CA1158520A - Transparent soap - Google Patents
Transparent soapInfo
- Publication number
- CA1158520A CA1158520A CA000379241A CA379241A CA1158520A CA 1158520 A CA1158520 A CA 1158520A CA 000379241 A CA000379241 A CA 000379241A CA 379241 A CA379241 A CA 379241A CA 1158520 A CA1158520 A CA 1158520A
- Authority
- CA
- Canada
- Prior art keywords
- oil
- composition
- mixture
- soap
- fatty
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000344 soap Substances 0.000 title claims abstract description 67
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 63
- 239000000203 mixture Substances 0.000 claims abstract description 56
- 239000010685 fatty oil Substances 0.000 claims abstract description 23
- 238000007127 saponification reaction Methods 0.000 claims abstract description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 19
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 16
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims abstract description 11
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 claims abstract description 11
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims abstract description 10
- 239000004094 surface-active agent Substances 0.000 claims abstract description 7
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 4
- 239000003906 humectant Substances 0.000 claims abstract description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 3
- 239000001257 hydrogen Substances 0.000 claims abstract description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 49
- 238000000034 method Methods 0.000 claims description 24
- 239000003760 tallow Substances 0.000 claims description 23
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 21
- 235000019864 coconut oil Nutrition 0.000 claims description 19
- 239000003240 coconut oil Substances 0.000 claims description 19
- 239000004359 castor oil Substances 0.000 claims description 17
- 235000019438 castor oil Nutrition 0.000 claims description 17
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 17
- NSOXQYCFHDMMGV-UHFFFAOYSA-N Tetrakis(2-hydroxypropyl)ethylenediamine Chemical group CC(O)CN(CC(C)O)CCN(CC(C)O)CC(C)O NSOXQYCFHDMMGV-UHFFFAOYSA-N 0.000 claims description 13
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 13
- 235000021355 Stearic acid Nutrition 0.000 claims description 12
- 150000004985 diamines Chemical class 0.000 claims description 12
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 12
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 12
- 239000008117 stearic acid Substances 0.000 claims description 12
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 11
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 11
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 11
- 239000005642 Oleic acid Substances 0.000 claims description 11
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 11
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 11
- 239000000194 fatty acid Substances 0.000 claims description 11
- 229930195729 fatty acid Natural products 0.000 claims description 11
- 150000004665 fatty acids Chemical class 0.000 claims description 11
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 11
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 10
- 235000011187 glycerol Nutrition 0.000 claims description 10
- 229910052708 sodium Inorganic materials 0.000 claims description 10
- 239000011734 sodium Substances 0.000 claims description 10
- 229940012017 ethylenediamine Drugs 0.000 claims description 9
- 239000007787 solid Substances 0.000 claims description 7
- 239000002904 solvent Substances 0.000 claims description 7
- ONLRKTIYOMZEJM-UHFFFAOYSA-N n-methylmethanamine oxide Chemical compound C[NH+](C)[O-] ONLRKTIYOMZEJM-UHFFFAOYSA-N 0.000 claims description 4
- 239000002280 amphoteric surfactant Substances 0.000 claims description 3
- 125000000129 anionic group Chemical group 0.000 claims description 3
- 239000003945 anionic surfactant Substances 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 235000011121 sodium hydroxide Nutrition 0.000 abstract description 15
- 239000004615 ingredient Substances 0.000 abstract description 10
- 229960005150 glycerol Drugs 0.000 description 10
- 238000009472 formulation Methods 0.000 description 7
- 239000002304 perfume Substances 0.000 description 6
- -1 alcohol amine Chemical class 0.000 description 5
- 150000001412 amines Chemical class 0.000 description 5
- 235000013162 Cocos nucifera Nutrition 0.000 description 4
- 244000060011 Cocos nucifera Species 0.000 description 4
- 238000013019 agitation Methods 0.000 description 4
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 4
- 239000003205 fragrance Substances 0.000 description 4
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 3
- 230000032683 aging Effects 0.000 description 3
- 239000003963 antioxidant agent Substances 0.000 description 3
- 235000006708 antioxidants Nutrition 0.000 description 3
- 238000005187 foaming Methods 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- ZZNDQCACFUJAKJ-UHFFFAOYSA-N 1-phenyltridecan-1-one Chemical compound CCCCCCCCCCCCC(=O)C1=CC=CC=C1 ZZNDQCACFUJAKJ-UHFFFAOYSA-N 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000004166 Lanolin Substances 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 239000003518 caustics Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 239000003974 emollient agent Substances 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 229940039717 lanolin Drugs 0.000 description 2
- 235000019388 lanolin Nutrition 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 2
- BDDLHHRCDSJVKV-UHFFFAOYSA-N 7028-40-2 Chemical compound CC(O)=O.CC(O)=O.CC(O)=O.CC(O)=O BDDLHHRCDSJVKV-UHFFFAOYSA-N 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical class [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- NPPQSCRMBWNHMW-UHFFFAOYSA-N Meprobamate Chemical compound NC(=O)OCC(C)(CCC)COC(N)=O NPPQSCRMBWNHMW-UHFFFAOYSA-N 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 235000004443 Ricinus communis Nutrition 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000004872 foam stabilizing agent Substances 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000010297 mechanical methods and process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229940104261 taurate Drugs 0.000 description 1
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical compound NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 1
- 229930003799 tocopherol Natural products 0.000 description 1
- 239000011732 tocopherol Substances 0.000 description 1
- 235000019149 tocopherols Nutrition 0.000 description 1
- QUEDXNHFTDJVIY-UHFFFAOYSA-N γ-tocopherol Chemical class OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0095—Solid transparent soaps or detergents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/30—Organic compounds, e.g. vitamins containing nitrogen
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/211,557 US4290904A (en) | 1980-12-01 | 1980-12-01 | Transparent soap |
| US06/211,557 | 1980-12-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1158520A true CA1158520A (en) | 1983-12-13 |
Family
ID=22787421
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000379241A Expired CA1158520A (en) | 1980-12-01 | 1981-06-08 | Transparent soap |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US4290904A (enExample) |
| EP (1) | EP0053222B1 (enExample) |
| JP (1) | JPS5796099A (enExample) |
| CA (1) | CA1158520A (enExample) |
| DE (1) | DE3163977D1 (enExample) |
Families Citing this family (47)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4490280A (en) * | 1982-09-02 | 1984-12-25 | Colgate-Palmolive Company | Process for manufacturing translucent antibacterial soap |
| US4493786A (en) * | 1982-09-02 | 1985-01-15 | Colgate-Palmolive Company | Translucent soaps and processes for manufacture thereof |
| US4891160A (en) * | 1982-12-23 | 1990-01-02 | The Proctor & Gamble Company | Detergent compositions containing ethoxylated amines having clay soil removal/anti-redeposition properties |
| US4468338A (en) * | 1983-06-13 | 1984-08-28 | Purex Corporation | Transparent soap composition |
| GB8518910D0 (en) * | 1985-07-26 | 1985-09-04 | Procter & Gamble Ltd | Toilet compositions |
| NL8601701A (nl) * | 1986-06-30 | 1988-01-18 | Unilever Nv | Transparante zeep. |
| US4778825A (en) * | 1986-08-29 | 1988-10-18 | The University Of Akron | Macrophage stimulation by quadrol |
| CA1329350C (en) * | 1986-11-04 | 1994-05-10 | Michael Irwin Hill | Transparent soap bar |
| US4749507A (en) * | 1987-02-12 | 1988-06-07 | Clairol, Incorporated | Process for removing hair dyes from hair and skin, and product for carrying out the process |
| US4851147A (en) * | 1987-02-26 | 1989-07-25 | Finetex, Inc. | Transparent combination soap-synthetic detergent bar |
| US4839080A (en) * | 1987-04-30 | 1989-06-13 | Neutrogena Corporation | Antibacterial iodophor soap base composition and method of making same |
| JPH07122078B2 (ja) * | 1988-02-27 | 1995-12-25 | クローダジャパン株式会社 | 透明固型洗浄剤 |
| LU87179A1 (fr) * | 1988-03-24 | 1989-10-26 | Oreal | Composition de savon transparent a base de savons d'acides gras de suif et d'eau et d'au moins un alcanediol-1,2 |
| ES2034203T3 (es) * | 1988-03-31 | 1993-04-01 | Unilever Nv | Barra de jabon transparente. |
| WO1990003964A1 (en) * | 1988-10-14 | 1990-04-19 | University Of Akron | Microphage stimulation by homolog or analog of quadrol |
| AU626273B2 (en) * | 1988-10-14 | 1992-07-30 | University Of Akron | Macrophage stimulation by homolog or analog of quadrol |
| GB8904938D0 (en) * | 1989-03-03 | 1989-04-12 | Unilever Plc | Detergent bar |
| US5082600A (en) * | 1989-04-26 | 1992-01-21 | Ethyl Corporation | Transparent soap bar process using trialkylamine oxide dihydrate |
| US5055233A (en) * | 1989-04-26 | 1991-10-08 | Ethyl Corporation | Detergent bar process using trialkylamine oxide dihydrate |
| EP0521980A4 (en) * | 1990-03-27 | 1993-08-25 | Richardson-Vicks, Inc. | Novel surfactants and surfactant compositions |
| EP0449503A3 (en) * | 1990-03-27 | 1991-12-18 | Richardson-Vicks, Inc. | Surfactant compositions |
| US5116543A (en) * | 1990-05-29 | 1992-05-26 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Whole body cleaning agent containing n-acyltaurate |
| US5114717A (en) * | 1991-02-08 | 1992-05-19 | Chesebrough-Pond's Usa Co., Division Of Conopco, Inc. | Clear cosmetic sticks with compatible fragrance components |
| US5198218A (en) * | 1991-02-08 | 1993-03-30 | Chesebrough-Pond's Usa Co., Division Of Conopco, Inc. | Clear cosmetic sticks with compatible fragrance components |
| US5128123A (en) * | 1991-02-08 | 1992-07-07 | Chesebrough-Pond's Usa Co., Division Of Conopco, Inc. | Clear cosmetic sticks |
| US5186856A (en) * | 1992-06-02 | 1993-02-16 | Basf Corp. | Aqueous prewash stain remover compositions with efficacy on tenacious oily stains |
| US5221496A (en) * | 1992-06-02 | 1993-06-22 | Basf Corp. | Aqueous prewash stain remover compositions with efficacy on tenacious oily stains |
| BR9407135A (pt) * | 1993-07-23 | 1996-09-17 | Unichema Chemie Bv | Processo para produzir material de sabão transparente e barras macarrões ou pelotas de sabão transparentes |
| US5417876A (en) * | 1993-10-25 | 1995-05-23 | Avon Products Inc. | Transparent soap formulations and methods of making same |
| MA23637A1 (fr) * | 1994-08-03 | 1996-04-01 | Procter & Gamble | Procede exempt de monoalcool pour la production d'un pain nettoyant corporel transparent, moule par coulage |
| US5703025A (en) * | 1994-08-03 | 1997-12-30 | The Procter & Gamble Company | Monohydric alcohol-free process for making a transparent pour molded personal cleansing bar |
| US5728663A (en) * | 1996-07-02 | 1998-03-17 | Johnson & Johnson Consumer Products, Inc. | Clear, colorless soap bar with superior mildness, lathering and discolorization resistence |
| US6395692B1 (en) | 1996-10-04 | 2002-05-28 | The Dial Corporation | Mild cleansing bar compositions |
| JP3947606B2 (ja) * | 1997-10-27 | 2007-07-25 | 株式会社Ａｄｅｋａ | 脂肪酸石鹸及び洗浄剤組成物 |
| CN1179031C (zh) * | 1999-01-11 | 2004-12-08 | 荷兰联合利华有限公司 | 改良的条形洗涤剂组合物 |
| US6297205B1 (en) | 1999-08-30 | 2001-10-02 | Amway Corporation | Monohydric alcohol-free transparent moisturizing bar soap |
| JP2002060795A (ja) * | 2000-08-24 | 2002-02-26 | Kawaken Fine Chem Co Ltd | 透明固形石鹸組成物 |
| JP2002060794A (ja) * | 2000-08-24 | 2002-02-26 | Kawaken Fine Chem Co Ltd | 透明固形石鹸組成物 |
| US6838420B2 (en) | 2002-02-28 | 2005-01-04 | Colgate-Palmolive Company | Soap composition |
| US20050000046A1 (en) * | 2003-07-03 | 2005-01-06 | Michael Popovsky | Cleansing pad |
| GB0403411D0 (en) * | 2003-11-25 | 2004-03-24 | Unilever Plc | Process to prepare a shaped solid detergent |
| JP3699719B1 (ja) * | 2004-03-30 | 2005-09-28 | 株式会社ピーアンドピーエフ | 固型石鹸組成物 |
| US20060047005A1 (en) * | 2004-08-26 | 2006-03-02 | Salamone Joseph C | Compositions containing N,N,N',N'-tetrakis(hydroxyalkyl)diamine-or N,N,N',N'-tetrakis(hydroxyalkoxy)diamine-based buffers |
| US7728044B2 (en) * | 2005-03-16 | 2010-06-01 | Baker Hughes Incorporated | Saponified fatty acids as breakers for viscoelastic surfactant-gelled fluids |
| CN103301051B (zh) * | 2012-03-07 | 2015-01-21 | 南京华狮化工有限公司 | 一种透明美容皂组合物 |
| CN104568553B (zh) * | 2014-12-30 | 2018-01-05 | 深圳先进技术研究院 | 一种组织光透明剂及其应用 |
| CN105018253A (zh) * | 2015-07-02 | 2015-11-04 | 上海制皂(集团)如皋有限公司 | 防止洗衣皂开裂的透明皂粒的生产配方 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2697113A (en) * | 1951-01-26 | 1954-12-14 | Albert J Kramer | Method of removing protein from fatty tissue |
| BE511361A (enExample) * | 1952-05-13 | |||
| US2835604A (en) * | 1953-09-28 | 1958-05-20 | Aronberg Lester | Dye stick and process of making it |
| US2774735A (en) * | 1955-03-22 | 1956-12-18 | Colgate Palmolive Co | Detergent bars |
| US2970116A (en) * | 1957-07-16 | 1961-01-31 | Lever Brothers Ltd | Soapmaking process |
| NL264272A (enExample) * | 1960-01-26 | 1900-01-01 | ||
| CA796279A (en) * | 1966-02-08 | 1968-10-08 | The Procter & Gamble Company | Soap compositions |
| US3562167A (en) * | 1966-10-28 | 1971-02-09 | Revlon | Solid transparent detergent compositions and method of making the same |
| US3793214A (en) * | 1971-10-22 | 1974-02-19 | Avon Prod Inc | Transparent soap composition |
| US3903008A (en) * | 1972-05-01 | 1975-09-02 | Lanvin Charles Of The Ritz Inc | Cleansing bar |
| US3864272A (en) * | 1973-01-12 | 1975-02-04 | Armour Dial Inc | Process for making translucent soap bars |
| US3969259A (en) * | 1974-03-18 | 1976-07-13 | Lever Brothers Company | Transparent soap bar |
| NL7700444A (nl) * | 1976-02-06 | 1977-08-09 | Henkel & Cie Gmbh | Wasmiddelen met een gehalte aan hydroxyalkyl- aminen. |
| US4165293A (en) * | 1977-05-16 | 1979-08-21 | Amway Corporation | Solid transparent cleanser |
-
1980
- 1980-12-01 US US06/211,557 patent/US4290904A/en not_active Expired - Lifetime
-
1981
- 1981-06-08 CA CA000379241A patent/CA1158520A/en not_active Expired
- 1981-06-26 JP JP56098432A patent/JPS5796099A/ja active Granted
- 1981-07-14 DE DE8181105518T patent/DE3163977D1/de not_active Expired
- 1981-07-14 EP EP81105518A patent/EP0053222B1/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5796099A (en) | 1982-06-15 |
| US4290904A (en) | 1981-09-22 |
| DE3163977D1 (en) | 1984-07-12 |
| EP0053222B1 (en) | 1984-06-06 |
| EP0053222A1 (en) | 1982-06-09 |
| JPH0214960B2 (enExample) | 1990-04-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |