CA2056937A1 - Dispositif electrochromique a l'etat solide avec electrolyte polymerique conducteur protonique - Google Patents

Dispositif electrochromique a l'etat solide avec electrolyte polymerique conducteur protonique

Info

Publication number
CA2056937A1
CA2056937A1 CA2056937A CA2056937A CA2056937A1 CA 2056937 A1 CA2056937 A1 CA 2056937A1 CA 2056937 A CA2056937 A CA 2056937A CA 2056937 A CA2056937 A CA 2056937A CA 2056937 A1 CA2056937 A1 CA 2056937A1
Authority
CA
Canada
Prior art keywords
electrochromic
disclosed
proton
polymer electrolyte
copolymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA2056937A
Other languages
English (en)
Other versions
CA2056937C (fr
Inventor
Kuo-Chuan Ho
Thomas G. Rukavina
Ralph E. Spindler
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
PPG Industries Ohio Inc
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US07/633,894 external-priority patent/US5209980A/en
Priority claimed from US07/633,893 external-priority patent/US5161048A/en
Priority claimed from US07/633,895 external-priority patent/US5215821A/en
Application filed by Individual filed Critical Individual
Publication of CA2056937A1 publication Critical patent/CA2056937A1/fr
Application granted granted Critical
Publication of CA2056937C publication Critical patent/CA2056937C/fr
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K9/00—Tenebrescent materials, i.e. materials for which the range of wavelengths for energy absorption is changed as a result of excitation by some form of energy
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/15—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect
    • G02F1/1514—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect characterised by the electrochromic material, e.g. by the electrodeposited material
    • G02F1/1523—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect characterised by the electrochromic material, e.g. by the electrodeposited material comprising inorganic material
    • G02F1/1524—Transition metal compounds
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/15—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect
    • G02F1/1514—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect characterised by the electrochromic material, e.g. by the electrodeposited material
    • G02F1/1523—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect characterised by the electrochromic material, e.g. by the electrodeposited material comprising inorganic material
    • G02F1/1525—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect characterised by the electrochromic material, e.g. by the electrodeposited material comprising inorganic material characterised by a particular ion transporting layer, e.g. electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
    • H01B1/122—Ionic conductors
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0565—Polymeric materials, e.g. gel-type or solid-type
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/15—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect
    • G02F2001/1502—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect complementary cell
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/15—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect
    • G02F1/1514—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect characterised by the electrochromic material, e.g. by the electrodeposited material
    • G02F1/1516—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect characterised by the electrochromic material, e.g. by the electrodeposited material comprising organic material
    • G02F2001/1517—Cyano complex compounds, e.g. Prussian blue
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Nonlinear Science (AREA)
  • Inorganic Chemistry (AREA)
  • Electrochemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Optics & Photonics (AREA)
  • Manufacturing & Machinery (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Dispersion Chemistry (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Electrochromic Elements, Electrophoresis, Or Variable Reflection Or Absorption Elements (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Conductive Materials (AREA)
  • Manufacturing Of Electric Cables (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
CA002056937A 1990-12-26 1991-12-04 Dispositif electrochromique a l'etat solide avec electrolyte polymerique conducteur protonique Expired - Fee Related CA2056937C (fr)

Applications Claiming Priority (8)

Application Number Priority Date Filing Date Title
US63387090A 1990-12-26 1990-12-26
US633,894 1990-12-26
US633,893 1990-12-26
US07/633,894 US5209980A (en) 1990-12-26 1990-12-26 Transparent counterelectrodes
US633,895 1990-12-26
US07/633,893 US5161048A (en) 1990-12-26 1990-12-26 Electrochromic window with metal grid counter electrode and acidic polyelectrolyte
US07/633,895 US5215821A (en) 1990-12-26 1990-12-26 Solid-state electrochromic device with proton-conducting polymer electrolyte and Prussian blue counterelectrode
US633,870 1990-12-26

Publications (2)

Publication Number Publication Date
CA2056937A1 true CA2056937A1 (fr) 1992-06-27
CA2056937C CA2056937C (fr) 1996-12-10

Family

ID=27505205

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002056937A Expired - Fee Related CA2056937C (fr) 1990-12-26 1991-12-04 Dispositif electrochromique a l'etat solide avec electrolyte polymerique conducteur protonique

Country Status (5)

Country Link
EP (3) EP0737883A3 (fr)
JP (1) JP2617641B2 (fr)
AU (2) AU643093B2 (fr)
CA (1) CA2056937C (fr)
DE (2) DE69124353T2 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113127913A (zh) * 2021-05-08 2021-07-16 山东大学 一种基于自驱动电致变色显示器件的信息加密/解密的方法

Families Citing this family (16)

* Cited by examiner, † Cited by third party
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FR2746934B1 (fr) * 1996-03-27 1998-05-07 Saint Gobain Vitrage Dispositif electrochimique
US5825526A (en) * 1996-04-24 1998-10-20 Minnesota Mining And Manufacturing Company Tape for use in manufacturing electrochromic devices
TWI352252B (en) * 2003-09-18 2011-11-11 Dainippon Ink & Chemicals Ionic conductor and electrochemical display elemen
US7372610B2 (en) 2005-02-23 2008-05-13 Sage Electrochromics, Inc. Electrochromic devices and methods
DE102006002948A1 (de) * 2006-01-21 2007-08-02 Alexander Von Gencsy Sichtsystem mit Stroboskopeffekt
DE102006044069A1 (de) * 2006-09-20 2008-03-27 Bayer Materialscience Ag Elektrochrome Anordnung
AU2008201373B1 (en) 2008-03-26 2009-07-23 University Of South Australia Processes for producing electrochromic substrates and electrochromic articles made therefrom
EP2312386A1 (fr) * 2009-10-05 2011-04-20 Acreo AB Dispositif d'affichage électrochrome à matrice passive
EP2625565B1 (fr) 2010-10-05 2016-05-18 Acreo Swedish ICT AB Dispositif d'affichage électrochrome à matrice passive ayant une tension de seuil
US9709867B2 (en) * 2010-10-05 2017-07-18 Rise Acreo Ab Display device
CN103201676B (zh) * 2010-10-05 2016-11-16 阿克里奥瑞典信息和通信技术研究（Ict)公司 显示装置
EP2695020B1 (fr) 2011-04-05 2016-05-18 Acreo Swedish ICT AB Procédé de fabrication d'un dispositif électrochimiquement actif utilisant l'auto-alignement d'électrolytes sur des électrodes
CN102759835B (zh) * 2012-07-18 2014-10-22 西安科技大学 一种纤维状柔性电致变色器件及其制备方法
KR20190095163A (ko) * 2018-02-05 2019-08-14 연세대학교 산학협력단 투명 전극 및 이를 포함하는 금속-공기 이차 전지
DE202018000981U1 (de) 2018-02-23 2018-04-26 Adrien Jathe Richtungsabhängige Verdunklungstechnik um eine blitzartige automatische helligkeitsgesteuerte progressive sektorale stufenlose Lichtreduzierung zu bewirken (unter sektoral wird die Einteilung des Blickfeldes in viele kleine Sektoren verstanden); anwendbar für Brillen, (Helm-)Visiere und optische Geräte
WO2022035771A1 (fr) * 2020-08-12 2022-02-17 University Of South Florida Dispositifs électrochromiques à électrolyte organique à base d'eau ayant une consommation d'énergie inférieure et une cyclabilité améliorée

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* Cited by examiner, † Cited by third party
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US4116545A (en) * 1976-10-27 1978-09-26 American Cyanamid Company Polymeric electrolyte for electrochromic display devices
US4082551A (en) * 1977-03-31 1978-04-04 Eastman Kodak Company Electrophotographic element containing a multilayer interlayer
US4174152A (en) * 1978-02-13 1979-11-13 American Cyanamid Company Electrochromic devices with polymeric electrolytes
US4331385A (en) * 1979-04-17 1982-05-25 Matsushita Electric Industrial Co., Ltd. Electrochromic display device
JPS56126624U (fr) * 1980-02-26 1981-09-26
EP0038165B1 (fr) * 1980-04-15 1984-07-25 Asahi Glass Company Ltd. Dispositif électro-optique et dispositif de contrôle de lumière électro-optique
US4361385A (en) * 1980-10-23 1982-11-30 American Cyanamid Company Electrochromic device containing acid copolymer electrolyte
JPS59155833A (ja) * 1983-02-25 1984-09-05 Nissan Motor Co Ltd エレクトロクロミツク表示素子
JPS6023835A (ja) * 1983-07-19 1985-02-06 Seiko Instr & Electronics Ltd 電気化学表示素子
JPS6087316A (ja) * 1983-10-20 1985-05-17 Nissan Motor Co Ltd エレクトロクロミツク素子
JPS61138925A (ja) * 1984-12-12 1986-06-26 Tokuyama Soda Co Ltd エレクトロクロミツクデイスプレイ素子
JPS61213828A (ja) * 1985-03-19 1986-09-22 Hitachi Maxell Ltd エレクトロクロミツク表示素子
JPS61219030A (ja) * 1985-03-25 1986-09-29 Nippon Sheet Glass Co Ltd エレクトロクロミツク素子
EP0197465A3 (fr) * 1985-03-29 1991-07-03 Sagami Chemical Research Center Matériaux solides électrochimiquement réactifs et dispositifs à couches minces les utilisant
JPS61261724A (ja) * 1985-05-16 1986-11-19 Alps Electric Co Ltd エレクトロクロミツク表示素子
US4773741A (en) * 1987-04-09 1988-09-27 Central Glass Company, Limited Electrochromic display device having auxiliary electrode
JPS63271321A (ja) * 1987-04-30 1988-11-09 Hidetoshi Tsuchida 全固体高分子系エレクトロクロミツク表示素子
US4768865A (en) * 1987-06-10 1988-09-06 Ppg Industries, Inc. Electrochromic window with metal grid counter electrode
FR2629222B1 (fr) * 1988-03-25 1992-04-30 Saint Gobain Vitrage Vitrage a transmission variable du type electrochrome
JP2716448B2 (ja) * 1988-02-26 1998-02-18 株式会社クラレ 微粒子分散体及びそれを用いる電極の製法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113127913A (zh) * 2021-05-08 2021-07-16 山东大学 一种基于自驱动电致变色显示器件的信息加密/解密的方法

Also Published As

Publication number Publication date
EP0492387B1 (fr) 1997-01-22
JP2617641B2 (ja) 1997-06-04
EP0737883A2 (fr) 1996-10-16
DE69132341D1 (de) 2000-08-31
EP0492387A2 (fr) 1992-07-01
AU643093B2 (en) 1993-11-04
EP0735408A1 (fr) 1996-10-02
DE69132341T2 (de) 2001-02-15
CA2056937C (fr) 1996-12-10
JPH04308819A (ja) 1992-10-30
EP0492387A3 (en) 1993-03-03
AU4447393A (en) 1993-11-11
DE69124353D1 (de) 1997-03-06
EP0737883A3 (fr) 1996-12-11
AU664766B2 (en) 1995-11-30
DE69124353T2 (de) 1997-07-24
EP0735408B1 (fr) 2000-07-26
AU8838391A (en) 1992-07-09

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Effective date: 20021204