CA1084239A - Purification of wet-processed phosphoric acid - Google Patents
Purification of wet-processed phosphoric acidInfo
- Publication number
- CA1084239A CA1084239A CA293,248A CA293248A CA1084239A CA 1084239 A CA1084239 A CA 1084239A CA 293248 A CA293248 A CA 293248A CA 1084239 A CA1084239 A CA 1084239A
- Authority
- CA
- Canada
- Prior art keywords
- phosphoric acid
- solvent
- acid
- wet
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 title claims abstract description 112
- 229910000147 aluminium phosphate Inorganic materials 0.000 title claims abstract description 56
- 238000000746 purification Methods 0.000 title abstract 2
- 239000002253 acid Substances 0.000 claims abstract description 42
- 239000002904 solvent Substances 0.000 claims abstract description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 238000000605 extraction Methods 0.000 claims abstract description 22
- 239000000284 extract Substances 0.000 claims abstract description 16
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 15
- 239000011707 mineral Substances 0.000 claims abstract description 15
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 8
- 239000010452 phosphate Substances 0.000 claims abstract description 8
- 239000003960 organic solvent Substances 0.000 claims abstract description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 4
- 150000001768 cations Chemical class 0.000 claims abstract description 3
- 238000000034 method Methods 0.000 claims description 27
- 230000008569 process Effects 0.000 claims description 26
- 238000005201 scrubbing Methods 0.000 claims description 15
- 235000010755 mineral Nutrition 0.000 claims description 14
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 8
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 239000007787 solid Substances 0.000 claims description 8
- 239000000243 solution Substances 0.000 claims description 8
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 claims description 7
- 238000011084 recovery Methods 0.000 claims description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000000292 calcium oxide Substances 0.000 claims description 4
- 235000012255 calcium oxide Nutrition 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 3
- 230000007935 neutral effect Effects 0.000 claims description 3
- 239000003513 alkali Substances 0.000 claims description 2
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims description 2
- 229910000318 alkali metal phosphate Inorganic materials 0.000 claims description 2
- 230000003247 decreasing effect Effects 0.000 claims description 2
- 229920006395 saturated elastomer Polymers 0.000 claims description 2
- 238000000926 separation method Methods 0.000 claims description 2
- 239000002699 waste material Substances 0.000 claims description 2
- 239000008346 aqueous phase Substances 0.000 claims 1
- 229960004756 ethanol Drugs 0.000 claims 1
- 229960004838 phosphoric acid Drugs 0.000 abstract description 35
- 235000011007 phosphoric acid Nutrition 0.000 abstract description 35
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000000356 contaminant Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 3
- 230000009102 absorption Effects 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000000287 crude extract Substances 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- LEHOTFFKMJEONL-UHFFFAOYSA-N Uric Acid Chemical compound N1C(=O)NC(=O)C2=C1NC(=O)N2 LEHOTFFKMJEONL-UHFFFAOYSA-N 0.000 description 1
- TVWHNULVHGKJHS-UHFFFAOYSA-N Uric acid Natural products N1C(=O)NC(=O)C2NC(=O)NC21 TVWHNULVHGKJHS-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000000975 co-precipitation Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000002844 continuous effect Effects 0.000 description 1
- MCWXGJITAZMZEV-UHFFFAOYSA-N dimethoate Chemical compound CNC(=O)CSP(=S)(OC)OC MCWXGJITAZMZEV-UHFFFAOYSA-N 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229940116269 uric acid Drugs 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/46—Preparation involving solvent-solvent extraction
- C01B25/461—Preparation involving solvent-solvent extraction the phosphoric acid present in the medium obtained after reaction being first extracted from the liquid phase formed or separated then re-extracted as free acid by using water or as a phosphate by using a basic compound
- C01B25/462—Preparation involving solvent-solvent extraction the phosphoric acid present in the medium obtained after reaction being first extracted from the liquid phase formed or separated then re-extracted as free acid by using water or as a phosphate by using a basic compound the extracting agent being alcohol or a mixture of alcohols
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/18—Phosphoric acid
- C01B25/234—Purification; Stabilisation; Concentration
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/46—Preparation involving solvent-solvent extraction
- C01B25/461—Preparation involving solvent-solvent extraction the phosphoric acid present in the medium obtained after reaction being first extracted from the liquid phase formed or separated then re-extracted as free acid by using water or as a phosphate by using a basic compound
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Extraction Or Liquid Replacement (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEP2657189.1 | 1976-12-17 | ||
| DE2657189A DE2657189B2 (de) | 1976-12-17 | 1976-12-17 | Verfahren zur Reinigung von NaBverfahrensphosphorsäure |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1084239A true CA1084239A (en) | 1980-08-26 |
Family
ID=5995769
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA293,248A Expired CA1084239A (en) | 1976-12-17 | 1977-12-16 | Purification of wet-processed phosphoric acid |
Country Status (22)
| Country | Link |
|---|---|
| US (1) | US4222994A (enExample) |
| JP (1) | JPS5376996A (enExample) |
| AT (1) | AT378760B (enExample) |
| BE (1) | BE861919A (enExample) |
| BR (1) | BR7708378A (enExample) |
| CA (1) | CA1084239A (enExample) |
| CH (1) | CH631681A5 (enExample) |
| DD (1) | DD134635A5 (enExample) |
| DE (1) | DE2657189B2 (enExample) |
| DK (1) | DK147680C (enExample) |
| EG (1) | EG12812A (enExample) |
| ES (1) | ES463636A1 (enExample) |
| FI (1) | FI65609C (enExample) |
| FR (1) | FR2374262A1 (enExample) |
| GB (1) | GB1553319A (enExample) |
| IL (1) | IL53619A0 (enExample) |
| IT (1) | IT1092168B (enExample) |
| MX (1) | MX146677A (enExample) |
| NL (1) | NL184944C (enExample) |
| PH (1) | PH13877A (enExample) |
| SE (1) | SE429543B (enExample) |
| ZA (1) | ZA777231B (enExample) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2909572A1 (de) * | 1979-03-12 | 1980-09-25 | Hoechst Ag | Verfahren zur ueberfuehrung von extraktionsrueckstaenden aus der phosphorsaeurereinigung in feste deponieprodukte |
| DE2926943A1 (de) | 1979-07-04 | 1981-01-29 | Hoechst Ag | Verfahren zur reinigung von nassverfahrensphosphorsaeure |
| DE2945874A1 (de) * | 1979-11-14 | 1981-05-27 | Hoechst Ag, 6000 Frankfurt | Verfahren zur reinigung von nassverfahrenphosphorsaeure |
| US4311681A (en) * | 1980-05-19 | 1982-01-19 | Fmc Corporation | Method of regenerating phosphoric acid extraction solvent |
| JPS5933527B2 (ja) * | 1980-11-29 | 1984-08-16 | 東ソー株式会社 | リン酸の溶媒抽出法 |
| DE3135801A1 (de) * | 1981-09-10 | 1983-03-24 | Hoechst Ag, 6000 Frankfurt | Verfahren zur nachbehandlung von extraktionsrueckstaenden der phosphorsaeurereinigung |
| JPS58217413A (ja) * | 1982-05-12 | 1983-12-17 | Toyo Soda Mfg Co Ltd | リン酸の精製法 |
| DE19703884C2 (de) * | 1997-02-03 | 1999-04-29 | Bk Giulini Chem Gmbh & Co Ohg | Verfahren zur Reinigung von Naßverfahrensphosphorsäure |
| DE102016212242B4 (de) | 2016-07-05 | 2019-02-07 | Technische Universität Bergakademie Freiberg | Verfahren zur Herstellung von Phosphorsäure aus phosphorhaltigen Primär- und Sekundärrohstoffen |
| CN117547861B (zh) * | 2023-12-27 | 2024-04-02 | 昆明红海磷肥有限责任公司 | 一种萃余磷酸和含渣磷酸提纯分离装置及其方法 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2880063A (en) * | 1956-06-25 | 1959-03-31 | Makhtsavei Israel | Process for the preparation of phosphoric acid |
| FI43731B (enExample) * | 1965-02-04 | 1971-03-01 | Typpi Oy | |
| FR2093372A5 (en) * | 1970-06-12 | 1972-01-28 | Azote & Prod Chim | Purification of wet-process phosphoric acid - by extraction - with part water-misc organic solvent |
| US3956465A (en) * | 1970-06-12 | 1976-05-11 | Azote Et Produits Chimiques S.A. | Solvent purification of wet process phosphoric acid |
| SE366972B (enExample) * | 1970-06-12 | 1974-05-13 | Azote & Prod Chim | |
| FR2128968A6 (en) * | 1971-03-10 | 1972-10-27 | Azote & Prod Chim | Purification of wet-process phosphoric acid - by extraction - with part water-misc organic solvent |
| US3684439A (en) * | 1970-09-22 | 1972-08-15 | Monsanto Co | Handling of raffinates from wet phosphoric acid purification |
| DE2321751C3 (de) * | 1973-04-30 | 1981-11-19 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Reinigung von Naßphosphorsäure |
| FR2259787B1 (enExample) * | 1974-02-01 | 1977-09-16 | Rhone Poulenc Ind | |
| DE2605106C2 (de) * | 1976-02-10 | 1984-06-14 | Hoechst Ag, 6230 Frankfurt | Verfahren und Vorrichtung zur Herstellung von alkoholischen Phosphorsäurelösungen aus sauren Phosphaten |
-
1976
- 1976-12-17 DE DE2657189A patent/DE2657189B2/de not_active Ceased
-
1977
- 1977-09-06 CH CH1089077A patent/CH631681A5/de not_active IP Right Cessation
- 1977-10-28 ES ES463636A patent/ES463636A1/es not_active Expired
- 1977-12-05 ZA ZA00777231A patent/ZA777231B/xx unknown
- 1977-12-08 NL NLAANVRAGE7713607,A patent/NL184944C/xx not_active IP Right Cessation
- 1977-12-09 GB GB51347/77A patent/GB1553319A/en not_active Expired
- 1977-12-12 US US05/859,681 patent/US4222994A/en not_active Expired - Lifetime
- 1977-12-14 IT IT52201/77A patent/IT1092168B/it active
- 1977-12-14 EG EG691/77A patent/EG12812A/xx active
- 1977-12-14 PH PH20553A patent/PH13877A/en unknown
- 1977-12-15 DD DD77202672A patent/DD134635A5/xx unknown
- 1977-12-15 SE SE7714258A patent/SE429543B/sv not_active IP Right Cessation
- 1977-12-15 FI FI773802A patent/FI65609C/fi not_active IP Right Cessation
- 1977-12-15 IL IL53619A patent/IL53619A0/xx not_active IP Right Cessation
- 1977-12-15 MX MX171731A patent/MX146677A/es unknown
- 1977-12-15 AT AT0898177A patent/AT378760B/de not_active IP Right Cessation
- 1977-12-16 BE BE183508A patent/BE861919A/xx not_active IP Right Cessation
- 1977-12-16 BR BR7708378A patent/BR7708378A/pt unknown
- 1977-12-16 DK DK562777A patent/DK147680C/da active
- 1977-12-16 CA CA293,248A patent/CA1084239A/en not_active Expired
- 1977-12-16 JP JP15231577A patent/JPS5376996A/ja active Pending
- 1977-12-16 FR FR7738056A patent/FR2374262A1/fr active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| FI773802A7 (fi) | 1978-06-18 |
| CH631681A5 (de) | 1982-08-31 |
| FI65609C (fi) | 1984-06-11 |
| MX146677A (es) | 1982-07-27 |
| IL53619A0 (en) | 1978-03-10 |
| DE2657189A1 (de) | 1978-06-22 |
| IT1092168B (it) | 1985-07-06 |
| NL184944B (nl) | 1989-07-17 |
| ES463636A1 (es) | 1978-07-16 |
| BE861919A (fr) | 1978-06-16 |
| FR2374262A1 (fr) | 1978-07-13 |
| AT378760B (de) | 1985-09-25 |
| NL7713607A (nl) | 1978-06-20 |
| JPS5376996A (en) | 1978-07-07 |
| DD134635A5 (de) | 1979-03-14 |
| ZA777231B (en) | 1978-11-29 |
| ATA898177A (de) | 1985-02-15 |
| GB1553319A (en) | 1979-09-26 |
| SE7714258L (sv) | 1978-06-18 |
| EG12812A (en) | 1981-03-31 |
| DK147680C (da) | 1985-05-13 |
| SE429543B (sv) | 1983-09-12 |
| NL184944C (nl) | 1989-12-18 |
| DK562777A (da) | 1978-06-18 |
| DE2657189B2 (de) | 1980-02-07 |
| FR2374262B1 (enExample) | 1982-10-08 |
| FI65609B (fi) | 1984-02-29 |
| US4222994A (en) | 1980-09-16 |
| PH13877A (en) | 1980-10-24 |
| DK147680B (da) | 1984-11-12 |
| BR7708378A (pt) | 1978-08-08 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |