CA2103939C - Process and reactor for the preparation of a gas which is rich in hydrogen and/or carbon monoxide - Google Patents

Process and reactor for the preparation of a gas which is rich in hydrogen and/or carbon monoxide Download PDF

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Publication number
CA2103939C
CA2103939C CA002103939A CA2103939A CA2103939C CA 2103939 C CA2103939 C CA 2103939C CA 002103939 A CA002103939 A CA 002103939A CA 2103939 A CA2103939 A CA 2103939A CA 2103939 C CA2103939 C CA 2103939C
Authority
CA
Canada
Prior art keywords
reactor
steam
upper portion
reforming catalyst
feedstock
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CA002103939A
Other languages
English (en)
French (fr)
Other versions
CA2103939A1 (en
Inventor
Ivar Ivarsen Primdahl
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Topsoe AS
Original Assignee
Haldor Topsoe AS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Haldor Topsoe AS filed Critical Haldor Topsoe AS
Publication of CA2103939A1 publication Critical patent/CA2103939A1/en
Application granted granted Critical
Publication of CA2103939C publication Critical patent/CA2103939C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/02—Apparatus characterised by being constructed of material selected for its chemically-resistant properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J15/00—Chemical processes in general for reacting gaseous media with non-particulate solids, e.g. sheet material; Apparatus specially adapted therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/36—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using oxygen; using mixtures containing oxygen as gasifying agents
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/382—Processes with two or more reaction steps, of which at least one is catalytic, e.g. steam reforming and partial oxidation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00477—Controlling the temperature by thermal insulation means
    • B01J2208/00495—Controlling the temperature by thermal insulation means using insulating materials or refractories
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00504—Controlling the temperature by means of a burner
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/02—Apparatus characterised by their chemically-resistant properties
    • B01J2219/0204—Apparatus characterised by their chemically-resistant properties comprising coatings on the surfaces in direct contact with the reactive components
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/82—Several process steps of C01B2203/02 - C01B2203/08 integrated into a single apparatus

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Catalysts (AREA)
CA002103939A 1992-08-13 1993-08-12 Process and reactor for the preparation of a gas which is rich in hydrogen and/or carbon monoxide Expired - Lifetime CA2103939C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DKDK1013/92 1992-08-13
DK101392A DK169614B1 (da) 1992-08-13 1992-08-13 Fremgangsmåde og reaktor til fremstilling af hydrogen- og carbonmonoxidrige gasser

Publications (2)

Publication Number Publication Date
CA2103939A1 CA2103939A1 (en) 1994-02-14
CA2103939C true CA2103939C (en) 2000-04-25

Family

ID=8100018

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002103939A Expired - Lifetime CA2103939C (en) 1992-08-13 1993-08-12 Process and reactor for the preparation of a gas which is rich in hydrogen and/or carbon monoxide

Country Status (7)

Country Link
US (1) US5958297A (https=)
EP (1) EP0583211B1 (https=)
JP (1) JP2716650B2 (https=)
CA (1) CA2103939C (https=)
DE (1) DE69300627T2 (https=)
DK (1) DK169614B1 (https=)
RU (1) RU2109560C1 (https=)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2726821B1 (fr) * 1994-11-16 1997-01-03 Patillet Henri Procede et appareil de production de methanol par gazeification de matieres carbonees
MY128194A (en) * 1997-04-11 2007-01-31 Chiyoda Corp Process for the production of synthesis gas
AU6749398A (en) * 1997-04-11 1998-11-11 Chiyoda Corporation Process for preparing synthesis gas by autothermal reforming
DE69925052T2 (de) * 1998-01-21 2006-03-02 Haldor Topsoe A/S Verfahren zur Herstellung von wasserstoffreichem Gas
DE69808521T2 (de) 1998-07-21 2003-01-30 Haldor Topsoee A/S, Lyngby Synthesegasherstellung durch dampfreformierung
FR2789691B1 (fr) 1999-02-11 2001-04-27 Inst Francais Du Petrole Procede de synthese de distillat atmospherique comprenant l'utilisation de la technologie fischer-tropsch
ES2218012T3 (es) * 1999-03-05 2004-11-16 Haldor Topsoe A/S Procedimiento para reformado catalitico autotermico con vapor.
TWI241392B (en) 1999-09-20 2005-10-11 Japan Science & Tech Agency Apparatus and method for gasifying solid or liquid fuel
EP1116689A1 (en) * 2000-01-11 2001-07-18 Haldor Topsoe A/S Process and reactor for the preparation of hydrogen and carbon monoxide rich gas
US20030228267A1 (en) * 2001-07-09 2003-12-11 Aust Duncan T. Suncreen composition wit enhanced spf and water resistant properties
DE60143610D1 (de) 2000-07-10 2011-01-20 Versa Power Systems Ltd Integriertes modul für festoxid-brennstoffzellensystem
US6387843B1 (en) 2001-04-05 2002-05-14 Chiyoda Corporation Method of preparing Rh- and/or Ru-catalyst supported on MgO carrier and reforming process using the catalyst
US6656978B2 (en) 2001-04-05 2003-12-02 Chiyoda Corporation Process of producing liquid hydrocarbon oil or dimethyl ether from lower hydrocarbon gas containing carbon dioxide
EP1403215B1 (en) 2002-09-26 2013-03-13 Haldor Topsoe A/S Process and apparatus for the preparation of synthesis gas
EP1403217A1 (en) 2002-09-26 2004-03-31 Haldor Topsoe A/S Process and apparatus for the preparation of synthesis gas
ATE548324T1 (de) 2003-02-05 2012-03-15 Haldor Topsoe As Verfahren zur aufbereitung von synthesegas
US7037485B1 (en) * 2004-11-18 2006-05-02 Praxair Technology, Inc. Steam methane reforming method
EP1838611B1 (en) 2004-11-18 2013-09-25 Praxair Technology, Inc. Steam methane reforming method
US20070013144A1 (en) * 2005-07-13 2007-01-18 Seungdoo Park Reactor sealing methods
DE102014004264A1 (de) * 2014-03-14 2015-09-17 Universität Stuttgart Wärmeintegrierte Hochtemperatur-Reaktoren für die autotherme partielle Oxidation
DK201600605A1 (en) 2016-10-07 2018-04-16 Haldor Topsoe As Combustion Chamber Hot Face Refractory Lining

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2655442A (en) * 1948-08-23 1953-10-13 Phillips Petroleum Co Process and apparatus for the manufacture of synthesis gas
US2943062A (en) * 1956-01-19 1960-06-28 Kellogg M W Co Conversion of hydrocarbons to a hydrogen-rich gas
US3071454A (en) * 1960-08-04 1963-01-01 Phelps Dodge Corp Apparatus for reforming gases
CA944563A (en) * 1971-12-02 1974-04-02 Robert W. Pfeiffer Process and apparatus for reforming hydrocarbon oils
US3920579A (en) * 1974-04-24 1975-11-18 Texaco Inc Synthesis gas production by partial oxidation
SU811551A1 (ru) * 1977-07-08 1982-12-15 Ордена Трудового Красного Знамени Институт Катализа Со Ан Ссср Способ получени трехокиси серы
US4456703A (en) * 1982-05-07 1984-06-26 Exxon Research And Engineering Co. High surface area nickel aluminate spinel catalyst for steam reforming
DE3382193D1 (de) * 1982-09-30 1991-04-11 Engelhard Corp Verfahren zur herstellung von wasserstoffreichem gas aus kohlenwasserstoffen.
US4863707A (en) * 1982-09-30 1989-09-05 Engelhard Corporation Method of ammonia production
IN160096B (https=) * 1982-12-02 1987-06-27 Exxon Research Engineering Co
GB8309359D0 (en) * 1983-04-06 1983-05-11 Ici Plc Synthesis gas
DE3663652D1 (en) * 1985-03-05 1989-07-06 Ici Plc Steam reforming hydrocarbons
ES2019383B3 (es) * 1986-05-27 1991-06-16 Ici Plc Metodo para iniciar un proceso para la produccion de una corriente gaseosa que contiene hidrogeno y oxidos de carbono.
FR2608581B1 (fr) * 1986-12-18 1989-04-28 Inst Francais Du Petrole Procede et dispositif operant par voie de flamme pour la fabrication de gaz de synthese
JPH01261201A (ja) * 1988-04-12 1989-10-18 Mitsubishi Gas Chem Co Inc 炭化水素改質反応器

Also Published As

Publication number Publication date
DE69300627D1 (de) 1995-11-16
RU2109560C1 (ru) 1998-04-27
JPH06279002A (ja) 1994-10-04
CA2103939A1 (en) 1994-02-14
DE69300627T2 (de) 1996-03-21
DK101392D0 (da) 1992-08-13
JP2716650B2 (ja) 1998-02-18
EP0583211A2 (en) 1994-02-16
DK169614B1 (da) 1994-12-27
EP0583211B1 (en) 1995-10-11
US5958297A (en) 1999-09-28
DK101392A (da) 1994-02-14
EP0583211A3 (https=) 1994-03-23

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