CA2044698C - Microbilles de polymere organique chargees utilisees dans la fabrication du papier - Google Patents
Microbilles de polymere organique chargees utilisees dans la fabrication du papier Download PDFInfo
- Publication number
- CA2044698C CA2044698C CA002044698A CA2044698A CA2044698C CA 2044698 C CA2044698 C CA 2044698C CA 002044698 A CA002044698 A CA 002044698A CA 2044698 A CA2044698 A CA 2044698A CA 2044698 C CA2044698 C CA 2044698C
- Authority
- CA
- Canada
- Prior art keywords
- microbead
- ton
- lbs
- cationic
- anionic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000011325 microbead Substances 0.000 title claims abstract description 161
- 238000000034 method Methods 0.000 title claims abstract description 59
- 230000008569 process Effects 0.000 title abstract description 25
- 229920000620 organic polymer Polymers 0.000 title abstract description 6
- 229940037003 alum Drugs 0.000 claims abstract description 54
- 239000000654 additive Substances 0.000 claims abstract description 25
- 229920001282 polysaccharide Polymers 0.000 claims abstract description 22
- 239000005017 polysaccharide Substances 0.000 claims abstract description 22
- 150000004676 glycans Chemical class 0.000 claims abstract 7
- 125000002091 cationic group Chemical group 0.000 claims description 100
- 125000000129 anionic group Chemical group 0.000 claims description 83
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 80
- 229920002472 Starch Polymers 0.000 claims description 55
- 235000019698 starch Nutrition 0.000 claims description 55
- 239000000440 bentonite Substances 0.000 claims description 51
- 229910000278 bentonite Inorganic materials 0.000 claims description 51
- 239000008107 starch Substances 0.000 claims description 51
- 229920000642 polymer Polymers 0.000 claims description 49
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 46
- 239000000377 silicon dioxide Substances 0.000 claims description 39
- 239000000203 mixture Substances 0.000 claims description 38
- 239000002245 particle Substances 0.000 claims description 33
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 27
- 229920000831 ionic polymer Polymers 0.000 claims description 15
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 13
- 239000007787 solid Substances 0.000 claims description 12
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 230000000996 additive effect Effects 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- 239000000701 coagulant Substances 0.000 claims description 2
- 239000000834 fixative Substances 0.000 claims description 2
- 230000014759 maintenance of location Effects 0.000 abstract description 57
- 230000015572 biosynthetic process Effects 0.000 abstract description 17
- 239000000123 paper Substances 0.000 description 59
- 229920006317 cationic polymer Polymers 0.000 description 40
- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 description 38
- 239000000178 monomer Substances 0.000 description 31
- 239000000839 emulsion Substances 0.000 description 30
- 239000011324 bead Substances 0.000 description 21
- 229920001577 copolymer Polymers 0.000 description 20
- 239000004094 surface-active agent Substances 0.000 description 20
- 238000006116 polymerization reaction Methods 0.000 description 18
- -1 polyethylene Polymers 0.000 description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 14
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 14
- 229920006318 anionic polymer Polymers 0.000 description 14
- 239000004530 micro-emulsion Substances 0.000 description 14
- 150000004804 polysaccharides Chemical class 0.000 description 13
- 230000000694 effects Effects 0.000 description 11
- 229920001131 Pulp (paper) Polymers 0.000 description 10
- 229910000019 calcium carbonate Inorganic materials 0.000 description 10
- 229910052757 nitrogen Inorganic materials 0.000 description 10
- 229920002401 polyacrylamide Polymers 0.000 description 10
- 229920001592 potato starch Polymers 0.000 description 10
- 238000012360 testing method Methods 0.000 description 10
- 239000003431 cross linking reagent Substances 0.000 description 9
- 239000004615 ingredient Substances 0.000 description 9
- 239000003921 oil Substances 0.000 description 9
- 230000009467 reduction Effects 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- 229920000126 latex Polymers 0.000 description 8
- 239000012071 phase Substances 0.000 description 8
- PQUXFUBNSYCQAL-UHFFFAOYSA-N 1-(2,3-difluorophenyl)ethanone Chemical compound CC(=O)C1=CC=CC(F)=C1F PQUXFUBNSYCQAL-UHFFFAOYSA-N 0.000 description 7
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 7
- 244000061456 Solanum tuberosum Species 0.000 description 7
- 235000002595 Solanum tuberosum Nutrition 0.000 description 7
- 239000008346 aqueous phase Substances 0.000 description 7
- 235000010216 calcium carbonate Nutrition 0.000 description 7
- 229920006158 high molecular weight polymer Polymers 0.000 description 7
- 229940047670 sodium acrylate Drugs 0.000 description 7
- 239000012190 activator Substances 0.000 description 6
- 239000004927 clay Substances 0.000 description 6
- 229910052570 clay Inorganic materials 0.000 description 6
- 239000000945 filler Substances 0.000 description 6
- 239000001257 hydrogen Substances 0.000 description 6
- 229910052739 hydrogen Inorganic materials 0.000 description 6
- 230000006872 improvement Effects 0.000 description 6
- 229920005684 linear copolymer Polymers 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 5
- 239000004793 Polystyrene Substances 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 239000006185 dispersion Substances 0.000 description 5
- 229920002223 polystyrene Polymers 0.000 description 5
- WTXXSZUATXIAJO-OWBHPGMISA-N (Z)-14-methylpentadec-2-enoic acid Chemical compound CC(CCCCCCCCCC\C=C/C(=O)O)C WTXXSZUATXIAJO-OWBHPGMISA-N 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 4
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 4
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 4
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 4
- 239000008119 colloidal silica Substances 0.000 description 4
- 238000004132 cross linking Methods 0.000 description 4
- 239000008367 deionised water Substances 0.000 description 4
- 229910021641 deionized water Inorganic materials 0.000 description 4
- 239000011121 hardwood Substances 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 150000002430 hydrocarbons Chemical class 0.000 description 4
- 239000012074 organic phase Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 238000004513 sizing Methods 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 102100024133 Coiled-coil domain-containing protein 50 Human genes 0.000 description 3
- QMMFVYPAHWMCMS-UHFFFAOYSA-N Dimethyl sulfide Chemical compound CSC QMMFVYPAHWMCMS-UHFFFAOYSA-N 0.000 description 3
- 101000910772 Homo sapiens Coiled-coil domain-containing protein 50 Proteins 0.000 description 3
- 239000005662 Paraffin oil Substances 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- RKZXQQPEDGMHBJ-LIGJGSPWSA-N [(2s,3r,4r,5r)-2,3,4,5,6-pentakis[[(z)-octadec-9-enoyl]oxy]hexyl] (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCC\C=C/CCCCCCCC)[C@@H](OC(=O)CCCCCCC\C=C/CCCCCCCC)[C@H](OC(=O)CCCCCCC\C=C/CCCCCCCC)[C@@H](OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC RKZXQQPEDGMHBJ-LIGJGSPWSA-N 0.000 description 3
- 238000013019 agitation Methods 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000002296 dynamic light scattering Methods 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 239000005457 ice water Substances 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 239000011859 microparticle Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 229940001584 sodium metabisulfite Drugs 0.000 description 3
- 235000010262 sodium metabisulphite Nutrition 0.000 description 3
- 239000011122 softwood Substances 0.000 description 3
- 238000006467 substitution reaction Methods 0.000 description 3
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 3
- FZGFBJMPSHGTRQ-UHFFFAOYSA-M trimethyl(2-prop-2-enoyloxyethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CCOC(=O)C=C FZGFBJMPSHGTRQ-UHFFFAOYSA-M 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 2
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- 239000004147 Sorbitan trioleate Substances 0.000 description 2
- PRXRUNOAOLTIEF-ADSICKODSA-N Sorbitan trioleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCC\C=C/CCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCC\C=C/CCCCCCCC PRXRUNOAOLTIEF-ADSICKODSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- 229920002522 Wood fibre Polymers 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N alpha-methacrylic acid Natural products CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- 229920006320 anionic starch Polymers 0.000 description 2
- WPKYZIPODULRBM-UHFFFAOYSA-N azane;prop-2-enoic acid Chemical compound N.OC(=O)C=C WPKYZIPODULRBM-UHFFFAOYSA-N 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000009977 dual effect Effects 0.000 description 2
- 238000007720 emulsion polymerization reaction Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 238000012688 inverse emulsion polymerization Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000000693 micelle Substances 0.000 description 2
- 238000012703 microemulsion polymerization Methods 0.000 description 2
- 239000002105 nanoparticle Substances 0.000 description 2
- WTEVQBCEXWBHNA-YFHOEESVSA-N neral Chemical compound CC(C)=CCC\C(C)=C/C=O WTEVQBCEXWBHNA-YFHOEESVSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-M oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC([O-])=O ZQPPMHVWECSIRJ-KTKRTIGZSA-M 0.000 description 2
- 229940049964 oleate Drugs 0.000 description 2
- 229920000768 polyamine Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 229930195734 saturated hydrocarbon Natural products 0.000 description 2
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- FWFUWXVFYKCSQA-UHFFFAOYSA-M sodium;2-methyl-2-(prop-2-enoylamino)propane-1-sulfonate Chemical compound [Na+].[O-]S(=O)(=O)CC(C)(C)NC(=O)C=C FWFUWXVFYKCSQA-UHFFFAOYSA-M 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 235000019337 sorbitan trioleate Nutrition 0.000 description 2
- 229960000391 sorbitan trioleate Drugs 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 229940014800 succinic anhydride Drugs 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- RRHXZLALVWBDKH-UHFFFAOYSA-M trimethyl-[2-(2-methylprop-2-enoyloxy)ethyl]azanium;chloride Chemical compound [Cl-].CC(=C)C(=O)OCC[N+](C)(C)C RRHXZLALVWBDKH-UHFFFAOYSA-M 0.000 description 2
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- 239000002025 wood fiber Substances 0.000 description 2
- LTVDFSLWFKLJDQ-UHFFFAOYSA-N α-tocopherolquinone Chemical compound CC(C)CCCC(C)CCCC(C)CCCC(C)(O)CCC1=C(C)C(=O)C(C)=C(C)C1=O LTVDFSLWFKLJDQ-UHFFFAOYSA-N 0.000 description 2
- CUNWUEBNSZSNRX-RKGWDQTMSA-N (2r,3r,4r,5s)-hexane-1,2,3,4,5,6-hexol;(z)-octadec-9-enoic acid Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O CUNWUEBNSZSNRX-RKGWDQTMSA-N 0.000 description 1
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- FNMJFZYRSQTKIH-HXPMCKFVSA-N (4ar,7as)-2-amino-7a-(2,4-difluorophenyl)-6-(5-fluoro-4-methoxy-6-methylpyrimidin-2-yl)-3-methyl-5,7-dihydro-4ah-pyrrolo[3,4-d]pyrimidin-4-one Chemical compound CC1=C(F)C(OC)=NC(N2C[C@@]3(N=C(N)N(C)C(=O)[C@@H]3C2)C=2C(=CC(F)=CC=2)F)=N1 FNMJFZYRSQTKIH-HXPMCKFVSA-N 0.000 description 1
- UCWYGNTYSWIDSW-QXMHVHEDSA-N (z)-n-[3-(dimethylamino)propyl]octadec-9-enamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)NCCCN(C)C UCWYGNTYSWIDSW-QXMHVHEDSA-N 0.000 description 1
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 description 1
- KSEZPRJUTHMFGZ-UHFFFAOYSA-N 1-(3-ethyl-5,5,8,8-tetramethyl-6,7-dihydronaphthalen-2-yl)ethanone Chemical compound CC1(C)CCC(C)(C)C2=C1C=C(C(C)=O)C(CC)=C2 KSEZPRJUTHMFGZ-UHFFFAOYSA-N 0.000 description 1
- KQHZEKNQJJSVDN-KVVVOXFISA-N 2-(2-hydroxyethylamino)ethanol;(z)-octadec-9-enoic acid Chemical compound OCCNCCO.CCCCCCCC\C=C/CCCCCCCC(O)=O KQHZEKNQJJSVDN-KVVVOXFISA-N 0.000 description 1
- DPBJAVGHACCNRL-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate Chemical class CN(C)CCOC(=O)C=C DPBJAVGHACCNRL-UHFFFAOYSA-N 0.000 description 1
- XHZPRMZZQOIPDS-UHFFFAOYSA-N 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(C)(C)NC(=O)C=C XHZPRMZZQOIPDS-UHFFFAOYSA-N 0.000 description 1
- TURITJIWSQEMDB-UHFFFAOYSA-N 2-methyl-n-[(2-methylprop-2-enoylamino)methyl]prop-2-enamide Chemical compound CC(=C)C(=O)NCNC(=O)C(C)=C TURITJIWSQEMDB-UHFFFAOYSA-N 0.000 description 1
- AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical compound OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 description 1
- WHNPOQXWAMXPTA-UHFFFAOYSA-N 3-methylbut-2-enamide Chemical compound CC(C)=CC(N)=O WHNPOQXWAMXPTA-UHFFFAOYSA-N 0.000 description 1
- CDAONLSCCBFDIN-UHFFFAOYSA-N 4-amino-n,n-dimethyl-2-methylidenebutanamide Chemical class CN(C)C(=O)C(=C)CCN CDAONLSCCBFDIN-UHFFFAOYSA-N 0.000 description 1
- 101150094949 APRT gene Proteins 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 241001135931 Anolis Species 0.000 description 1
- 101100172871 Arabidopsis thaliana EXA1 gene Proteins 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- 101100096977 Caenorhabditis elegans unc-41 gene Proteins 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- WTEVQBCEXWBHNA-UHFFFAOYSA-N Citral Natural products CC(C)=CCCC(C)=CC=O WTEVQBCEXWBHNA-UHFFFAOYSA-N 0.000 description 1
- 241000518994 Conta Species 0.000 description 1
- 229920002261 Corn starch Polymers 0.000 description 1
- 244000303965 Cyamopsis psoralioides Species 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 241000408495 Iton Species 0.000 description 1
- 229920006063 Lamide® Polymers 0.000 description 1
- 241000218652 Larix Species 0.000 description 1
- 235000005590 Larix decidua Nutrition 0.000 description 1
- 244000147568 Laurus nobilis Species 0.000 description 1
- 235000017858 Laurus nobilis Nutrition 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- 235000009421 Myristica fragrans Nutrition 0.000 description 1
- 239000011837 N,N-methylenebisacrylamide Substances 0.000 description 1
- CNCOEDDPFOAUMB-UHFFFAOYSA-N N-Methylolacrylamide Chemical compound OCNC(=O)C=C CNCOEDDPFOAUMB-UHFFFAOYSA-N 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- 240000000543 Pentas lanceolata Species 0.000 description 1
- 241000364051 Pima Species 0.000 description 1
- 101100409194 Rattus norvegicus Ppargc1b gene Proteins 0.000 description 1
- 238000001919 Rayleigh scattering spectroscopy Methods 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 239000004113 Sepiolite Substances 0.000 description 1
- 241000201776 Steno Species 0.000 description 1
- 235000005212 Terminalia tomentosa Nutrition 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229920006322 acrylamide copolymer Polymers 0.000 description 1
- 150000003926 acrylamides Chemical class 0.000 description 1
- 229940048053 acrylate Drugs 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 229920001586 anionic polysaccharide Polymers 0.000 description 1
- 150000004836 anionic polysaccharides Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 239000006085 branching agent Substances 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 229920003118 cationic copolymer Polymers 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 239000012986 chain transfer agent Substances 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- BULLHNJGPPOUOX-UHFFFAOYSA-N chloroacetone Chemical compound CC(=O)CCl BULLHNJGPPOUOX-UHFFFAOYSA-N 0.000 description 1
- WTEVQBCEXWBHNA-JXMROGBWSA-N citral A Natural products CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- JZCCFEFSEZPSOG-UHFFFAOYSA-L copper(II) sulfate pentahydrate Chemical compound O.O.O.O.O.[Cu+2].[O-]S([O-])(=O)=O JZCCFEFSEZPSOG-UHFFFAOYSA-L 0.000 description 1
- 239000008120 corn starch Substances 0.000 description 1
- 229920006037 cross link polymer Polymers 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 125000004386 diacrylate group Chemical group 0.000 description 1
- 125000004985 dialkyl amino alkyl group Chemical group 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 229960001484 edetic acid Drugs 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- UXYBXUYUKHUNOM-UHFFFAOYSA-M ethyl(trimethyl)azanium;chloride Chemical compound [Cl-].CC[N+](C)(C)C UXYBXUYUKHUNOM-UHFFFAOYSA-M 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- IMBKASBLAKCLEM-UHFFFAOYSA-L ferrous ammonium sulfate (anhydrous) Chemical compound [NH4+].[NH4+].[Fe+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O IMBKASBLAKCLEM-UHFFFAOYSA-L 0.000 description 1
- 239000008394 flocculating agent Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000005865 ionizing radiation Effects 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 239000001115 mace Substances 0.000 description 1
- 235000009973 maize Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000012764 mineral filler Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- PNLUGRYDUHRLOF-UHFFFAOYSA-N n-ethenyl-n-methylacetamide Chemical compound C=CN(C)C(C)=O PNLUGRYDUHRLOF-UHFFFAOYSA-N 0.000 description 1
- OFESGEKAXKKFQT-UHFFFAOYSA-N n-ethenyl-n-methylformamide Chemical compound C=CN(C)C=O OFESGEKAXKKFQT-UHFFFAOYSA-N 0.000 description 1
- ILCQQHAOOOVHQJ-UHFFFAOYSA-N n-ethenylprop-2-enamide Chemical compound C=CNC(=O)C=C ILCQQHAOOOVHQJ-UHFFFAOYSA-N 0.000 description 1
- YPHQUSNPXDGUHL-UHFFFAOYSA-N n-methylprop-2-enamide Chemical compound CNC(=O)C=C YPHQUSNPXDGUHL-UHFFFAOYSA-N 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
- QPCDCPDFJACHGM-UHFFFAOYSA-K pentetate(3-) Chemical compound OC(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O QPCDCPDFJACHGM-UHFFFAOYSA-K 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 239000013055 pulp slurry Substances 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229910052624 sepiolite Inorganic materials 0.000 description 1
- 235000019355 sepiolite Nutrition 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229940083542 sodium Drugs 0.000 description 1
- 235000015424 sodium Nutrition 0.000 description 1
- 229910001388 sodium aluminate Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 239000001593 sorbitan monooleate Substances 0.000 description 1
- 235000011069 sorbitan monooleate Nutrition 0.000 description 1
- 229940035049 sorbitan monooleate Drugs 0.000 description 1
- 229960005078 sorbitan sesquioleate Drugs 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 235000015096 spirit Nutrition 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 229920005613 synthetic organic polymer Polymers 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 230000029305 taxis Effects 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 230000000930 thermomechanical effect Effects 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 229920003176 water-insoluble polymer Polymers 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H5/00—Special paper or cardboard not otherwise provided for
- D21H5/12—Special paper or cardboard not otherwise provided for characterised by the use of special fibrous materials
- D21H5/14—Special paper or cardboard not otherwise provided for characterised by the use of special fibrous materials of cellulose fibres only
- D21H5/141—Special paper or cardboard not otherwise provided for characterised by the use of special fibrous materials of cellulose fibres only of fibrous cellulose derivatives
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/50—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by form
- D21H21/52—Additives of definite length or shape
- D21H21/54—Additives of definite length or shape being spherical, e.g. microcapsules, beads
Landscapes
- Paper (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Glass Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/540,667 US5167766A (en) | 1990-06-18 | 1990-06-18 | Charged organic polymer microbeads in paper making process |
| US07/540,667 | 1990-06-18 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2044698A1 CA2044698A1 (fr) | 1991-12-19 |
| CA2044698C true CA2044698C (fr) | 2003-09-09 |
Family
ID=24156437
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002044698A Expired - Lifetime CA2044698C (fr) | 1990-06-18 | 1991-06-14 | Microbilles de polymere organique chargees utilisees dans la fabrication du papier |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US5167766A (fr) |
| EP (1) | EP0462365B1 (fr) |
| JP (1) | JP2948358B2 (fr) |
| KR (1) | KR100189327B1 (fr) |
| AR (1) | AR247438A1 (fr) |
| AT (1) | ATE161910T1 (fr) |
| AU (1) | AU646441B2 (fr) |
| BR (1) | BR9101722A (fr) |
| CA (1) | CA2044698C (fr) |
| DE (1) | DE69128563T2 (fr) |
| DK (1) | DK0462365T3 (fr) |
| ES (1) | ES2111543T3 (fr) |
| FI (1) | FI105841B (fr) |
| MX (1) | MX174548B (fr) |
| NO (1) | NO178441C (fr) |
| NZ (1) | NZ238402A (fr) |
| ZA (1) | ZA914628B (fr) |
Families Citing this family (104)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2684676A1 (fr) * | 1991-12-09 | 1993-06-11 | Hoechst France | Nouveaux copolymeres cationiques insolubles dans l'eau, de nouvelles dispersions et leur application dans l'enduction des papiers. |
| US5415733A (en) * | 1993-05-27 | 1995-05-16 | High Point Chemical Corp. | Method of removing hydrophilic ink |
| US5431783A (en) * | 1993-07-19 | 1995-07-11 | Cytec Technology Corp. | Compositions and methods for improving performance during separation of solids from liquid particulate dispersions |
| US5354801A (en) * | 1993-08-12 | 1994-10-11 | Cytec Technology Corp. | Process for producing small polymer phase droplet microemulsions by multistep aqueous phase addition |
| US5393827A (en) * | 1993-08-17 | 1995-02-28 | Cytec Technology Corp. | Preparation of high solids polymeric microemulsions |
| US5700893A (en) * | 1993-11-12 | 1997-12-23 | Betzdearborn Inc. | Water-soluble cationic copolymers and their use as flocculants and drainage aids |
| US5516852A (en) * | 1993-11-12 | 1996-05-14 | W. R. Grace & Co.-Conn. | Method of producing water-soluble cationic copolymers |
| US5473033A (en) * | 1993-11-12 | 1995-12-05 | W. R. Grace & Co.-Conn. | Water-soluble cationic copolymers and their use as drainage retention aids in papermaking processes |
| US5720888A (en) * | 1993-11-12 | 1998-02-24 | Betzdearborn Inc. | Water-soluble cationic copolymers and their use as flocculants |
| US5482595A (en) * | 1994-03-22 | 1996-01-09 | Betz Paperchem, Inc. | Method for improving retention and drainage characteristics in alkaline papermaking |
| US6273998B1 (en) * | 1994-08-16 | 2001-08-14 | Betzdearborn Inc. | Production of paper and paperboard |
| US20030192664A1 (en) * | 1995-01-30 | 2003-10-16 | Kulick Russell J. | Use of vinylamine polymers with ionic, organic, cross-linked polymeric microbeads in paper-making |
| US6011089A (en) * | 1995-06-07 | 2000-01-04 | Cytec Technology Corp. | Spray drying of polymer-containing dispersions, water-in-oil emulsions and water-in-oil microemulsions, and dry polymer products formed thereby |
| US5869542A (en) * | 1995-06-07 | 1999-02-09 | Cytec Technology Corp. | Spray drying of polymer-containing dispersions, water-in-oil emulsions and microemulsions and dry polymer products formed thereby |
| US5849862A (en) * | 1995-06-07 | 1998-12-15 | Cytec Technology Corp. | Processes of spray drying polymer-containing dispersions, water-in-oil emulsions and water-in-oil microemulsions |
| GB9603909D0 (en) | 1996-02-23 | 1996-04-24 | Allied Colloids Ltd | Production of paper |
| US5789472A (en) * | 1996-03-20 | 1998-08-04 | Cytec Technology Corp. | Quaternary mannich polymer microemulsion (QMM) with rapid standard viscosity (SV) development |
| US5783163A (en) * | 1996-08-27 | 1998-07-21 | Solv-Ex Corporation | Process for making basic sodium and/or potassium aluminum sulphates and for making paper with such |
| PT1167392E (pt) * | 1996-12-31 | 2004-11-30 | Ciba Spec Chem Water Treat Ltd | Materiais para utilizacao no fabrico de papel |
| US5922794A (en) * | 1997-03-26 | 1999-07-13 | General Electric Company | Compositions stabilized with tertiary amine oxides |
| GB9719472D0 (en) | 1997-09-12 | 1997-11-12 | Allied Colloids Ltd | Process of making paper |
| FR2779752B1 (fr) * | 1998-06-12 | 2000-08-11 | Snf Sa | Procede de fabrication de papier et carton et nouveaux agents de retention correspondants, et papiers et cartons ainsi obtenus |
| US6168686B1 (en) | 1998-08-19 | 2001-01-02 | Betzdearborn, Inc. | Papermaking aid |
| TW524910B (en) | 1999-11-08 | 2003-03-21 | Ciba Spec Chem Water Treat Ltd | Manufacture of paper and paperboard |
| TW550325B (en) | 1999-11-08 | 2003-09-01 | Ciba Spec Chem Water Treat Ltd | Manufacture of paper and paperboard |
| TW527457B (en) * | 1999-11-08 | 2003-04-11 | Ciba Spec Chem Water Treat Ltd | Manufacture of paper and paperboard |
| TW483970B (en) | 1999-11-08 | 2002-04-21 | Ciba Spec Chem Water Treat Ltd | A process for making paper and paperboard |
| US6417268B1 (en) | 1999-12-06 | 2002-07-09 | Hercules Incorporated | Method for making hydrophobically associative polymers, methods of use and compositions |
| US6262012B1 (en) * | 1999-12-20 | 2001-07-17 | Kurita Water Industries Ltd. | Wet paint spray booth treating agent |
| MY140287A (en) * | 2000-10-16 | 2009-12-31 | Ciba Spec Chem Water Treat Ltd | Manufacture of paper and paperboard |
| ES2336769T3 (es) * | 2001-06-12 | 2010-04-16 | Akzo Nobel N.V. | Composicion acuosa. |
| US7189776B2 (en) * | 2001-06-12 | 2007-03-13 | Akzo Nobel N.V. | Aqueous composition |
| US7250448B2 (en) * | 2001-12-07 | 2007-07-31 | Hercules Incorporated | Anionic copolymers prepared in an inverse emulsion matrix and their use in preparing cellulosic fiber compositions |
| US20030136534A1 (en) * | 2001-12-21 | 2003-07-24 | Hans Johansson-Vestin | Aqueous silica-containing composition |
| US20050178517A1 (en) * | 2002-03-28 | 2005-08-18 | Tomoyuki Nakano | Bulky paper |
| US6723204B2 (en) * | 2002-04-08 | 2004-04-20 | Hercules Incorporated | Process for increasing the dry strength of paper |
| EP1538260A4 (fr) * | 2002-07-19 | 2009-07-08 | Kao Corp | Agent ameliorant pour papier |
| AU2003261765A1 (en) * | 2002-08-27 | 2004-03-19 | Kao Corporation | Paper quality improver |
| US20040084162A1 (en) | 2002-11-06 | 2004-05-06 | Shannon Thomas Gerard | Low slough tissue products and method for making same |
| US7396874B2 (en) * | 2002-12-06 | 2008-07-08 | Hercules Incorporated | Cationic or amphoteric copolymers prepared in an inverse emulsion matrix and their use in preparing cellulosic fiber compositions |
| US7244339B2 (en) * | 2003-05-05 | 2007-07-17 | Vergara Lopez German | Retention and drainage system for the manufacturing of paper |
| MXPA04003942A (es) * | 2003-05-05 | 2007-06-29 | German Vergara Lopez | Un sistema de retencion y drenaje recomendado para la fabricacion de papel, cartulina, carton y otros productos similares. |
| US20040244929A1 (en) * | 2003-06-03 | 2004-12-09 | Henke Jason D. | Process for producing a fade-resistant paper |
| DE10346750A1 (de) * | 2003-10-06 | 2005-04-21 | Basf Ag | Verfahren zur Herstellung von Papier, Pappe und Karton |
| JP4517662B2 (ja) * | 2004-02-10 | 2010-08-04 | 栗田工業株式会社 | 紙及び板紙の製造方法 |
| US20050236123A1 (en) * | 2004-04-26 | 2005-10-27 | Mcnamara Bruce A | Retention and drainage in the manufacture of paper |
| FR2869625B1 (fr) * | 2004-04-29 | 2007-09-21 | Snf Sas Soc Par Actions Simpli | Procede de fabrication de papier et carton, nouveaux agents de retention et d'egouttage correspondants, et papiers et cartons ainsi obtenus |
| FR2869626A3 (fr) * | 2004-04-29 | 2005-11-04 | Snf Sas Soc Par Actions Simpli | Procede de fabrication de papier et carton, nouveaux agents de retention et d'egouttage correspondants, et papiers et cartons ainsi obtenus |
| US7799169B2 (en) * | 2004-09-01 | 2010-09-21 | Georgia-Pacific Consumer Products Lp | Multi-ply paper product with moisture strike through resistance and method of making the same |
| US20060084771A1 (en) * | 2004-10-15 | 2006-04-20 | Wong Shing Jane B | Method of preparing modified diallyl-N,N-disubstituted ammonium halide polymers |
| US7473334B2 (en) * | 2004-10-15 | 2009-01-06 | Nalco Company | Method of preparing modified diallyl-N,N-disubstituted ammonium halide polymers |
| US7615135B2 (en) * | 2004-12-14 | 2009-11-10 | Hercules Incorporated | Retention and drainage aids |
| US7955473B2 (en) | 2004-12-22 | 2011-06-07 | Akzo Nobel N.V. | Process for the production of paper |
| US8308902B2 (en) | 2004-12-29 | 2012-11-13 | Hercules Incorporated | Retention and drainage in the manufacture of paper |
| US20060142432A1 (en) * | 2004-12-29 | 2006-06-29 | Harrington John C | Retention and drainage in the manufacture of paper |
| US20060142431A1 (en) * | 2004-12-29 | 2006-06-29 | Sutman Frank J | Retention and drainage in the manufacture of paper |
| US8932433B2 (en) * | 2004-12-29 | 2015-01-13 | Solenis Technologies, L.P. | Retention and drainage in the manufacture of paper |
| US20060142430A1 (en) * | 2004-12-29 | 2006-06-29 | Harrington John C | Retention and drainage in the manufacture of paper |
| US20060137843A1 (en) * | 2004-12-29 | 2006-06-29 | Sutman Frank J | Retention and drainage in the manufacture of paper |
| US20060142429A1 (en) * | 2004-12-29 | 2006-06-29 | Gelman Robert A | Retention and drainage in the manufacture of paper |
| US20060260509A1 (en) * | 2005-04-22 | 2006-11-23 | Evers Glenn R | Compositions for enhanced paper brightness and whiteness |
| ES2358529T3 (es) * | 2005-05-11 | 2011-05-11 | Stora Enso Ab | Procedimiento para la producción de un papel y papel producido según ese procedimiento. |
| US20060254464A1 (en) | 2005-05-16 | 2006-11-16 | Akzo Nobel N.V. | Process for the production of paper |
| US20060266488A1 (en) * | 2005-05-26 | 2006-11-30 | Doherty Erin A S | Hydrophobic polymers and their use in preparing cellulosic fiber compositions |
| US20060289139A1 (en) * | 2005-06-24 | 2006-12-28 | Fushan Zhang | Retention and drainage in the manufacture of paper |
| US8206553B2 (en) * | 2005-06-24 | 2012-06-26 | Hercules Incorporated | Retention and drainage in the manufacture of paper |
| US20060289136A1 (en) * | 2005-06-24 | 2006-12-28 | Doherty Erin A S | Retention and drainage in the manufacture of paper |
| DE102005043800A1 (de) | 2005-09-13 | 2007-03-22 | Basf Ag | Verfahren zur Herstellung von Papier, Pappe und Karton |
| PT1969183E (pt) | 2005-12-30 | 2015-03-06 | Akzo Nobel Nv | Processo para a produção de papel |
| US8273216B2 (en) * | 2005-12-30 | 2012-09-25 | Akzo Nobel N.V. | Process for the production of paper |
| CA2649435A1 (fr) | 2006-04-24 | 2007-11-01 | Ciba Holding Inc. | Polysaccharide cationique, sa synthese et ses applications |
| US7981250B2 (en) * | 2006-09-14 | 2011-07-19 | Kemira Oyj | Method for paper processing |
| US8728274B2 (en) * | 2006-09-22 | 2014-05-20 | Akzo Nobel N.V. | Treatment of pulp |
| KR101506920B1 (ko) | 2006-10-25 | 2015-03-30 | 시바 홀딩 인크 | 종이 강도를 향상시키는 방법 |
| EP2086757A1 (fr) * | 2006-12-01 | 2009-08-12 | Akzo Nobel N.V. | Stratifié de conditionnement |
| GB0702248D0 (en) * | 2007-02-05 | 2007-03-14 | Ciba Sc Holding Ag | Manufacture of Filled Paper |
| GB0702249D0 (en) * | 2007-02-05 | 2007-03-14 | Ciba Sc Holding Ag | Manufacture of paper or paperboard |
| US8088250B2 (en) | 2008-11-26 | 2012-01-03 | Nalco Company | Method of increasing filler content in papermaking |
| US9752283B2 (en) * | 2007-09-12 | 2017-09-05 | Ecolab Usa Inc. | Anionic preflocculation of fillers used in papermaking |
| FR2928383B1 (fr) | 2008-03-06 | 2010-12-31 | Georgia Pacific France | Feuille gaufree comportant un pli en materiau hydrosoluble et procede de realisation d'une telle feuille. |
| FR2929963B1 (fr) * | 2008-04-10 | 2010-04-23 | Snf Sas | Procede de fabrication de papier et carton |
| ES2691384T3 (es) * | 2008-09-02 | 2018-11-27 | Basf Se | Procedimiento para la fabricación de papel, cartón y cartulina usando endo-beta-1,4-glucanasas como agente de drenaje |
| CN102869830A (zh) | 2010-05-05 | 2013-01-09 | 巴斯夫欧洲公司 | 纸张和纸板生产用纤维状组合物 |
| FR2963364B1 (fr) * | 2010-08-02 | 2014-12-26 | Snf Sas | Procede de fabrication de papier et carton presentant des proprietes de retention et d'egouttage ameliorees. |
| WO2012058258A1 (fr) | 2010-10-29 | 2012-05-03 | Buckman Laboratories International, Inc. | Fabrication de papier et produits fabriqués ainsi avec microparticules polymères réticulées ioniques |
| EP2599823A1 (fr) * | 2011-12-03 | 2013-06-05 | BK Giulini GmbH | Compositions de colle à base d'amidon sans borax |
| CN104114766B (zh) * | 2011-12-15 | 2016-06-01 | 因文提亚公司 | 用于改进纸和纸板的体系和方法 |
| JP5995534B2 (ja) * | 2012-06-01 | 2016-09-21 | ハイモ株式会社 | 凝集処理剤および排水処理方法 |
| CN104755159B (zh) | 2012-08-28 | 2017-09-22 | 巴斯夫欧洲公司 | 用于将至少一种化学物质送入至主工艺流中的方法和装置 |
| ES2948357T3 (es) | 2015-08-06 | 2023-09-11 | Solenis Technologies Cayman Lp | Procedimiento para la fabricación de papel |
| WO2017065740A1 (fr) | 2015-10-12 | 2017-04-20 | Solenis Technologies, L.P. | Procédé d'augmentation de performance de drainage d'une suspension épaisse de pâte à papier au cours de la fabrication de produits de papier, et produits obtenus à partir de celui-ci |
| TW201739983A (zh) | 2016-01-14 | 2017-11-16 | 亞齊羅馬Ｉｐ公司 | 丙烯酸酯共聚物之用途、使用其之具有纖維素纖維之基材之製造方法及其基板 |
| CN105820290B (zh) * | 2016-05-04 | 2019-06-07 | 山东源根化学技术研发有限公司 | 一种提升细小纤维-碳酸钙留着率的乳液聚合物的制备方法 |
| CN105801783B (zh) * | 2016-05-11 | 2017-10-03 | 中国石油大学(北京) | 改性的二氧化硅纳米颗粒及其制备方法和适合页岩气井的钻井液 |
| US9783725B1 (en) * | 2016-05-20 | 2017-10-10 | China University Of Petroleum (Beijing) | Drilling fluid additive composition and water-based drilling fluid suitable for horizontal shale gas wells |
| US9790417B1 (en) * | 2016-05-20 | 2017-10-17 | China University Of Petroleum (Beijing) | High-density water-based drilling fluid suitable for horizontal shale gas wells |
| US9834717B1 (en) * | 2016-05-20 | 2017-12-05 | China University Of Petroleum (Beijing) | Drilling fluid additive composition and pseudo oil-based drilling fluid suitable for horizontal shale gas wells |
| EP3246466B1 (fr) * | 2016-05-20 | 2018-02-28 | Kemira Oyj | Procédé et système de traitement destinés à fabriquer du papier |
| US20180051417A1 (en) | 2016-08-16 | 2018-02-22 | Solenis Technologies, L.P. | Method of manufacturing paper with unbleached cellulose pulp suspension containing organic residues |
| RU2753445C2 (ru) | 2016-09-16 | 2021-08-16 | Соленис Текнолоджиз, Л.П. | Повышенная эффективность обезвоживания в бумагоделательных системах с использованием микрофибриллированной целлюлозы |
| KR20200052339A (ko) * | 2017-09-08 | 2020-05-14 | 솔레니스 테크놀러지스 케이맨, 엘.피. | 가교된 음이온성, 유기 중합체 마이크로입자를 포함하는 조성물, 그의 제조 및 종이 및 판지 제조 공정에서의 용도 |
| US11926966B2 (en) * | 2017-10-03 | 2024-03-12 | Solenis Technologies, L.P. | Method of increasing efficiency of chemical additives in a papermaking system |
| WO2022021283A1 (fr) * | 2020-07-31 | 2022-02-03 | Dow Global Technologies Llc | Dispersion aqueuse de particules de polymères, microsphères et particules de silice colloïdale |
| WO2022094597A1 (fr) * | 2020-10-30 | 2022-05-05 | Solenis Technologies Cayman, L.P. | Procédé d'augmentation de l'efficacité d'additifs chimiques dans des systèmes de fabrication de papier |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3702799A (en) * | 1969-04-04 | 1972-11-14 | Rohm & Haas | Polymers of quaternary ammonium compounds used as wet strength agents in paper |
| US4178205A (en) * | 1977-08-17 | 1979-12-11 | The Dow Chemical Company | High strength non-woven fibrous material |
| SE8306739L (sv) * | 1983-12-06 | 1985-06-07 | Svenska Traeforskningsinst | Sett att framstella papper med hog fyllmedelshalt |
| DE3401573A1 (de) * | 1984-01-18 | 1985-07-25 | Bayer Ag, 5090 Leverkusen | Kationisches leimungsmittel fuer papier und verfahren zu seiner herstellung |
| US4759856A (en) * | 1984-04-30 | 1988-07-26 | Allied Colloids, Ltd. | Flocculation processes |
| GB8531558D0 (en) * | 1985-12-21 | 1986-02-05 | Wiggins Teape Group Ltd | Loaded paper |
| GB8602121D0 (en) * | 1986-01-29 | 1986-03-05 | Allied Colloids Ltd | Paper & paper board |
| US4643801A (en) * | 1986-02-24 | 1987-02-17 | Nalco Chemical Company | Papermaking aid |
| JPH0662779B2 (ja) * | 1986-11-11 | 1994-08-17 | 住友化学工業株式会社 | カチオン性ポリマーの水分散液およびその用途 |
| US4798653A (en) * | 1988-03-08 | 1989-01-17 | Procomp, Inc. | Retention and drainage aid for papermaking |
| SE461404C (sv) * | 1988-06-22 | 1999-11-15 | Betzdearborn Inc | Limningskomposition, förfarande för framställning därav, förfarande för framställning av limmat papper, och limmat papper |
| DE68906623T2 (de) * | 1988-09-16 | 1993-11-11 | Du Pont | Polysilikatmikrogele als Rückhaltungs-/Entwässerungshilfsmittel bei der Papierherstellung. |
| US4968435A (en) * | 1988-12-19 | 1990-11-06 | American Cyanamid Company | Cross-linked cationic polymeric microparticles |
-
1990
- 1990-06-18 US US07/540,667 patent/US5167766A/en not_active Expired - Lifetime
-
1991
- 1991-03-27 DK DK91104837.9T patent/DK0462365T3/da active
- 1991-03-27 ES ES91104837T patent/ES2111543T3/es not_active Expired - Lifetime
- 1991-03-27 AT AT91104837T patent/ATE161910T1/de not_active IP Right Cessation
- 1991-03-27 EP EP91104837A patent/EP0462365B1/fr not_active Revoked
- 1991-03-27 DE DE69128563T patent/DE69128563T2/de not_active Revoked
- 1991-04-02 AU AU74021/91A patent/AU646441B2/en not_active Expired
- 1991-04-05 AR AR91319406A patent/AR247438A1/es active
- 1991-04-29 BR BR919101722A patent/BR9101722A/pt not_active IP Right Cessation
- 1991-06-05 NZ NZ238402A patent/NZ238402A/xx not_active IP Right Cessation
- 1991-06-07 MX MX026158A patent/MX174548B/es unknown
- 1991-06-12 JP JP3166104A patent/JP2948358B2/ja not_active Expired - Lifetime
- 1991-06-14 CA CA002044698A patent/CA2044698C/fr not_active Expired - Lifetime
- 1991-06-17 NO NO912348A patent/NO178441C/no not_active IP Right Cessation
- 1991-06-17 FI FI912924A patent/FI105841B/fi active
- 1991-06-17 ZA ZA914628A patent/ZA914628B/xx unknown
- 1991-06-17 KR KR1019910010011A patent/KR100189327B1/ko not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| DE69128563T2 (de) | 1998-04-16 |
| JPH04241197A (ja) | 1992-08-28 |
| NO912348D0 (no) | 1991-06-17 |
| KR920001035A (ko) | 1992-01-29 |
| AU646441B2 (en) | 1994-02-24 |
| AU7402191A (en) | 1991-12-19 |
| ATE161910T1 (de) | 1998-01-15 |
| NZ238402A (en) | 1993-07-27 |
| AR247438A1 (es) | 1994-12-29 |
| DK0462365T3 (da) | 1998-03-02 |
| ZA914628B (en) | 1992-03-25 |
| KR100189327B1 (ko) | 1999-06-01 |
| FI105841B (fi) | 2000-10-13 |
| DE69128563D1 (de) | 1998-02-12 |
| BR9101722A (pt) | 1991-12-24 |
| NO178441C (no) | 1996-03-27 |
| NO912348L (no) | 1991-12-19 |
| CA2044698A1 (fr) | 1991-12-19 |
| ES2111543T3 (es) | 1998-03-16 |
| EP0462365A1 (fr) | 1991-12-27 |
| EP0462365B1 (fr) | 1998-01-07 |
| FI912924A0 (fi) | 1991-06-17 |
| JP2948358B2 (ja) | 1999-09-13 |
| FI912924A (fi) | 1991-12-19 |
| MX174548B (es) | 1994-05-25 |
| NO178441B (no) | 1995-12-18 |
| US5167766A (en) | 1992-12-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA2044698C (fr) | Microbilles de polymere organique chargees utilisees dans la fabrication du papier | |
| US5274055A (en) | Charged organic polymer microbeads in paper-making process | |
| AU673082B2 (en) | Compositions and methods for improving performance during separation of solids from liquid particulate dispersions | |
| US5171808A (en) | Cross-linked anionic and amphoteric polymeric microparticles | |
| EP1451234B1 (fr) | Composition comprenant une fibre cellulosique et un copolymère anionique hydrosoluble ainsi que procédé de préparation de cette composition | |
| US7396874B2 (en) | Cationic or amphoteric copolymers prepared in an inverse emulsion matrix and their use in preparing cellulosic fiber compositions | |
| US20030192664A1 (en) | Use of vinylamine polymers with ionic, organic, cross-linked polymeric microbeads in paper-making | |
| US20060266488A1 (en) | Hydrophobic polymers and their use in preparing cellulosic fiber compositions | |
| AU6597996A (en) | Synthetic cationic polymers as promoters for ASA sizing | |
| EP0484617B2 (fr) | Microperles de polymères anioniques et amphotères réticulés | |
| WO1999050500A1 (fr) | Amelioration de la retention et de l'essorage dans la fabrication de papier fin alcalin | |
| US5200037A (en) | Absorbent structures from mixed furnishes | |
| US20060289139A1 (en) | Retention and drainage in the manufacture of paper | |
| AU2011213761B2 (en) | Improved retention and drainage in the manufacture of paper | |
| NZ237837A (en) | Composition comprising cross-linked anionic or amphoteric polymer |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed | ||
| MKEC | Expiry (correction) |
Effective date: 20121202 |