen storage

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Powder Metallurgy (AREA)
CA002218271A 1997-10-10 1997-10-10 Method of fabrication of complex alkali mental hydrides Abandoned CA2218271A1 (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
CA002218271A CA2218271A1 (en) 1997-10-10 1997-10-10 Method of fabrication of complex alkali mental hydrides
CA002305717A CA2305717A1 (en) 1997-10-10 1998-09-30 Method of fabrication of complex alkali metal hydrides
AU93344/98A AU9334498A (en) 1997-10-10 1998-09-30 Method of fabrication of complex alkali metal hydrides
JP2000515828A JP2001519312A (ja) 1997-10-10 1998-09-30 複合体アルカリ金属水素化物の製造方法
PCT/CA1998/000927 WO1999019250A1 (en) 1997-10-10 1998-09-30 Method of fabrication of complex alkali metal hydrides
DE69823686T DE69823686T2 (de) 1997-10-10 1998-09-30 Verfahren zur herstellung komplexer alkalimetallhydriden
EP98946187A EP1025040B1 (en) 1997-10-10 1998-09-30 Method of fabrication of complex alkali metal hydrides
US09/544,977 US6251349B1 (en) 1997-10-10 2000-04-07 Method of fabrication of complex alkali metal hydrides

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CA002218271A CA2218271A1 (en) 1997-10-10 1997-10-10 Method of fabrication of complex alkali mental hydrides

Publications (1)

Publication Number Publication Date
CA2218271A1 true CA2218271A1 (en) 1999-04-10

Family

ID=4161628

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002218271A Abandoned CA2218271A1 (en) 1997-10-10 1997-10-10 Method of fabrication of complex alkali mental hydrides

Country Status (7)

Country Link
US (1) US6251349B1 (enExample)
EP (1) EP1025040B1 (enExample)
JP (1) JP2001519312A (enExample)
AU (1) AU9334498A (enExample)
CA (1) CA2218271A1 (enExample)
DE (1) DE69823686T2 (enExample)
WO (1) WO1999019250A1 (enExample)

Families Citing this family (44)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19758384C2 (de) * 1997-12-23 2002-08-01 Geesthacht Gkss Forschung Verfahren zur Herstellung nanokristalliner Metallhydride
JP2001253702A (ja) * 2000-03-08 2001-09-18 Toyota Central Res & Dev Lab Inc 水素発生方法及び水素発生材料
DE10012794A1 (de) * 2000-03-16 2001-09-20 Studiengesellschaft Kohle Mbh Verfahren zur reversiblen Speicherung von Wasserstoff auf der Basis von Alkalimetallen und Aluminium
DE10049097B4 (de) * 2000-09-27 2004-08-26 Chemetall Gmbh Verfahren zur Trocknung von organischen Flüssigelektrolyten
US6680042B1 (en) * 2000-11-07 2004-01-20 Hydro-Quebec Method of rapidly carrying out a hydrogenation of a hydrogen storage material
JP4115119B2 (ja) * 2001-04-06 2008-07-09 株式会社水素エネルギー研究所 テトラヒドロホウ酸アルカリ金属塩の製造方法
SG117426A1 (en) * 2001-10-31 2005-12-29 Univ Singapore Method for alkali hydride formation and materials for hydrogen storage
US6680043B2 (en) * 2001-11-29 2004-01-20 General Motors Corporation Process for enhancing the kinetics of hydrogenation/dehydrogenation of MAIH4 and MBH4 metal hydrides for reversible hydrogen storage
DE10163697A1 (de) * 2001-12-21 2003-07-03 Studiengesellschaft Kohle Mbh Reversible Speicherung von Wasserstoff mit Hilfe von dotierten Alkalimetallaluminiumhydriden
US6793909B2 (en) * 2002-01-29 2004-09-21 Sandia National Laboratories Direct synthesis of catalyzed hydride compounds
US6593017B1 (en) * 2002-01-30 2003-07-15 Energy Conversion Devices, Inc. High capacity calcium lithium based hydrogen storage material and method of making the same
CA2389939A1 (en) * 2002-06-25 2003-12-25 Alicja Zaluska New type of catalytic materials based on active metal-hydrogen-electronegative element complexes for reactions involving hydrogen transfer
EP1558520B1 (en) * 2002-11-01 2011-01-26 Savannah River Nuclear Solutions, LLC Complex hydrides for hydrogen storage
US7354461B2 (en) 2003-02-28 2008-04-08 Uop Llc Solid fuels for fuel cells
US20070104998A1 (en) * 2003-02-28 2007-05-10 Towler Gavin P Solid Fuel Devices for Fuel Cells
GB0308253D0 (en) * 2003-04-10 2003-05-14 Univ Birmingham Metal hydride synthesis and hydrogen store
US7037632B2 (en) * 2003-09-25 2006-05-02 Samsung Electronics Co. Ltd. Organophotoreceptor with charge transport material with fluorenone azine groups
CN1938220B (zh) * 2004-03-26 2010-05-05 通用汽车公司 可逆储氢体系及其使用方法
US7462344B2 (en) * 2004-03-26 2008-12-09 Gm Global Technology Operations, Inc. Methods for reversibly storing hydrogen
TWI314918B (en) * 2004-04-12 2009-09-21 Rohm And Haas Compan Process for production of a borohydride compound
JP2006008446A (ja) * 2004-06-25 2006-01-12 Toyota Central Res & Dev Lab Inc 水素貯蔵方法、水素貯蔵物質、およびそれを用いた燃料電池システム
US20110180753A1 (en) * 2008-02-22 2011-07-28 Toyota Motor Engineering & Manufacturing North America, Inc. Destabilized and catalyzed borohydride for reversible hydrogen storage
US20060194695A1 (en) * 2004-08-27 2006-08-31 Westinghouse Savannah River Co., Llc Destabilized and catalyzed borohydrided for reversible hydrogen storage
US20060067878A1 (en) * 2004-09-27 2006-03-30 Xia Tang Metal alanates doped with oxygen
DE102004061286B4 (de) 2004-12-14 2021-09-16 Helmholtz-Zentrum Geesthacht Zentrum für Material- und Küstenforschung GmbH Wasserstoff speicherndes Kompositmaterial sowie eine Vorrichtung zur reversiblen Speicherung von Wasserstoff
CA2529427C (en) * 2004-12-17 2011-03-15 University Of New Brunswick Synthesis, recharging and processing of hydrogen storage materials using supercritical fluids
DE102005010700A1 (de) * 2005-03-09 2006-09-14 Studiengesellschaft Kohle Mbh Verfahren zur Synthese von Verbindungen
US20070264182A1 (en) * 2005-03-22 2007-11-15 Gm Global Technology Operations, Inc. Reversible hydrogen storage systems
US7455821B2 (en) * 2005-04-04 2008-11-25 Rohm And Haas Company Process for production of a borohydride compound
DE102005019108B4 (de) * 2005-04-25 2008-11-06 Gkss-Forschungszentrum Geesthacht Gmbh Verwendung von Diamantpulver zur Herstellung von Metallhydriden
US20070192710A1 (en) * 2006-02-15 2007-08-16 Frank Platz Lean context driven user interface
WO2007106513A2 (en) * 2006-03-13 2007-09-20 University Of Utah Research Foundation Hydrogen storage in a combined mxaih6/m'y(nh2)z system and a methods of making and using the same
NO327822B1 (no) * 2006-05-16 2009-10-05 Inst Energiteknik Fremgangsmate for fremstilling av AlH3 og strukturelt relaterte faser, og anvendelse av slikt materiale
US7608233B1 (en) * 2007-02-12 2009-10-27 Sandia Corporation Direct synthesis of calcium borohydride
US8147788B1 (en) * 2007-05-24 2012-04-03 Sandia Corporation Direct synthesis of magnesium borohydride
GB0715649D0 (en) 2007-08-10 2007-09-19 Isis Innovation Hydrogen storage material
US8153020B1 (en) 2008-03-19 2012-04-10 University Of South Florida Hydrogen-storing hydride complexes
US20100233076A1 (en) * 2008-09-18 2010-09-16 Ford Global Technologies, Llc Hydrogen Storage Materials
JP2011005485A (ja) * 2009-06-16 2011-01-13 Toyota Motor Engineering & Manufacturing North America Inc 可逆的な水素貯蔵のための不安定化及び触媒された水素化ホウ素
US8377415B2 (en) 2010-12-07 2013-02-19 Savannah River Nuclear Solutions, Llc Methods for synthesizing alane without the formation of adducts and free of halides
WO2016156195A2 (de) * 2015-04-02 2016-10-06 Rockwood Lithium GmbH Hochreaktive metallhydride, verfahren zu deren herstellung und anwendung
US11453585B2 (en) 2019-07-30 2022-09-27 Savannah River Nuclear Solutions, Llc Formation of high quality alane
US11430512B2 (en) * 2020-06-29 2022-08-30 Taiwan Semiconductor Manufacturing Company Limited Semiconducting metal oxide memory device using hydrogen-mediated threshold voltage modulation and methods for forming the same
CN114702006A (zh) * 2022-03-31 2022-07-05 浙江工业大学 一种碱金属铝配位氢化物的合成方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2067844A5 (en) * 1969-11-19 1971-08-20 France Etat Lithium dialuminium heptahydride prepn
DE19526434A1 (de) * 1995-07-19 1997-01-23 Studiengesellschaft Kohle Mbh Verfahren zur reversilben Speicherung von Wasserstoff
US5882623A (en) * 1996-05-13 1999-03-16 Hydro Quebec Method for inducing hydrogen desorption from a metal hydride

Also Published As

Publication number Publication date
DE69823686D1 (de) 2004-06-09
US6251349B1 (en) 2001-06-26
WO1999019250A1 (en) 1999-04-22
AU9334498A (en) 1999-05-03
EP1025040B1 (en) 2004-05-06
EP1025040A1 (en) 2000-08-09
DE69823686T2 (de) 2005-04-21
JP2001519312A (ja) 2001-10-23

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Legal Events

Date Code Title Description
FZDE Discontinued