CA2024593A1 - Catalyseur et porteur pour la polymerisation de l'ethylene - Google Patents

Catalyseur et porteur pour la polymerisation de l'ethylene

Info

Publication number
CA2024593A1
CA2024593A1 CA2024593A CA2024593A CA2024593A1 CA 2024593 A1 CA2024593 A1 CA 2024593A1 CA 2024593 A CA2024593 A CA 2024593A CA 2024593 A CA2024593 A CA 2024593A CA 2024593 A1 CA2024593 A1 CA 2024593A1
Authority
CA
Canada
Prior art keywords
polymerization
ethylene
titanium compound
new carrier
carrier catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA2024593A
Other languages
English (en)
Other versions
CA2024593C (fr
Inventor
Sirpa Ala-Huikku
Ulf Palmqvist
Marjaana Lommi
Eero Iiskola
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Borealis Holding AS
Original Assignee
Neste Oyj
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Neste Oyj filed Critical Neste Oyj
Publication of CA2024593A1 publication Critical patent/CA2024593A1/fr
Application granted granted Critical
Publication of CA2024593C publication Critical patent/CA2024593C/fr
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/941—Synthetic resins or natural rubbers -- part of the class 520 series having the transition metal bonded directly to carbon

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Fittings On The Vehicle Exterior For Carrying Loads, And Devices For Holding Or Mounting Articles (AREA)
  • Nonmetallic Welding Materials (AREA)
  • Paints Or Removers (AREA)
CA002024593A 1989-09-06 1990-09-04 Catalyseur et porteur pour la polymerisation de l'ethylene Expired - Fee Related CA2024593C (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FI894216 1989-09-06
FI894216A FI85151C (fi) 1989-09-06 1989-09-06 Ny baerarkatalysator foer polymerisation av eten.

Publications (2)

Publication Number Publication Date
CA2024593A1 true CA2024593A1 (fr) 1992-03-05
CA2024593C CA2024593C (fr) 1998-11-24

Family

ID=8528953

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002024593A Expired - Fee Related CA2024593C (fr) 1989-09-06 1990-09-04 Catalyseur et porteur pour la polymerisation de l'ethylene

Country Status (7)

Country Link
US (1) US5324698A (fr)
EP (1) EP0416928B1 (fr)
AT (1) ATE120213T1 (fr)
CA (1) CA2024593C (fr)
DE (1) DE69017987T2 (fr)
FI (1) FI85151C (fr)
NO (1) NO175314C (fr)

Families Citing this family (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69310101T2 (de) * 1992-11-18 1997-09-25 Mitsui Petrochemical Ind Katalysator für Olefinpolymerisation und Verfahren für Olefinpolymerisation unter Anwendung desselben
AU672905B2 (en) * 1993-03-25 1996-10-17 Mobil Oil Corporation Process for forming a granular resin
JP2882241B2 (ja) * 1993-06-07 1999-04-12 東ソー株式会社 オレフィン重合用触媒およびオレフィンの重合方法
EP0776909B1 (fr) * 1994-08-18 2003-11-19 Asahi Kasei Kabushiki Kaisha Polymere ethylenique a haute densite et son procede de production
AU3894395A (en) * 1994-10-31 1996-05-23 W.R. Grace & Co.-Conn. Preparation of modified polyolefin catalysts and in situ preparation of supported metallocene and ziegler-natta/metallocene polyolefin catalysts
US6271164B1 (en) * 1995-09-28 2001-08-07 Cornelia Fritze Supported catalyst system, process for its production and its use in polymerizing olefins
CA2163681C (fr) * 1995-11-24 2007-02-13 Daryll G. Harrison Catalyseur a base de monocyclopentadienylzirconium
US5965477A (en) * 1997-02-21 1999-10-12 Council Of Scientific & Industrial Research Process for the preparation of supported metallocene catalyst
EP0878484B1 (fr) * 1997-03-27 2004-12-15 Council of Scientific and Industrial Research Procédé de préparation d'un catalyseur métallocène supporté sur un halogénure de magnésium
US5955554A (en) * 1997-03-27 1999-09-21 Council Of Scientific Industrial Research Process for polymerization and copolymerization of olefins
EP0878485B1 (fr) * 1997-05-14 2006-04-26 Council of Scientific and Industrial Research Procédé pour la polymérisation des oléfines
GB9722447D0 (en) * 1997-10-23 1997-12-24 Borealis As Process
ES2572756T3 (es) 1998-05-18 2016-06-02 Chevron Phillips Chemical Company Lp Proceso para la polimerización de un monómero con una composición de catalizador que contiene un compuesto organometálico, un compuesto de organoaluminio y un compuesto de óxido sólido tratado
US6300271B1 (en) 1998-05-18 2001-10-09 Phillips Petroleum Company Compositions that can produce polymers
US6323148B1 (en) * 1998-12-04 2001-11-27 Equistar Chemicals, Lp Ethylene polymerization catalyst and catalyst system
US6355594B1 (en) 1999-09-27 2002-03-12 Phillips Petroleum Company Organometal catalyst compositions
US6395666B1 (en) * 1999-09-29 2002-05-28 Phillips Petroleum Company Organometal catalyst compositions
US6391816B1 (en) 1999-10-27 2002-05-21 Phillips Petroleum Organometal compound catalyst
US6548442B1 (en) 1999-12-03 2003-04-15 Phillips Petroleum Company Organometal compound catalyst
US6750302B1 (en) 1999-12-16 2004-06-15 Phillips Petroleum Company Organometal catalyst compositions
HUP0203789A2 (en) 1999-12-16 2003-04-28 Phillips Petroleum Co Organometal compound catalyst
US6524987B1 (en) 1999-12-22 2003-02-25 Phillips Petroleum Company Organometal catalyst compositions
AU2003292199A1 (en) * 2002-12-18 2004-07-09 Basell Poliolefine Italia S.P.A. Catalyst components for the polymerization of olefins
US7217676B2 (en) * 2004-01-16 2007-05-15 Exxon Mobil Chemical Patents Inc. Hydrophobization and silica for supported catalyst
US7456021B2 (en) * 2004-01-16 2008-11-25 Exxonmobil Chemical Patents Inc. Analysis method
BRPI0703586B1 (pt) 2007-10-19 2018-02-06 Braskem S.A Catalisador metaloceno suportado, e, copolímeros de etileno com alfa-olefinas de alto e ultra alto peso molecular
CA2760264C (fr) * 2011-12-05 2018-08-21 Nova Chemicals Corporation Supports passives pour utilisation avec catalyseurs de polymerisation d'olefine
US8895679B2 (en) 2012-10-25 2014-11-25 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US8937139B2 (en) 2012-10-25 2015-01-20 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US9034991B2 (en) 2013-01-29 2015-05-19 Chevron Phillips Chemical Company Lp Polymer compositions and methods of making and using same
US8877672B2 (en) 2013-01-29 2014-11-04 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
CN116693729A (zh) * 2023-08-02 2023-09-05 研峰科技(北京)有限公司 茂金属催化剂环戊二烯三氯化钛的合成方法

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL162664B (nl) * 1969-06-20 1980-01-15 Montedison Spa Werkwijze om een katalysator te bereiden voor de poly- merisatie van alkenen-1.
GB1348655A (en) * 1970-05-22 1974-03-20 Montedison Spa Catalysts for the polymerization of olefins
NL163523C (nl) * 1970-07-31 1983-11-16 Montedison Spa Werkwijze om een polymerisatiekatalysator te bereiden.
US4107414A (en) * 1971-06-25 1978-08-15 Montecatini Edison S.P.A. Process for the stereoregular polymerization of alpha olefins
US4107413A (en) * 1971-06-25 1978-08-15 Montedison S.P.A. Process for the stereoregular polymerization of alpha olefins
DE2543181C2 (de) * 1975-09-27 1986-08-28 Basf Ag, 6700 Ludwigshafen Verfahren zur Polymerisation von Äthylen oder zu dessen Copolymerisation mit C↓3↓- bis C↓1↓↓0↓-α-Monoolefinen
DE2835944A1 (de) * 1978-08-17 1980-03-13 Heyl & Co Metallhaltige loesliche polymere katalysatoren fuer polymerisationen, verfahren zur herstellung derselben und ihre verwendung in polymerisationsverfahren
US4383095A (en) * 1979-02-16 1983-05-10 Union Carbide Corporation Process for the preparation of high density ethylene polymers in fluid bed reactor
US4684703A (en) * 1979-02-27 1987-08-04 Union Carbide Corporation Polymerization catalyst for ethylene homopolymerization
DE3882513T2 (de) * 1987-06-17 1994-02-10 Dow Chemical Co Katalysator und verfahren zur herstellung syndiotaktischer polystyrene.

Also Published As

Publication number Publication date
FI894216A0 (fi) 1989-09-06
NO903866D0 (no) 1990-09-05
CA2024593C (fr) 1998-11-24
EP0416928A3 (en) 1991-11-21
US5324698A (en) 1994-06-28
DE69017987T2 (de) 1995-11-02
FI894216A (fi) 1991-03-07
NO903866L (no) 1991-03-07
FI85151B (fi) 1991-11-29
ATE120213T1 (de) 1995-04-15
DE69017987D1 (de) 1995-04-27
NO175314B (no) 1994-06-20
EP0416928B1 (fr) 1995-03-22
NO175314C (no) 1994-09-28
EP0416928A2 (fr) 1991-03-13
FI85151C (fi) 1992-03-10

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