CA1202951A - Catalyseurs de reformage a base de carbures de tungstene et de molybdene, et leur methode d'utilisation - Google Patents
Catalyseurs de reformage a base de carbures de tungstene et de molybdene, et leur methode d'utilisationInfo
- Publication number
- CA1202951A CA1202951A CA000450212A CA450212A CA1202951A CA 1202951 A CA1202951 A CA 1202951A CA 000450212 A CA000450212 A CA 000450212A CA 450212 A CA450212 A CA 450212A CA 1202951 A CA1202951 A CA 1202951A
- Authority
- CA
- Canada
- Prior art keywords
- catalysts
- mass
- products
- supported
- carbides
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 68
- 238000002407 reforming Methods 0.000 title claims abstract description 12
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 title 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 32
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000000203 mixture Substances 0.000 claims abstract description 11
- 238000000034 method Methods 0.000 claims abstract description 9
- 239000003209 petroleum derivative Substances 0.000 claims abstract description 8
- 239000002245 particle Substances 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 23
- 229910052750 molybdenum Inorganic materials 0.000 abstract description 21
- 229910052721 tungsten Inorganic materials 0.000 abstract description 19
- 239000011733 molybdenum Substances 0.000 abstract description 11
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 abstract description 10
- 239000010937 tungsten Substances 0.000 abstract description 10
- 229910052717 sulfur Inorganic materials 0.000 abstract description 7
- 239000011593 sulfur Substances 0.000 abstract description 7
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract description 6
- -1 tungsten carbides Chemical class 0.000 abstract description 4
- 231100000572 poisoning Toxicity 0.000 abstract description 3
- 230000000607 poisoning effect Effects 0.000 abstract description 3
- 238000005121 nitriding Methods 0.000 abstract description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 24
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 24
- 150000001247 metal acetylides Chemical class 0.000 description 21
- 239000000047 product Substances 0.000 description 20
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 17
- 238000006243 chemical reaction Methods 0.000 description 16
- 238000006356 dehydrogenation reaction Methods 0.000 description 14
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 12
- 239000001257 hydrogen Substances 0.000 description 12
- 229910052739 hydrogen Inorganic materials 0.000 description 12
- 238000007327 hydrogenolysis reaction Methods 0.000 description 11
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 9
- 235000013844 butane Nutrition 0.000 description 9
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical class CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 9
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 9
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 8
- 239000001273 butane Substances 0.000 description 8
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 6
- 125000004122 cyclic group Chemical group 0.000 description 6
- QIJNJJZPYXGIQM-UHFFFAOYSA-N 1lambda4,2lambda4-dimolybdacyclopropa-1,2,3-triene Chemical compound [Mo]=C=[Mo] QIJNJJZPYXGIQM-UHFFFAOYSA-N 0.000 description 5
- 229910039444 MoC Inorganic materials 0.000 description 5
- 150000002430 hydrocarbons Chemical class 0.000 description 5
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 5
- 102100026925 Myosin regulatory light chain 2, ventricular/cardiac muscle isoform Human genes 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 4
- 238000006317 isomerization reaction Methods 0.000 description 4
- 239000001294 propane Substances 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 238000005336 cracking Methods 0.000 description 3
- XAYGUHUYDMLJJV-UHFFFAOYSA-Z decaazanium;dioxido(dioxo)tungsten;hydron;trioxotungsten Chemical compound [H+].[H+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O XAYGUHUYDMLJJV-UHFFFAOYSA-Z 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 108010065781 myosin light chain 2 Proteins 0.000 description 3
- 150000004767 nitrides Chemical class 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 229940015849 thiophene Drugs 0.000 description 3
- 229930192474 thiophene Natural products 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 101100401739 Caenorhabditis elegans mlc-3 gene Proteins 0.000 description 2
- 101100130592 Caenorhabditis elegans mlc-4 gene Proteins 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- 101000573526 Homo sapiens Membrane protein MLC1 Proteins 0.000 description 2
- 101000635885 Homo sapiens Myosin light chain 1/3, skeletal muscle isoform Proteins 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 102100030739 Myosin light chain 4 Human genes 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- BKHJHGONWLDYCV-UHFFFAOYSA-N [C]=O.[C] Chemical compound [C]=O.[C] BKHJHGONWLDYCV-UHFFFAOYSA-N 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000001282 iso-butane Substances 0.000 description 2
- GDOPTJXRTPNYNR-UHFFFAOYSA-N methylcyclopentane Chemical compound CC1CCCC1 GDOPTJXRTPNYNR-UHFFFAOYSA-N 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 2,3-dimethylbutane Chemical class CC(C)C(C)C ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 0.000 description 1
- WECIKJKLCDCIMY-UHFFFAOYSA-N 2-chloro-n-(2-cyanoethyl)acetamide Chemical compound ClCC(=O)NCCC#N WECIKJKLCDCIMY-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- UAEPNZWRGJTJPN-UHFFFAOYSA-N Methylcyclohexane Natural products CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 1
- 101710109784 Myosin regulatory light chain 12B Proteins 0.000 description 1
- 101710092698 Myosin regulatory light chain 2 Proteins 0.000 description 1
- 101710112127 Myosin regulatory light chain 2, skeletal muscle isoform Proteins 0.000 description 1
- 101710105127 Myosin regulatory light chain 2, ventricular/cardiac muscle isoform Proteins 0.000 description 1
- 235000010678 Paulownia tomentosa Nutrition 0.000 description 1
- 240000002834 Paulownia tomentosa Species 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 235000011124 aluminium ammonium sulphate Nutrition 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- LCQXXBOSCBRNNT-UHFFFAOYSA-K ammonium aluminium sulfate Chemical compound [NH4+].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O LCQXXBOSCBRNNT-UHFFFAOYSA-K 0.000 description 1
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 description 1
- 229940010552 ammonium molybdate Drugs 0.000 description 1
- 235000018660 ammonium molybdate Nutrition 0.000 description 1
- 239000011609 ammonium molybdate Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000001833 catalytic reforming Methods 0.000 description 1
- 238000007036 catalytic synthesis reaction Methods 0.000 description 1
- 210000004534 cecum Anatomy 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- MGNZXYYWBUKAII-UHFFFAOYSA-N cyclohexa-1,3-diene Chemical class C1CC=CC=C1 MGNZXYYWBUKAII-UHFFFAOYSA-N 0.000 description 1
- HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 description 1
- 239000000686 essence Substances 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000007970 homogeneous dispersion Substances 0.000 description 1
- 238000011905 homologation Methods 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- JAGQSESDQXCFCH-UHFFFAOYSA-N methane;molybdenum Chemical compound C.[Mo].[Mo] JAGQSESDQXCFCH-UHFFFAOYSA-N 0.000 description 1
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
- 150000005673 monoalkenes Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- VVRQVWSVLMGPRN-UHFFFAOYSA-N oxotungsten Chemical class [W]=O VVRQVWSVLMGPRN-UHFFFAOYSA-N 0.000 description 1
- 125000004817 pentamethylene group Chemical class [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 230000036647 reaction Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003463 sulfur Chemical class 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- CTMHWPIWNRWQEG-UHFFFAOYSA-N trans cyclohexenyl ester Natural products CC1=CCCCC1 CTMHWPIWNRWQEG-UHFFFAOYSA-N 0.000 description 1
- 229910001930 tungsten oxide Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/20—Carbon compounds
- B01J27/22—Carbides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G35/00—Reforming naphtha
- C10G35/04—Catalytic reforming
- C10G35/06—Catalytic reforming characterised by the catalyst used
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8305480 | 1983-03-25 | ||
| FR8305480A FR2543152B1 (fr) | 1983-03-25 | 1983-03-25 | Catalyseurs de reformage a base de carbures de tungstene et/ou molybdene et leur methode d'utilisation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1202951A true CA1202951A (fr) | 1986-04-08 |
Family
ID=9287503
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000450212A Expired CA1202951A (fr) | 1983-03-25 | 1984-03-22 | Catalyseurs de reformage a base de carbures de tungstene et de molybdene, et leur methode d'utilisation |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US4522708A (https=) |
| EP (1) | EP0120798B1 (https=) |
| JP (1) | JPS59222233A (https=) |
| CA (1) | CA1202951A (https=) |
| DE (1) | DE3460029D1 (https=) |
| FR (1) | FR2543152B1 (https=) |
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4851206A (en) * | 1981-07-15 | 1989-07-25 | The Board Of Trustees Of The Leland Stanford Junior University, Stanford University | Methods and compostions involving high specific surface area carbides and nitrides |
| US5138111A (en) * | 1988-05-23 | 1992-08-11 | Exxon Research And Engineering Company | Eta phase materials, methods of producing the same, and use thereof as catalysts for alcohol synthesis, hydrocarbon synthesis, hydrocarbon hydrogenation and hydrocarbon conversion reactions |
| US5071813A (en) * | 1988-05-23 | 1991-12-10 | Exxon Research & Engineering Company | ETA phase materials, methods of producing the same, and use thereof as catalysts for alcohol synthesis, hydrocarbon synthesis, hydrocarbon hydrogenation and hydrocarbon conversion reactions |
| CA1333004C (en) * | 1988-05-23 | 1994-11-15 | Larry Eugene Mccandlish | Eta phase materials, methods of producing the same and use thereof as catalysts for alcohol synthesis hydrocarbon synthesis, hydrocarbon hydrogenation and hydrocarbon conversion reactions |
| ATE124666T1 (de) * | 1989-03-28 | 1995-07-15 | Pechiney Recherche | Herstellung von schwermetallkarbiden mit erhöhter spezifischer oberfläche. |
| FR2680984B1 (fr) * | 1991-09-06 | 1993-11-05 | Pechiney Recherche | Preparation de catalyseur a partir d'oxydes metalliques par reduction et carburation partielle par les gaz reactionnels. |
| KR100270152B1 (ko) * | 1991-10-04 | 2000-10-16 | 로디아 쉬미 | 탄화텅스텐 기재 촉매 및 이촉매를 사용한 방향족 니트로 또는 니트로 소유도체의 수소 첨가방법 |
| US5338716A (en) * | 1992-12-01 | 1994-08-16 | Akzo Nobel Nv | Non-oxide metal ceramic catalysts comprising metal oxide support and intermediate ceramic passivating layer |
| US5384027A (en) * | 1993-11-09 | 1995-01-24 | Akzo Nobel N.V. | Reforming hydrocarbons using transition metal carbide catalyst and gaseous oxygen |
| US5573991A (en) * | 1994-02-24 | 1996-11-12 | Akzo Nobel N.V. | Preparation of metal carbide catalyst supported on carbon |
| DE19516318A1 (de) * | 1995-04-28 | 1996-10-31 | Inst Angewandte Chemie Berlin | Selektiver Aromatisierungskatalysator, Verfahren zur Herstellung und Verwendung |
| FR2798135B1 (fr) * | 1999-09-02 | 2001-10-26 | Inst Francais Du Petrole | Procede d'isomerisation d'une charge comprenant des paraffines a l'aide d'un catalyseur comprenant du phosphore et un nitrure de metal du groupe vib |
| US6207609B1 (en) * | 1999-09-30 | 2001-03-27 | N.V. Union Miniere S.A. | Method of forming molybdenum carbide catalyst |
| US6461539B1 (en) * | 1999-10-18 | 2002-10-08 | Conoco Inc. | Metal carbide catalysts and process for producing synthesis gas |
| KR20020073147A (ko) | 1999-12-21 | 2002-09-19 | 몬산토 테크놀로지 엘엘씨 | 탄소-지지된, 귀금속-함유 촉매의 존재하에 보충적촉진제의 액상 산화 반응에서의 용도 |
| US6623720B2 (en) * | 2000-03-31 | 2003-09-23 | The Regents Of The University Of Michigan | Transition metal carbides, nitrides and borides, and their oxygen containing analogs useful as water gas shift catalysts |
| US7390920B2 (en) * | 2002-02-14 | 2008-06-24 | Monsanto Technology Llc | Oxidation catalyst and process |
| MX261990B (es) * | 2002-02-14 | 2008-11-07 | Monsanto Technology Llc | Catalizador de oxidacion y procedimiento para su preparacion y procedimiento para oxidacion mediante el uso del mismo. |
| FR2845622B1 (fr) * | 2002-10-15 | 2005-12-30 | Inst Francais Du Petrole | Catalyseur d'hydroraffinage et/ou d'hydroconversion prepare a partir d'une nouvelle phase active de type oxycarbonitrure |
| CN102276644B (zh) | 2003-08-14 | 2014-09-03 | 孟山都技术公司 | 含有过渡金属-碳化物和氮化物的催化剂、它们的制备方法和作为氧化和脱氢催化剂的用途 |
| AR051926A1 (es) * | 2004-09-15 | 2007-02-21 | Monsanto Technology Llc | Catalizadores de oxidacion, procedimientos de preparacion de dichos catalizadores y proceso para la elaboracion de n-( fosfonometil)glicina o una sal de la misma |
| BRPI0608355B1 (pt) | 2005-02-17 | 2016-05-24 | Monsanto Technology Llc | processo para oxidação de ácido n-(fosfonometil) iminodiacético ou seu sal e catalisador de oxidação |
| WO2007028153A2 (en) * | 2005-09-02 | 2007-03-08 | Hrd Corp. | Catalyst and method for converting low molecular weight paraffinic hydrocarbons into alkenes and organic compounds with carbon numbers of 2 or more |
| AU2007217054A1 (en) * | 2006-02-17 | 2007-08-30 | Monsanto Technology Llc | Transition metal-containing catalysts and processes for their preparation and use as fuel cell catalysts |
| US8129305B2 (en) * | 2007-04-25 | 2012-03-06 | Hrd Corporation | Catalyst and method for converting natural gas to higher carbon compounds |
| US8252953B2 (en) | 2008-05-01 | 2012-08-28 | Monsanto Technology Llc | Metal utilization in supported, metal-containing catalysts |
| WO2013149014A1 (en) * | 2012-03-29 | 2013-10-03 | Wayne State University | Bimetal catalysts |
| WO2020178683A1 (en) * | 2019-03-05 | 2020-09-10 | Sabic Global Technologies B.V. | Distribution hub for c4 conversion to ethane/propane feedstock network |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2755228A (en) * | 1952-02-25 | 1956-07-17 | Gulf Research Development Co | Hydroreforming employing carbide catalysts |
| US3865750A (en) * | 1971-12-27 | 1975-02-11 | Exxon Research Engineering Co | Titanium carbide catalysts, and the catalyst compositions |
| US4155928A (en) * | 1975-05-16 | 1979-05-22 | Phillips Petroleum Company | Methanation of carbon monoxide over tungsten carbide-containing catalysts |
| CH621749A5 (https=) * | 1977-08-09 | 1981-02-27 | Battelle Memorial Institute | |
| SE425003B (sv) * | 1978-02-28 | 1982-08-23 | Sandvik Ab | Modifikation av molybden-volfram-karbonitrid enligt kraven i patentet 7800756-4 |
| US4271041A (en) * | 1979-02-08 | 1981-06-02 | The Board Of Trustees Of Leland Stanford Junior University | High surface area molybdenum oxycarbide catalysts |
| US4219445A (en) * | 1979-02-26 | 1980-08-26 | Phillips Petroleum Company | Methanation of carbon monoxide over tungsten carbide-containing alumina catalyst for methanation of carbon monoxide |
| US4331544A (en) * | 1980-02-01 | 1982-05-25 | Director-General Of The Agency Of Industrial Science And Technology | Catalyst for methanation and method for the preparation thereof |
| US4325843A (en) * | 1980-12-08 | 1982-04-20 | Shell Oil Company | Process for preparing a supported tungsten carbide composition |
| US4326992A (en) * | 1980-12-08 | 1982-04-27 | Shell Oil Company | Process for preparing a supported molybdenum carbide composition |
| US4325842A (en) * | 1980-12-08 | 1982-04-20 | Shell Oil Company | Process for preparing a supported molybdenum carbide composition |
| JPS57140302A (en) * | 1981-02-18 | 1982-08-30 | Hitachi Ltd | Production of hydrogen |
-
1983
- 1983-03-25 FR FR8305480A patent/FR2543152B1/fr not_active Expired
-
1984
- 1984-03-15 US US06/589,683 patent/US4522708A/en not_active Expired - Fee Related
- 1984-03-16 JP JP59052053A patent/JPS59222233A/ja active Granted
- 1984-03-22 CA CA000450212A patent/CA1202951A/fr not_active Expired
- 1984-03-23 DE DE8484420057T patent/DE3460029D1/de not_active Expired
- 1984-03-23 EP EP84420057A patent/EP0120798B1/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR2543152B1 (fr) | 1985-06-14 |
| US4522708A (en) | 1985-06-11 |
| JPH0238256B2 (https=) | 1990-08-29 |
| FR2543152A1 (fr) | 1984-09-28 |
| DE3460029D1 (en) | 1986-03-13 |
| JPS59222233A (ja) | 1984-12-13 |
| EP0120798B1 (fr) | 1986-01-29 |
| EP0120798A1 (fr) | 1984-10-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA1202951A (fr) | Catalyseurs de reformage a base de carbures de tungstene et de molybdene, et leur methode d'utilisation | |
| Sinfelt | Heterogeneous Catalysis: Some Recent Developments: Some properties of metal catalysts and recent advances in alloys and bimetallic systems are discussed. | |
| US6765026B2 (en) | Process for carbon monoxide hydrogenation | |
| RU2562459C2 (ru) | Способ получения легких олефинов из синтез-газа | |
| JPH06158058A (ja) | 炭化水素燃料の製造方法 | |
| JPH01301787A (ja) | 合成原油及び高級化炭化水素製品を製造するためにフィッシャー・トロプッシュワックスを水素化異性化し水素化分解する方法 | |
| EP0167215B1 (en) | Process for the preparation of hydrocarbons | |
| JPH0581635B2 (https=) | ||
| AU8018800A (en) | Process for preparing group viii metal-containing catalysts, catalytic compositions, use thereof in carbon monoxide hydrogenation | |
| WO1998050497A1 (en) | Processes, and catalyst for upgrading waxy, paraffinic feeds | |
| CA1300115C (fr) | Catalyseur a base de mordenite pour l'isomerisation de paraffines normales | |
| JP2000104078A (ja) | 炭素ガスを含む低級炭化水素ガスから液体炭化水素油を製造する方法 | |
| US20020169218A1 (en) | Co-hydroprocessing of fischer-tropsch products and natural gas well condensate | |
| EP0987236B1 (fr) | Procédé de conversion du gaz de synthèse en présence d'un catalyseur à base de métal du groupe VIII, les particules du métal étant réparties sour forme d'agrégats | |
| AU7877800A (en) | Process for the preparation of high activity carbon monoxide hydrogenation catalyst and the catalyst composition obtained | |
| FR2745820A1 (fr) | Conversion du gaz de synthese en hydrocarbures en presence d'une phase liquide | |
| RU2087187C1 (ru) | Катализатор для селективного гидрирования и способ его получения | |
| JP4236170B2 (ja) | ガソリン基材の製造方法 | |
| GB2379667A (en) | Hydroprocessing of hydrocarbons having a reduced sulfur content | |
| JPH02119943A (ja) | イータ相物質、その製造法、並びにそれらのアルコール合成、炭化水素合成、炭化水素水素化および炭化水素転化反応に対する触媒としての使用 | |
| GB2379666A (en) | Hydroprocessing of hydrocarbons having a reduced sulfur content | |
| JP3890513B2 (ja) | メチルシクロペンタン含有炭化水素の製造方法 | |
| JPS5830915B2 (ja) | 合成ガスを炭化水素混合物に転化する方法 | |
| JP2884050B2 (ja) | ルテニウム担持金属酸化物触媒による選択的核水素化反応 | |
| JPH11512394A (ja) | ナフテン環の選択的開環方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |