CA1111494A - Molded metal oxide electrodes containing an ethylene acrylic acid additive - Google Patents
Molded metal oxide electrodes containing an ethylene acrylic acid additiveInfo
- Publication number
- CA1111494A CA1111494A CA322,242A CA322242A CA1111494A CA 1111494 A CA1111494 A CA 1111494A CA 322242 A CA322242 A CA 322242A CA 1111494 A CA1111494 A CA 1111494A
- Authority
- CA
- Canada
- Prior art keywords
- metal oxide
- silver oxide
- electrode
- acrylic acid
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920006226 ethylene-acrylic acid Polymers 0.000 title claims abstract description 46
- 229910044991 metal oxide Inorganic materials 0.000 title claims abstract description 45
- 150000004706 metal oxides Chemical class 0.000 title claims abstract description 44
- QHZOMAXECYYXGP-UHFFFAOYSA-N ethene;prop-2-enoic acid Chemical compound C=C.OC(=O)C=C QHZOMAXECYYXGP-UHFFFAOYSA-N 0.000 title claims abstract description 30
- 239000000654 additive Substances 0.000 title abstract description 9
- 230000000996 additive effect Effects 0.000 title abstract description 8
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 claims abstract description 192
- 229910001923 silver oxide Inorganic materials 0.000 claims abstract description 101
- 229920000642 polymer Polymers 0.000 claims abstract description 33
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 9
- 239000011701 zinc Substances 0.000 claims abstract description 9
- 238000004519 manufacturing process Methods 0.000 claims abstract description 5
- 239000003792 electrolyte Substances 0.000 claims description 22
- 239000000843 powder Substances 0.000 claims description 19
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 17
- 239000000470 constituent Substances 0.000 claims description 13
- UQLDLKMNUJERMK-UHFFFAOYSA-L di(octadecanoyloxy)lead Chemical compound [Pb+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O UQLDLKMNUJERMK-UHFFFAOYSA-L 0.000 claims description 10
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- CXKCTMHTOKXKQT-UHFFFAOYSA-N cadmium oxide Inorganic materials [Cd]=O CXKCTMHTOKXKQT-UHFFFAOYSA-N 0.000 claims description 3
- CFEAAQFZALKQPA-UHFFFAOYSA-N cadmium(2+);oxygen(2-) Chemical compound [O-2].[Cd+2] CFEAAQFZALKQPA-UHFFFAOYSA-N 0.000 claims description 3
- 229910000474 mercury oxide Inorganic materials 0.000 claims description 3
- UKWHYYKOEPRTIC-UHFFFAOYSA-N mercury(ii) oxide Chemical compound [Hg]=O UKWHYYKOEPRTIC-UHFFFAOYSA-N 0.000 claims description 3
- 229910000480 nickel oxide Inorganic materials 0.000 claims description 3
- BFDHFSHZJLFAMC-UHFFFAOYSA-L nickel(ii) hydroxide Chemical compound [OH-].[OH-].[Ni+2] BFDHFSHZJLFAMC-UHFFFAOYSA-L 0.000 claims description 3
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 claims description 3
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 2
- 239000008116 calcium stearate Substances 0.000 claims description 2
- 235000013539 calcium stearate Nutrition 0.000 claims description 2
- RKISUIUJZGSLEV-UHFFFAOYSA-N n-[2-(octadecanoylamino)ethyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCNC(=O)CCCCCCCCCCCCCCCCC RKISUIUJZGSLEV-UHFFFAOYSA-N 0.000 claims description 2
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 claims 4
- 239000008188 pellet Substances 0.000 description 32
- 239000000314 lubricant Substances 0.000 description 16
- 229910000108 silver(I,III) oxide Inorganic materials 0.000 description 11
- OTCVAHKKMMUFAY-UHFFFAOYSA-N oxosilver Chemical compound [Ag]=O OTCVAHKKMMUFAY-UHFFFAOYSA-N 0.000 description 10
- 238000010521 absorption reaction Methods 0.000 description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
- 229910002804 graphite Inorganic materials 0.000 description 7
- 239000010439 graphite Substances 0.000 description 7
- 238000000465 moulding Methods 0.000 description 7
- 239000006182 cathode active material Substances 0.000 description 6
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 5
- 230000006870 function Effects 0.000 description 5
- 229910052709 silver Inorganic materials 0.000 description 5
- 239000004332 silver Substances 0.000 description 5
- 238000003860 storage Methods 0.000 description 5
- 238000005259 measurement Methods 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000005977 Ethylene Substances 0.000 description 3
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- -1 silver oxide Chemical class 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 229940114077 acrylic acid Drugs 0.000 description 2
- 239000011149 active material Substances 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000001627 detrimental effect Effects 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- CPRMKOQKXYSDML-UHFFFAOYSA-M rubidium hydroxide Chemical compound [OH-].[Rb+] CPRMKOQKXYSDML-UHFFFAOYSA-M 0.000 description 2
- MFGOFGRYDNHJTA-UHFFFAOYSA-N 2-amino-1-(2-fluorophenyl)ethanol Chemical compound NCC(O)C1=CC=CC=C1F MFGOFGRYDNHJTA-UHFFFAOYSA-N 0.000 description 1
- 208000023514 Barrett esophagus Diseases 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- HUCVOHYBFXVBRW-UHFFFAOYSA-M caesium hydroxide Inorganic materials [OH-].[Cs+] HUCVOHYBFXVBRW-UHFFFAOYSA-M 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000002788 crimping Methods 0.000 description 1
- 229920003020 cross-linked polyethylene Polymers 0.000 description 1
- 239000004703 cross-linked polyethylene Substances 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000011255 nonaqueous electrolyte Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- UUCCCPNEFXQJEL-UHFFFAOYSA-L strontium dihydroxide Chemical compound [OH-].[OH-].[Sr+2] UUCCCPNEFXQJEL-UHFFFAOYSA-L 0.000 description 1
- 229910001866 strontium hydroxide Inorganic materials 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/621—Binders
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/06—Electrodes for primary cells
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Primary Cells (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US890,972 | 1978-03-28 | ||
| US05/890,972 US4146685A (en) | 1978-03-28 | 1978-03-28 | Molded metal oxide electrodes containing an ethylene acrylic acid additive |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1111494A true CA1111494A (en) | 1981-10-27 |
Family
ID=25397404
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA322,242A Expired CA1111494A (en) | 1978-03-28 | 1979-02-22 | Molded metal oxide electrodes containing an ethylene acrylic acid additive |
Country Status (16)
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1128121A (en) * | 1978-03-30 | 1982-07-20 | Union Carbide Corporation | Cadium compound additive for cells using divalent silver oxide |
| US4167609A (en) * | 1978-03-30 | 1979-09-11 | Union Carbide Corporation | Zinc oxide additive for divalent silver oxide electrodes |
| FR2440086A1 (fr) * | 1978-10-27 | 1980-05-23 | Comp Generale Electricite | Electrode pour accumulateur au plomb |
| US4228228A (en) * | 1979-10-04 | 1980-10-14 | Bell Telephone Laboratories, Incorporated | Electrode structure for energy cells |
| US4391729A (en) * | 1979-12-17 | 1983-07-05 | Wilson Greatbatch Ltd. | Metal oxide composite cathode material for high energy density batteries |
| EP0563394B1 (en) * | 1991-10-09 | 1998-08-05 | Yuasa Corporation | Use of a macromolecular compound for making a depolarizing mixture |
| US5981105A (en) * | 1996-07-08 | 1999-11-09 | Emf Systems, Inc. | High rate metal oxide electrodes |
| US6165641A (en) * | 1997-05-09 | 2000-12-26 | The United States Of America As Represented By The United States Department Of Energy | Nanodisperse transition metal electrodes (NTME) for electrochemical cells |
| EP1341248A1 (en) * | 2000-11-17 | 2003-09-03 | Toshiba Battery Co., Ltd. | Enclosed nickel-zinc primary battery, its anode and production methods for them |
| NZ510554A (en) * | 2001-03-15 | 2003-08-29 | Univ Massey | Rechargeable zinc electrode comprising a zinc salt and a derivative of a fatty acid or alkyl sulfonic acid |
| US20030129410A1 (en) * | 2001-12-27 | 2003-07-10 | General Electric Company | Ultraviolet protective dual layer laminate for polycarbonate resin substrates and method of manufacture thereof |
| US7846575B2 (en) * | 2004-07-30 | 2010-12-07 | Medtronic, Inc. | Anode cup and methods of fabrication for medical grade electrochemical cells |
| CN101111957B (zh) * | 2005-02-10 | 2010-05-12 | 日立化成工业株式会社 | 能源装置电极用粘合剂树脂乳液、使用其的能源装置电极和能源装置 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1047395A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | ||||
| US2811572A (en) * | 1955-04-01 | 1957-10-29 | Fischbach Adolph | Method for making silver peroxide electrodes |
| US2902530A (en) * | 1955-10-12 | 1959-09-01 | Bjorksten Res Lab Inc | Battery constituents |
| DE1790849U (de) * | 1958-09-24 | 1959-06-25 | Accumulatoren Fabrik Ag | Positive elektrode fuer galvanische primaerelemente. |
| FR1314538A (fr) * | 1961-11-30 | 1963-01-11 | Gadot Soc D Accumulateurs Ets | Procédé de préparation d'électrodes pour éléments primaires ou réversibles, notamment éléments à l'argent |
| US3184339A (en) * | 1962-04-10 | 1965-05-18 | Grenville B Ellis | Battery electrode |
| US3120457A (en) * | 1962-11-23 | 1964-02-04 | Electric Storage Battery Co | Method of manufacturing fuel cell and/or battery electrode |
| DE1771522A1 (de) * | 1968-06-04 | 1972-03-09 | Varta Ag | Silberoxidelektrode fuer alkalische Primaerelemente und Verfahren zu ihrer Herstellung |
| US3706601A (en) * | 1970-01-28 | 1972-12-19 | Mc Donnell Douglas Corp | Method of producing an electrode with a polymer binder by rolling |
| US3918989A (en) * | 1971-01-18 | 1975-11-11 | Gates Rubber Co | Flexible electrode plate |
| US3954506A (en) * | 1971-11-16 | 1976-05-04 | Polaroid Corporation | Zinc anode and composition and method for producing same |
| JPS5234734B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1972-10-28 | 1977-09-05 | ||
| US3898099A (en) * | 1974-03-18 | 1975-08-05 | Energy Res Corp | Hydrophilic electrode and method for making the same |
| JPS52125724A (en) * | 1976-04-13 | 1977-10-21 | Hitachi Maxell | Alkaline battery |
| JPS5931185B2 (ja) * | 1976-04-13 | 1984-07-31 | 日立マクセル株式会社 | アルカリ２次電池 |
| US4056664A (en) * | 1977-01-28 | 1977-11-01 | P. R. Mallory & Co. Inc. | Electrochemical cell having an AgO electrode discharging at an Ag2 O voltage level |
-
1978
- 1978-03-28 US US05/890,972 patent/US4146685A/en not_active Expired - Lifetime
-
1979
- 1979-02-22 CA CA322,242A patent/CA1111494A/en not_active Expired
- 1979-03-21 DE DE2911013A patent/DE2911013C2/de not_active Expired
- 1979-03-27 IT IT21349/79A patent/IT1113048B/it active
- 1979-03-27 SE SE7902720A patent/SE445277B/sv not_active IP Right Cessation
- 1979-03-27 JP JP3618179A patent/JPS54164224A/ja active Granted
- 1979-03-27 DK DK124679A patent/DK124679A/da not_active IP Right Cessation
- 1979-03-27 NL NL7902382A patent/NL7902382A/xx not_active Application Discontinuation
- 1979-03-27 GB GB7910714A patent/GB2020477B/en not_active Expired
- 1979-03-27 AU AU45427/79A patent/AU528526B2/en not_active Ceased
- 1979-03-27 AT AT0227679A patent/AT369928B/de not_active IP Right Cessation
- 1979-03-27 CH CH283679A patent/CH629625A5/fr not_active IP Right Cessation
- 1979-03-27 FR FR7907682A patent/FR2421469A1/fr active Granted
- 1979-03-27 MX MX177079A patent/MX151479A/es unknown
- 1979-03-27 BE BE0/194244A patent/BE875128A/xx not_active IP Right Cessation
-
1986
- 1986-11-20 HK HK882/86A patent/HK88286A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US4146685A (en) | 1979-03-27 |
| JPS54164224A (en) | 1979-12-27 |
| SE7902720L (sv) | 1979-09-29 |
| IT1113048B (it) | 1986-01-20 |
| ATA227679A (de) | 1982-06-15 |
| AU528526B2 (en) | 1983-05-05 |
| NL7902382A (nl) | 1979-10-02 |
| DK124679A (da) | 1979-09-29 |
| CH629625A5 (fr) | 1982-04-30 |
| AT369928B (de) | 1983-02-10 |
| BE875128A (fr) | 1979-09-27 |
| FR2421469B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1984-10-12 |
| GB2020477B (en) | 1982-08-04 |
| HK88286A (en) | 1986-11-28 |
| JPS6241381B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1987-09-02 |
| AU4542779A (en) | 1979-10-04 |
| SE445277B (sv) | 1986-06-09 |
| IT7921349A0 (it) | 1979-03-27 |
| DE2911013A1 (de) | 1979-10-11 |
| DE2911013C2 (de) | 1982-06-03 |
| FR2421469A1 (fr) | 1979-10-26 |
| MX151479A (es) | 1984-12-03 |
| GB2020477A (en) | 1979-11-14 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |